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The purpose of this paper is to achieve a hard and protective borided layer on commercially pure Ti (grade-2) by applying boriding, and to investigate the changes in its microstructure, hardness, friction and wear behaviors.

Pack boriding technique was used to form a hard boron diffusion layer on titanium substrate. A powder mixture of amorphous boron and anhydrous borax was used as a solid-state boriding media, and then the boriding was carried out under inert atmosphere.

A thick dual boride layer consisting of a monolithic titanium diboride (TiB₂) on the top and titanium monoboride (TiB) whiskers beneath that layer formed at relatively low diffusion temperature under pressured inert argon atmosphere in a boriding media containing boron source and activator. With boriding at specified conditions, very hard (4100 Hv0.01) and thick monolithic TiB₂ layer formed on the top-most layer which is required for improved tribological applications. Hardness decreased gradually through the TiB whisker layer and finally reached to the hardness of base material.

This paper investigates the effects of components of boriding mixture and conditions of thermal treatment on the formation of borided layer and its properties. In previous studies, boriding mixtures containing a boron source, an activator and a filler material was generally used at high temperatures around or above 1,050°C to achieve a thick monolithic layer on the top of the surface of titanium. In the present study, no filler material was used to accelerate the boron diffusion because filler materials may inhibit the diffusion of boron atom through the surface of substrate of titanium. Also, diffusion treatment was carried out under pressurized argon atmosphere at relatively low diffusion temperature to achieve boride layer with the improved hardness and durability.

Kaolin is a soft, white mineral mainly composed of coarse‐ to fine‐grained, plate‐like aluminum silicate particles. As kaolin assists with desired rheological properties that help maintain proper dispersion and provide bulk to the product, it is used as an important extender in paint manufacture. It can be used to reduce the amount of expensive pigments, such as titanium dioxide. In spite of these uses, kaolin has the disadvantage of having coarse particles and low hiding power. The purpose of this paper is to introduce a new class of pigments based on kaolin as a core and titanium dioxide as the shell.

In the work reported in this paper, kaolin was used as a core covered with a surface layer of titanium dioxide comprising the shell in order to combine their properties and get over kaolin's disadvantages, besides enhancing its corrosion protection properties. The pigments prepared were characterised using X‐ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Deposition of titanium dioxide on the surface of kaolin was confirmed by Energy‐dispersive X‐ray analysis (EDAX) and X‐ray fluorescence (XRF) techniques. Pigment properties were estimated according to American standard testing methods (ASTM) methods and then were incorporated in anticorrosive paint formulations based on medium oil alkyd resin. The physico‐mechanical and corrosion properties of dry paint films were determined according to ASTM methods.

The tests revealed that the concentration of titanium dioxide layer deposited on kaolin surface was inversely proportional to the anticorrosive behaviour of these pigments.

The pigments can be applied in other polymer composites, e.g. rubber and plastics as filler and reinforcing agent.

The pigments prepared are eco‐friendly that can replace other expensive pigments. These pigments can compensate for the presence of titanium dioxide in paint formulations successfully, and thus lower the costs. The main advantage of these pigments is that they combine the properties of both of their counterparts, they are of lower cost, and they also overcome the disadvantages of both its counterparts, e.g. low hiding power of kaolin, photochemical activity of titanium dioxide. Also, they can be applied in other industries other than paints, e.g. paper, rubber and plastics composites.

Discusses the results of impedance measurements done for titanium metal in methanolic 1M HCl containing 0,1,3 and 5 volume per cent H2O. Titanium metal behaved actively in such solutions and became passive when a sufficient amount of water (5 per cent) was present. As a result of anodic oxidation a porous layer has been formed at the metal surface, characterized by the presence of an additional maximum in the phase angle curves. The radii of the pores were calculated from a kugel diffusion impedance element.

The purpose of this paper is to investigate the anticorrosive effects of a new pigment based on bulk of talc covered with a surface layer of titanium dioxide.

