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This study aims to identify the bioactive compounds in the Onion (Allium burdickii [A.B]) bulb using Raman and Fourier transform infrared spectroscopy (FTIR) spectroscopy. It assessed the extraction conditions of bioactive compounds from A.B. while evaluating the best extraction conditions.

The research opted for an experimental qualitative approach. It examined the extraction conditions of A.B., namely, temperature (°C), time (min) and mass-to-liquor ratio (M:R) using ultraviolet-visible spectrophotometry. Identification of bioactive compounds present in the dye was performed using Raman spectroscopy and the validation of the results was done by FTIR spectroscopy.

The study determined the best extraction conditions (time, temperature, M:R) for A.B bulb. The study confirmed the presence of bioactive compounds.

The limitation was quantification of bioactive compounds in A.B bulb.

The findings prove that the A.B. bulb can provide a sustainable source of bioactive compounds (functionalized compounds). The study provides suitable extraction conditions for A.B. and further elaborates on the techniques for identifying bioactive compounds in A.B. bulb extracts.

The study provides A.B. as a source of bioactive compounds and a clean dye for textile coloration.

To the best of the authors’ knowledge, there is no documented study on the qualitative analysis of bioactive compounds in A.B using Raman and FTIR. Therefore, the study fulfils the identified need to ascertain alternative procedures for the analysis of bioactive compounds.

Visible and near infrared spectroscopy have been applied widely in fruits quality assessment especially on the measurement of soluble solids content (SSC) measured in ^oBrix and acidity measured in pH. Spectroscopy technique has been applied on three botanically different categories of fruits, that is: imported Californian table grape, Mandarin lime and star fruit. The purpose is to examine the ability of spectroscopy technique to quantify internal quality parameters with very narrow variability due to the characteristics of the raw material analyzed. This work also presents comparative study on peak wavelengths that can best be used to calibrate SSC and pH of different types of fruits.

The effective wavelengths chosen for calibration development are compared with those selected by other researchers in similar experiments. NIR wavelengths 910 nm (C−H band) and 950 nm (O−H band) are the most important wavelengths for the prediction of SSC for all examined fruits while wavelengths 922‐923 nm and 990‐995 nm for pH. Visible wavelength 605, 675 and 654 nm can efficiently improve the SSC and pH prediction for grape, lime and star fruit, respectively.

The best prediction for SSC has been achieved with R²=0.953 and RMSE=0.182 for grape, R²=0.918 and RMSE=0.109 for lime and R²=0.957 and RMSE=0.354 for star fruit. The best prediction for pH has been achieved with R²=0.763 and RMSE=0.110 for grape, R²=0.841 and RMSE=0.073 for lime and R²=0.862 and RMSE=0.261 for star fruit.

Currently, the spectroscopy research conducted for the measurement of fruits qualities is conducted through wide range spectrometer. However, the peak responses are only located at specific wavelengths. Hence, the selection of wavelengths related to SSC and pH will allow the design of low cost instruments for the prediction of these internal quality parameters.

Ballpoint pen ink analysis is important for forensic scientist which can collect valuable information on questioned document. Inks widely used now constitute many substances to improve needed ink characteristics, including the coloring material (dyes or pigments), inks, solvents and resins. The complex components of the inks confront forensic ink chemists with a big challenge to carry out this analysis. However, because of the great importance of determining whether two pieces of written text originated from the same ink, therefore, comparison of different writing inks on a document to forensic scientist, many techniques have been tentatively employed in the ink analysis. In this study, Raman microscope was employed successfully in the analysis of inks. The paper aims to discuss these issues.

Damped or wet samples cannot be analyzed by IR if dehydration is not carried out FTIR observation, because of the extremely strong absorbance of water. Raman spectroscopy can cover the shortage of FTIR spectroscopy because water has weak absorbance in Raman spectroscopy. Raman shifts can give extra peak information because it usually has different positions with FTIR spectroscopy. A Renishaw inVia confocal Raman microscope system with two lasers emitting at 532/633 nm, charge-coupled device detector was employed collecting the Raman spectrum. Laser was chosen for emission in 1-100 percent power depending on the proper energy to get signal strong enough and protect the samples from burning. At least triple-tests were performed for each sample.

