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Article
Publication date: 3 July 2017

Osama A.G. Wahba, Ali M. Hassan, Abdelrahman M. Naser and Adel M.G. Hanafi

The purpose of this study to investigate the synthesis of new Cr(III), Fe(III), Ni(II) and Cu(II) Schiff base complexes by a simple technique (microwave technique). The evaluation…

Abstract

Purpose

The purpose of this study to investigate the synthesis of new Cr(III), Fe(III), Ni(II) and Cu(II) Schiff base complexes by a simple technique (microwave technique). The evaluation of the prepared complexes as pigments as corrosion resistant was also explored.

Design/methodology/approach

The Schiff base complexes were prepared by using microwave method (green chemistry), and then, the physico-chemical requirements according to standards for the synthesised pigments were investigate.

Findings

The prepared complexes exhibit good physical, mechanical and corrosion properties as pigments in paint formulations.

Research limitations/implications

The simple technique used for synthesis of metal complex pigments will significantly increase the cost saving for the manufacturing of such pigments category. Also, the used technique is considered a green method (eco-friendly), as there no organic solvent was used.

Practical implications

The evaluation of the prepared complex pigments as corrosion resistants was also studied.

Originality/value

It is a simple technique, green synthesis (no solvent used) is involved and high yield is obtained.

Details

Pigment & Resin Technology, vol. 46 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 November 2016

Yi He, Ranran Yang, Yanqiu Zhou, Lan Ma, Lei Zhang and Zhao Chen

The purpose of this paper is to adopt both the fragments of imidazole and thiosemicarbazide as reaction centers, to synthesize a water-soluble corrosion inhibitor named as…

Abstract

Purpose

The purpose of this paper is to adopt both the fragments of imidazole and thiosemicarbazide as reaction centers, to synthesize a water-soluble corrosion inhibitor named as thiosemicarbazide-imidazole derivative (TH-IM).

Design/methodology/approach

This paper presents potentiodynamic polarization tests, electrochemical impedance spectroscopy tests and morphology study of metal surface by scanning electron microscope and thermodynamic study.

Findings

In the aggressive condition of CO2 saturated Wt. NaCl solution at 333 K for 72 h with 400 ppm inhibitor dosage, the efficiency of inhibition increases approximately 98 per cent through the method of weight loss.

Originality/value

This paper finds a new corrosion inhibitor about TH-IM which has a good solubility in water.

Details

Anti-Corrosion Methods and Materials, vol. 63 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

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