The new pigments were characterized using different analytical and spectro‐photometric techniques. Characterization of these pigments using X‐ray diffraction, scanning electron microscopy and transmission electron microscopy. The energy‐dispersive X‐ray analysis technique was used to assure the presence of titanium dioxide on talc surface, then X‐ray fluorescence (XRF) was employed to elucidate the concentration of different elements in the prepared pigments. Evaluation of these pigments was undertaken using international standard testing methods. The pigments were then incorporated in solvent‐based paint formulations based on medium oil alkyd resin. The physico‐mechanical properties of dry films and their corrosion properties were tested using accelerated laboratory tests in 3.5 percent NaCl for 28 days.

The results of this work reveal that as the layer of titanium dioxide is increased in thickness, enhanced anticorrosive properties of the new pigments are obtained.

These pigments can be applied in other polymer composites, e.g. rubber and plastics, as a reinforcing agent.

These prepared pigments are environmentally friendly and impart high anticorrosive behavior to paint films, a unique homogenous texture, and deliver concomitant cost savings.

The purpose of this paper is to consider the corrosion properties of laser nitrided Ti‐6Al‐4V alloys that have been reported previously by several researchers.

Different kinds of surface nitriding methods of titanium alloys, such as plasma nitriding, ion nitriding, gas and laser nitriding, are introduced. Microstructure changes, such as phase formation and the influence of laser processing parameters in laser nitriding layers of Ti‐6Al‐4V alloys, were investigated using scanning electron microscope, transmission electron microscope, X‐ray photo‐electron spectroscopy, and X‐ray diffraction. Based on investigations presented in the literature, the effect of laser nitriding on the corrosion behavior of Ti‐6Al‐4V alloy was reviewed.

By regulating the laser processing parameter, the microstructure of the nitrided layer can be controlled to optimize corrosion properties. This layer improves corrosion behavior in most environments, due to the formation of a continuous TiNxOy passive film, which can retard the ingress of corrosive ions into the substrate and can maintain a constant value of a current density. Therefore, the laser gas nitrided specimens have a relatively noble corrosion potential and a very small corrosion current, as compared to untreated specimens.

This paper comprises a critical review, and its collection of references is useful. It summarizes current knowledge in laser surface treatment research.

The electrodeposition of any metal over titanium substrates meets with many problems due to the formation of a non‐conductive layer of titanium oxide on the surface of substrates during the electroplating process. Trials were made to overcome these problems by the pre‐anodisation of titanium substrates in oxalic acid solution of concentration 100g/l, at high current density of 60‐95mA/cm^–2, and at ambient temperature. In these conditions, a thin, porous and conductive titanium oxide film can be obtained, which will then support electroplating processes. Rhodium metal was electrodeposited over the anodised titanium substrates from a bath consisting of Rh₂(SO₄)₃, 5.2g/l and H₂SO₄, 100g/l. At optimum conditions of electroplating, the rhodium electrodeposits were formed over the anodised titanium substrate with high adhesion, brightness and high current efficiency (92.05 per cent).

The purpose of this paper is to characterize carbide coatings obtained by thermo reactive diffusion (TRD) method on AISI 52100 and 440C bearing steels, which are extensively used in industry, and to study wear behaviour of coated steels at elevated temperatures.

For coatings of vanadium and titanium carbides, TRD treatment is performed on AISI 52100 and 440C steels using pack method at 950°C for 3 h. Carbide coatings are characterized using X‐ray diffraction (XRD). The Daimler‐Benz Rockwell‐C adhesion test and micro‐Knoop indenter is used to assess the adhesion and hardness of the carbide layers, respectively. Ball‐on‐disc arrangement is used for determination of tribological properties of carbide‐coated steels. Friction and wear tests are carried out against Si₃N₄ ball at elevated temperatures up to 600°C under 5 N load, for sliding speed of 0.3 m/s.

The presence of carbides formed on AISI 52100 (Ti₆C_3.75 and VC_0.88 phases) and on AISI 440C (Ti₆C_3.75, VC_0.88 and minor Cr₂₃C₆ and Cr₇C₃ phases) is confirmed by XRD analysis. Hardness values of titanium and vanadium carbides on the 52100 and 440C steels are about 2,175‐2,464 and 2,128‐2,433 HK_0.05, respectively. Friction experiments show that this type of coating is more effective than the substrates in regards to achieving lower friction up to 300°C. Above this temperature, the effect of substrate is more dominant on the friction coefficient. Scanning electron microscopy and energy‐dispersive X‐ray analysis results show the presence of the compact oxide layers at elevated temperatures as a result of increased sintering and oxidation of the wear debris.

