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Article
Publication date: 20 September 2019

Mei Yang, Tingyu Huang, Ning Tang, Ben Ou and Wenhao Zhang

This paper aims to investigate the photocatalytic activity of zinc doped MAO-TiO2 films under the optimum MAO treatment condition.

Abstract

Purpose

This paper aims to investigate the photocatalytic activity of zinc doped MAO-TiO2 films under the optimum MAO treatment condition.

Design/methodology/approach

The coating was prepared by micro arc oxidation, and the influence of doping on the properties of the coating was also investigated.

Findings

The results show that the BET surface area is 78.25±0.03m2/g, total pore area is 76.32 ± 0.04m2/g, and the total pore volume is 0.2135 ± 0.0004cm3/g. The degradation ratio of the film electrode with Zn-doped in methyl orange solution is up to 94%. When the react circles is 10 times, the degradation ratio is up to more than 85% and remains steady. With the different reaction conditions, these kinetics of the reactions show some different formulas.

Originality/value

A kinetic equation for photocatalytic activity is established.

Details

Pigment & Resin Technology, vol. 48 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 April 2019

Mian-En Yeoh, Adrian Jaloman and Kah-Yoong Chan

The purpose of this paper is to elucidate the aging effect in dye-sensitized solar cells (DSSCs) sealed with thermoplastic film and to compare it with unsealed DSSCs.

Abstract

Purpose

The purpose of this paper is to elucidate the aging effect in dye-sensitized solar cells (DSSCs) sealed with thermoplastic film and to compare it with unsealed DSSCs.

Design/methodology/approach

The paper presents the steps of the fabrication of standard DSSC, as well as the DSSC-sealing processes, by using thermoplastic film. Current-voltage characterization was performed to observe the changes in efficiency, fill factor, short circuit current density and open circuit voltage for both unsealed and sealed DSSCs for aging time up to 336 h.

Findings

The unsealed DSSC showed significant drop in efficiency from 4.26 to 2.42 per cent within the first 5.5 h of aging time because of the leakage and volatilization of the solvent in the electrolyte. On the other hand, the sealed DSSC exhibited a gradual improvement of efficiency from 4.16 to 4.73 per cent after the first 216 h of aging time. The initial efficiency increment can be ascribed to the improved adsorption of electrolyte into the titanium dioxide film because of the gradual desorption of excess dye from TiO2 with increasing aging time.

Originality/value

This paper demonstrates the importance of the proper sealing process for the long-term operation of DSSC.

Details

Microelectronics International, vol. 36 no. 2
Type: Research Article
ISSN: 1356-5362

Keywords

Article
Publication date: 1 January 1987

R. Dell'Acqua

Thick‐film technology to implement passive elements, network and hybrid circuits has been widely used for four decades and its importance is still growing. While on one hand the…

Abstract

Thick‐film technology to implement passive elements, network and hybrid circuits has been widely used for four decades and its importance is still growing. While on one hand the technology has been improved to meet the requirements for more sophisticated circuits, on the other hand a better knowledge of its outstanding properties has promoted its application to a certain number of sometimes exotic devices, many of which are in the sensor and actuator area. This paper presents examples of a variety of applications to illustrate what thick film technology can offer outside the familiar area, and to stimulate the imagination of scientists towards possible new applications.

Details

Microelectronics International, vol. 4 no. 1
Type: Research Article
ISSN: 1356-5362

Article
Publication date: 1 January 1996

M.M. Al‐Abdallah

Addresses the effect of Dead Sea water on the electrochemical behaviour of titanium metal and zircalloy‐4 and evaluates the stability of the oxide films in such a medium, by way…

Abstract

Addresses the effect of Dead Sea water on the electrochemical behaviour of titanium metal and zircalloy‐4 and evaluates the stability of the oxide films in such a medium, by way of an experiment which uses the electrochemical impedance spectroscopy technique, i.e. a three‐electrode electrochemical cell assembly. Presents and discusses the results.

Details

Anti-Corrosion Methods and Materials, vol. 43 no. 1
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 11 December 2018

Dongdong Peng, Kang Huang, Yuntao He, Zhan Zhang, Yi Wang and Junsheng Wu

This paper aims to improve the anti-corrosive properties of aluminum alloy AA2024-T3 by coating of hybrid sol-gel coating incorporated with TiO2 nanosheets and to investigate the…

Abstract

Purpose

This paper aims to improve the anti-corrosive properties of aluminum alloy AA2024-T3 by coating of hybrid sol-gel coating incorporated with TiO2 nanosheets and to investigate the effect of nanosheets’ size on the improvement of corrosion-resistant performance.

