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Urethane Acrylate Oligomer with 100% solids was synthesised and characterised in order to study the application in electron beam curing with varying ratio of Trimethylol propane triacrylate (TMPTA). The purpose of this paper is to study effect of TMPTA addition on the crosslink density and different coating properties.

Polyester polyol was synthesised by reacting single diacid, adipic acid (AA), with Pentaerythritol (PENTA) and 1,6‐hexanediol (HD). Further, Urethane acrylate resin was synthesised by using Isophorone diisocyanate (IPDI), hydroxy ethyl acrylate (HEA) and Polyester polyol. The polyester polyol and urethane acrylate oligomer were characterised by 1H NMR, 13C NMR, FTIR and GPC. Further, TMPTA was added as a crosslinker to the urethane acrylate oligomer and cured by electron beam radiation. The cured UA films having varying concentration of TMPTA were employed to evaluate thermal property, contact angle analysis, mechanical and chemical properties.

The obtained results showed improvement in their chemical properties, mechanical properties, thermal properties and water contact angle at 20% of TMPTA iconcentration. The TMPTA also reduced the dose required for the curing.

The resin can be synthesised from different isocyanates as TDI, MDI and HMDI, etc. The study can also be done with different multi or mono functional monomers such as methacrylate, hexanediol diacrylate, ethylene glycol diacrylate, etc.

The paper provides the better solution to reduce the cost of the electron beam radiation required for the curing.

The method presented in the paper could be very useful for controlling environmental pollution; as the conventional method of curing releases volatile organic compounds (VOC).

In this paper, urethane acrylate and TMTPA cured with electron beam are shown to offer good coating properties. A high‐solid urethane acrylate coating would find numerous industrial applications in surface coatings.

The purpose of this work was to perform a systematic study on the effect of formulation on the physical and mechanical properties of ultaviolet (UV) curable urethane acrylate resins. In addition, the authors wanted to derive mathematical formula for the prediction of physical and mechanical properties for the aforementioned system.

The experiments were carried out based on mixture experimental design to determine the effect of different multifunctional acrylates (i.e. 1,6-hexanediol diacrylate (HDDA), tripropylene glycol diacrylate (TPGDA), trimethyolpropane triactylate (TMPTA)) concentration on the physical and mechanical properties of a UV curable polyurethane acrylate system. The urethane oligomer was synthesized and characterized by the research team. Microhardness, adhesion strength and scratch resistance of the cured films were evaluated as the physical and mechanical properties.

The results revealed that the resin and TMPTA concentrations had the most significant effects on the microhardness property. Adhesion strength of the films showed a linear trend with respect to all variables. Moreover, all components also had a significant and complex influence on the scratch resistance of the cured systems. In addition, mathematical equations proposed by mixture experimental design were derived for all the mentioned properties.

Other multifunctional acrylate monomers (i.e. more than three functional) can be used in the formulations. The kinetics of the curing can affect on the network formation and consequently on the properties of the cured films.

The obtained results can be used by the researchers who are active in the field of structure-property relationship of polymers and surface coatings. The reported data and the mathematical equations can also be used for the formulating of an appropriate formulation based on a specific application.

A systematic and statistical-based approach, i.e. mixture experimental design, was used to evaluate the effect of formulation on some of the properties of a UV curable polyurethane acrylate system. A urethane oligomer and three different multifunctional acrylate monomers as reactive diluents were used in the formulations. Noteworthy to mention that several mathematical models were derived by using analysis of variance for the prediction of the properties studied in this system.

Summarizes the different techniques for the removal of conformal coatings from printed circuit boards and other electronic assemblies. Addresses each of the four techniques for the removal of conformal coating (thermal, mechanical, chemical and abrasive), along with how they work with each type of conformal coating (urethane, acrylic, silicone, epoxy, parylene and UV curable coatings). Also provides summaries for the removal times and clean up for each technique.

This paper aims to synthesize new terpolymers by the emulsion polymerization technique composed of acrylamide-based polyurethane monomers (TPM and MPM) with different vinyl acetate copolymer systems, such as vinyl acetate/butyl acrylate (VAc/BA), vinyl acetate/ethylhexyl acrylate (VAc/2-EHA) and vinyl acetate/vinyl ester of versatic acid (VAc/VEOVA 10) systems. The performance of the prepared terpolymers as binders in emulsion coatings and textile industries was investigated and compared with the analogous commercial ones.

New waterborne polyurethane-vinyl ester-vinyl acetate terpolymers with high solid content and nano-scale emulsions have been successfully synthesized in two steps. The polyurethane oligomers were prepared by the prepolymer method as the first step. The second step involved polymerization with different vinyl monomers. The synthesized terpolymers were characterized using FTIR, scanning electron microscope, thermogravimetric analysis, minimum film forming temperature and particle size analyzer methods.

