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Much that has been written on the subject of white hiding power has been considerably less useful to the average paint laboratory than it was intended to be, simply because it has been excessively complicated by a complex theory better suited to the research laboratories of pigment producers.

The purpose of this paper is to modify light hollow polymer microsphere (LHPM) with titanium dioxide nanoparticles (nano-TiO2) to improve its compatibility with latex and apply the obtained nano-TiO2/LHPM composite particles in external wall thermal insulation coatings.

The nano-TiO2/LHPM composite particles were prepared via vigorous stirring. The morphology and chemical composition of the produced nano-TiO2/LHPM composite particles were characterized using scanning electron microscopy, energy dispersion spectrum, thermo-gravimetric analyzer and Fourier transform infrared. The performance of this new composite coating was evaluated by checking its stability, density, radiation reflectivity, thermal conductivity and the resulting insulation temperature difference when forming coating film.

It was found that a 9:1 mass ratio of nano-TiO2/LHPM with total 10 weight per cent composite particles in the thermal insulation paint showed low density, good stability, low thermal conductivity (0.1687 W/m·K) and high insulation temperature difference (5.8°C).

The LHPM can be modified by other nanoparticles to improve its insulation performance in thermal insulation coatings.

This work provides a simple, robust, but effective approach to produce new thermal insulation coatings with nano-TiO2/LHPM composite particles.

This method for surface modification of LHPMs is novel and the modified hollow polymer microspheres could be applied to external wall insulation coatings.

This paper aims to improve the anti-corrosive properties of aluminum alloy AA2024-T3 by coating of hybrid sol-gel coating incorporated with TiO₂ nanosheets and to investigate the effect of nanosheets’ size on the improvement of corrosion-resistant performance.

A series of hybrid sol-gel films incorporated with varying amounts of TiO2 nanosheets were developed to enhance the corrosion protection performance of the bare metal. Scanning electron microscopy, transmission electron microscopy and atomic force microscopy were used to investigate the structure and morphology of the coatings obtained. In addition, the corrosion-resistant properties of the coatings were evaluated using salt spray test and electrochemical impedance spectroscopy.

The corrosion current was as low as 9.55 × 10-4 µA/cm² and optimal positive corrosion potential reached −0.6 V when the size and loading amount of TiO₂ nanosheet were optimized, resulting in a remarkable improvement in anti-corrosive properties.

This work first investigates the effect of incorporation of TiO₂ nanoparticles on hybrid sol-gel coating on the improvement of anti-corrosive performance of aluminum alloy AA2024-T3.

Over the last few years there have been several trials to replace inorganic corrosion inhibitors, which in organic coatings are pigments, with materials which are, in principle, organic corrosion inhibitors. This coincides primarily with the toxic properties of the anti‐corrosive pigments employed and also with the scarcity of raw materials for their production.

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

The developed coating shows high potential for glass window application.

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

The aim of this paper is to synthesize graphene-modified titanium dioxide (GR-TiO₂) nanorod arrays nanocomposite films, so that these can enhance the photocatalytic properties of titanium dioxide and overcome the problem of difficult separation and recovery of photocatalysts.

The GR-TiO₂ nanocomposite films were synthesized via hydrothermal method and spin-coating. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), ultraviolet–visible (UV-Vis) diffuse reflectance spectrum and Raman spectrum. The photocatalytic performance of the GR-TiO₂ nanocomposite films for degrading Rhodamin B under ultraviolet (UV) was studied by a UV-Vis spectrophotometer. The photocatalytic enhancement mechanism of graphene was studied by photoelectrochemical analysis.

The introduction of graphene expanded the range of the optical response of TiO₂ nanorod arrays, improving the separation efficiency of the photogenerated electron-hole pairs, and thus dramatically increasing its photocatalytic performance.

A simple and novel way for synthesizing GR-TiO₂ nanocomposite films has enhanced the photocatalytic performance of TiO₂.

The photocatalyst synthesized is easy to separate and recycle in the process of photocatalytic reaction, so it is possible to achieve industrialization.

A commonly accepted practice for comparative evaluations of the exterior durability properties of titanium dioxide pigment grades is to prepare alkyd paints on each pigment grade, then apply the paints on test panels and send the properly dried panels to a Florida exposure centre for 12 months. During these 12 months the condition of the panels is examined monthly and gloss, chalking, cracking and other eventual changes are recorded and reported.

Structural color is more brilliant in color, more resistant to sunshine and will not fade away with time, and more environmental friendly than traditional dyes and pigments. The purpose of this paper is to prepare structural colors of fabrics coated with Ag/TiO₂ composite films by magnetron sputtering, and analyze the relationship between the colors and the thicknesses of TiO₂ films in Ag/TiO₂ composite films.

Preparation of Ag/TiO₂ composite films by magnetron sputtering and their deposition on textiles were investigated. The chemical compositions and surface morphology of Ag/TiO₂ composite films were examined by X-ray photoelectron spectroscopy and scanning electron microscopy, and the structural color of fabric coated with Ag/TiO₂ composite film was also analyzed.

Ag/TiO₂ composite films deposited on textile substrate exhibited structural colors, and the bright colors could be adjusted and controlled by the thickness of TiO₂ thin films in Ag/TiO₂ composite films without any dyes or pigments. By comparing the results of theoretical calculation and experimental results, it was found that the creation of structural colors by the experiment was coincident to the colors by theoretical calculation according to the film interference principle. There was a linear relationship between the thickness of TiO₂ film and the wavelength of the structural color.

Compared to traditional coloration by dyes or pigments, the coloration of textile by structural color from Ag/TiO₂ composite films prepared by magnetron sputtering was very environmental friendly and simple without water consuming, time consuming and tedious work. Structural colors have great potential applications in textiles in place of traditional dyes and pigments. Furthermore, the textiles coated with Ag/TiO₂ composite films have good electrical, optical and magnetic properties, and can be used in apparel, home furnishings and industrial fabrics.

This paper aims to design the nano-titanium dioxide (TiO₂) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Two hydrophilic materials have been used such as TiO₂ nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

The nano-TiO₂ superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO₂ coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

The developed nano-TiO₂ coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO₂ network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

The synthesis of nano-TiO₂ superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.

The purpose of this paper is to provide an investigation on a new kind of photocatalytic material, namely, the porous ceramic foam loading titanium dioxide, which can make an effective photocatalytic degradation of the methyl orange (MO) solution in the wastewater.

The natural zeolite powder has been used as the primary raw material to produce a sort of lightweight porous ceramic foam by impregnating polymer foam in slurry and then sintering. With the sol-gel method, a kind of open-cell reticular porous ceramic foam loading TiO₂ film was obtained having a good photocatalytic action, and the resultant porous composite product presents the bulk density of 0.3~0.6 g/cm³ to be able to float on water.

The MO could tend to be completely degraded in the solution with a certain concentration by the TiO₂-loaded ceramic foam irradiated with ultraviolet light, and this composite foam was found to have high degradation efficiency for the MO solution in a wide range of pH.

This work presents a TiO₂-loaded ceramic foam that can effectively photo-catalyze to degrade the MO in water, and the degradation efficiency were examined under different conditions of the MO solution with various pH values.