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The purpose of this paper is to prepare stabile emulsions with 0–15% of colloidal silica and high monomer/water ratio and to investigate the influence of silica addition and surface modification on the polyacrylate properties.

Improving the properties of the composite can be achieved by optimizing the compatibility between the phases of the composite system with improving the interactions at the matrix/filler interface. Therefore, the silica surface was modified with nonionic emulsifier octylphenol ethoxylate, cationic initiator 2,2'-azobis-(amidinopropane dihydrochloride) and 3-methacryloxypropyltrimethoxysilane and polyacrylate/silica nanocomposites were prepared via in situ emulsion polymerization. Particle size distribution, rheological properties of the emulsions and morphology, thermal properties and mechanical properties of the film prepared from the emulsions were investigated.

Polyacrylate/silica systems with unmodified silica, silica modified with nonionic emulsifier and cationic initiator have micrometer, while pure PA matrix and systems with silica modified with silane have nanometer particle sizes. Addition and surface modification of the filler increased emulsion viscosity. Agglomeration of silica particles in composites was reduced with silica surface modification. Silica filler improves thermal stability and tensile strength of polyacrylate.

This paper provides broad spectrum of information depending on filler surface modification and latex preparation via in situ emulsion polymerization and properties with high amount of filler and monomer/water ratio with the aim that prepared latex is suitable for film formation and final application.

This study aims to improve the tribological performance of Babbitt alloy under oil lubricant condition. Thus, the surface was treated into oleophobic state by modifying with low surface energy fluorosilane (1H,1H,2H,2H-perfluorodecyltriethoxysilane). It is believed that the oleophobic surface offered excellent wear resistance of Babbitt-based tribo-pairs.

By modifying the Babbitt alloy with low surface energy fluorosilane and measuring the oil contact angle, the wetting behavior was evaluated. Using Pin on Disk tribometer, the tribological properties of bare Babbitt and modified Babbitt were quantified. The samples after the friction test were characterized by scanning electron microscope (SEM) and the anti-wear performance was evaluated under dry and oil lubrication conditions.

Results showed that oil contact angle of modified Babbitt was109° which was tripled compared to that of prime surface, which indicates the oleophobic behavior was greatly improved. Under dry conditions, the friction coefficient of the modified surface with different load conditions is slightly lower than that of the bare surface, while the friction coefficient of the modified surface under lubrication conditions is significantly decreased compared to that of the bare surface. Interestingly, under low load and high load, the wear rate of the modified Babbitt alloy surface is only 1/4 and 1/3 of that of the bare surface, respectively.

The work proposed an effective method to improve the Babbitt tribological performances and will lighten future ideas for the Babbitt alloy bearing with high wear resistance, which is beneficial to improve the service life of sliding bearings and has huge promotion and application value in the manufacture of sliding bearings.

Traditional nanocomposite production methods such as in situ polymerization, melt blending and solvent technique, have some deficits. Some of these are non-homogeneous particle distribution, setup difficulties, time-consuming and costly. On the other hand, three-dimensional printing technology is a quite popular method. Especially, Stereolithography (SLA) printing offers some benefits such as fast printing, easy setup and smooth surface specialties. Furthermore, surface modification of Graphene Oxide (GO) and its effects on polymer nanocomposites are quite important. The purpose of this study is to examine the effect of surface modification of GO nanoparticles on the mechanical properties and morphology of epoxy acrylate (BisGMA/1,6 hexane diol diacrylate) matrix nanocomposites.

In this study, Ultraviolet (UV) curable end groups of synthesized resin were linked to functional groups of graphene oxide, which are synthesized by the Tour method, which is a kind of modified Hummer method. In addition, synthesized GO nanoparticle’s surfaces were modified by 3-(methacryloyloxy) propyl trimethoxysilane. Significant weight percentages of GO were added into the epoxy acrylate resin. Different Wt.% of modified graphene oxide/acrylate resins was used to print test specimens with SLA type three-dimensional printer.

Surface modification has a significant effect on tensile strength for graphene oxide nanoparticles contained composites. In addition, a specific trend was not observed for tensile test results of non-modified graphene oxide. The tendency of impact and hardness test finding were similar for both surfaces modified and non-modified nanoparticles. Finally, the distribution of particles was homogeneous.

This paper is unique because of the inclusion of both surface modifications of graphene oxide nanoparticles and SLA production of nanocomposites with its own production of three-dimensional printer and photocurable polymer resin.

Surface of precipitated silica was modified with 3‐aminopropyltriethoxysilane. The optimum solvent was selected, in which the silane coupling agent was deposited on silica surface. Basic physicochemical properties of the modified silica were estimated. Methods of evaluating silica surface modification extent were presented, taking advantage first of all of its altered hydrophilicity and of differences in condensation extent of surface silanol groups. The modified silica was used as adsorbent capable of trapping water soluble organic amines.