The synthesized emulsion terpolymers have shown small particle sizes averaged of 70 nm and a narrow distribution range, along with good mechanical, thermal and chemical stabilities. The surface coating layers of the terpolymers also have some important in terms of smoothness, clarity and binding ability in water-based coating for up to 4425 scrub cycles at 30 GU. Further, a high potential application textile printing was achieved at high solid content of 47–50%.

The effects of different isocyanates and vinyl monomers on the properties of obtained emulsion coatings have been studied. The improvement consequences of the coating evaluation of the waterborne binders for emulsion paints have been described. The properties of polyester/cotton fabric print pigment printing of textiles appear to be most promising enhancements by using the prepared nanocomposites of PU-co-vinyl acetate-co-vinyl ester as waterborne binders. So that the prepared emulsions have the potential to replace solvent-based coatings as waterborne binders for both emulsion coating and textile printing applications.

Development of new radiation‐curable materials for the application in radiation curing technology is of significant importance. Most of the commercially available radiation‐curable resins are derived from synthetic raw materials. The synthesis of acrylated, epoxidised soybean oil (ESO) from ESO had been carried out by reacting acrylic acid with the oxirane group in ESO. The acrylated ESO products were characterised using a variety of analytical techniques. Thus, the oxygen value, the iodine value, the acid value and the infrared spectra of the acrylated ESO products were obtained. Pigmented acrylated ESO systems were prepared and found to cure on exposure to UV radiation.

Epoxy acrylate which is commercially utilized for UV curable coatings although has excellent adhesion, flexibility, hardness and chemical resistance, they lack in antimicrobial properties. Citric acid (CA) is economical as well as a bio-based compound which possess an antimicrobial activity. So, the purpose of this research investigation is the preparation of CA-based oligomer which can be further incorporated with epoxy acrylate and tri (propylene glycol) Diacrylate (TPGDA) to form uv curable coating and the study of its antimicrobial property.

A UV-curable unsaturated oligomer (CUV) was synthesized from CA and glycidyl methacrylate (GMA). The chemical structure of CUV was confirmed by FTIR, ¹H NMR, GPC, hydroxyl value, acid value and iodine value. Further, CUV was assimilated as an antimicrobial as well as crosslinking agent to copolymerize with epoxy acrylate oligomer and a series of UV-cured antimicrobial coatings were concocted by employing UV-curing machine. The consequence of varying the fraction of CUV on the mechanical, chemical, thermal and antimicrobial properties of UV-cured wood coatings was explored.

Results exhibited good mechanical, chemical and thermal properties. In addition, it was perceived that the zone of inhibition against S. aureus got enlarged with increasing content of CUV in the coating formulation.

The synthesized bio-based CUV reveals an extensive potential to ameliorate the antimicrobial properties of UV-curable coatings.

Zemid is a new line of reinforced mineral‐filled polyethylene resins. According to the company, these resins can be processed by all conventional methods and have exceptional properties, especially in low temperature applications. They are said to be unique in retaining virtually all their stiffness/toughness performance at temperatures as low as −40°C. This capability makes the resins suitable for many winter applications, including snow moving equipment and recreational products.

New ground was broken this year when the Annual Paint Industries Show was held for the first time in Canada, the location being the Place Bonaventure in Montreal, a city in which the main language being French added an extra interest.

In this paper the types of screen printing inks available for curing by ultra‐violet light are described. A comparison is made with conventional thermally cured inks and the author asserts that the current drive towards energy conservation and reduction in atmospheric pollution has been a powerful stimulus to the development of UV cured inks. The cost effectiveness of these inks is examined by reference to the energy required, operational costs, equipment, the ink itself and reject rates.

This study aims to present an architectural application of 4D-printed climate-adaptive kinetic architecture and parametric façade design.

This work investigates experimental prototyping of a reversibly self-shaping façade, by integrating the parametric design approach, smart material and 4D-printing techniques. Thermo-responsive building skin modules of two-way shape memory composite (TWSMC) was designed and fabricated, combining the shape memory alloy fibers (SMFs) and 3D-printed shape memory polymer matrices (SMPMs). For geometry design, deformation of the TWSMC was simulated with a dimension-reduced mathematical model, and an optimal arrangement of three different types of TWSMC modules were designed and fabricated into a physical scale model.

Model-based experiments show robust workability and formal reversibility of the developed façade. Potential utility of this module for adaptive building design and construction is discussed based on the results. Findings help better understand the shape memory phenomena and presented design-inclusive technology will benefit architectural communities of smart climate-adaptive building.

Two-way reversibility of 4D-printed composites is a topic of active research in material science but has not been clearly addressed in the practical context of architectural design, due to technical barriers. This research is the first architectural presentation of the whole design procedure, simulation and fabrication of the 4D-printed and parametrically movable façade.