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Article
Publication date: 5 October 2023

Minakshi Koundal, Ajay Kumar Singh and Chhaya Sharma

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

Abstract

Purpose

This paper aims to investigate the eco-friendly neodymium tartrate (NdTar) inhibitor for mild steel in sodium chloride (NaCl) solution.

Design/methodology/approach

The mild steel 1010 coupon was considered for the current study. Weight loss and the electrochemical methods were used to evaluate the inhibitory effects of neodymium chloride (NdCl3) and NdTar on mild steel in NaCl solution. Scanning electron microscopy, energy-dispersive X-ray analysis and attenuated total reflectance-Fourier transform infrared spectroscopy measurements were carried out to study the morphology and composition of the film, nature of deposits and corrosion products formed in test media on the corroded steel, with the objective of further analyzing the observed behavior of the two inhibitors.

Findings

Of the two, NdTar performs better than NdCl3 because it shields mild steel surfaces for longer. According to the results, when NdCl3 is present in a corrosive solution, the protective film only comprises Nd/Fe oxide/hydroxide/carbonate. However, when neodymium is coupled with the tartrate group (an organic group) and then added to the NaCl solution, the inhibitor film comprises both bimetallic complexes (Fe-Tar-Nd) and metal oxide/hydroxide/carbonate, which results in a more compact film and has higher inhibition efficiency.

Originality/value

This study evaluated the combined effects of inorganic and organic inhibitors with those of an inorganic inhibitor used alone for mild steel in NaCl solution.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 24 January 2024

Dexin Chen, Hongyuan He, Zhixin Kang and Wei Li

This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.

Abstract

Purpose

This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.

Design/methodology/approach

One-step electrodeposition is a versatile and simple technology to prepare superhydrophobic coatings on metal surfaces.

Findings

Preparing superhydrophobic coatings by one-step electrodeposition is an efficient method to protect metal surfaces.

Originality/value

Even though there are several technologies, one-step electrodeposition still plays a significant role in producing superhydrophobic coatings.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 18 December 2023

Yingying Li, Lanlan Liu, Jun Wang, Song Xu, Hui Su, Yi Xie and Tangqing Wu

The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils.

Abstract

Purpose

The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils.

Design/methodology/approach

The corrosion behavior of Q235 steel in saturated red and yellow soils was compared by weight-loss, SEM/EDS, 3D ultra-depth microscopy and electrochemical measurements.

Findings

Rp of the steel gradually increases and icorr gradually decreases in both the red and yellow soils with time. The Rp of the steel in the red soil is lower, but its icorr is higher than that in the yellow soil. The uniform corrosion rate, diameter and density of the corrosion pit on the steel surface in the red soil are greater than those in the yellow soil. Lower pH, higher contents of corrosive anions and high-valence Fe oxides in the red soil are responsible for its higher corrosion rates and local corrosion susceptibility.

Originality/value

This paper investigates the difference in corrosion behavior of carbon steel in saturated acidic red and yellow soils, which can help to understand the mechanism of soil corrosion.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 26 September 2023

Jiabo Chen, Xiaokai Guo, Hao Liu, Xuantong Lv, Shichuan Fan, Liankui Wu, Fahe Cao and Qingqing Sun

This study aims to discuss the influences of surface severe plastic deformation (S2PD) on the electrochemical corrosion, pitting corrosion, intergranular corrosion, stress…

Abstract

Purpose

This study aims to discuss the influences of surface severe plastic deformation (S2PD) on the electrochemical corrosion, pitting corrosion, intergranular corrosion, stress corrosion cracking of aluminum (Al) alloys and attempt to correlate the microstructural/compositional changes with the performances.

Design/methodology/approach

This study provides a novel gradient design of structure/composition caused by S2PD for the purpose of enhancing Al alloys’ corrosion resistance.

Findings

S2PD has a significant effect on corrosion behavior of Al alloys through tuning the grain size, residual stress, composition, grain boundary phase and second phase particle distribution.

Originality/value

Although Al alloys are known to form a protective Al2O3 film, corrosion is a major challenge for the longevity of Al structures across numerous industries, especially for the infrastructures made of high-strength Al alloys. Traditional strategies of improving corrosion resistance of Al alloys heavily relied on alloying and coatings. In this review, gradient design of structure/composition caused by S2PD provides a novel strategy for corrosion protection of Al alloys, especially in the enhancement of localized corrosion resistance.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 October 2023

Yuchen Xi, Qinying Wang, Xinyu Tan, Xingshou Zhang, Lijin Dong, Yuhui Song, Liyang Liu and Dezhi Zeng

The purpose of this work is to design the wire beam electrode (WBE) of P110 steel and study its corrosion behavior and mechanism under high temperature and pressure.

Abstract

Purpose

The purpose of this work is to design the wire beam electrode (WBE) of P110 steel and study its corrosion behavior and mechanism under high temperature and pressure.

