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1 – 4 of 4A. Laurentowska, F. Ciesielczyk, K. Siwińska‐Stefańska and T. Jesionowski
The purpose of this paper is to obtain ZnO‐SiO2 oxide composites of low bulk density, high homogeneity and consisting of the smallest possible particles. The optimum parameters of…
Abstract
Purpose
The purpose of this paper is to obtain ZnO‐SiO2 oxide composites of low bulk density, high homogeneity and consisting of the smallest possible particles. The optimum parameters of precipitation of ZnO‐SiO2 oxide composites impregnated with natural latex rubber were established. The formation and impregnation the ZnO‐SiO2 oxide composites were made to occur simultaneously.
Design/methodology/approach
The influence of non‐ionic surfactants added during the precipitation process on the physico‐chemical properties of the oxide systems obtained was investigated. The products were characterised by determination of bulk density, absorption capacities of water and paraffin oil, particle size distribution (applying NIBS and laser diffraction methods), as well as SEM observations of surface morphology and microstructure. Moreover, the colorimetric characteristics of the oxide composites obtained and sedimentation profiles in water were analysed. Energo‐dispersive microanalysis of the products enabled determination of the content of ZnO and SiO2. The surface area (BET) and the size and volume of pores were also estimated.
Findings
Modification of the oxide composites with nonylphenylpolyoxyethyleneglycol ethers was found to improve the basic physico‐chemical parameters of the ZnO‐SiO2 hybrid systems and to change the character of its surface to become more hydrophobic. The conditions in which samples with the best properties were obtained were concluded to be optimum.
Research limitations/implications
Only the selected non‐ionic surfactants were applied as modifying agents of ZnO‐SiO2.
Practical implications
There is a possible application of ZnO‐SiO2 oxide composites as activators of rubber compounds and barrier materials in textiles.
Originality/value
The proposed method of ZnO‐SiO2 oxide composite synthesis in the process of precipitation with simultaneous modification with non‐ionic surfactants provides products with desirable dispersive‐morphological parameters and a hydrophobic surface character.
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Thien Vuong Nguyen, Vy Do Truc, Tuan Anh Nguyen and Dai Lam Tran
This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First…
Abstract
Purpose
This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First, cerium nitrate inhibitors are absorbed on the surface of various oxide nanoparticles. Thereafter, epoxy nanocomposite coatings have been fabricated on carbon steel substrate using these oxide@Ce nanoparticles as both nano-fillers and nano-inhibitors.
Design/methodology/approach
To evaluate the impact of oxides@Ce nanoparticles on mechanical properties of epoxy coating, the abrasion resistance and impact resistance of epoxy coatings have been examined. To study the impact of oxides@Ce nanoparticles on anti-corrosion performance of epoxy coating for steel, the electrochemical impedance spectroscopy has been carried out in 3% NaCl solution.
Findings
ZnO@Ce3+ and SiO2@Ce3+ nanoparticles provide more enhancement in the epoxy pore network than modification of the epoxy/steel interface. Whereas, Fe2O3@Ce3+ nanoparticles have more to do with modification of the epoxy/steel interface than to change the epoxy pore network.
Originality/value
Incorporation of both oxide nanoparticles and inorganic inhibitor into the epoxy resin is a promising approach for enhancing the anti-corrosion performance of carbon steel.
Amirul Syafiq, Lilik Jamilatul Awalin, Syukri Ali and Mohd Arif
The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create…
Abstract
Purpose
The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.
Design/methodology/approach
TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.
Findings
T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.
Research limitations/implications
The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.
Practical implications
The developed coating shows high potential for glass window application.
Originality/value
The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.
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Amirul Syafiq, Nasrudin Abd. Rahim, Vengadaesvaran Balakrishnan and A.K. Pandey
This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium…
Abstract
Purpose
This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium carbonate (nano-CaCO3) and titanium dioxide (TiO2).
Design/methodology/approach
The synthesis method of PDMS/nano-CaCO3-TiO2 is based on sol-gel process. The crosslinking between PDMS and nanoparticles is driven by the covalent bond at temperature of 50°C. The 3-Aminopropyltriethoxysilane is used as binder for nanoparticles attachment in polymer matrix. Two fabrication methods are used, which are dip- and spray-coating methods.
Findings
The prepared coated glass fulfilled the requirement of standard self-cleaning and fog-resistance performance. For the self-cleaning test BS EN 1096-5:2016, the coated glasses exhibited the dust haze value around 20%–25% at tilt angle of 10°. For the antifog test, the coated glasses showed the fog haze value were below 2% and the gloss value were above 85%. The obtained results completely achieved the standard antifog value ASTM F659-06 protocol.
Research limitations/implications
Findings will provide an infrastructure support for the building glass to enhance building’s energy efficiency, cleaning performance and friendly environment.
Practical implications
This study proposed the simple synthesis method using hydrophobic polymer and nano-CaCO3 and nano-TiO2, which can achieve optimum self-cleaning property at low tilt angle and fog-resistance performance for building glass.
Social implications
The research findings have high potential for building company, cleaning building company and government sector. The proposed project capable to reduces the energy consumption about 20% per annum due to labor cost, time-consuming and safety during manual cleaning.
Originality/value
The novel method to develop self-cleaning coating with fog-resistance using simple synthesis process and fabrication method for building glass application.
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