Design/methodology/approach

A series of hybrid sol-gel films incorporated with varying amounts of TiO2 nanosheets were developed to enhance the corrosion protection performance of the bare metal. Scanning electron microscopy, transmission electron microscopy and atomic force microscopy were used to investigate the structure and morphology of the coatings obtained. In addition, the corrosion-resistant properties of the coatings were evaluated using salt spray test and electrochemical impedance spectroscopy.

Findings

The corrosion current was as low as 9.55 × 10-4 µA/cm2 and optimal positive corrosion potential reached −0.6 V when the size and loading amount of TiO2 nanosheet were optimized, resulting in a remarkable improvement in anti-corrosive properties.

Originality/value

This work first investigates the effect of incorporation of TiO2 nanoparticles on hybrid sol-gel coating on the improvement of anti-corrosive performance of aluminum alloy AA2024-T3.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 2 January 2018

Pei Qin, Guobin Yi, Xihong Zu, Huan Wang, Hongsheng Luo and Miao Tan

The aim of this paper is to synthesize graphene-modified titanium dioxide (GR-TiO2) nanorod arrays nanocomposite films, so that these can enhance the photocatalytic properties of…

Abstract

Purpose

The aim of this paper is to synthesize graphene-modified titanium dioxide (GR-TiO2) nanorod arrays nanocomposite films, so that these can enhance the photocatalytic properties of titanium dioxide and overcome the problem of difficult separation and recovery of photocatalysts.

Design/methodology/approach

The GR-TiO2 nanocomposite films were synthesized via hydrothermal method and spin-coating. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), ultraviolet–visible (UV-Vis) diffuse reflectance spectrum and Raman spectrum. The photocatalytic performance of the GR-TiO2 nanocomposite films for degrading Rhodamin B under ultraviolet (UV) was studied by a UV-Vis spectrophotometer. The photocatalytic enhancement mechanism of graphene was studied by photoelectrochemical analysis.

Findings

The introduction of graphene expanded the range of the optical response of TiO2 nanorod arrays, improving the separation efficiency of the photogenerated electron-hole pairs, and thus dramatically increasing its photocatalytic performance.

Research limitations/implications

A simple and novel way for synthesizing GR-TiO2 nanocomposite films has enhanced the photocatalytic performance of TiO2.

Originality/value

The photocatalyst synthesized is easy to separate and recycle in the process of photocatalytic reaction, so it is possible to achieve industrialization.

Details

Pigment & Resin Technology, vol. 47 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 March 2015

Hamid Omidvar, Mohammad Sajjadnejad, Guy Stremsdoerfer, Yunny Meas and Ali Mozafari

This paper aims to coat ternary composite NiBP-graphite films by Dynamic Chemical Plating “DCP” technique with a growth rate of at least 5 μm/h, which makes this technique a…

Abstract

Purpose

This paper aims to coat ternary composite NiBP-graphite films by Dynamic Chemical Plating “DCP” technique with a growth rate of at least 5 μm/h, which makes this technique a worthy candidate for production of composite films. Electroless nickel plating method can be used to deposit nickel–phosphorous and nickel–boron coatings on metals or plastic surface. However, restrictions such as toxicity, short lifetime of the plating-bath and limited plating rate have limited applications of conventional electroless processes.

Design/methodology/approach

DCP is an alternative for producing metallic deposits on non-conductive materials and can be considered as a modified electroless coating process. Using a double-nozzle gun, two different solutions containing the precursors are sprayed simultaneously and separately onto the surface. With this technique, NiBP-graphite films are fabricated and their corrosion and tribological properties are investigated.

Findings

With a film thickness of 2 μm, tribological analysis confirms that these coatings have favorable anti-friction and anti-wear properties. Corrosion resistance of NiBP-graphite composite films was investigated, and it was found that graphite incorporation significantly enhances corrosion resistance of NiBP films.

Originality/value

DCP is faster and simpler to perform compared to other electroless deposition techniques. Using a double-nozzle gun, metal salt solution and reducing agents are sprayed to the surface, forming a deposit. Previously, coatings such as Cu, Cu-graphite, Cu-PTFE, Ni-B-TiO2, Ni-P, Ni-B-P and Ni-B-Zn with favorable compactness and adherence by DCP were reported. In this paper, the authors report the application of the DCP technique for depositing NiBP-PTFE nanocomposite films.

