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The purpose of this study is to investigate the effects of the cementite morphology on the hydrogen trapping behavior in low-alloy pipeline steel.

In this study, the hydrogen trapping behavior in low-alloy pipeline steel was quantitatively studied by a combination of microstructural observations, electrochemical hydrogen permeation experiments and thermal desorption spectroscopy (TDS) analyses.

P-1 and P-2 steels are two samples with different microstructures. The morphology of cementite precipitates in the P-1 and P-2 steels was different. Lamellar cementite is present in P-2 steel and only granular cementite in P-1 steel, which led to a better irreversible hydrogen trapping ability of P-2 steel, which was confirmed by subsequent hydrogen permeation and TDS experiments.

The study of these deep hydrogen trap sites is helpful in improving the hydrogen embrittlement resistance of low-alloy pipeline steels.

The purpose of this study is to develop a model extending Oriani’s formula by introducing a normalised concentration to simulate hydrogen diffusion in a multi-material system such as coated steels, under the presence of traps.

Implemented through the finite element method based on the analogy between mass diffusion and heat transfer, the governing equation was applied to investigate the combined effects of hydrogen traps and surface oxide films on hydrogen permeation in ferritic steels.

This study shows that the effective diffusivity varies over several orders of magnitude depending on the traps and films. This explains the divergence of measured hydrogen diffusivities in steels. It is revealed that hydrogen permeation in steels with Pd or Ni film is a trapping-dominant transport process, while hydrogen permeation in steel with oxide film is a process controlled by both trapping effect and retarding effect of oxide film. The oxide film enhances total hydrogen concentration within the steel substrate and is therefore detrimental. The Pd or Ni film has a little influence on total hydrogen concentration distribution depending on trapping energy.

Hydrogen flux curves and transient hydrogen concentration distributions can be directly obtained through the developed model. The proposed approach can also be extended to investigate other interstitial (i.e. carbon, oxygen and nitrogen) diffusion with traps revisited in complex systems.

The purpose of this paper is to optimize and improve a bipolar charge transport (BCT) model used to simulate charge dynamics in insulating polymer materials, specifically low-density polyethylene (LDPE).

An optimization algorithm is applied to optimize the BCT model by comparing the model outputs with experimental data obtained using two kinds of measurements: space charge distribution using the pulsed electroacoustic (PEA) method and current measurements in nonstationary conditions.

The study provides an optimal set of parameters that offers a good correlation between model outputs and several experiments conducted under varying applied fields. The study evaluates the quantity of charges remaining inside the dielectric even after 24 h of short circuit. Moreover, the effects of increasing the electric field on charge trapping and detrapping rates are addressed.

This study only examined experiments with different applied electric fields, and thus the obtained parameters may not suit the experimental outputs if the experimental temperature varies. Further improvement may be achieved by introducing additional experiments or another source of measurements.

This work provides a unique set of optimal parameters that best match both current and charge density measurements for a BCT model in LDPE and demonstrates the use of trust region reflective algorithm for parameter optimization. The study also attempts to evaluate the equations used to describe charge trapping and detrapping phenomena, providing a deeper understanding of the physics behind the model.

The purpose of this paper is to describe a rapid and robust axisymmetric hybrid algorithm to create dynamic temporal and spatial charge distributions, or charge map, in the simulation of bipolar charge injection using Schottky emission and Fowler-Nordheim tunneling, field-dependent transport, recombination, and bulk and interfacial trapping/de-trapping for layered polymer films spanning the range from initial injection to near breakdown.

This hybrid algorithm uses a source distribution technique based on an axisymmetric boundary integral equation method (BIEM) to solve the Poisson equation and a fourth-order Runge-Kutta (RK4) method with an upwind scheme for time integration. Iterative stability is assured by satisfying the Courant-Friedrichs-Levy (CFL) stability criterion. Dynamic charge mapping is achieved by allowing conducting and insulating boundaries and material interfaces to be intuitively represented by equivalent free and bound charge distributions that collectively satisfy all local and far-field conditions.

Charge packets cause substantial increase of electric stress and could accelerate the breakdown of polymeric capacitors. Conditions for the creation of charge packets are identified and numerically demonstrated for a combination of impulsive step excitation, high charge injection, and discontinuous interface.

Metallized bi-axially oriented polypropylene (BOPP) dielectric thin film capacitor with self-clearing and enhanced current carrying capability offer an inexpensive and lightweight alternative for efficient power conditioning, energy storage, energy conversion, and pulsed power. The originality is the comprehensive physics and multi-dimensional modeling which span the dynamic range from initial injection to near breakdown. This model has been validated against some empirical data and may be used to identify failure mechanisms such as charge packets, gaseous voids, and electroluminescence. The value lies in the use of this model to develop mitigation strategies, including re-designs and materials matching, to avoid these failure mechanisms.

