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This study aims to investigate the effect of different pore diameter and pore length on corrosion properties of anodic aluminum oxide (AAO) film.

AAO layer was produced by two-step anodization aluminum in oxalic acid. The surface morphology was investigated using field emission scanning electron microscopy. The pore diameters were ranging from 25 ± 5 to 65 ± 5 nm and the pore length ranging from 5 to 17 µm. The corrosion properties of the AAO films was analyzed by potentiodynamic polarization and electrochemical impedance spectroscopy tests. Corrosion properties and morphology of the anodic films depending on anodization times and pore expansion times were evaluated.

All highlights of this work can be summarized with the following specified below: more treatment with the protective barrier layer of the solution as the pore diameter increases depends on the morphology of the nanotube structured AAO layer. The excellent corrosion resistance renders AAO films without pore expansion very promising. The oxide layer thickness does not affect the corrosion resistance. The better corrosion resistance of AAO films at low pore length can be ascribed to the barrier layer thickness and the more homogeneous structure. The presence of defects for the higher pore length decreases its corrosion resistance.

The AAO films were fabricated by a two-step anodization method in oxalic acid. The anodization times and pore expansion times affect the corrosion performance. The AAO film without pore expansion has good corrosion resistance. The corrosion resistance decreases as the pore length increases.

The novel structures and properties of nanostructure and nanomaterials give people perfect artistic expression of feeling and sense, then the nanoart discipline is developed and is closely related on the nanotechniques. The many achieved novel nanostructures with strong anti-corrosion prepared by the anodization have been reviewed. The paper would raise public awareness of nanotechnology, nanomaterial and their impact on our lives.

Anodization is a very effective and simple technique to form various nanostructures of metal oxide. It includes hard anodization, mild anodization and pulse anodization. Many measures have been introduced anodization process to improve the quality of formed nanostructure and enhance its properties, such as anti-corrosion.

The formation mechanism of anodic aluminum oxide (AAO) by using the mild, hard and pulse anodization has been discussed. The pretexture process and many other measures have been taken in mild and hard anodization to improve the regularity of pore array and greatly accelerate the formation rate of AAO. The pulse anodization has been used to prepare the multilayer Y-branched AAO film, which exhibits steady rich and vivid structure colors and gives a very good artistic expression. Furthermore, many other metal oxide nanostructures such as TiO₂ and CuO have also been fabricated using the anodization techniques.

Various nanostructures of metal oxide prepared by anodization have been reviewed and are itself a perfect artwork in mesoscale. Also, many nanostructures have exhibited steady, rich and vivid structure colors and give people a very good artistic expression.

‘Alorode’ is a new metallising process developed by Selectrons (Redditch) Ltd which it is claimed, will overcome many of the practical difficulties associated with selective anodising.

FRANCE. Internal corrosion in pipes. Mild‐steel pipes as used in town gas distribution networks are corroded by the mixture of water vapour, carbon dioxide and oxygen. Corrosion occurs only if changes in temperature will cause condensation. The condensate forming on the metal is a heavily corroding agent. Once formed, the corrosion products will act as protective layers in certain circumstances.—(J. Morlet and G. Geoffray, paper read at the 74th Congress of the Association Technique de l'Industrie du Gaz en France, June 1957.)

To obtain an optimized microarc oxidation (MAO) coating on magnesium alloy from an environmentally‐friendly electrolyte free of Cr^6 + and PO₄³⁻ and to investigate the influence of oxidation potential on the morphology, composition, structure, and other properties such as micro‐hardness and corrosion resistance.

A constant potential regime was applied to produce the coatings and scanning electron microscopy, energy dispersive spectroscope, X‐ray diffraction, hardness testing and electrochemical methods were used to study coating properties.

The results clearly show that oxidation potential plays an important role in the formation of coating structure and properties. The MAO coating is smooth and white and consists of two layers. The external layer is loose and porous and enriched in Al and Si. Moreover, the content of Al and Si increase with operated potential. The inner layer is compact and the content of Al and Si are lower than are those of the external layer. The coating is composed of several phases: the main phase is MgAl₂O₄/MgO, and the minor phase is Al₂O₃/SiO₂ when the potential is higher. The micro‐hardness of the coating obtained a maximum at a potential of 45 V, as does the corrosion resistance.

This paper provides information relating to MAO technology and the morphology, structure and properties of MAO coatings.

This paper aims to study the anodization of aluminum in a mixture solution of 1,3-propanediol solutions and 0.4 mol l⁻¹ H₃PO₄ at a low temperature.

The morphology and composition of the resulting anodic aluminum oxide (AAO) template was characterized by means of a scanning electron microscope in combination with an energy dispersive spectrometer.

Pore density and pore diameter both were found to be dependent on the temperature of anodization.

The resulting AAO templates exhibited uniform and regular pores with diameters that were significantly smaller than those found in AAO templates anodized at room temperature.

This paper aims to find a way to improve the surface insulation, corrosion resistance and mechanical properties of Fe-Cr-Al electrothermal alloy, exploring the best oxidation condition and analyzing the oxidation mechanism.

