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1 – 10 of 105Adhithya Sreeram and Jayaraman Kathirvelan
Artificial fruit ripening is hazardous to mankind. In the recent past, artificial fruit ripening is increasing gradually due to its commercial benefits. To discriminate the type…
Abstract
Purpose
Artificial fruit ripening is hazardous to mankind. In the recent past, artificial fruit ripening is increasing gradually due to its commercial benefits. To discriminate the type of fruit ripening involved at the vendors’ side, there is a great demand for on-sight ethylene detection in a nondestructive manner. Therefore, this study aims to deal with a comparison of various laboratory and portable methods developed so far with high-performance metrics to identify the ethylene detection at fruit ripening site.
Design/methodology/approach
This paper focuses on various types of technologies proposed up to date in ethylene detection, fabrication methods and signal conditioning circuits for ethylene detection in parts per million and parts per billion levels. The authors have already developed an infrared (IR) sensor to detect ethylene and also developed a lab-based setup belonging to the electrochemical sensing methods to detect ethylene for the fruit ripening application.
Findings
The authors have developed an electrochemical sensor based on multi-walled carbon nanotubes whose performance is relatively higher than the sensors that were previously reported in terms of material, sensitivity and selectivity. For identifying the best sensing technology for optimization of ethylene detection for fruit ripening discrimination process, authors have developed an IR-based ethylene sensor and also semiconducting metal-oxide ethylene sensor which are all compared with literature-based comparable parameters. This review paper mainly focuses on the potential possibilities for developing portable ethylene sensing devices for investigation applications.
Originality/value
The authors have elaborately discussed the new chemical and physical methods of ethylene detection and quantification from their own developed methods and also the key findings of the methods proposed by fellow researchers working on this field. The authors would like to declare that the extensive analysis carried out in this technical survey could be used for developing a cost-effective and high-performance portable ethylene sensing device for fruit ripening and discrimination applications.
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Alexander Y. Yashin, Dmitry V. Yashunsky, Aleksander N. Vedenin, Nikolay E. Nifantiev, Yakov I. Yashin and Boris V. Nemzer
The purpose of this paper is to determine the antioxidant activity of natural polyphenols from larch wood by the amperometric method.
Abstract
Purpose
The purpose of this paper is to determine the antioxidant activity of natural polyphenols from larch wood by the amperometric method.
Design/methodology/approach
Direct measurements of antioxidant activity were carried out by the amperometric method in an oxidizing mode with glassy carbon as a working electrode, set potential +1.3V and using a flow-injection system with 2.2 mM phosphoric acid as the mobile phase with a flow rate of 1.2 ml/min.
Findings
The reported results show the following values of antioxidant activity for the tested compounds: (−)-secoisolariciresinol – 0.199 ± 0.002 mg/L (p < 0.05); isolariciresinol – 0.196 ± 0.002 mg/L (p < 0.05); lariciresinol - 0.222 ± 0.001 mg/L (p < 0.05); O-isopropylidene derivative of (−)-secoisolariciresinol - 0.143 ± 0.002 mg/L (p < 0.05); (+)-dihydroquercetin – 0.153 ± 0.002 mg/L (p < 0.05); and quercetin – 0.521 ± 0.001 mg/L (p < 0.05). The last product was tested as the reference of a widely used current antioxidant. General tendencies of determined values of antioxidant activity for studied compounds are in good correlation with published data as determined by the t-BuOOH-initiated lipid peroxidation method.
Practical implications
Described results show practical applicability of the amperometric method as being faster and cheaper in comparison to other methods, including oxygen radical absorbance capacity (ORAC) assay or 2,2′diphenyl-1-picrylhydrazyl (DPPH) reagent based assay.
Originality/value
The described results show the first-time application of the amperometric method for the evaluation of the antioxidant activity of phenolic compounds from larch wood.
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Huda Abdullah, Norshafadzila Mohammad Naim, Kok Seng Shum, Aidil Abdul Hamid, Mohd Hafiz Dzarfan Othman, Vidhya Selvanathan, Wing Fen Yap and Seri Mastura Mustaza
Regular monitoring of bacteria, especially Escherichia coli, in wastewater is crucial to ensure the maintenance of public health. Amperometric detection proves to be a fast…
Abstract
Purpose
Regular monitoring of bacteria, especially Escherichia coli, in wastewater is crucial to ensure the maintenance of public health. Amperometric detection proves to be a fast, sensitive and economically viable solution for E. coli enumeration. This paper reported a prototype amperometric sensor based on PANI-ZnO-NiO nanocomposite thin films prepared by sol–gel method and irradiated with gamma ray. The purpose of this study is to investigate the sensor performance of PANI-ZnO-NiO nanocomposite thin films to detect E. coli in water.
Design/methodology/approach
The films were varied with different compositions of ZnO and NiO by using the formula PANI-(ZnO)1-x-(NiO)x, with x = 0.2, 0.4, 0.6 and 0.8. PANI-ZnO-NiO nanocomposite thin films were characterized by using X-ray diffraction (XRD) and atomic force microscopy (AFM) to study the crystallinity and surface morphology of the films. The sensor performance was conducted using the current–voltage (I-V) measurement by testing the films in clean water and E. coli solution.
