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The aim of this research is to study the role and formation of hydration products particularly crystalline portlandite Ca(OH)2 in MWCNT-reinforced concrete at 28 days. Concrete is the largest manufactured building material in world in which cement, sand aggregates and water cement ratio plays governing role. Water–Cement ratio decides it strength, usage, serviceability and durability. As strength of concrete depends on formation of crystalline hydrates; therefore, water–cement ratio can alter formation of hydrates also. Unfortunately, concrete is the most brittle material and to overcome brittleness of conventional concrete is tailored with some fibers. Till now, multiwalled carbon nano tubes are the most tensile and strongest materials discovered. Addition of multiwalled carbon nano tubes changes basic properties of conventional concrete. Therefore, it is important to evaluate formation of crystalline hydrates in multiwalled carbon nano tube–reinforced concrete by micro structure analysis.

Till now, multiwalled carbon nano tube–reinforced concrete has not been analyzed at micro structure level. To accomplish the objective, four concrete mixes with 0.45, 0.48, 0.50 and 0.55 water–cement ratio having 0.5 and 1% multiwalled carbon nano tubes incorporated by weight of cement, respectively. For hardening property analysis, compressive strength was obtained by crushing cubes; flexural strength was obtained by three-point loading; and split tensile strength was obtained by splitting cylindrical specimens. For analyzing role and formation of crystalline portlandite Ca(OH)2 hydrates, X-ray diffraction test was conducted on 75-µ dust of each mix. Scanning electron microscopy analysis was performed on fractured samples of crushed cubes of multiwalled carbon nano tube–reinforced concrete samples to check aggloremation.

It was observed multiwalled carbon nano tubes successfully enhanced compressive strength, flexural strength and split tensile strength by 8.89, 5.33 and 28.90%, respectively, in comparison to reference concrete at 0.45 water–cement ratio and 0.5% multiwalled carbon nano tubes by weight of cement. When its content was increased from 0.5 to 1% by weight of cement compressive strength, flexural strength and split tensile strength diminished by 2.04, 0.32 and 1.18%, respectively, at 0.45 water–cement ratio. With the increment of water–cement ratio, overall strength decreased in all mixes, but in multiwalled carbon nano tube–reinforced concrete mixes, strength was more than reference mixes. In reference, concrete at 0.45 water–cement ratio crystalline portlandite Ca(OH)2 crystals are of nano metre size, but in carbon nano tube–reinforced concrete mix having 0.45 water–cement ratio and 0.5% multiwalled carbon nano tubes by weight of cement, its size is much smaller than reference mix, thereby enhancing mechanical strength. In reference, concrete at 0.55 water–cement ratio size of crystalline portladite Ca(OH)2 crystals is large, but with incorporation of multiwalled carbon nano tubes, their size reduced, thereby enhancing mechanical strength of carbon nano tube–reinforced concrete having 0.55 water–cement ratio and 0.5 and 1% multiwalled carbon nano tubes by weight of cement, respectively. Also at 1% multiwalled carbon nano tubes by weight of cement, agglomeration and reduction in formation of crystalline portlandite Ca(OH)2 crystals were observed. Multiwalled carbon nano tubes effectively refine pores and restrict propagation of micro cracks and act as nucleation sites for Calcium-Silicate-Hydrate phase. Geometry of crystalline axis of fracture for portlandite Ca(OH)2 crystals is altered with incorporation of multiwalled carbon nano tubes. Crystalline portlandite Ca(OH)2 crystals and bridging effect of multiwalled carbon nano tubes is governing factor for enhancing strength of multiwalled carbon nano tube reinforced concrete.

Multiwalled carbon nano tube–reinforced concrete can be used to make strain sensing concrete.

Change in geometry and size of axis of fracture of crystalline portladite Ca(OH)2 crystals with incorporation of multiwalled carbon nano tubes.

Hardened cement paste is a heterogeneous system resulting from the grouping of particles, films, microcrystals and other solid structural elements bounded in a porous mass. The cement paste microstructure must be understood firstly due to its influence on concrete properties. The behaviour of concrete greatly depends on the conformation of localised special structures rather than on general structures found in the mass cement paste. The objective of this paper was to study the cement paste microstructure, as a function of the water–cement ratio, in order to interpret the variations of the steel–mortar bond strength and the developing of the corrosion process in steel–mortar specimens kept in tap water and 3 percent sodium chloride solutions for 1 year. A description of the steel–mortar interface was also provided.

The growing quantity of waste is a worrying reality that has resulted in environmental sustainability challenges. Waste paper sludge (WPS) in large quantities from paper mill industry are produced every year. Their disposal in landfills, in general, pollutes the environment. Cement manufacture also contributes to global warming by emitting carbon dioxide. As a result, a novel use of industrial wastes as a supplemental cementitious ingredient in concrete formulation can help to mitigate the environmental problem. This paper aims to study the possibility of usage of WPS as partial replacements of cement for sustainable development of concrete.