The result indicated that Raman spectroscopy could easily remove the interference caused by the paper which could hardly be removed with infrared spectroscopy. No sample preparation was required and only 30 s was needed for each sample in the optimized method. The method proved to be fast, accurate, non-destructive and could be easily applied to the real cases. The primary survey on inks from different market indicated five kinds of inks could be identified. The indicative peaks of each kind of ink (693, 1,150-1,210, 1,280-1,300, 1,360-1,400 and 1,531 cm−1) were summarized. The distributions of the inks in markets were also illustrated. Ink using alkyd resin as connecting materials or copper phthalocyanine as pigment decreased significantly. The data in this study would be helpful for the forensic scientists to identify these inks and examine the questioned document.

No previous studies on the analysis of inks in China market were found to the authors’ best, so the forensic scientists have no idea about the method using Raman for discrimination which proved to be effective, accurate and fast, the indicative peaks of each inks, the distributions in the markets, and therefore, the possibility to encounter specific ink in cases The data in this study would be helpful for the forensic scientists to identify these inks and examine the questioned document.

This study aims to examine the association of frontal functioning with subclinical bipolar spectrum by a newly developed convenient method. We investigated subclinical bipolar tendency and frontal lobe activation during word productions using multi-channel near infrared spectroscopy. Participants: 44 healthy university students (mean ages 20.5 years old, and 29 female) gave their written informed consent, and we strictly protected privacy and anonymity was carefully preserved. A 13-items self-report questionnaire (Mood Disorders Questionnaire; MDQ) and a 16-channel near-infrared spectroscopy were used to compare frontal activations between two samples divided by median (4 points) of the total MDQ scores and to analyze correlations between relative changes of cerebral blood volume and bipolarity levels. There was no case suspected as bipolar disorders by MDQ screening (mean 3.4, max 10). Significant differences in lower activations were noted in the right and left pre-frontal cortex (PFC) with higher bipolarity scores using the specific software to analyze the NIRS waveform (P<0.05). Total MDQ were correlated significantly with frontal activation negatively in many channels; therefore, we conducted multiple linear regression to select significant frontal activations using the MDQ as a dependent variable. Stepwise method revealed that activation in left lateral PFC was negatively associated to bipolar tendency, and this regression model was significant (R2=0.10, F=4.5, P=0.04). Differences in frontal functioning suggest that subclinical bipolar tendencies might be related to left lateral PFC activations. It should be confirmed whether the identical pattern can be identified for clinical subjects with bipolar disorders.

Parallel factor analysis (PARAFAC) coupled with support-vector machine (SVM) was carried out to identify and discriminate between the fluorescence spectroscopies of coconut water brands.

PARAFAC was applied to reduce three-dimensional data of excitation emission matrix (EEM) to two-dimensional data. SVM was applied to discriminate between six commercial coconut water brands in this study. The three largest variation data from fluorescence spectroscopy were extracted using the PARAFAC method as the input data of SVM classifiers.

The discrimination results of the six commercial coconut water brands were achieved by three SVM methods (Ga-SVM, PSO-SVM and Grid-SVM). The best classification accuracies were 100.00%, 96.43% and 94.64% for the training set, test set and CV accuracy.

The above results indicate that fluorescence spectroscopy combined with PARAFAC and SVM methods proved to be a simple and rapid detection method for coconut water and perhaps other beverages.

This study aims to using Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy and scanning electron microscope/energy dispersive Xray spectrometer to identify different automotive coatings for forensic purpose.

Two four-layered samples in a hit-and-run case were compared layer by layer with three different methods. FTIR spectroscopy was used to primarily identify the organic and inorganic compositions. Raman spectrum and scanning electron microscope/energy dispersive Xray spectrometer (SEM-EDS) were further used to complement the FTIR results.

Two weak and tiny peaks in one layer found between two samples by FTIR, Raman microscope and SEM-EDS verified the result of differences. The study used the three instruments in combination and found it’s effective in sensing coatings, especially in the inorganic additives.

Using these three instruments in combination is more accurate than individually in multilayered coating analysis for forensic purpose.

The three different instruments all present unique information on the composition, and provided similar and mutually verifiable results on the two samples.

With this method, scientists could identify and discriminate important coating evidences with tiny but characteristic differences.

To review the use of near‐infrared (NIR) spectroscopy in the process control of foodstuffs.

Presents two spectroscopy products used in the production environment: a single‐board system aimed at OEMs, and a complete fibre‐optic spectrometer ready for the end‐user. Gives examples of applications within the food and drink industry.