Findings
XRD diffractograms show the peaks of ZnO (1 0 0) and NiO (1 0 2). AFM analysis shows the surface roughness, and the grain size of PANI-ZnO-NiO thin films decreases when the concentration ratios of NiO increased. I-V curves show the difference in current flow, where the current in E. coli solution is higher than the clean water.
Originality/value
PANI-(ZnO)1-x-(NiO)x nanocomposite thin film with the highest concentration of ZnO performed the highest sensitivity among the other concentrations, which can be used to indicate the presence of E. coli bacteria in water.
Discusses intelligent materials, intelligent material‐based sensors, their transducing methods, and different kinds of transducers used with smart material‐based sensors. Assumes…
Abstract
Discusses intelligent materials, intelligent material‐based sensors, their transducing methods, and different kinds of transducers used with smart material‐based sensors. Assumes that the future of intelligent sensors will almost totally depend on intelligent chemistry and intelligent instrumentation. Molecular recognition will widen the horizons of smart systems with the help of VLSI‐based design and fabrication. Discusses different sensor mechanisms, such as ENFETs, immunoFETs, ISFETs and chemFETs and takes a detailed look at potentiometric, amperometric and optical biosensors.
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Jayaraman Kathirvelan and Rajagopalan Vijayaraghavan
This work encompasses the various laboratory-based and portable methods evolved in recent times for sensitive and selective detection of ethylene for fruit-ripening application…
Abstract
Purpose
This work encompasses the various laboratory-based and portable methods evolved in recent times for sensitive and selective detection of ethylene for fruit-ripening application. The role of ethylene in natural and artificial fruit ripening and the associated health hazards are well known. So there is a growing need for ethylene detection. This paper aims to highlight potential methods developed for ethylene detection by various researchers, including ours. Intense efforts by various researchers have been on since 2014 for societal benefits.
Design/methodology/approach
The paper focuses on types of sensors, fabrication methods and signal conditioning circuits for ethylene detection in ppm levels for various applications. The authors have already designed, developed a laboratory-based set-up belonging to the electrochemical and optical methods for detection of ethylene.
Findings
The authors have developed a carbon nanotube (CNT)-based chemical sensor whose performance is higher than the reported sensor in terms of material, sensitivity and response, the sensor element being multi-walled carbon nanotube (MWCNT) in comparison to single-walled carbon nanotube (SWCNT). Also the authors have developed infrared (IR)-based physical sensor for the first time based on the strong IR absorption of ethylene at 10.6 µm. These methods have been compared with literature based on comparable parameters. The review highlights the potential possibilities for development of portable device for field applications.
Originality/value
The authors have reported new chemical and physical sensors for ethylene detection and quantification. It is demonstrated that it could be used for fruit-ripening applications A comparison of reported methods and potential opportunities is discussed.
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Lochan Singh and Vijay Singh Sharanagat
Nature and occurrence of food-borne pathogens in raw and processed food products evolved greatly in the past few years due to new modes of transmission and resistance build-up…
Abstract
Purpose
Nature and occurrence of food-borne pathogens in raw and processed food products evolved greatly in the past few years due to new modes of transmission and resistance build-up against sundry micro-/macro-environmental conditions. Assurance of food health and safety thus gained immense importance, for which bio-sensing technology proved very promising in the detection and quantification of food-borne pathogens. Considering the importance, different studies have been performed, and different biosensors have been developed. This study aims to summarize the different biosensors used for the deduction of food-borne pathogens.
Design/methodology/approach
The present review highlights different biosensors developed apropos to food matrices, factors governing their selection, their potential and applicability. The paper discusses some related key challenges and constraints and also focuses on the needs and future research prospects in this field.
Findings
The shift in consumers’ and industries’ perceptions directed the further approach to achieve portable, user and environmental friendly biosensing techniques. Despite of these developments, it was still observed that the comparison among the different biosensors and their categories proved tedious on a single platform; since the food matrices tested, pathogen detected or diagnosed, time of detection, etc., varied greatly and very few products have been commercially launched. Conclusively, a challenge lies in front of food scientists and researchers to maintain pace and develop techniques for efficiently catering to the needs of the food industry.
Research limitations/implications
Biosensors deduction limit varied with the food matrix, type of organism, material of biosensors’ surface, etc. The food matrix itself consists of complex substances, and various types of food are available in nature. Considering the diversity of food there is a need to develop a universal biosensor that can be used for all the food matrices for a pathogen. Further research is needed to develop a pathogen-specific biosensor that can be used for all the food products that may have accuracy to eliminate the traditional method of deduction.
Originality/value
The present paper summarized and categorized the different types of biosensors developed for food-borne pathogens.
