Search results

11 – 14 of 14
Article
Publication date: 16 March 2012

Nilgün Kızılcan and Özlem Tamküpeli Koşar

The purpose of this paper is to report the synthesis of resins having conducting and fluorescence properties, with carbazole and oligocarbazole with a one step method of in situ

Abstract

Purpose

The purpose of this paper is to report the synthesis of resins having conducting and fluorescence properties, with carbazole and oligocarbazole with a one step method of in situ modification of ketonic resin. Cyclohexanone‐formaldehyde (CFR), and acetophenone‐formaldehyde (AFR) resins were in situ modified with carbazole in the presence of sodium hydroxide.

Design/methodology/approach

Carbazole modified ketonic resins were synthesised by the condensation reaction of Cz, formaldehyde and ketone. Oligo carbazole was synthesised by redox reaction of carbazole and ceric ammonium nitrate (CAN). Then, for the in situ modification of oligo carbazole modified ketonic resin, reaction mixture of oligocarbazole carbazole was added to the cyclohexanone/formaldehyde solution.

Findings

The carbazole modified cyclohexanone‐formaldehyde and acetophenone formaldehyde resins have conductivity values of 10−5‐10−6 S/cm and may be considered as semi‐conductive ketonic resins. These new carbazole modified ketonic resins (CCzFR, ACzFR) have fluorescence properties.

Research limitations/implications

This study focused on obtaining a conductive and fluorescence resin using a carbazole monomer which is an insulator.

Practical implications

This study provides technical information for the synthesis of fluorescence comonomer.

Originality/value

New CCzFR, ACzFR comonomers were synthesised. These comonomers have higher Tm values than CFR and AFR alone and also have fluorescence property.

Details

Pigment & Resin Technology, vol. 41 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 10 May 2011

Ng Sha Shiong, Ching Chin Guan, Zainuriah Hassan and Haslan Abu Hassan

The purpose of this paper is to report the structural properties of AlxGa1−xN (0≤x≤1) grown on sapphire substrate by means of X‐ray diffraction (XRD) technique. The main purpose…

Abstract

Purpose

The purpose of this paper is to report the structural properties of AlxGa1−xN (0≤x≤1) grown on sapphire substrate by means of X‐ray diffraction (XRD) technique. The main purpose of this work was to investigate the effects of Al(x) composition to the structural and microstructural properties of AlxGa1−xN ternary alloy such as the crystalline quality, crystalline structure and lattice constant c.

Design/methodology/approach

AlxGa1−xN thin films with wurtzite structure in the composition range of 0≤x≤1 are used in this study. The compositions of the samples are calculated using Vegard's law and verified by energy dispersive X‐ray analysis. The samples are then characterized by means of XRD rocking curve (RC) and phase analysis.

Findings

Investigation revealed that the full width half maximum (FWHM) of RC increase with the increase x value. This indicates that the crystalline quality of the samples deteriorate with the increase of Al compositions. The best fit of the non‐linear interpolation of the FWHM of the (002) diffraction RC data suggested that a maximum disorder should be expected in this mixed crystals system when the composition x≈45 percent.

Originality/value

This paper provides valuable information on the effect of Al compositions to the structural characteristics of AlxGa1−xN alloy system. The availability of information about maximum disorder of Al composition in AlxGa1−xN (0≤x≤1) alloy system provides useful reference in device fabrications where researchers are able to choose correct alloy composition in order to fabricate good quality devices.

Details

Microelectronics International, vol. 28 no. 2
Type: Research Article
ISSN: 1356-5362

Keywords

Article
Publication date: 29 May 2007

X. Jiang, L. Lin, X. Bai and J. Gu

To identify the causes to the variation of shade of coloured acrylic sheets from one batch to another and to propose solution to alleviate such a phenomenon.

Abstract

Purpose

To identify the causes to the variation of shade of coloured acrylic sheets from one batch to another and to propose solution to alleviate such a phenomenon.

Design/methodology/approach

A number of analytical techniques, including spectrophotometric measurement, evaluation of dispersion stability, pigment particle size analysis, scanning electron microscopy and transmission electron microscopy, were employed to assess the degree of colour shade variation, the degree of dispersion and nature of the particles within the acrylic sheet formulations and the acrylic sheet products.

Findings

It was found that the variation of shade of the coloured acrylic sheets from one batch to another was mainly caused by the lack of dispersion stability of the pigment particles concerned over time.

Practical implications

The investigation found solutions to the variation of shade of the coloured acrylic sheets from one batch to another.

Originality/value

Colour and colour consistency are a key attribute of the coloured acrylic sheets. Although not frequently encountered, such imperfections were undesirable. The investigation identified the causes to such imperfections and found a way to eliminate such imperfections.

Details

Pigment & Resin Technology, vol. 36 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 November 2009

C.B. Li, G.X. Yang, Z.H. Huang, Y. Xin, C. Wang and J.H. Yuan

The purpose of this paper is to focus on the development of highly efficient emission materials for light‐emitting diodes (LEDs).

Abstract

Purpose

The purpose of this paper is to focus on the development of highly efficient emission materials for light‐emitting diodes (LEDs).

Design/methodology/approach

The equilibrium geometries of silole‐based derivatives are optimised by means of DFT/B3LYP method with the 6‐31G(d) basis set in this paper. The geometries of single‐excitation are optimised using the ab initio configuration interaction with single excitations/6‐31G(d), the first singlet excited states and optical properties are calculated by using time‐dependent density‐functional theory based on the 6‐31G(d) basis set.

Findings

The highest occupied molecular orbital and lowest unoccupied molecular orbital suffer larger effects from the variation of the substituent groups of methyls and phenyls. The absorption wavelengths of all the cases are similar, but the emission wavelengths are significantly different.

Research limitations/implications

Solid‐state stacking effect is not included in this paper.

Originality/value

In view of the application of silole‐based derivatives systems, the control of photophysical properties and electronic structures by structural modification is relevant to further molecular design.

Details

Pigment & Resin Technology, vol. 38 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

11 – 14 of 14