Search results

Concrete is a building material widely used for the infrastructural development. Cement is the binding material used for the development of concrete. It is the primary cause of CO₂ emission globally. The purpose of this study is to develop sustainable concrete material to satisfy the present need of construction sector. Geopolymer concrete (GPC) is a sustainable concrete developed without the use of cement. Therefore, investigations are being conducted to replace the cement by 100% with high calcium fly ash (FA) as binding material.

High calcium FA is used as cementitious binder, sodium hydroxide (NaOH) and sodium silicates (Na₂SiO₃) are used as alkaline liquids for developing the GPC. Mix proportions with different NaOH molarities of 4, 6, 8 and 10 M are considered to attain the appropriate mix. The method of curing adopted is ambient and oven curing. Workability, compressive strength and microstructure characteristics of GPC are analysed and presented.

An increase of NaOH in the mix decreases the workability. Compressive strength of 29 MPa is obtained for Mix-I with 8 M under ambient curing. A polynomial relationship is obtained to predict the compressive strength of GPC. Scanning electron microscope analysis is used to confirm the geo-polymerisation process in the microstructure of concrete.

This research work focuses on finding some alternative cementitious material for concrete that can replace ordinary portland cement (OPC) to overcome the CO₂ emission owing to the utilisation of cement in the construction industry. An attempt has been made to use the waste material (high calcium FA) from thermal power plant for the production of GPC. GPC concrete is the novel building material and alternative to conventional concrete. It is the ecofriendly product contributing towards the improvement of the circular economy in the construction industry. There are several factors that affect the property of GPC such as type of binder material, molarity of activator solution and curing condition. The novelty of this work lies in the approach of using locally available high calcium FA along with manufactured sand for the development of GPC. As this approach is rarely investigated, to prove the attainment of compressive strength of GPC with high calcium FA, an attempt has been made during the present investigation. Other influencing parameter which affects the strength gain has also been analysed in this paper.

The alkali metal hydroxides LiOH, NaOH and KOH have been studied in the desizing of woven cotton fabrics under different treatment conditions. The % fabric weight loss, the TEGEVA rating on the desized fabric, the effect of desizing bath pH and the molarity of the alkalis to the desizing results, and the starch removal rate of the treatments was studied. It was found that the removal of starch size from the warp yams of the woven cotton fabric is not only bath pH dependent, but also depending on the nature of the alkali that used, in that NaOH has the best desizing ability among the others. In addition, the temperature of the desizing bath is the most important in order to obtain a good desizing result. Although alkali desizing can improve the water absorption and the whiteness of the grey cotton fabric, it is not good enough for use in subsequent coloration processes.

This paper aims to describe the physiological analysis of L. rhamnosus VTT E‐97800 and its adaptive response to osmotic stress induced by trehalose.

Cells of L. rhamnosus E800 in the stationary phase of growth were subjected to osmotic stress induced by trehalose treatments. The effects of osmotic stress on the viability of the study strain were determined by conducting flow cytometric analysis with carboxyfluorescein diacetate (cFDA) and propidium iodide (PI) and by observing the corresponding cells growth on MRS agar plates. Osmotic‐induced changes of esterase activity and membrane integrity were monitored. Ability to extrude intracellular accumulated cF (additional vitality marker) was taken into consideration.

The fluorescence‐based approach gave additional insights on osmotic induced changes of cellular events, which could not be explicitly assessed by culture techniques. Trehalose treatments caused a transient membrane permeabilization as revealed by a gradual decrease in esterase activity (a measure of enzyme activity and thus of viability) with increase in trehalose molarity. However, culturability on MRS agar was not significantly affected. Membrane integrity was maintained and there was an improvement in the ability of cells to extrude intracellular accumulated cF.

The paper provides a comparative study of the conventional culture techniques and the flow cytometric viability assessment which showed that esterase activity cannot be relied on to ascertain the culturability and viability status of an organism.