This paper deals with only characterization of vanadium and titanium carbide coatings and high temperature wear properties of the coated steels.

Carbide coatings obtained by TRD method are satisfactory in terms of high temperature tribological applications in comparison with those produced vapor deposition processes, which are expensive and complicated equipment.

There is no literature about high temperature wear and friction behaviour of TRD carbide‐coated 52100 and 440C steels. In this study, there are new results on high temperature wear of TRD carbide‐coated steels.

This paper aims to improve the wear resistance of titanium alloy using a high-hardness boride layer, which was fabricated on Ti6Al4V by a high-temperature boronizing process.

The boride layers on Ti6Al4V were obtained at 1000°C for 5–15 h. Scanning electron microscopy, energy dispersive analysis and X-ray diffractometer were used to characterize the properties of the boride layer. The tribological performance of the boride layer at room and elevated temperatures was investigated.

The X-ray diffraction analysis showed that the boride layers were a dual-phase structure of TiB and TiB₂. When the boronizing time increased from 5 h to 15 h, the microhardness increased from 1192 HV_0.5 to 1619.8 HV_0.5. At 25°C and elevated temperatures, the friction coefficients of the boride layers were higher than that of Ti6Al4V. The wear track areas of T-5 at 200°C and 400°C were 2.5 × 10^–3 and 1.1 × 10^–3 mm², respectively, which were 6.1% and 2.6% of that of Ti6Al4V, indicating boride layer exhibited a significant wear resistance. The wear mechanisms of the boride layer transformed from slight peeling to oxidative wear and abrasive wear as the temperature was raised.

The findings provide an effective strategy for improving the wear resistance of Ti6Al4V and have important implications for the application of titanium alloy in a high-temperature field.

Metalworking fluids can significantly increase the tool life in titanium cutting, however, full-scale cutting tests to determine the performance of metalworking fluid are expensive. The aim of this study is therefore to introduce a reliable and inexpensive alternative testing method.

A newly developed in-process tribometer allows emulating the sliding conditions of the chip formed in cutting as closely as possible. It uses a cutting action in front of a pin to eliminate the influence of the oxidation layer. To observe the wear pattern on the pin, adhering workpiece material is removed by selective etching. A high temperature oxidation test is used to study the wear mechanism.

The wear pattern on the pin correlates well with the wear pattern observed on cutting tools when using the same metalworking fluid while being much more cost-effective than a tool life test. The high temperature oxidation test reveals that cobalt leaching is causing notch wear.

The correlation between pin and tool wear is verified for the case of roughing turning of titanium with cemented carbide tools and two metalworking fluids.

The method is applicable in an industrial context, potentially replacing the currently used tribological analyzes.

Submitted in connection with the special issue “young tribologists – insights into the work of the new generation”.

Methods tailored to model the tool wear in titanium cutting are rare. For the first time, an in-process tribometer, which is especially suited for the analysis of titanium cutting, is used to assess the wear behavior. The design of the high temperature oxidation test is new.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-08-2019-0311

This paper aims to investigate the structural, tribological and electrochemical properties of Ag₂O, ZnO, NiO coatings and Ag₂O/ZnO/NiO nanocomposite films deposited on commercially pure titanium.

Ceramic thin films (Ag₂O, ZnO, NiO coatings and Ag₂O/ZnO/NiO nanocomposite film) were deposited on commercially pure titanium (CP-Ti) substrate. Surface characterization of the uncoated and coated samples was made by structural surveys (scanning electron microscopic examinations and X-ray diffraction analyses), hardness measurements, tribological and corrosion experiments.

Results were indicated that sol-gel coatings improved the wear and corrosion resistance of CP-Ti, and the best results were seen at the nanocomposite coating. It may be attributed to its small grain size, high surface hardness and high film thickness.

This study can be a practical reference and offers insight into the influence of nanocomposite ceramic films on the increase of hardness, tribological and corrosion performance. Also, the paper displayed a promising approach to produce Ag₂O/ZnO/NiO nanocomposite coating on commercially pure titanium implants for biomedical applications.