Search results

The purpose of this paper is to prepare water‐soluble TiO₂ nanoparticles and evaluate the tribological properties as additives in water.

Nanoparticles present excellent friction‐reducing and antiwear properties as additives in base oils. However, there are seldom literatures about the nanoparticles as additives in water as yet. In this work, water‐soluble TiO₂ nanoparticles were prepared by sol‐gel method and characterized with transmission electron microscopy and selected area electron diffraction. The tribological properties as additives in water were investigated by SRV and the surface analysis by scanning electron microscope and X‐ray photon electron spectroscope.

TiO₂ nanoparticles modified with polyethylene glycol have uniform size about 10 nm and easily dissolve in water. The tribological experiments showed TiO₂ nanoparticles exhibit excellent friction‐reducing and antiwear properties.

The paper is restricted to only TiO₂ nanoparticles. Some other water‐soluble nanoparticles also should be prepared and their tribological properties investigated.

Water‐soluble TiO₂ nanoparticles could be used as water additives and improve the tribological properties.

This paper emphasises that the water‐soluble nanoparticles are prepared and could be used as water additives.

The purpose of this study is to investigate the tribological performance (anti-friction and anti-wear properties) of commercial Mobil grade lubricants used in a journal bearing system in a power plant.

Three grades of Mobil lubricants (DTE 24, DTE 25 and DTE 26) are considered during the study. Titanium dioxide nanoparticles (TiO₂, 0.5 Wt.%) of size 40 nm are used as a lubricant additive to examine the performance of the lubricants. The viscosity of the lubricant is computed using modified Krieger–Dougherty viscosity model. The morphology of TiO₂ nanoparticles is studied with the help of scanning electron microscopy, ultra violet spectrophotometer and X-ray diffraction. The study of antifriction and antiwear properties for lubricants is carried out on four-ball tribo-tester for operating conditions specified by ASTM standards.

The tribochemical reaction film is formed between ball surfaces during the experiments on four-ball tester that minimizes the asperity contact due to addition of TiO₂ nanoparticles in the lubricant. The viscosity of the lubricant is enhanced due to the addition of TiO₂ nanoparticles. The frictional coefficient and wear scar diameters of balls in the lubricants are reduced in the range of 6-26 and 2-7 per cent, respectively.

The tribological properties of TiO₂ as a lubricant additive in three commercial Mobil grade lubricants are investigated in this paper. The results obtained in this paper are expected to be helpful to bearing designers, researchers and academicians concerned with the relevant study.

The purpose of this study is to evaluate the possibility of using titanium dioxide coating in the field of architectural heritage.

In this research, a titanium dioxide coating was prepared and then applied to the travertine stone surfaces. The nature of the coating was determined through various observations and analyses. Moreover, the effect of photocatalytic self-cleaning was evaluated using an organic dye (Rhodamine B).

The results of XRD, DLS and SEM confirmed the formation of small anatase crystals. The hydrophilic behavior on the surface was observed by coatings based on titanium dioxide.

The self-cleaning ability of titanium dioxide is due to the synergistic effect of its optical inductive property, which is activated with sunlight.

The self-cleaning coatings are interested for many industries. The reported data can be used by the formulators working in the research and development departments.

Self-cleaning systems are considered as smart coatings. Therefore, the developing of its knowledge can help to extend its usage to different applications.

The application of titanium dioxide coating in the field of architectural heritage is a great challenge. Therefore, in this research, a titanium dioxide coating was prepared by sol-gel method and then applied on travertine surfaces and its properties were studied.

The boundary-layer analysis is required to reveal the fluid flow behavior in several industrial processes and enhance the products’ effectiveness. Therefore, this research aims to investigate the buoyancy or mixed convective stagnation-point flow (SPF) and heat transfer of a micropolar fluid filled with hybrid nanoparticles over a vertical plate. The nanoparticles silver (Ag) and titanium dioxide (TiO₂) are scattered into various base fluids to form a new-fangled class of (Ag-TiO₂/various base fluid) hybrid nanofluid along with different shape factors.

The self-similarity transformations are used to reformulate the leading requisite partial differential equations into renovated non-linear dimensionless ordinary differential equations. The numerical dual solutions are gained for the transmuted requisite equations with the help of the bvp4c built-in package in MATLAB software. The results are validated by comparing them with previously available published data for a particular case of the present study.

The impact of various pertaining parameters such as nanoparticle volume fraction, material parameter, shape factor and mixed convective on temperature, heat transfer, fluid motion, micro-rotation and drag force are visualized and scrutinized through tables and graphs. It is observed that dual or non-uniqueness outcomes are found for the case of buoyancy assisting flow, whereas the solution is unique in the buoyancy opposing flow case. Additionally, the fluid motion and micro-rotation profiles decelerate in the presence of nanoparticle volume fraction, while the temperature augments.