High-strength martensitic steels having strong hydrogen embrittlement (HE) susceptibility and the metal carbide (MC) nanoprecipitates of microalloying elements such as Nb, V, Ti and Mo in the steel matrix can effectively improve the HE resistance of steels. This paper aims to review the effect of MC nanoprecipitates on the HE resistance of high-strength martensitic steels.

In this paper, the effects of MC nanoprecipitates on the HE resistance of high-strength martensitic steels are systematically described in terms of the types of MC nanoprecipitates, the influencing factors, along with numerical simulations.

The MC nanoprecipitates, which are fine and semicoherent with the matrix, effectively improve the HE resistance of steel through the hydrogen trapping effects and microstructure optimization, but its effect on the HE resistance of steel is controlled by its size, number and distribution state.

This paper summarizes the effects and mechanisms of MC nanoprecipitates on HE performance of high-strength martensitic steel and provides the theoretical basis for corrosion engineers to design high-strength martensitic steels with excellent HE resistance and improve production processes.

The peristaltic motion for Carreau fluid by means of an infinite train of sinusoidal waves traveling along the walls of a circular cylindrical flexible tube is investigated. The fluid is subjected to a constant transverse magnetic field. A perturbation solution is obtained for the case in which Weissenberg number is small. The effects of Hartmann number, Weissenberg number, power‐law index and amplitude ratio on the pressure rise and the friction force are discussed. The trapping limit and the trapping occurrence region at the centerline decrease by increasing Hartmann number but they are independent approximately of Weissenberg number and power‐law index.

The Library of the School of Oriental and African Studies (SOAS) has ordered a security turnstile from ALS Limited. SOAS has already installed an ALS label‐based circulation control system which includes amongst its features, a ‘trapping store’ for the identification of delinquent readers. At present, the trapping store can only operate when a reader uses his card to borrow a book. To link the Library turnstile to the trapping store is only a logical development of this basic concept. Thus, once the system is installed, any reader wishing to enter the SOAS Library will have to have his or her card read by ALS equipment at the turnstile. If for any reason that reader's number has been entered on the Library's trapping store, the turnstile will lock. Further information concerning the ALS turnstile can be obtained from ALS Limited, Vector House, Brownfields, Welwyn Garden City, Herts. AL7 1AN — Telephone Welwyn (07073) 29344.

The manual loans system previously in use at Loughborough is described and the reasons behind automation are examined. In looking at the requirements of an automated system a trapping store is found to be essential to maintain the standard of reader service if an off‐line system is to be used. The Plessey Library Pen equipment is described, followed by details of the programs making up the new system. There is an account of the change‐over period from the old to the new system and the manual processes involved in working the system are explained.

This paper discusses the lower concentration reinforcement of cathodic ultrafine ceramic particulates, on metal matrices like Zn, Al and alloy‐matrices like Cu Zn, Cu Mn, Al Zn and Ni‐P‐B alloy‐electrodeposits, etc. It is assumed that these ultrafine ceramic particulates in lower concentration‐range are effective in covering the anodic grain‐boundary networks and other anodic‐defect sites, such that there is an effective reduction of surface anodic‐current. It is shown that at a critical threshold particulate concentration, the surface dissolution is minimum, followed by a drastic increase above that concentration. Such increase in dissolution is attributed to the random dispersion of the particulates on the grain‐proper, as these cannot be accommodated within the anodic grain‐boundary channels, micro‐voids and other defect sites. As such they form stress‐raiser points and enhance surface dissolution. This paper also discusses the correlation of the grain boundary structures, particulate trapping capacity of the matrix and the galvanic stress factors due to random distribution of particulates.

The study aims to compare tribological properties between laser dimple textured surface and drilled dimple textured surface, and to analyze the influence of dimple hardened edges and ability of trapping wear debris on wear properties of dimple textured surfaces.

Circular textured dimples were produced on AISI 1,045 specimen surfaces using laser surface texturing (LST) and drilled surface texturing (DST) methods. Tribological behaviors of LST, DST and non-textured specimens were studied using ball-on-disc tribo-tester. Metallographic structures, dimples and worn surface morphologies were observed using a three-dimensional digital microscope. Hardnesses of substrate and dimple edges were measured.

There was no obvious difference in wear and friction coefficients between LST and DST specimens. Hardnesses of laser dimple edges were much higher than that of drilled dimple edges and specimen substrate. The hardened materials of laser dimple edge included recast zone and heat affect zone. Laser dimple was cone-shaped and drilled dimple was cylinder-shaped. Drilled dimple had a better ability of trapping wear debris than laser dimple. Non-uniform wear phenomenon occurred on worn surfaces of LST dimple specimens.

The ability of textured dimples to trap wear debris is affected by single dimple volume. Hardened edges of dimples cause non-uniform wear on worn surfaces of LST specimens.