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The management issues of this article, and the author is attempting to address these issues, are as follows: What is the optimal decision of each entity in the closed-loop supply chain for the cascading utilization of power batteries under three government measures: no subsidies, subsidies and rewards and punishments? How do different measures affect the process of cascading the utilization of power batteries? Which measures will help incentivize cascading utilization and battery recycling efforts?

The paper uses game analysis methods to study the optimal decisions of various stakeholders in the supply chain under the conditions of subsidies, non-subsidies and reward and punishment policies. The impact of various parameters on the returns of game entities is tested through Matlab numerical simulation.

The analysis discovered that each party in the supply chain will see an increase in earnings if the government boosts trade-in subsidies, which means that the degree of recycling efforts of each entity will also increase; under the condition with subsidies, the recycling efforts and echelon utilization rates of each stakeholder are higher than those under the incentive and punishment measure. In terms of the power battery echelon’s closed-loop supply chain incentive, the subsidy policy exceeds the reward and punishment policy.

The article takes the perspective of differential games and considers the dynamic process of exchanging old for new, providing important value for the practice of using old for new behavior in the closed-loop supply chain of power battery cascading utilization.

The purpose of this paper is to investigate the tribological performance of graphene oxide (GO) sheets as water-based lubricant additive when ultra-high molecular weight polyethylene (UHMWPE) plates slid against 316L stainless steel ball using a reciprocating tribometre.

The factors influencing the tribological performance were considered, including the viscosity of the GO dispersion, normal load, sliding velocity and the roughness of UHMWPE. The surface microstructure and properties of UHMWPE were studied by means of scanning electron microscopy, laser confocal microscopy, Raman spectroscopy and contact angle measurements.

The results revealed that the GO dispersion reduced friction and sliding-wear. The surface images of the wear UHMWPE plates indicated that GO sheets were prone to adsorption on the surface and form a thin physical tribofilms at the substrate.

Based on the experimental findings for the evolution of the microstructure morphology and the development of subsurface cracks, less debris and cracking can be observed in the UHMWPE plates lubricated by GO dispersion.

To study some tribochemical properties of tetrazole derivatives, n‐hexadecanyl (1H‐tetrazol‐1‐yl) acetate (HTA) and 1‐phenyl‐5‐(octylthio)‐tetrazole (PCT) as lubricating oil additives in hydrogenised oil, and estimate the action mechanism.Design/methodology/approach – The two tetrazole compounds were synthesized, and added them in hydrogenised oil with different concentrations. Their anti‐wear properties were evaluated with a four‐ball machine, the wear scar was analyzed with a X‐ray photoelectron spectroscopy (XPS).Findings – The novel compounds possess good anti‐wear, friction reduction properties and good load‐carrying capacity. According to the XPS results, the novel compounds were migrated onto the surface of the steel balls and adsorbed on the surface. The two additive compounds, themselves, and their decomposers contributed to the corresponding tribological performances. With S element contained in the compound PCT, the influence on the load‐carrying capacity of the base oil was enhanced. It may be due to the formation of S²⁻ and SO₄²⁻ compounds on the worn surface which could form a protective film.Research limitations/implications – Their antioxidant, anticorrosion, anti‐wear properties are not estimated.Practical implications – Two useful EP and AW lubricating oil additives were synthesized, and maybe it is the potential industrial applied lubricating oil additives.Originality/value – This paper provided a study way of some N‐containing heterocyclic compounds as lubricating oil additives.

This paper seeks to study the tribological properties, corrosion inhibition properties and action mechanism of two triazine‐containing disulfides, TOSS and TOMA, as additives in combustion engine base oil (5CST); those properties of an alkyl disulfide dodecyl disulfide and zinc dialkyldithiophosphate (ZDDP) were also evaluated for comparison to discover whether these additives could be used as potential substitute candidates for ZDDP.

Their tribological performances were evaluated using a four‐ball machine. The worn surfaces were investigated by scanning electron microscopy and X‐ray photoelectron spectroscopy (XPS)

The three additives have good load‐carrying capacity and corrosion inhibition properties comparable with those of ZDDP. The anti‐wear properties of the triazine‐containing disulfides TOSS and TOMA are good but a little inferior to those of ZDDP. The friction‐reducing performances of the additives are better than those of ZDDP. The XPS results show that absorption and tribochemical reactions occur to generate a complex boundary lubrication films comprising inorganic sulfate, sulfide, iron oxide and organic nitrogen, and sulfur‐containing compounds.