The construction industries at present are focusing on designing sustainable concrete with less carbon footprint. Considering this aspect, a Fibre-Reinforced Geopolymer Concrete (FGC) was developed with 8 and 10 molarities (M). At elevated temperatures, concrete experiences deterioration of its mechanical properties which is in some cases associated with spalling, leading to the building collapse.

In this study, six geopolymer-based mix proportions are prepared with crimped steel fibre (SF), polypropylene fibre (PF), basalt fibre (BF), a hybrid mixture consisting of (SF + PF), a hybrid mixture with (SF + BF), and a reference specimen (without fibres). After temperature exposure, ultrasonic pulse velocity, physical characteristics of damaged concrete, loss of compressive strength (CS), split tensile strength (TS), and flexural strength (FS) of concrete are assessed. A polynomial relationship is developed between residual strength properties of concrete, and it showed a good agreement.

The test results concluded that concrete with BF showed a lower loss in CS after 925 °C (i.e. 60 min of heating) temperature exposure. In the case of TS, and FS, the concrete with SF had lesser loss in strength. After 986 °C and 1029 °C exposure, concrete with the hybrid combination (SF + BF) showed lower strength deterioration in CS, TS, and FS as compared to concrete with PF and SF + PF. The rate of reduction in strength is similar to that of GC-BF in CS, GC-SF in TS and FS.

Performance evaluation under fire exposure is necessary for FGC. In this study, we provided the mechanical behaviour and physical properties of SF, PF, and BF-based geopolymer concrete exposed to high temperatures, which were evaluated according to ISO standards. In addition, micro-structural behaviour and linear polynomials are observed.

Lactobacillus rhamnosus GG, a probiotic of human origin, known to have health beneficial effects can be exposed to osmotic stress when applied in food production as important quantities of sugars are added to the food product. The aim of this study is to assess the mode of action of non‐electrolytes stress on its viability.

Investigations were carried out on stationary phase cells treated with 0‐1.5M sugars, by means of flow cytometric method (FCM) and plate enumeration method. Osmotically induced changes of microbial carboxyfluorescein (cF)‐accumulation capacity and propidium iodide‐exclusion were monitored. The ability of the cells to extrude intracellularly accumulated cF upon glucose energization was ascertained as an additional vitality marker, in which the kinetics of dye extrusion were taken into consideration as well. Sugar analysis by HPLC was also carried out.

The results of FCM analysis revealed that with sucrose, only cells treated at 1.5M experienced membrane perturbation but there was a preservation of membrane integrity and enzymatic activity. There was no loss of viability as shown by plate counts. In contrast, the majority of trehalose‐treated cells had low extent of cF‐accumulation. For these samples a slight loss of viability was recorded on plating (logN/N_o ∼ −0.45). At 0.6M, cells had similar extrusion ability as the control cells upon glucose energization. However, 20 per cent of sucrose‐treated cells and 80 per cent of trehalose‐treated cells extruded the dye in the first 10min.

This finding pointed out the importance of trehalose to enhance the dye extrusion activity, which is regarded as an analogue of the capability of cells to extrude toxic compounds. Sugars exert different effects on the physiological and metabolic status of LGG but none caused a significant viability loss. LGG can be a choice probiotic bacterium in sugar‐rich food production e.g. candies, marmalade etc., in which exposure to high osmotic pressure is be expected.

The purpose of this paper is to investigate the effect of the replacement of natural coarse aggregate (NCA) with different percentages of recycled coarse aggregate (RCA) on properties of low calcium fly ash (FA)-based geopolymer concrete (GPC) cured at oven temperature. Further, this paper aims to study the effect of partial replacement of FA by ground granulated blast slag (GGBS) in GPC made with both NCA and RCA cured under ambient temperature curing.

