Search results

1 – 10 of 30
Article
Publication date: 17 July 2023

Zulfiqar Ali Raza, Aisha Rehman, Faiza Anwar and Naseer Ahmad

This study aims to investigate the effect of the copresence of ferrous (Fe2+) ions and sodium dodecyl sulfate (SDS) on the activity of an amylase enzyme during the desizing of…

35

Abstract

Purpose

This study aims to investigate the effect of the copresence of ferrous (Fe2+) ions and sodium dodecyl sulfate (SDS) on the activity of an amylase enzyme during the desizing of greige viscose fabric for potential industrial applications. The removal of starches is an essential step before processing the fabric for dyeing and finishing operations. The authors tend to accomplish it in eco-friendly and sustainable ways.

Design/methodology/approach

The experiments were designed under the Taguchi approach, and the results were analyzed using grey relational analysis to optimize the process. The textile properties of absorbency, reducing sugars, bending length, weight loss, Tegawa rating and tensile strength were assessed using the standard protocols. The control and optimized viscose specimens were investigated for certain surface chemical properties using advanced analytical techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermal gravimetric analysis (TGA).

Findings

The results demonstrate that the Fe2+ concentration and process time were the main influencing factors in the amylolytic desizing of viscose fabric. The optimized process conditions were found to be 0.1 mm Fe2+ ions, 3 mm SDS, 80°C, 7 pH and 30 min process time. The copresence of Fe2+ ions and SDS promoted the biodesizing of viscose fabric. The SEM, Fourier transform infrared spectroscopy, XRD and TGA results demonstrated that the sizing agent has efficiently been removed from the fabric surface.

Practical implications

The amylase desizing of viscose fabric in the presence of certain metal ions and surfactants is a significant subject as the enzyme may face them due to their prevalence in the water systems. This could also support the biodesizing and bioscouring operations to be done in one bath, thus making the textile pretreatment process both economical and environmentally sustainable.

Originality/value

The authors found no report on the biodesizing of viscose fabric in the copresence of Fe2+ ions and the SDS surfactant under statistical multiresponse optimization. The biodesized viscose fabric has been investigated using both conventional and analytical approaches.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 April 2023

Saima Habib, Farzana Kishwar, Zulfiqar Ali Raza and Sharjeel Abid

This study aims to present a sustainable approach in the natural dyeing of cellulose fabric followed by nanosilver finishing through a green crosslinker of citric acid for…

Abstract

Purpose

This study aims to present a sustainable approach in the natural dyeing of cellulose fabric followed by nanosilver finishing through a green crosslinker of citric acid for potential antibacterial surgical gown fabrication.

Design/methodology/approach

The nanosilver finish was reproduced using the chemical reduction method. The fabric dyeing was performed on a lab-scale dyeing machine, whereas silver nano-finishing through a pad-dry-cure approach. Citric acid was used as an eco-friendly crosslinker. The specimens were characterized for antibacterial activity, surface chemical, textile, color properties and finish release trend.

Findings

The results demonstrated the successful application of curcumin dye followed by silver nano-finishing. The resultant fabric exhibited appropriate textile, dyeing performance indicators, hydrophobic behavior and sustainable broad-spectrum antibacterial activity.

Practical implications

The prepared nanosilver-finished/curcumin-treated fabric expressed desirable properties for potential applications in the fabrication of surgical gowns.

Originality/value

The authors found no reports on an extensive examination of nanosilver finishing on the color parameters of curcumin-dyed cellulose fabric while retaining its textile and comfort properties for possible surgical gown fabrication.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 13 July 2023

Abdul Lateef, Zulfiqar Ali Raza, Muhammad Aslam, Muhammad Shoaib Ur Rehman, Asma Iftikhar and Abdul Zahir

This study aims to fabricate multiwalled carbon nanotubes (MWCNTs)-mediated polyvinyl alcohol (PVA) composite films using the solution casting approach.

Abstract

Purpose

This study aims to fabricate multiwalled carbon nanotubes (MWCNTs)-mediated polyvinyl alcohol (PVA) composite films using the solution casting approach.

Design/methodology/approach

The prepared films were evaluated for diverse structural, surface, optical and electrical attributes using advanced analytical techniques, i.e. electron microscopy for surface morphology, Fourier transform infrared spectroscopy for tracing chemical functionalities, x-ray diffraction (XRD) for crystal patterns, water contact angle (WCA) analysis for surface wettability and UV visible spectroscopy for optical absorption parameters. The specimens were also investigated for certain rheological, mechanical and electrical properties, where applicable.