The anti‐oxidation properties are still to be estimated, and the synergistic effectiveness with other additives could be demonstrated.

These additives are good extreme pressure and anti‐wear additives in combustion engine base oil and, through further modification of molecular structure or combination with other additives, they may be a potential replacement for ZDDP.

To reduce the cost, the products synthesized were not finely separated. Their tribological properties as additives in the widely used combustion engine base oil were first investigated and results indicate that they show excellent performances.

The purpose of the research was to test whether the novel synthesized additive TEAT can be a substitution for the traditional additive ZDDP partly or entirely in mineral oil.

The extreme pressure, antiwear (AW) and friction reducing property of TEAT was examined, the tribological property of the combination of TEAT and ZDDP was also examined. The worn surfaces of the steel balls were observed using a polarizing optical microscope and x‐ray absorption near edge structure spectroscopy.

The results show that: TEAT can enhance the P_B value of the base oil obviously; TEAT shows better AW performance than ZDDP in high load and a wide range of concentration, it shows better friction‐reducing performance than ZDDP in high load and all the concentration tested; TEAT alone can provide a better AW and friction reducing property than ZDDP and the combination of TEAT and ZDDP; and the tribochemical reaction occurs between novel compound and metallic surface, generating sulfur containing layer mainly exists in the form of FeS.

These findings indicate that TEAT presents better tribological properties than ZDDP in a wide range of practical conditions. TEAT may be a substitute for ZDDP in the future.

This paper sets out to study tribological properties, anticorrosive performances and thermal stabilities of two novel S‐N type triazinyl‐containing polysulfides {Bis[2,4‐bis(diethylamino)‐s‐triazin‐6‐yl] polysulfide (BBET‐PS) and Bis[2,4‐bis(di‐n‐butylamino)‐s‐triazin‐6‐yl] polysulfide (BBBT‐PS)} as additives in biodegradable grease, and to estimate the tribochemical mechanism.

Extreme pressure (EP) and anti‐wear (AW) properties of two compounds at different addition concentration were evaluated using a four‐ball machine. Their wear scar was analyzed with X‐ray photoelectron spectroscopy (XPS) and a scanning electron microscope.

Two novel S‐N type triazinyl‐containing polysulfides possess excellent load‐carrying capacity, good AW and show good corrosion‐inhibiting performance. The thermal stability of BBB‐PS is better than that of BBE‐PS. According to the XPS results, the triazinyl‐containing polysulfides react with the metal to generate a surface protective film consisting of sulfate, FeS and absorbed compounds containing organic‐N.

The antioxidant and biodegradability of the two novel compounds were not investigated.

Two effective EP and AW additives were synthesized, and maybe potentially industrial applied lubricating grease additives.

The achievement of this study is the synthesis of two triazinyl‐containing polysulfides, which can be effective additives to improve the tribological performance of biodegradable grease.

Nanoparticles are not well dispersed in non‐polar organic solvents due to their hydrophilic property which limits their applications in lubricant oils. To improve the oil‐solubility of nanoparticles, a novel technology was used to prepare a kind of lubricant containing calcium borate nanoparticles.

The microstructures of the prepared nanoparticles were characterized by transmission electron microscope (TEM) and infrared spectra (IR). Tribological properties of calcium borate nanoparticles used as additive in base oil were evaluated using four‐ball tribotester and SRV tribotester, and the worn surface of the steel ball was investigated by Polarized microscope (PM) and X‐ray photoelectron spectroscopy (XPS). In addition, the dispersing stability and antioxidation property of lubricant containing nanoparticles were also studied.