This study aims at testing the mechanical properties of concrete that has been mixed with WPS. Between 5% and 20% of the weight of cement, WPS was used to substitute it. The water binder ratios of 0.55, 0.50, 0.45 and 0.42 were all considered for an experiment to better understand the impact of WPS on concrete. In terms of workability, density, water absorption (WA), compressive strength (CS) and flexural strength (FS), concrete mixtures were created, tested and compared to traditional concrete mixes.

According to the findings, the initial and final setting times of the concrete mixtures were both significantly delayed, and the workability and density of the concrete mixtures were both significantly lowered at all water binder ratios and replacement levels. Both compressive and FS of concrete made with WSP declined significantly at all water binder ratio. Substitution of cement by WPS enhanced the WA of all the concrete mixes. The mechanical performance of concrete mixtures that were made with a replacement level of 5% exhibited noticeable improvements. Whereas the more is the replacement levels the more the loss in the mechanical properties were noted. The ideal replacement levels for the WPS are up to 5% only.

This paper contributes to the literature by exploring the ecological and sustainable effects of using WPS in construction materials.

This paper aims to assess the suitability of cement combination containing CEM I, fly ash, silica fume and metakaolin for durability design against carbonation-induced corrosion in concrete.

Cube compressive strengths at 28 days and accelerated carbonation depths at 28 days and at various exposure ages were determined at the water/cement ratios of 0.35, 0.50 and 0.65. To assess their suitability for carbonation-induced corrosion, the material costs and embodied carbon dioxide (eCO₂) contents of the concretes at equivalent performance were compared.

Cement combination concretes achieved equal carbonation resistance with CEM I at higher compressive strengths, lower water/cement ratios and higher cement contents. The comparison of the concretes, at equivalent performance, based on the carbonation-induced corrosion exposure classes XC3 and XC4 (Table A.4 of BS 8500-1), shows that ternary and more binary cement concretes have lower costs and eCO₂ contents than those recommended in Table A.6 of BS 8500-1.

This analysis is limited to a working life of 50 years. Further research is needed to verify the suitability of the cement combinations for a working life of 100 years and for the other aspects of durability design covered in BS 8500.

Cement combination concretes have lower eCO₂ content. Hence, when they are cheaper than CEM I concrete at equivalent performance, they would make concrete construction more economic and environmentally compatible.

This research suggests the inclusion of metakaolin and ternary cement combination concretes in BS 8500 for durability design against carbonation-induced corrosion.

The purpose of this paper is to investigate the mechanical properties changing of geopolymer cement under different brine salinity.

Geopolymer Cement of Class F Fly Ash and Class G Cement slurries were prepared according to API RP 10B. The optimum alkaline activator/cement and water/cement ratio of 0.44 was used for geopolymer and Class G cement samples, respectively. The alkaline activator was prepared by mixing the proportion of Sodium Hydroxide (NaOH) solutions of 8 M and Sodium Silicate (Na2SiO3) using ratio of 1:2.5 by weight. The slurries were cured for 24 hours at 130^oC and 3,000 psi in HPHT Curing Chamber followed by coring process. Both cement sample were immersed in brine water salinity up to 28 days with different brine salinity up to 30 per cent of NaCl. The mechanical properties were investigated using OYO Sonic Viewer-SX and Uniaxial Compressive Strength. The surfaces of the cement samples were extracted for Scanning Electron Microscope (SEM) and EDS tests to evaluate the morphology and chemical compositions of the cured samples.

The paper shows that geopolymer samples experiences strength reduction in brine water but the reduction rate of geopolymer is about half of the Ordinary Portland cement based oil well cement. The finding was also verified by SEM and EDS result.

This paper investigates the mechanical property changes of emerging geopolymer cement due to different water salinity. The results provide potential application of geopolymer cement for oil well cementing.

The purpose of this paper is to investigate the effect of an admixture, Swine-waste Bio-char (SB), on the water absorption characteristics of cement pastes.

The effect of SB percentages, heat treatment temperatures, water/binder ratios, and age on the water absorption percentages (WAPs) of SB modified cement pastes were investigated using scanning electron microscopy-energy dispersive spectra, FTIR, Brunauer-Emmett-Teller, and laboratory experiments.

The WAPs of cement pastes with SBs produced at the low treatment temperature (LTT) of 340°C and 400°C were significantly lower (p<0.01) than pastes with SBs produced at the high treatment temperature (HTT) of 600°C and 800°C. This was attributed primarily to the more dominant presence of hydrophobic alkyl surface groups from non-volatilized matter in LTT-SBs. This had also resulted in lower surface areas and pore volumes in LTT-SBs. As a result of the volatilization of these labile hydrophobic groups at HTT, HTT-SBs were more hydrophilic and had higher surface areas and pore volumes. Consequently, HTT-SB pastes had higher WAPs and no significant differences (p<0.05) existed between HTT-SB pastes and control pastes. Also, low water/binder ratios and aging reduced water absorption of SB modified cement pastes.