Findings

The surface morphology results expressed a better dispersion of MWCNTs in the resultant PVA-based nanocomposite film. The XRD analysis exhibited that the nanocomposite film was crystalline. The surface wettability analysis indicated that with the inclusion of MWCNTs, the WCA of the resultant nanocomposite film improved to 89.4° from 44° with the pristine PVA film. The MWCNTs (1.00%, w/w) incorporated PVA-based film exhibited a tensile strength of 54.0 MPa as compared to that of native PVA as 25.3 MPa film. There observed a decreased bandgap (from 5.25 to 5.14 eV) on incorporating the MWCNTs in the PVA-based nanocomposite film.

Practical implications

The MWCNTs’ inclusion in the PVA matrix could enhance the AC conductivity of the resultant nanocomposite film. The prepared nanocomposite film might be useful in designing certain optoelectronic devices.

Originality/value

The results demonstrated the successful MWCNTs mediation in the PVA-based composite films expressed good intercalation of the precursors; this resulted in decreased bandgap, usually, desirable for optoelectronic applications.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 24 April 2023

Saima Habib, Zulfiqar Ali Raza, Farzana Kishwar and Sharjeel Abid

This paper aims to develop an indigo-dyed denim fabric treated with a nanosilver colloid in the presence of a natural crosslinker of citric acid for possible surgical gown…

Abstract

Purpose

This paper aims to develop an indigo-dyed denim fabric treated with a nanosilver colloid in the presence of a natural crosslinker of citric acid for possible surgical gown fabrication applications.

Design/methodology/approach

A bleached denim fabric was dyed with the sustainable indigo dye followed by silver nanofinishing through citric acid crosslinking under the pad-dry-cure method. The prepared denim samples were analyzed for chemo-physical, textile, dyeing, antibacterial and finish release properties.

Findings

The results demonstrated that the comfort and textile characteristics of nanosilver-treated/indigo-dyed cellulosic fabric were affected due to the crosslinking, surface amphiphilicity and air permeability. These properties were, still, in the acceptable range for the fabrication of naturally dyed and antibacterial nanofinished denim gowns.

Practical implications

The dyeing of denim with synthetic dyes may cause harmful effects on the skin and health of the wearer, and the authors present an eco-friendly sustainable approach.

Originality/value

The authors used the fabric substrate, natural indigo dye and reducing/crosslinker agent of citric acid, all being bio-based, in the fabrication of antibacterial dyed fabric for health care garments.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 12 May 2023

Saima Habib, Zulfiqar Ali Raza, Farzana Kishwar and Sharjeel Abid

Present study aimed to nanosilver-treat some commercially dyed denim fabric using an eco-friendly cross-linker of citric acid for possible application in the fabrication of…

Abstract

Purpose

Present study aimed to nanosilver-treat some commercially dyed denim fabric using an eco-friendly cross-linker of citric acid for possible application in the fabrication of sustainable antibacterial and nontoxic surgical gowns.

Design/methodology/approach

The conventional untreated surgical gowns are prone to bacterial attack making them unprotective and infection carriers. Thereby, nanosilver finishing of the surgical-grade dyed denim fabric was achieved via citrate cross-linking under the pad-dry-cure method. The hence treated denim fabrics were characterized for surface chemical, crystalline, textile, color and antibacterial attributes using both conventional and advanced analytical approaches.

Findings

The results expressed that the prepared denim specimens contained surface roughness at the nanoscale besides some alterations in their textile and color parameters. Both textile and comfort properties of the finished fabric remained in the acceptable range with effective antibacterial activity.

Practical implications

The silver nano-finished dyed denim expressed broad-spectrum antibacterial activity and qualified as a potential substrate in the fabrication of surgical gowns. Such sustainable application of nanosilver finishing could be perused for industrial implications.

Originality/value

This study presents citric acid as a crosslinking agent to impregnate the commercially dyed denim fabric for potential application in the fabrication of surgical gowns. The application of nanosilver on prior citrated dyed-grown fabrics could be a novel approach. This study used approximately all the reagents and auxiliaries as bio-based to ensure the nontoxicity and sustainability of the resultant fabric.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 November 2016

Zulfiqar Ali Raza, Aisha Rehman and Rashid Masood

The purpose of this study was to overcome discomfort associated with it, a resin finish was applied in conjunction with hydrophilic polyurethane.