Electrochemical workstation was used for anodic oxidation, and the effect of current density, ethylene glycol concentration and oxidation time on properties of the film were investigated by resistivity test, scanning electron microscope, electrochemical tests (potentiodynamic polarization and electrochemical impedance spectroscopy) and mechanical tests, and the oxidation process was analyzed by X-ray photoelectron spectroscopy (XPS).

According to the potential-time curves of anodic oxidation and the analysis of XPS, the whole oxidation process can be divided into four stages. When the current density is 0.8 A/dm², the ethylene glycol concentration is 10%, and the oxidation time is 60 min, the film has the best corrosion protection, mechanical properties and surface morphology. The resistivity of the samples is about 13 orders magnitude than that of the matrix.

In this paper, a protective electrically insulating film was prepared by anodic oxidation in an alkaline electrolyte solution. The oxidation conditions were optimized and the oxidation mechanism was analyzed.

The purpose of this paper is to study the effect of micro-nano surface texture on the corrosion resistance of a titanium alloy and investigate the correlation between corrosion resistance and hydrophobicity.

The surface of the Ti₆Al₄V alloy was modified by laser processing and anodizing to fabricate micro-pits, nanotubes and micro-nano surface textures. Afterward, the surface morphology, hydrophobicity and polarization curve of the samples were analyzed by cold field scanning electron microscopy, contact angle measurement instruments and a multi-channel electrochemical workstation.

The micro-nano surface texture can enhance the hydrophobicity of the Ti₆Al₄V surface, which may lead to better drag reduction to ease the friction of implants in vivo. Nevertheless, no correlation existed between surface hydrophobicity and corrosion resistance; the corrosion resistance of samples with nanotubes and high-density samples with micro-nano surface texture was extremely enhanced, indicating the similar corrosion resistance of the two.

The mechanism of micro-dimples on the corrosion resistance of the micro-nano surface texture was not studied.

The density of micro-pits needs to be optimized to guarantee excellent corrosion resistance in the design of the micro-nano surface texture; otherwise, it will not fulfill the requirement of surface modification.

The influence of the micro-nano surface texture on the corrosion resistance, as well as the relationship between hydrophobicity and corrosion resistance of the titanium alloy surface, were systematically investigated for the first time. These conclusions offer new knowledge.

This study aims to examine the corrosion and flexural behaviour of advanced hybrid aluminium matrix nanocomposites (HAMNCs) made with a vacuum-assisted stir die casting (two-layer feeding) and reinforced with titanium oxide (TiO₂) and yttrium oxide (Y₂O₃) nanoparticles. The previous researchers have shown that TiO₂ and Y₂O₃ nanoparticles make aluminium composites much more resistant to corrosion and wear.

Salt spray corrosion tests were done on the samples over time as well as the pre-and post-corrosion morphology of the test samples was also investigated. The density, porosity and energy dispersive X-ray of the fabricated samples were observed.

It was observed that a lower corrosion rate of 0.127 mils/year and 0.573 mils/year was seen in the Al/5 Wt.%TiO₂/5 Wt.%Y₂O₃ (HAMNC1) and Al/7.5 Wt.%TiO₂/2.5 Wt.%Y₂O₃ (HAMNC3), respectively. It was evident from the results that the pores and densities of the samples varied with the filler concentrations and matrix filler wettability. HAMNC1 has the lowest values of density and porosity at 2.568 g/cm³ and 9.91%, respectively. At the same time, a significant improvement in the flexural strength of 72 N/mm² was also seen in the HAMNC1 configuration.

The proposed hybrid samples are well suited for aerospace and automobile structural components such as brake drums, discs, engine cylinders and fins.

The mixed influence evaluation of TiO₂ and Y₂O₃ nanoparticles with pure Al on composite samples has not been studied. This research aims to examine the combined influence of nanoparticles on the corrosion aspects of two-step feeding vacuum stir casted products, as well as their morphology.

Porous silicon (Si) was fabricated by using three different wet etching methods, namely, direct current photo-assisted electrochemical (DCPEC), alternating CPEC (ACPEC) and two-step ACPEC etching. This study aims to investigate the structural properties of porous structures formed by using these etching methods and to identify which etching method works best.

Si n(100) was used to fabricate porous Si using three different etching methods (DCPEC, ACPEC and two-step ACPEC). All the samples were etched with the same current density and etching duration. The samples were etched by using hydrofluoric acid-based electrolytes under the illumination of an incandescent lamp.

Field emission scanning electron microscopy (FESEM) images showed that porous Si etched using the two-step ACPEC method has a higher porosity and density than porous Si etched using DCPEC and ACPEC. The atomic force microscopy results supported the FESEM results showing that porous Si etched using the two-step ACPEC method has the highest surface roughness relative to the samples produced using the other two methods. High resolution X-ray diffraction revealed that porous Si produced through two-step ACPEC has the highest peak intensity out of the three porous Si samples suggesting an improvement in pore uniformity with a better crystalline quality.

Two-step ACPEC method is a fairly new etching method and many of its fundamental properties are yet to be established. This work presents a comparison of the effect of these three different etching methods on the structural properties of Si. The results obtained indicated that the two-step ACPEC method produced an etched sample with a higher porosity, pore density, surface roughness, improvement in uniformity of pores and better crystalline quality than the other etching methods.