LTT-SBs reduce water absorption and could reduce concrete deterioration; and as such, associated building repair, maintenance, and adaptation costs. Notably, reductions in concrete water absorption will extend the service life of concrete buildings and infrastructures, particularly in unfavorable environmental conditions. The observed benefits are tempered by the current lack of information on the effects of SB on compression strength, workability, and other durability properties.

SB utilization in concrete buildings will enhance swine-waste disposal and reduce negative environmental impacts on swine farming communities; consequently, improving their quality of life.

Current bio-char research is focused on plant-derived bio-char toward soil remediation and contaminant removal, with very limited applications in concrete. This research advances knowledge for developing livestock-derived bio-char, as a PCRM, toward more sustainable and durable concrete structures.

The purpose of this paper is to investigate the influence of cement/sand ratio on behaviour of cement mortar.

Literature review was used to confirm that the cement/sand ratio have influence on the mortar strength and that its influence is not very studied. The literature points out also that the constitutive model of mortar is very important in the structural design of masonry but it has not been investigated much.

The results of study allow to forecast the mortar strength by the cement/sand ratio when the water/cement ratio is fixed (0.50). Besides, the obtained experimental results allow defining a constitutive model for sand mortar.

Other experiments would be proper to extend the research field.

The findings are of particular importance to mix design of cement mortar and to structural design of masonry. In fact, for mortar in the practices, there are no constitutive equations to use in the structural calculation, and so, normally the engineers use the constitutive equations of concrete (very rough). The idea is to find constitutive equations that, using simple and economic tests, allow to engineers to model more correctly the realty.

There are few studies which try to investigate the relationship between the behaviour of cement mortar and cement/sand ratio, as well as to study constitutive model of cement mortar. This paper contributes to bridging that gap.

This paper aims to investigate the 28-day compressive strength of concrete produced with aggregates from different sources.

Coarse aggregates were crushed granite and natural local stones mined from Umunneochi, Lokpa and Uturu, Isuakwato, respectively, in Abia State, Nigeria. Fine aggregate (river sand) and another coarse aggregate (river stone) were dredged from Otammiri River in Owerri, Imo State, Nigeria. The nominal mix ratios were 1:1:2, 1:2:4 and 1:3:6, whereas the respective water–cement ratios were 0.45, 0.5, 0.55 and 0.6.

The compressive strength of granite concrete, river stone concrete and local stone concrete ranged 17.79-38.13, 15.37-34.57 and 14.17-31.96 N/mm², respectively. Compressive strength was found to increase with decreasing water–cement ratio and increasing cement content.

Granite concrete should be used in reinforced-concrete construction, especially when a cube compressive strength of 30 N/mm² or higher is required.

Granite concrete exceeded the target compressive strength for all the concrete specimens, whereas river stone concrete and local stone concrete failed to achieve the target strength for some mix proportions and water–cement ratios.

This paper describes the effect of factors on the strength characteristics of cement treated clay from laboratory tests performed on cement mixed clay specimens. It is considered that several factors such as soil type, sample preparing method, quantity of binder, curing time, etc. can have an effect on strength characteristics of cement stabilized clay. A series of unconfined compression tests have been performed on samples prepared with different conditions. The results indicated that soil type, mixing method, curing time, dry weight ratio of cement to clay (Aw), and water‐clay to cement (wc/c) ratio were main factors which can have an influence on unconfined compressive strength, modulus of elasticity, and failure strain of cement stabilized clay. Unconfined compressive strength of soil‐cement samples prepared from dry mixing method was higher than those prepared from wet mixing method.

The purpose of this paper is to obtain a theoretical model to analyze the effective modulus of cement paste in early age, including the setting and hardening periods, which has a great impact on mechanical properties of concrete structure.

Based on a power law approximation, a generalized mixture rule is used to construct the relationship between the effective modulus and hydration degree. In addition, a new model of the dependence of the Poisson's ratio on the hydration degree and water cement ratio is proposed for cement paste in early age.

The effective Young's modulus, storage shear modulus and Poisson's ratio of cement pastes with different water cement ratios and hydration degrees are studied by the presented model. The model can be applied to simulate the behavior of early-age cement paste at both the setting and the hardening periods. Compared with the experimental results, the correctness of the model is validated.

This work presents a mathematical model that can effectively estimate the effective Young's modulus and Poisson's ratio in the hardening period, and the storage shear modulus in the setting period of cement pastes.