M25 grade of ordinary Portland cement (OPC) concrete was designed according to IS: 10262-2019 with 100% NCA as control concrete. Since no standard guidelines are available in the literature for GPC, the same mix proportion was adopted for the GPC by replacing the OPC with 100% FA and W/C ratio by alkalinity/binder ratio. All FA-based GPC mixes were prepared with 12 M of sodium hydroxide (NaOH) and an alkalinity ratio, i.e. sodium hydroxide to sodium silicate (NaOH:Na₂SiO₃) of 1:1.5, subjected to 90^°C temperature for 48 h of curing. The NCA were replaced with 50% and 100% RCA in both OPC and GPC mixes. Further, FA was partially replaced with 15% GGBS in GPC made with the above percentages of NCA and RCA, and they were given ambient temperature curing with the same molarity of NaOH and alkalinity ratio.

The workability, compressive strength, split tensile strength, flexural strength, water absorption, density, volume of voids and rebound hammer value of all the mixes were studied. Further, the relationship between compressive strength and other mechanical properties of GPC mixes were established and compared with the well-established relationships available for conventional concrete. From the experimental results, it is found that the compressive strength of GPC under ambient curing condition at 28 days with 100% NCA, 50% RCA and 100% RCA were, respectively, 14.8%, 12.85% and 17.76% higher than those of OPC concrete. Further, it is found that 85% FA and 15% GGBS-based GPC with RCA under ambient curing shown superior performance than OPC concrete and FA-based GPC cured under oven curing.

The scope of the present paper is limited to replace the FA by 15% GGBS. Further, only 50% and 100% RCA are used in place of natural aggregate. However, in future study, the replacement of FA by different amounts of GGBS (20%, 25%, 30% and 35%) may be tried to decide the optimum utilisation of GGBS so that the applications of GPC can be widely used in cast in situ applications, i.e. under ambient curing condition. Further, in the present study, the natural aggregate is replaced with only 50% and 100% RCA in GPC. However, further investigations may be carried out by considering different percentages between 50 and 100 with the optimum compositions of FA and GGBS to enhance the use of RCA in GPC applications. The present study is further limited to only the mechanical properties and a few other properties of GPC. For wider use of GPC under ambient curing conditions, the structural performance of GPC needs to be understood. Therefore, the structural performance of GPC subjected to different loadings under ambient curing with RCA to be investigated in future study.

The replacement percentage of natural aggregate by RCA may be further enhanced to 50% in GPC under ambient curing condition without compromising on the mechanical properties of concrete. This may be a good alternative for OPC and natural aggregate to reduce pollution and leads sustainability in the construction.

The purpose of this investigation was to compare outcomes associated with peer tutoring vs. teacher-directed instruction for secondary level students with mild disabilities in inclusive chemistry classes. Thirty-nine students of whom 10 were classified with disabilities participated in a 9-week chemistry unit, under either experimental or traditional instruction conditions. The same co-teachers, including one chemistry and one special education teacher during the regularly assigned chemistry classes, taught both classes. The students in the experimental condition participated in classwide peer tutoring of important content required on statewide high stakes testing. Mnemonic and other verbal cues were included to facilitate verbal recall, and peer questioning provided for comprehension and elaboration of the concepts. Post-tests revealed that students in the tutoring condition outperformed students in the traditional condition, and that the gains of the students with learning disabilities descriptively exceeded those of the typically-achieving students. Students without learning disabilities outperformed students with learning disabilities, and students scored higher on factual items than on comprehension items. Implications for instruction and future research are discussed.

Sweating is thermo-regulatory behaviour that occurs when a person performs vigorous activity even in cold climatic condition. One of important component of sweat is the presence of lactate. Based on climatic condition, age, gender, maturity and nature of activity level, the change in lactate concentration is inevitable. Hence, the present study is focussed on the impact of change in the lactate concentration on the moisture transmission behaviour through the clothing. The purpose of this paper is to investigate the impact of changing lactate concentration on the moisture vapour transmission behaviour through multi-layered clothing ensembles.

For the investigation, sweat solution representing male and female sweat were taken for present study. Two different multi-layered ensembles consisting of either spacer or fleece as middle layer were considered. The water vapour permeability and drying rate test were done at standard atmospheric conditions. After testing, ANOVA analysis was done in order to determine the most significant parameters.