The mixed convective stagnation point flow conveying TiO₂/Ag hybrid nanofluid with micropolar fluid with various shape factors is the significant originality of the current investigation where multiple outcomes are obtained for the assisting flow. The various base fluids such as glycerin, water and water–ethylene glycol (50%:50%) are considered in the present problem. The bifurcation values of the considered problem do not exist, probably because of various base fluids. To the best of the authors’ knowledge, this work is new and original which were not previously reported.

Titanium is a naturally occurring mineral in the form of titanium dioxide (TiO₂) and is one of the most widely used food additives. The purpose of this review article is to show the importance of the accumulation of this mineral in the gut and its relation with inflammatory processes.

This is a literature review study from 2002 to 2016, focusing on studies with TiO₂ and its relation with inflammatory bowel diseases.

Articles describe that TiO₂ is resistant to gastrointestinal degradation, as it has high stability, and that its particles, ingested daily, may bind to biomolecules in the lumen or be absorbed by the intestinal mucosa, accumulating in the macrophages of lymphoid tissue in the gut, thus causing or aggravating the inflammatory response in the inflamed bowel.

There is a limited number of studies on the long-term impact of dietary microparticles in animal models, in healthy subjects and in patients with inflammatory bowel diseases.

It is necessary to regulate the amount of TiO₂ used in industrialized products.

The high consumption of processed foods, as opposed to a healthy diet based on the balanced consumption of nutrients, is relevant, as it may lead to or exacerbate intestinal inflammation.

This review indicates that titanium particles may mediate toxicological processes leading to an abnormal increase in intestinal permeability, which may be particularly aggravating in patients with inflammatory bowel diseases.

The purpose of this paper is to study and analyze the converging/diverging channel flow and heat transfer with the multiple slips effect, which is a development of the Jeffery–Hamel problem using the mass-based hybrid nanofluid algorithm. Whereas transferring biological liquid by arteries is a vital issue, mathematical modeling of hybrid nanofluid flow containing titanium dioxide and silver as nanoparticles and blood as base liquid through a converging/diverging duct, which can be a useful analysis for the fields of drug delivery, has been investigated.

The present approach is based on the Tiwari–Das nanofluid method. In this modeling, the volume fraction of nanoparticles is replaced with nanoparticles masses. The partial differential equations of the mass, momentum and energy conservations are changed to the system of ordinary differential equations through the similarity solution method. The final governing equations are solved by Runge–Kutta–Fehlberg procedure and shooting method.

The effect of emerging parameters on the temperature, the velocity, the Nusselt number and the skin friction have been analyzed by graphical and tabular reports. It is observed that the opposition to hybrid nanofluid flow in the attendance of particles of nonspherical shapes is more enhanced than those in the attendance of particles of spherical shapes. This issue demonstrates that the rheology of a hybrid nanofluid is dependent on the shape of particles. Besides, backflow regimes form in the divergent channel for high values of Reynolds number, m₂ and a. Indeed, this modeling for the hybrid nanofluid can be useful in different technologies and industries such as biological ones. It is worth mentioning that the excellent achievement of the mass-based algorithm for heat transfer and hybrid nanofluid flow is the most important success of this study.

The main originality is related to the development of the Jeffery–Hamel problem using the mass-based hybrid nanofluid algorithm. This new mass-based method is a single-phase hybrid nanofluid approach that the inputs are masses of nanoparticles and base liquid. Besides, considering the multiple slips effect and also pure blood as base fluid in this problem are also new.

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

The developed coating shows high potential for glass window application.

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

The purpose of this paper is to introduce the simple synthesis process of thermal-insulation coating by using three different nanoparticles, namely, nano-zinc oxide (ZnO), nano-tin dioxide (SnO₂) and nano-titanium dioxide (TiO₂), which can reduce the temperature of solar cells.

The thermal-insulation coating is designed using sol-gel process. The aminopropyltriethoxysilane/methyltrimethoxysilane binder system improves the cross-linking between the hydroxyl groups, -OH of nanoparticles. The isopropyl alcohol is used as a solvent medium. The fabrication method is a dip-coating method.

The prepared S1B1 coating (20 Wt.% of SnO₂) exhibits high transparency and great thermal insulation property where the surface temperature of solar cells has been reduced by 13°C under 1,000 W/m² irradiation after 1 h. Meanwhile, the Z1B2 coating (20 Wt.% of ZnO) reduced the temperature of solar cells by 7°C. On the other hand, the embedded nanoparticles have improved the fill factor of solar cells by 0.2 or 33.33%.

Findings provide a significant method for the development of thermal-insulation coating by a simple synthesis process and low-cost materials.

The thermal-insulation coating is proposed to prevent exterior heat energy to the inside solar panel glass. At the same time, it can prevent excessive heating on the solar cell’s surface, later improves the efficiency of solar cell.

This study presents a the novel method to develop and compare the thermal-insulation coating by using various nanoparticles, namely, nano-TiO₂, nano-SnO₂ and nano-ZnO at different weight percentage.

