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Article
Publication date: 20 April 2022

Walaa M. Abd El-Gawad and Wael Mohamed Abdelmaksoud

This study aims to investigate the possibility of synthesizing cobalt doped willemite ceramic blue pigment by using Egyptian white sand as environmental and economical raw…

Abstract

Purpose

This study aims to investigate the possibility of synthesizing cobalt doped willemite ceramic blue pigment by using Egyptian white sand as environmental and economical raw material for multi-applications in coatings and inks.

Design/methodology/approach

After the synthesis process, the prepared blue pigment was characterized via X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray analysis technique. Then the blue pigment was integrated into both coating and ink formulations. The effect of the prepared multifunctional coatings on corrosion resistance and thermal stability was evaluated using different standard tests. Also, the effect of inclusion of blue pigment in flexographic printing ink formulation was done.

Findings

The results showed that the coating containing the cobalt doped willemite blue pigment offered good anticorrosive performance and high thermal stability. Additionally, the presented results revealed that integration of the blue pigment in flexographic printing ink formulation enhanced fineness, gloss, viscosity and color more than the commercial one “FX 430–201.”

Originality/value

In conclusion, relied on the eco-friendly principle which can be regarded as an economic and green strategy, it can be obtained that this new pigment can provide good multifunctions such as corrosion resistance and thermal stability in coatings and good fineness, gloss, viscosity and color in inks which can enable them to be widely applied in different industries.

Details

Pigment & Resin Technology, vol. 52 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 May 2020

Beata Synkiewicz-Musialska

The purpose of this paper is to report on fabrication procedure and present microstructure and dielectric behavior of willemite ceramic material with addition of 5% Li2CO3 as a…

Abstract

Purpose

The purpose of this paper is to report on fabrication procedure and present microstructure and dielectric behavior of willemite ceramic material with addition of 5% Li2CO3 as a sintering aid.

Design/methodology/approach

The samples were fabricated by ball milling of the ceramic powders, preparation of granulate and pressing and co-firing using temperature profile based on heating microscope observation. The dielectric properties of the material were measured by impedance spectroscopy (Hz-MHz), transmission method (GHz) and time domain spectroscopy (THz). The composition and microstructure of the material were investigated using X-ray diffraction, scanning electron microscopy and energy-dispersive spectroscopy analysis. Ceramic powder was used to fabricate a green tape and low temperature co-fired ceramics (LTCC) multilayer structures, which in the next steps of the research were examined at the angle of cooperation with conductive pastes, strength and geometric repeatability.

Findings

The fabricated material showed low sintering temperature (920°C–960°C), low dielectric constant 6.2–6.34 and low dissipation factor at the level of 0.004–0.007. As LTCC material, willemite with 5% Li2CO3 addition showed good compatibility with AgPd conductive paste.

Originality/value

Search for new materials with low dielectric constant, applicable in LTCC technology, and development of their fabrication procedure are important tasks for the progress in modern microwave circuits.

Details

Microelectronics International, vol. 37 no. 2
Type: Research Article
ISSN: 1356-5362

Keywords

Article
Publication date: 7 February 2022

Beata Synkiewicz-Musialska, Dorota Szwagierczak, Jan Kulawik and Elżbieta Czerwińska

This paper aims to report on fabrication procedure and presents microstructure and dielectric behaviour of LiZn0.92Cu0.08PO4 ceramic material with Li2CO3 as a sintering aid.

Abstract

Purpose

This paper aims to report on fabrication procedure and presents microstructure and dielectric behaviour of LiZn0.92Cu0.08PO4 ceramic material with Li2CO3 as a sintering aid.

Design/methodology/approach

Substrates based on LiZn0.92Cu0.08PO4 with Li2CO3 addition were prepared via solid-state synthesis, doping, milling, pressing and sintering. Characterization of the composition, microstructure and dielectric properties was performed using X-ray diffractometry, energy dispersive spectroscopy, scanning electron microscopy, impedance spectroscopy in the 100 Hz to 2 MHz range and time-domain spectroscopy in the 0.1–3 THz range.

Findings

Doped LiZnPO4 ceramic, which exhibits a low dielectric constant of 5.9 at 1 THz and low sintering temperature of 800 °C, suitable for low temperature co-fired ceramics (LTCC) technology, was successfully prepared. However, further studies are needed to lower dielectric losses by optimising the doping level, synthesis and sintering conditions.

Originality/value

Search for new low dielectric constant materials applicable in LTCC technology and optimization of processing are essential tasks for developing modern microwave circuits. The dielectric characterization of doped LiZnPO4 ceramic in the terahertz range, which was performed for the first time, is crucial for potential millimetre-wave applications of this substrate material.

Details

Microelectronics International, vol. 39 no. 4
Type: Research Article
ISSN: 1356-5362

Keywords

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