Abstract

Purpose

The purpose of this study was to overcome discomfort associated with it, a resin finish was applied in conjunction with hydrophilic polyurethane.

Design/methodology/approach

The process variables included concentrations of polyurethane and resin finishes, and pH under central composite design (CCD). The fabric specimens were assessed for crease recovery angle (CRA), tensile strength and moisture management properties.

Findings

Some models were developed for prediction of CRA and overall moisture management capability (OMMC) of treated fabric. It was observed that polyurethane concentration showed a parabolic relationship with CRA and a direct relationship with OMMC, whereas resin concentration showed a parabolic relationship with CRA and an inverse relationship with OMMC. Increase in pH from acidic to alkaline resulted in a decrease in CRA but an increase in OMMC. The untreated specimen had the highest tensile strength, whereas the specimen treated with polyurethane showed the least tensile strength loss, and the one treated with resin showed the highest loss in tensile strength.

Practical implications

As the polyurethane-based finish is soft and hydrophilic, so it was expected that it would overcome the uncomfortable feature of durable press finish, and with its flexibility, the strength losses might reduce.

Originality/value

This is the first report about the investigation of effects of increasing flexibility of the cross-link by incorporating polyurethane compounds into a typical dimethylol dihydroxy ethylene urea durable press resin formulation.

Details

Pigment & Resin Technology, vol. 45 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 15 March 2021

Zulfiqar Ali Raza, Faiza Anwar and Sharjeel Abid

Chitosan is widely considered as a natural polymer and a diverse finish to impart antibacterial property and enhanced dye uptake of textiles. Herein, the authors have investigated…

Abstract

Purpose

Chitosan is widely considered as a natural polymer and a diverse finish to impart antibacterial property and enhanced dye uptake of textiles. Herein, the authors have investigated the feasibility of using chitosan/starch blend as a thickener in screen printing of cellulosic fabrics with some natural dyes.

Design/methodology/approach

The polymeric blend of chitosan/starch was prepared and used as a thickener for screen printing with three natural dye extracts, namely, Curcuma tinctoria (turmeric), Beta vulgaris (beet) roots and Lawsonia alba (henna) leaves on cellulosic fabrics like cotton and viscose. The viscosity and rheological properties of print paste as a fresh and after overnight shelving were examined. The influence of polymeric blends on cellulosic fabrics' print properties was inspected by determining their colorfastness, rubbing fastness, tensile strength and antibacterial activity.

Findings

The results depicted that chitosan/starch blend as printing thickener increased the shade depth with good wet and dry rubbing fastness for all the test natural dyes. The antibacterial activity of resultant printed cellulosic fabrics was found to be satisfactory against broad-spectrum bacterial strains.

Practical implications

This study's outcome is the development of chitosan blend thickeners to print the cellulosic fabrics with indigenous natural dyes.

Originality/value

The authors found no previous report on the synthesis of chitosan-based antibacterial blend thickeners with three distinct natural dyes and their application in screen printing of native and regenerated cellulosic fabrics of cotton and viscose, respectively.

Details

International Journal of Clothing Science and Technology, vol. 33 no. 6
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 15 September 2022

Saima Habib, Farzana Kishwar and Zulfiqar Ali Raza

The purpose of this study is to apply silver nanoparticles on the cellulosic fabric via a green cross-linking approach to obtain antibacterial textiles. The cellulosic fabrics may…

Abstract

Purpose

The purpose of this study is to apply silver nanoparticles on the cellulosic fabric via a green cross-linking approach to obtain antibacterial textiles. The cellulosic fabrics may provide an ideal enclave for microbial growth due to their biodegradable nature and retention of certain nutrients and moisture usually required for microbial colonization. The application of antibacterial finish on the textile surfaces is usually done via synthetic cross-linkers, which, however, may cause toxic effects and halt the biodegradation process.

Design/methodology/approach

Herein, we incorporated citrate moieties on the cellulosic fabric as eco-friendly crosslinkers for the durable and effective application of nanosilver finish. The nanosilver finish was then applied on the citrate-treated cellulosic fabric under the pad-dry-cure method and characterized the specimens for physicochemical, textile and antibacterial properties.