Dyeing and printing are important steps in textile manufacturing. After the process completion, these dyes are released in the effluent. These dyes impart an unacceptable appearance but are also toxic to the soil and water bodies. The present research has been carried out to study the rate of photocatalytic degradation of an azo dye, namely, CI Direct Green 26, using titania nanoparticles under ultra violet (UV) irradiation as a function of temperature and time. Azo dyes account for the majority of all dyestuffs are produced and extensively used in the textile, paper, food, leather, cosmetics and pharmaceutical industries. Titania nanoparticles have been found to successfully degrade these dyes in the presence of UV light. The purpose of the present paper was to study the photodegradation of azo dyes using titania nanoparticles at different temperatures and time periods.

Titania nanoparticle concentration of 0.1% (w/v) was dispersed in distilled water by sonication for 1 h in sonication bath. The of rate of degradation of Direct Green 26 dye in the titania nanoparticle dispersion, under UV-A exposure was studied at different temperatures ranging from 25°C to 65 °C for time periods ranging from 1 h to 6 h. Photocatalytic degradation tests were performed in a specially designed UV reactor chamber. Raman spectroscopy of Titania nanoparticles, dye and titania/dye mixture before and after UV exposure was carried out using Confocal Laser Dispersion Raman Microscope (Renishaw, UK) with 785 nm excitation laser.

Titanium dioxide is an efficient photocatalyst for decolourisation of direct dye. The photodegradation of the direct Green dye was found to follow the pseudo first-order reaction. The Arrhenius activation energy was found to be 24.8 kJ/mol with A value of 0.0013 for the photocatalytic degradation of the dye. Raman spectroscopy also confirmed the adsorption of dye on titania nanoparticle and its complete degradation on exposure to UV light.

This research highlights the application of titania nanoparticles for the effective degradation of dye in the effluent from textiles, clothing, paper and any kind of dyeing process. Azo dyes account for the majority of all dyestuffs are produced and extensively used in the textile, paper, food, leather, cosmetics and pharmaceutical industries. Titania nanoparticles have been found to successfully degrade these dyes in the presence of UV light which can be very beneficial for the effluent treatment plants in textile and other industries.

Azo dyes are one of the harmful pollutants released in textile waste water. The degradation and removal of the coloured waste in the textile effluent is an important environmental concern and needs to be investigated. The research is one of the first to investigate and understand the mechanism of the degradation of an azo dye in the presence of titania nanoparticles by Raman spectroscopy.

This paper aims to study the Improvements in self-cleaning property of the white acrylic water-based paint by addition of different percentages of three commercially available titanium dioxide (TiO₂) nanoparticles as additives. Then, due to the risk of destruction of polymeric materials in the presence of nanoparticles, degradation of dry paint film samples was investigated for 15 days using two important chalking and yellowing factors. Finally, the TiO₂-modified paint sample with the best performance and optimum percentage of TiO₂ nanoparticles that produced desired self-cleaning and dry film properties was introduced.

Self-cleaning and dry film properties of white acrylic water-based paint were investigated by addition of three various types of commercial available TiO₂ nanoparticles (SSP-25, STA-100 and KA-100). X-ray diffraction, transmission electron microscopy and Brunauer–Emmett–Teller were used for characterization of TiO₂ samples. Colorimetric tests in decolourization of C.I. Basic Red 46 (BR46) were used for determination of self-cleaning properties of TiO₂-modified paints in comparison with unmodified paint sample. Also, paints defects such as chalking and yellowing were tested along two weeks.

The results indicated that, in all types of TiO₂ nanoparticles, by increasing the amount of TiO₂ in modified paint, self-cleaning property of the samples was enhanced. The paint containing SSP-25 indicated better self-cleaning properties than others due to its larger surface area. However, its usage above 3.5 weight per cent caused yellowing and chalking defects in dried paint film.

In this research, TiO₂-modified paint sample with the best performance in both self-cleaning and mechanical properties was selected among the nine sets of prepared paint samples. All the materials used in this research such as acrylic resin and three types of TiO₂ nanoparticles are of industrial grade. Therefore, the introduced TiO₂-modified paint sample has the potential for the commercial production as a building exterior paint.

In the present study, an attempt at introducing a self-cleaning paint sample with acceptable mechanical properties using three types of commercially available TiO₂ nanoparticles as additives and industrial grade of acrylic resin which is the most commonly used water-based resin in building paints, as binder. As far as it was searched in the literatures, the parallel study of the self-cleaning and mechanical properties of paints has not been reported as noteworthy. Self-cleaning property of the acrylic water-based paint samples was investigated by adding three types of the commercially available TiO₂ nanoparticles. Also considering the possible detrimental effects of TiO₂ nanoparticles on polymeric materials and consequently on physical properties of the paint, chalking and yellowing factors in dried paint samples were evaluated.