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Pyrolysis kinetics of recycled polyesters

Jaber Al-Juaidiyah (Department of Chemical Engineering Department, Kuwait University, Safat, Kuwait.)

International Journal of Clothing Science and Technology

ISSN: 0955-6222

Article publication date: 3 August 2015

274

Abstract

Purpose

The purpose of this paper is to study the non-isothermal degradation kinetics of recycled polybutylene terephthalate, polytrimethylene terephthalate and polyethylene terephthalate using thermogravimetric analysis (TGA) in a nitrogen atmosphere.

Design/methodology/approach

To achieve this goal, the author utilized standard kinetic models, such as Coats-Redfern and Kissinger equations, for analysis of the TGA data.

Findings

When applied to the TGA data, the Kissinger model resulted in a coefficient of determination (R2) value greater than 0.99.

Originality/value

This study describes the maiden application of the Kissinger model to obtain the pre-exponential factor (A) and activation energy (E) for different polyester systems used in the textile industry.

Keywords

Acknowledgements

The author would like to thank the research department at Kuwait University for funding this study through the project EC04/09.

Citation

Al-Juaidiyah, J. (2015), "Pyrolysis kinetics of recycled polyesters", International Journal of Clothing Science and Technology, Vol. 27 No. 4, pp. 523-531. https://doi.org/10.1108/IJCST-04-2014-0048

Publisher

:

Emerald Group Publishing Limited

Copyright © 2015, Emerald Group Publishing Limited

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