Design/methodology/approach

Packaging materials of the new type P110 steel WBE and high pressure stable WBE structure were designed. A metallurgical microscope (XJP-3C) and scanning electron microscopy (EV0 MA15 Zeiss) with an energy dispersive spectrometer were used to analyze the microstructure and composition of the P110 steel. The electrochemical workstation (CS310, CorrTest Instrument Co., Ltd) with a WBE potential and current scanner was used to analyze the corrosion mechanism of P110 steel.

Findings

According to the analysis of Nyquist plots at different temperatures, the corrosion resistance of P110 steel decreases with the increase of temperature under atmospheric pressure. In addition, Rp of P110 steel under high pressure is maintained in the range of 200 ∼ 375 Ωcm2, while that under atmospheric pressure is maintained in the range of 20 ∼ 160 Ωcm2, indicating that the corrosion products on P110 steel under high pressure is denser, which improves the corrosion resistance of P110 steel to a certain extent.

Originality/value

The WBE applied in high temperature and pressure environment is in blank. This work designed and prepared a WBE of P110 steel for high temperature and pressure environment, and the corrosion mechanism of P110 steel was revealed by using the designed WBE.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 14 August 2023

Yuchen Xi, Qinying Wang, Yafei Wu, Xingshou Zhang, Lijin Dong, ShuLin Bai and Yi Yang

The purpose of this study is to investigate the crevice corrosion behavior and mechanism of laser additive manufacturing (LAM) nickel-based alloy under wedge-shaped crevice.

Abstract

Purpose

The purpose of this study is to investigate the crevice corrosion behavior and mechanism of laser additive manufacturing (LAM) nickel-based alloy under wedge-shaped crevice.

Design/methodology/approach

First, the opening size of the wedge-shaped crevice was designed to 0.1, 0.3 and 0.5 mm by controlling the thickness of silicon rubber and the double-side adhesive tape. Then, one side of the glass sheet was stuck on the silicon strip and keep the electrodes of Rows 1 and 2 outside the crevice as a reference, and the opposite side was stuck to the wire beam electrode by silica gel.

Findings

The current density with a maximum value of 5.7 × 10−6 A/cm2 was observed at the crevice opening of 0.5 mm, while the lowest value of 9.2 × 10−7 A/cm2 was found at the crevice opening of 0.1 mm. In addition, the corrosion resistance at the inside of the crevice is higher than that at the outside and the middle of the crevice. It means that the internal width of the wedge-shaped crevice tends toward 0, which hinders the migration of ions in the corrosive medium. The generation of corrosive products further reduce the crevice size to cause the inhibition of corrosion at the inside of the crevice as well.

Originality/value

The multilayer and multipath LAM component is prepared to show the complex microstructure, which made the corrosion behavior and mechanism at wedge-shaped crevice nondeterminacy.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 October 2023

Zhijie Yuan, Hao Wang, Rou Li, Jianxiao Mao and Hui Gao

This paper aims to investigate the equivalent relationship between accelerated corrosion tests and real environmental spectrum of suspenders in long-span suspension bridge…

Abstract

Purpose

This paper aims to investigate the equivalent relationship between accelerated corrosion tests and real environmental spectrum of suspenders in long-span suspension bridge considering multiple factors action.

Design/methodology/approach

Based on Faraday's law, corrosion current was used as a measure of metal corrosion, and the equivalent conversion relationship between laboratory environment and real service environment was established. The equivalent conversion method for bridge structural steel had been determined under different temperature, humidity, pH value and NaCl concentration conditions. The compilation of environmental spectra for large span bridges considering multiple factors and the principle of equivalent conversion have been proposed.

Findings

Environmental factors, including temperature, humidity, pH value and NaCl concentration, have significant impact on the corrosion degree of suspension steel wires, and only considering these two factors for equivalent conversion cannot accurately reflect the true service environment of the bridge. The 33.8-h salt spray accelerated corrosion test using the standard conditions can be equivalent to one year of suspenders corrosion in a real service environment.

Originality/value

The equivalent accelerated corrosion method for steel wires proposed in this study can effectively predict the corrosion degree of the suspenders, which has been verified to be correct and can provide theoretical guidance for the development of corrosion test plans for steel wires and engineering technical basis for anti-corrosion control and calendar life research of suspension bridge suspenders.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 25 August 2023

Xin Zhou, Wenbin Zhou, Yang Zheng Zhang, Meng-Ran Li, Haijing Sun and Jie Sun

This paper aims to study the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass.

Abstract

Purpose

This paper aims to study the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass.

Design/methodology/approach

The authors performed weight loss experiments, electrochemical experiments including the polarization curve and electrochemical impedance spectrum, corrosion morphology observation using scanning electron microscope (SEM) and atomic force microscope (AFM) and surface composition analysis via X-ray photoelectron spectroscopy (XPS) to analyze the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass by using quantum chemical calculation (Gaussian 09), molecular dynamics simulation (M-S) and Langmuir adsorption isotherm.