The results indicate that the average size of the prepared nanoparticles is in the range of 50‐100 nm, and the surface of the nanoparticles was altered from hydrophilicity to hydrophobicity. At the same time, the nanoparticles can be well dispersed in the base oil totally under novel process which has no significantly negative effect on the antioxidation property. The results of tribological tests show that calcium borate nanoparticles under the novel process (CBNN) show better antiwear property and friction‐reducing property in base oil compared to calcium borate nanoparticles under tradition process (CBNT). Based on the results of PM and XPS, it can be deduced that a continuous resistance film containing depositions and the tribochemical reaction products such as B₂O₃, FeB, Fe₂O₃ and CaO formed during the sliding process.

The main innovative thought of this work lies in dealing with the oil‐solubility problem through the combination effect of surface modification and special blend process of lubricating oil, and this method was first used to prepare lubricant containing calcium borate nanoparticles. It should be helpful for the borate nanoparticles used as additives in engine oil, gear oil and other industrial lubricants.

Sulfurized olefins have been extensively used in many kinds of gear lubricants as EP additives. However, their commercial applications are not totally satisfactory because of the pungent, obnoxious odor and corrosion of copper and copper alloys. The purpose of this paper is to investigate the synergistic effects of one type of calcium borate nanoparticles modified by oleic acid (code to CaBN) and sulfurized olefin, in a kind of mineral base oil MVIS 250, in order to find a potential substitute for sulfurized olefins.

One kind of calcium borate nanoparticle modified by oleic acid (CaBN) was prepared, and its structures were characterized by inductively coupled plasma atomic emission spectroscopy (ICP‐AES), X‐ray power diffraction (XRD) and transmission electron microscope (TEM). The tribological properties of the complex of CaBN with sulfurized olefins (T321) in base oil were evaluated using four‐ball tribotester and compared with CaBN or T321 as individual component. The worn surfaces were investigated by scanning electron microscope (SEM) and X‐ray photoelectron spectroscopy (XPS). In addition, the corrosion‐inhibiting properties of additives were also studied.

The results of tests show that there are significant synergistic effects on tribological properties between two kinds of additives. Based on the results of SEM and XPS, it can be deduced that a wear resistance film containing B₂O₃, FeS, FeS₂ and CaO was formed on the worn surfaces during the sliding process. Moreover, CaBN and T321 also show excellent synergistic effect on the corrosion‐inhibiting property.

This paper provides a kind of “green” nanoparticle which possesses excellent synergic effect with sulfurized olefins, and gives another selection for industrial applications in which T321 is needed.

The purpose of this paper is to investigate the tribological properties of novel phosphorous-nitrogen (P-N) type additives in water.

The tribological properties of the novel P-N additives in water are compared with a commercial lubricant additive of the P-N type using a four-ball machine. The tribological mechanism was investigated by X-ray absorption near-edge structure (XANES) spectroscopy.

The experimental results indicate that the phosphoramidate derivatives possess good anti-wear and friction-reducing properties. The XANES analysis shows that the prepared compounds can form a protective film containing phosphate and/or polyphosphate that affects the tribological behavior.

The purpose of this paper is to investigate the tribological properties of the novel P-N type additives in water.

The purpose of this paper is to study the tribological properties of a thiazole derivatives (T561), overbased alkyl benzene calcium sulfonate (T106A) compounded with T561 and overbased alkyl benzene magnesium sulfonate (T107) compounded with T561 in rapeseed oil (RSO).

A four-ball machine was used to evaluate the tribological properties of each compound and their combinations with T561 in RSO. Scanning electron microscopy, EDX and X-ray photoelectron spectroscopy were applied to analyze the tribofilm formed on the worn surfaces.

Results of tribotesting demonstrated that synergistic effects exist between the overbased sulfonates, T106A and T107, and the thiazole derivative, T561. The texts of tribofilm indicated that iron sulfide and iron oxides exist in T561 single agent lubricant film and two composite additives lubricant film, and no sulfates were detected. It suggested that the addition of alkyl benzene sulfonate did not hinder the formation of iron sulfides and iron oxides. Meanwhile, CaSO₄ (MgSO₄) and CaCO₃ (MgCO₃) were detected on the worn surface of the composite additives, which were not detected on the single agent friction surface.

A tribofilm mainly contains CaSO₄ (MgSO₄) and CaCO₃ (MgCO₃) formed on the worn surfaces, which is responsible for excellent extreme pressure and anti-wear properties of the compound agents because of their high melting point and high shear stress.