Fabric structure (constituent layers) behaved differently when tested individually and as the layered component with different sweat solutions. Water vapour permeability of sweat solution with higher lactate concentration was lower as compared to sweat solution with lower lactate concentration. Individual layers showed higher rate of vapour permeability with sweat solution containing lower lactate concentration as compared to multi-layered ensembles. Role of PU coated nylon fabric was predominant in case of multi-layered ensembles. Difference in transmission of sweat solution was found higher in case of uni-directional stitched multi-layer spacer ensembles whereas marginal difference was observed in case of bi-directional seamed multi-layer spacer ensemble. Drying rate of sweat containing lower concentration of lactate was higher as compared to the other sweat solution for all the selected fabrics. Density of liquid and amount of the water available for drying influenced the drying behaviour and thus accounted for difference in drying rate of sweat solution differing in the lactate concentration. The contribution percentage of layers, i.e. type of structure was higher (nearly 93–96%) compared to that of solution type (3.3–4.9%) in case of individual layers whereas in the case of the multi-layer ensembles; type of seam had maximum contribution percentage (71–77%) followed by solution type (10–15%). Type of layers had least contribution percentage (nearly 7–9%).

The findings from the study are expected to be realistic and important in designing and development of cold weather garment ensemble for different gender type depending on their activity level especially in case of military personnel and those performing combat activities.

This experimental work based will provide the insight about the behaviour of actual sweat transmission through the layered fabric ensembles and ways to prevent the accumulation of moisture near to human skin surface by manufacturing suitable design structures (in terms of layering composition and seam patterns) per the morphology and requirement of specific consumers.

Environmental issues caused by the production of Portland cement have led to it being replaced by waste materials such as fly ash, which is more economical and safer for the environment. Also, fly ash is a material with sustainable properties. Therefore, this paper aims to focus on the development of sustainable construction materials using 100% high-calcium fly ash and potassium hydroxide (KOH)-based alkaline solution and study the engineering properties of the resulting fly ash-based geopolymer concrete. Laboratory tests were conducted to determine the mechanical properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In phase I of the study, carbon nanotubes (CNTs) were added to determine their effect on the strength of the geopolymer mortar. The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce similar (comparable) strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates a considerable amount of heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond was unable to form a stronger bond. This study also determined that the addition of CNTs to the mix makes the geopolymer concrete tougher than the traditional concrete without CNT.

Tests were conducted to determine properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In Phase I of the study, CNTs were studied to determine their effect on the strength of the geopolymer mortar.

The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce the same strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates too much heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond. This study also determined that the addition of CNTs to the mix makes the concrete tougher than concrete without CNT.

This study was conducted at the construction engineering and management concrete laboratory at North Dakota State University in Fargo, North Dakota. All the experiments were conducted and analyzed by the authors.

The objective of this article is to investigate the binding of several lactones to soya protein isolate and soya protein under different conditions and, particularly, the extent of binding of the lactones γ‐9, γ‐10, δ‐10 and δ‐11, in different concentrations as well as the effect of various parameters on their binding ability.

Capillary column gas chromatography was used for the determination of lactones and the manual system was used for taking samples and for headspace analysis. Infrared spectroscopy was used for confirmation and investigation.

The percentage of binding of lactones γ‐9, γ‐10, δ‐10, δ‐11 on the soya protein is almost the same (about 33‐34 per cent). According to the Klotz equation, the bound ligand concentration was calculating as the number of moles of ligand bound per mole of protein. The results varied, but were similar. Specific experiments in water system with soya protein isolate (1 per cent) showed that the time taken for lactones γ‐10 and δ‐11 to reach equilibrium, the factors of temperature and pH affected the percentage of lactone bound.

The amount of added lactone in products containing soya protein isolate should be investigated by using panel tests to confirm the improvement of flavour.

Flavour binding of lactones can be used to provide some foods with the required flavour impression by adding lactones to a bland soy protein base.

The flavour binding of lactones, which was investigated in the present paper, has not been adequately investigated in previous scientific research and the effects of the factors that influence their binding are very important.