Finds that these instruments are fast, effective and inexpensive, and rugged enough for the processing environment.

Draws attention to the potential of NIR spectroscopy outside the confines of the laboratory.

Organic and immersion metallic coatings are being used as a replacement for the hot air solder level (HASL) process. Use of these coatings provides advantages for both the fabricator and assembler. Advantages to assemblers include flatter pads (0.25‐0.5 micron thickness), no limitations on fine pitch or small hole cleaning, and greater solder joint strength. Advantages to the fabricator include lower operating costs, little or no rejects/rework, reduced safety hazard and a more environmentally friendly process. Current problems associated with the organic and immersion coatings include the inability to assess the solderability of the bare copper or the integrity of the coating (organic). These coatings also present a critical concern due to their reduced shelf life and potential inability to survive mishandling in manufacturing. Real time, non‐destructive methods of rapidly assessing the integrity these coatings are currently not available to the electronics industry. Surface Spectroscopy measurement techniques have the potential to measure the structure and characteristics of the organic and metallic coatings, and surface oxides that develop with time and temperature. The measurement techniques are rapid, non‐contact, and relatively inexpensive to make when compared to existing methods. Surface Spectroscopy can also provide critical surface information that is needed to troubleshoot solderability problems. The American Competitiveness Institute in association with the Navy EMPF program is working with several industry partners to develop a usable surface spectroscopy tool that will assess the quality and integrity of the coatings and correlate that reading with a solderability evaluation.

The purpose of this paper is to discuss the application of THz spectroscopy for the inspection and evaluation of the internal structure of complex samples with honeycomb fillers.

Three complex samples with honeycomb fillers are investigated using THz spectrometer in order to determine the applicability of chosen non-destructive method for the analysis of internal structure of structural components. The first analysed sample has aluminium honeycomb filler with some cells filled with water. The aim of the analysis is to distinguish empty and full cells. The other two sandwich samples are made of different non-metallic components and for them the possibility of THz spectroscopy application is analysed.

The empty and full cells in metal honeycomb filler were easily distinguished due to different absorption coefficients of electromagnetic waves in THz range for air and water. It was especially visible for frequency domain. The THz spectroscopy was able to inspect the non-metallic samples internal structures and distinguish skins (with layers), honeycomb fillers and adhesive layers between them. It was also possible to detect, localise and determine the size of a local damage of honeycomb walls due to impact influence.

The present study is an original research work. There are very limited literature papers which present analyses of internal structures of sandwich elements using THz spectroscopy and investigate utility of the method for mechanical damage and contamination (water) detection and localisation.

The purpose of this paper is to develop the models of the dielectric permittivity dispersion of heterogeneous systems based on semiconductors to a level that would allow to apply effectively the method of broadband dielectric spectroscopy for the study of electronic processes in ceramic and composite materials.

The new approach for determining the complex dielectric permittivity of heterogeneous systems with semiconductor particles is used. It includes finding the analytical expression of the effective dielectric permittivity of the separate semiconductor particle of spherical shape. This approach takes into account the polarization of the free charge carriers in this particle, including capturing to localized electron states. This enabled the authors to use the known equations for complex dielectric permittivity of two-component matrix systems and statistical mixtures.

The presented dispersion equations establish the relationship between the parameters of the dielectric spectrum and electronic processes in the structures like semiconductor particles in a dielectric matrix in a wide frequency range. Conditions of manifestation and location of the different dispersion regions of the complex dielectric heterogeneous systems based on semiconductors in the frequency axis and their features are established. The most high-frequency dispersion region corresponds to the separation of free charge carriers at polarization. After this region in the direction of reducing of the frequency, the dispersion regions caused by recharge bulk and/or surface localized states follow. The most low-frequency dispersion region is caused by recharging electron traps in the boundary layer of the dielectric matrix.

Dielectric dispersion models are developed that are associated with: electronic processes of separation of free charge carriers in the semiconductor component, recapture of free charge carriers in the localized electronic states in bulk and on the surface of the semiconductor and also boundary layers of the dielectric at the polarization. The authors have analyzed to situations that correspond applicable and promising materials: varistor ceramics and composite structure with conductive and semiconductor fillers. The modelling results correspond to the existing level of understanding of the electron phenomena in matrix systems and statistical mixtures based on semiconductors. It allows to raise efficiency of research and control properties of heterogeneous materials by dielectric spectroscopy.