Findings

According to the results, imidazole-pyridine and its derivatives were found to be modest or moderately mixed corrosion inhibitors; moreover, they were spontaneously adsorbed on the metal surface in a single-layer, mixed adsorption mode.

Originality/value

The corrosion inhibition properties of pyrazolo-[1,2-a]pyridine and its derivatives on brass in sulfuric acid solution were analyzed through weight loss and electrochemical experiments. Moreover, SEM and AFM were simultaneously used to observe the corrosion appearance. Furthermore, XPS was used to analyze the surface. Then, Gaussian 09 and M-S were combined along with the Langmuir adsorption isotherm to investigate the corrosion inhibition mechanism of imidazole-[1,2-a]pyridine and its derivatives.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 13 December 2023

Zhenyu Ma, Yupeng Zhang, Xuguang An, Jing Zhang, Qingquan Kong, Hui Wang, Weitang Yao and Qingyuan Wang

The purpose of this study is to investigate the effect of nano ZrC particles on the mechanical and electrochemical corrosion properties of FeCrAl alloys, providing a beneficial…

Abstract

Purpose

The purpose of this study is to investigate the effect of nano ZrC particles on the mechanical and electrochemical corrosion properties of FeCrAl alloys, providing a beneficial reference basis for the development of high-performance carbide reinforced FeCrAl alloys with good mechanical and corrosion properties in the future.

Design/methodology/approach

Nano ZrC reinforced FeCrAl alloys were prepared by mechanical alloying and spark plasma sintering. Phases composition, tensile fractography, corrosion morphology and chemical composition of nano ZrC reinforced FeCrAl alloys were analyzed by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy, respectively. Microhardness and tensile properties of nano ZrC reinforced FeCrAl alloys were investigated by mechanical testing machine and Vickers hardness tester. Electrochemical corrosion properties of nano ZrC reinforced FeCrAl alloys were investigated by electrochemical workstation in 3.5 wt.% NaCl solution.

Findings

The results showed that addition of nano ZrC can effectively improve the mechanical and corrosion properties. However, excessive nano ZrC could decrease the mechanical properties and reduce the corrosion resistance. In all the FeCrAl alloys, FeCrAl–0.6 wt.% ZrC alloy exhibits the optimum mechanical properties with an ultimate tensile strength, elongation and hardness of 990.7 MPa, 24.1% and 335.8 HV1, respectively, and FeCrAl–0.2 wt.% ZrC alloy has a lower corrosion potential (−0.179 V) and corrosion current density (2.099 µA/cm2) and larger pitting potential (0.497 V) than other FeCrAl–ZrC alloys, showing a better corrosion resistance.

Originality/value

Adding proper nano ZrC particles can effectively improve the mechanical and corrosion properties, while the excessive nano ZrC is harmful to the mechanical and corrosion properties of FeCrAl alloys, which provides an instruction to develop high-performance FeCrAl cladding materials.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 February 2024

Ayad Alameeri, Gholamreza Abdollahzadeh and Seyedkomeil Hashemiheidari

This study aims to determine the effect of replacing a portion of the cement in the concrete mixture with silica fume (SF) on the corrosion resistance of reinforcing bars, the…

Abstract

Purpose

This study aims to determine the effect of replacing a portion of the cement in the concrete mixture with silica fume (SF) on the corrosion resistance of reinforcing bars, the compressive strength of concrete and the tensile strength of hook bars in both corroded and non-corroded external joints of structures. The external beam-column connection was studied because of its critical role in maintaining structural continuity in all three directions and providing resistance to rotation.

Design/methodology/approach

In external concrete joints, the bars at the end of the beams are often bent at 90° to form hooks that embed in columns. Owing to the importance of embedding distance and the need to understand its susceptibility to corrosion damage from chloride attack, a series of experiments were conducted on 12 specimens that accurately simulate real-site conditions in terms of dimensions, reinforcement and hook bars. SF was replaced with 10% and 15% of the weight of cement in the concrete mixture. To simulate corrosion, the specimens were subjected to accelerated corrosion in the laboratory by applying a low continuous current of 0.35 mA for 58 days.

Findings

The results revealed the effect of SF in improving the compressive strength of concrete, the pullout resistance of the hook bars and the corrosion resistance. In addition, it showed an apparent effect of the corrosion of reinforcing bars in reducing the bonding strength of hook bars with concrete and the effect of SF in improving this strength.

Originality/value

It was noted that the improvement of the results, achieved by replacing 10% of the weight of cement with SF, was significantly close to the results obtained by replacing 15% of the SF. It is recommended that an SF ratio of 10% be adopted to achieve the greatest economic savings.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

1 – 10 of 113