Details

Anti-Corrosion Methods and Materials, vol. 62 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 June 1995

M.M. Al‐Abdallah

Introduction Titanium exhibits clear passivity in an aqueous medium, owing to the formation of different types of titanium oxides with very low specific conductance especially…

Abstract

Introduction Titanium exhibits clear passivity in an aqueous medium, owing to the formation of different types of titanium oxides with very low specific conductance especially titanium dioxide. These oxides act as a barrier between the surface of a titanium electrode and the active ionic species in the solution.

Details

Anti-Corrosion Methods and Materials, vol. 42 no. 6
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 5 May 2020

Aleksandra Drygała, Marek Szindler, Magdalena Szindler and Ewa Jonda

The purpose of this paper is to improve the efficiency of dye-sensitized solar cells (DSSCs) which present promising low-cost alternative to the conventional silicon solar cells…

Abstract

Purpose

The purpose of this paper is to improve the efficiency of dye-sensitized solar cells (DSSCs) which present promising low-cost alternative to the conventional silicon solar cells mainly due to comparatively low manufacturing cost, ease of fabrication and relatively good efficiency. One of the undesirable factor in DSSCs is the electron recombination process that takes place at the transparent conductive oxide/electrolyte interface, on the side of photoelectrode. To reduce this effect in the structure of the solar cell, a TiO2 blocking layer (BL) by atomic layer deposition (ALD) was deposited.

Design/methodology/approach

Scanning electron microscope, Raman and UV-Vis spectroscopy were used to evaluate the influence of BL on the photovoltaic properties. Electrical parameters of manufactured DSSCs with and without BL were characterized by measurements of current-voltage characteristics under standard AM 1.5 radiation.

Findings

The TiO2 BL prevents the physical contact of fluorine-doped tin oxide (FTO) and the electrolyte and leads to increase in the cell’s overall efficiency, from 5.15 to 6.18%. Higher density of the BL, together with larger contact area and improved adherence between the TiO2 layer and FTO surface provide more electron pathways from TiO2 to FTO which facilitates electron transfer.

Originality/value

This paper demonstrates that the introduction of a BL into the photovoltaic device structure is an important step in technology of DSSCs to improve its efficiency. Moreover, the ALD is a powerful technique which allows for the highly reproducible growth of pinhole-free thin films with excellent thickness accuracy and conformality at low temperature.

Details

Microelectronics International, vol. 37 no. 2
Type: Research Article
ISSN: 1356-5362

Keywords

Article
Publication date: 26 March 2024

Sajad Pirsa and Fahime Purghorbani

In this study, an attempt has been made to collect the research that has been done on the construction and design of the H2O2 sensor. So far, many efforts have been made to…

Abstract

Purpose

In this study, an attempt has been made to collect the research that has been done on the construction and design of the H2O2 sensor. So far, many efforts have been made to quickly and sensitively determine H2O2 concentration based on different analytical principles. In this study, the importance of H2O2, its applications in various industries, especially the food industry, and the importance of measuring it with different techniques, especially portable sensors and on-site analysis, have been investigated and studied.

Design/methodology/approach

Hydrogen peroxide (H2O2) is a very simple molecule in nature, but due to its strong oxidizing and reducing properties, it has been widely used in the pharmaceutical, medical, environmental, mining, textile, paper, food production and chemical industries. Sensitive, rapid and continuous detection of H2O2 is of great importance in many systems for product quality control, health care, medical diagnostics, food safety and environmental protection.

Findings

Various methods have been developed and applied for the analysis of H2O2, such as fluorescence, colorimetry and electrochemistry, among them, the electrochemical technique due to its advantages in simple instrumentation, easy miniaturization, sensitivity and selectivity.

Originality/value

Monitoring the H2O2 concentration level is of practical importance for academic and industrial purposes. Edible oils are prone to oxidation during processing and storage, which may adversely affect oil quality and human health. Determination of peroxide value (PV) of edible oils is essential because PV is one of the most common quality parameters for monitoring lipid oxidation and oil quality control. The development of cheap, simple, fast, sensitive and selective H2O2 sensors is essential.

Details

Sensor Review, vol. 44 no. 2
Type: Research Article
ISSN: 0260-2288

Keywords

1 – 10 of 116