Findings

The results expressed that the as-prepared silver particles possessed spherical morphology with their average size in the nano range and zeta potential being −40 ± 5 mV. The results of advanced analytical characterization demonstrated the successful application of nanosilver on the cellulosic surface with appropriate dispersibility.

Practical implications

The nanosilver-treated fabric exhibited appropriate textile and comfort and durable broad-spectrum antibacterial activity.

Originality/value

The treated cellulosic fabric expressed that the cross-linking, crystalline behavior, surface chemistry, roughness and amphiphilicity could affect some of its comfort and textile properties yet be in the acceptable range for potential applications in medical textiles and environmental sectors.

Details

Pigment & Resin Technology, vol. 53 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 October 2018

Zulfiqar Ali Raza, Faiza Anwar, Irshad Hussain, Sharjeel Abid, Rashid Masood and Hafiz Shahzad Maqsood

This study aimed to present fabrication of novel poly(lactic acid) (PLA) mediated chitosan nanoparticles (CNPs) and their impregnation on cotton fabric for enhanced antibacterial…

Abstract

Purpose

This study aimed to present fabrication of novel poly(lactic acid) (PLA) mediated chitosan nanoparticles (CNPs) and their impregnation on cotton fabric for enhanced antibacterial and physical properties.

Design/methodology/approach

The PLA-CNPs were characterized using scanning electron microscopy, energy dispersive x-ray spectroscopy, Fourier transform infrared (FTIR) spectroscopy and zeta size analysis. The prepared PLA-CNPs were impregnated on cotton fabric via pad-dry-cure method. The finished cotton fabric was then characterized for its antibacterial activity, functional and other physical textile properties.

Findings

The spectral and optical properties demonstrate that the NPs expressed spherical morphologies with an average particle diameter of 88.02 nm. The antibacterial activity of treated fabrics ranged between 75 and 90 per cent depending on the concentration of PLA-CNPs.

Practical implications

Because of enhanced awareness and desire for ecofriendly products, the use of sustainable and functional textiles is increasing day by day. For the said purpose, industries are using different chemical treatments to achieve desired end functionality. Currently, different synthetic antibacterial agents are in practice, but they lack sustainable approach to save the environment. In this study, the researchers have developed PLA mediated CNPs for sustainable antibacterial and physical properties of treated cotton fabric.

Originality/value

To the best of the authors’ knowledge, this is first attempt to fabricate PLA-incorporated CNPs for application on cotton fabric followed by a detailed characterization.

Details

Pigment & Resin Technology, vol. 48 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 May 2018

Amna Siddique, Tanveer Hussain, Waseem Ibrahim, Zulfiqar Ali Raza and Sharjeel Abid

This paper aims to investigate the feasibility of potassium permanganate (KMnO4) as an efficient discharging agent for indigo-dyed denim fabrics and identification of key…

Abstract

Purpose

This paper aims to investigate the feasibility of potassium permanganate (KMnO4) as an efficient discharging agent for indigo-dyed denim fabrics and identification of key variables for its cost-efficient implication.

Design/methodology/approach

Response surface methodology, which is a statistical technique for the optimization of process variables, was used to study the effect of three key variables, i.e. KMnO4 concentration, printing paste pH and reaction time on whiteness and strength of discharged printed fabric. Regression models were developed to predict response variables, i.e whiteness, tensile strength and tear strength of discharge printed denim.

Findings

It was found that some captivating discharge printing effects could be produced using appropriate KMnO4 concentration, printing paste pH and reaction time without any significant loss in the fabric strength.

Practical implications

This study highlights the practical implication of KMnO4 to be used as a safe and effective discharging agent under different conditions and to optimize the parameters using statistical analysis to ensure minimum loss in textile properties. The use of denim has evolved over the decades from a rough and tough workwear to highly fashionable apparel. Various dry and wet processing techniques have been introduced in recent years for the value-addition of denim – discharge printing is one of them. As lab to bulk reproducibility requires some sort of experience and adjustments in main parameters, the practical feasibility on the bulk scale should be adjusted in advance by means of the lab scale experimentation.

Originality/value

The KMnO4 oxidation process is considered eco-friendly because manganese dioxide, which is formed when permanganate is reduced, can be recycled. Thus, the use of KMnO4 can be considered as an eco-friendly safe process for the discharging of indigo dyes.

Details

Pigment & Resin Technology, vol. 47 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

1 – 10 of 30