Graphical abstract
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Mulayam Singh Gaur, Rajni Yadav, Mamta Kushwah and Anna Nikolaevna Berlina
This information will be useful in the selection of materials and technology for the detection and removal of mercury ions at a low cost and with high sensitivity and selectivity…
Abstract
Purpose
This information will be useful in the selection of materials and technology for the detection and removal of mercury ions at a low cost and with high sensitivity and selectivity. The purpose of this study is to provide the useful information for selection of materials and technology to detect and remove the mercury ions from water with high sensitivity and selectivity. The purpose of this study is to provide the useful information for selection of materials and technology to detect and remove the mercury ions from water with high sensitivity and selectivity.
Design/methodology/approach
Different nano- and bio-materials allowed for the development of a variety of biosensors – colorimetric, chemiluminescent, electrochemical, whole-cell and aptasensors – are described. The materials used for their development also make it possible to use them in removing heavy metals, which are toxic contaminants, from environmental water samples.
Findings
This review focuses on different technologies, tools and materials for mercury (heavy metals) detection and remediation to environmental samples.
Originality/value
This review gives up-to-date and systemic information on modern nanotechnology methods for heavy metal detection. Different recognition molecules and nanomaterials have been discussed for remediation to water samples. The present review may provide valuable information to researchers regarding novel mercury ions detection sensors and encourage them for further research/development.
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Sajad Pirsa and Fahime Purghorbani
In this study, an attempt has been made to collect the research that has been done on the construction and design of the H2O2 sensor. So far, many efforts have been made to…
Abstract
Purpose
In this study, an attempt has been made to collect the research that has been done on the construction and design of the H2O2 sensor. So far, many efforts have been made to quickly and sensitively determine H2O2 concentration based on different analytical principles. In this study, the importance of H2O2, its applications in various industries, especially the food industry, and the importance of measuring it with different techniques, especially portable sensors and on-site analysis, have been investigated and studied.
Design/methodology/approach
Hydrogen peroxide (H2O2) is a very simple molecule in nature, but due to its strong oxidizing and reducing properties, it has been widely used in the pharmaceutical, medical, environmental, mining, textile, paper, food production and chemical industries. Sensitive, rapid and continuous detection of H2O2 is of great importance in many systems for product quality control, health care, medical diagnostics, food safety and environmental protection.
Findings
Various methods have been developed and applied for the analysis of H2O2, such as fluorescence, colorimetry and electrochemistry, among them, the electrochemical technique due to its advantages in simple instrumentation, easy miniaturization, sensitivity and selectivity.
Originality/value
Monitoring the H2O2 concentration level is of practical importance for academic and industrial purposes. Edible oils are prone to oxidation during processing and storage, which may adversely affect oil quality and human health. Determination of peroxide value (PV) of edible oils is essential because PV is one of the most common quality parameters for monitoring lipid oxidation and oil quality control. The development of cheap, simple, fast, sensitive and selective H2O2 sensors is essential.
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Munir H. Shah, M. Jaffar, N. Shaheen and N. Rasool
This paper seeks to apply an improved electrometric method using polarized electrodes to quantify iodine in 241 salt samples pertaining to 15 different brands procured from the…
Abstract
Purpose
This paper seeks to apply an improved electrometric method using polarized electrodes to quantify iodine in 241 salt samples pertaining to 15 different brands procured from the local market.Design/methodology/approach – Comparative evaluation of the method is made with the iodometric titration and the colorimetric methods.
Findings
The results obtained reveal that the electrometric method excels in attaining higher level of accuracy, precision and lower detection limit, backed by ease of operation.
Practical implications
The method warrants reproducible results both for replicate synthetic and market samples, with a lower detection limit of about 0.1ppm within an acceptable limit of error.
Originality/value
The study shows significant difference between the estimated and labelled iodine values in various brands of iodized salts. Most of the salt samples analysed contain iodine levels far exceeding the WHO permitted limit. The method has the potential of application for in‐situ iodine measurement in iodine fortified salts to ensure rapid quality control, both at the retailer and production levels.
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The purpose of this paper is to evaluate and compare the protective, anticorrosion properties of silane- and polyrhodanine-based bilayer coatings pRh/IBTES and IBTES/pRh on an…
Abstract
Purpose
The purpose of this paper is to evaluate and compare the protective, anticorrosion properties of silane- and polyrhodanine-based bilayer coatings pRh/IBTES and IBTES/pRh on an X20Cr13 stainless steel substrate.
Design/methodology/approach
IBTES/pRh and pRh/IBTES have been coated using the dip-coating method and the cyclic voltammetry technique. The electrochemical measurements have been used to assess the anticorrosion properties of the resulting bilayer coatings. Morphological and chemical characterizations have been performed using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS).
Findings
The results clearly show that the combination of both the deposits of polyrhodanine and silane yields a more protective structure that affords better protection against corrosion with time. The best barrier properties are achieved by the substrates coated with polyrhodanine film upon which silane is subsequently adsorbed – the pRh/IBTES bilayer coating.
Originality/value
The paper reveals that the procedure of modification of silane films with polyrhodanine had a marked effect on the anti-corrosive performance of the obtained two types of bilayers coatings (pRh/IBTES, IBTES/pRh) applied on a stainless steel surface. The coating where polyrhodanine was first electrodeposited on the steel surface and then the silane layer adsorbed (pRh/IBTES) achieved the best protective properties.
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