Two types of amorphous silica namely, the precipitated silica and the pyrogenic silica, were studied. The surfaces of such silica were modified with silane coupling agents such as 3‐aminopropyltriethoxysilane, N‐2‐(aminoethyl)‐3‐aminopropyltrimethoxysilane and 3‐ureidopropyltrimethoxysilane. Pigments were obtained by the adsorption of organic dyes, C.I. Reactive Blue 19 and C.I. Acid Green 16, onto the modified silica surface. Structural properties of the modified silica and the pigments obtained were evaluated using scanning electron microscopy, zeta potential analysis and particle size measurement techniques. Moreover, colour of the pigments obtained was evaluated using the CIE L *a*b* colour space system. The specific surface area of the pigment obtained was estimated using the BET method.

Studies on the surface modification of sodium‐aluminium silicate P‐820 using silane coupling agents are described. The best modifiers were selected, which induced a change of the silicate surface from hydrophilic to hydrophobic. Physicochemical analyses of the modified silicate were performed. The methods of evaluating silicate surface modification degree were presented. The degree of hydrophobization of silicate surface was determined by a calorimetric method. Near infra‐red spectroscopy (NIR) was used to determine the degree of condensation of the silicate surface silanol groups. Studies on morphology and microstructure using transmission electron microscopy (TEM) were performed. Attempts were made to apply the unmodified and modified sodium‐aluminium silicate P‐820 as filler and pigment in silicate and dispersion paints.

In this paper, boric acid was loaded on the surface of expandable graphite (EG), polyvinyl alcohol (PVA) and silane coupling agent (KH550) served as a bridge. The purpose of this study was to improve the flame retardant properties of semi-rigid polyurethane, meanwhile, the mechanical properties of the foam got ameliorated.

PVA was dissolved in hot water. EG was added to this solution. After stirring for 0.5 h at 85°C in ultrasonic agitation, the system was put at room temperature to cool. The silane coupling agent KH550 was added dropwise into the solution system, stirring to fully hydrolyze. Boric acid was added into the system, placing it in an oven at 90°C to dry after filtration. Changing of flame retardant properties and mechanical properties of semi-rigid polyurethane adding modified EG were characterized.

The flame retardant performance of the foam with EG has been improved, whereas the tensile strength decreased with an increase in the content of EG. After adding modified EG, compared to semi-rigid polyurethane with EG, flame retardant performance and tensile strength of the foam improved.

In the study reported here, the surface of EG was modified by boric acid. The modified EG was added into semi-rigid polyurethane foam. The flame retardant performance and tensile strength of the foam after adding modified EG were discussed. Results of this research could benefit in-depth study of the influence of adding modified EG to semi-rigid polyurethane. The study could promote the application of flame-retardant polyurethane foam.

The flame retardant performance and tensile strength of the semi-rigid polyurethane were improved by adding modified EG. The effects of modified EG on the flame retardant performance and tensile strength of semi-rigid polyurethane were discussed in detail.

This paper aims to propose an automatic and direct method to manipulate global parameters of the object for prototyping and simulation, given an STL mesh model of a thin-walled object. Proposed method is useful in rapid prototyping, where changing the global parameters such as thickness, scaling local features or draft of walls of an STL mesh is often required. Presently, user needs to iterate over the cycle of modification of the computer-aided design (CAD) model and tessellating it to change the global parameters. The proposed algorithm eliminates the need for CAD model while manipulating those global properties, as it works directly with the mesh model.

Proposed algorithm automatically identifies walls and its thickness, and then, it extracts mid-surface from each wall. Global parameters are then modified by using these mid-surfaces.

Mesh directly modified and the mesh obtained by tessellating modified CAD model has same global properties; proposed method can also allow multiple parameters to be modified at the same time.

Input STL model is assumed to be error-free, where models containing errors like self-intersection will lead to incorrect mid-surfaces. Present algorithm assumes that the mid-surface represent of the input STL model is a manifold surface.

A novel algorithm of directly manipulating global parameters of a thin-walled object in its STL mesh model is proposed. The paper also presents a novel method of extracting mid-surface representation from a thin-wall STL mesh.

This paper aims to prepare highly hydrophobic films on aluminum AA3003 using myristic acid (MA) and evaluate its corrosion protection efficiency in a low-chloride solution.

The aluminum surface was initially treated with boiling water to develop a porous nanostructure, and then surface modification was carried out in ethanolic solutions with different concentrations of MA. The surface morphology, wetting behavior and film composition were first characterized, and then, the corrosion behavior was evaluated with electrochemical techniques.

The best hydrophobicity and corrosion resistance were obtained with 50 mM of MA. For such concentration, a water contact angle of 140° and protective efficiency of 96% were achieved. A multilayer structure was revealed by scanning electron microscope and X-ray photoelectron spectroscopy.

The results of this work shed light on the anticorrosion performance of fatty acid self-assembled multilayers on the surface of Al–Mn alloys.

The MoS₂/graphite composite coatings modified by La₂O₃ through spraying technique were successfully prepared on the inner rings of spherical plain bearings. As a comparison, unmodified coatings were also prepared. This paper aims to study the La-modified MoS₂/graphite composite coating experimentally and improve the tribological performance of self-lubricating spherical plain bearings.

The performance of La₂O₃ toward the friction coefficient, temperature rise and wear rate of the coatings was studied by a self-made tribo-tester under different swing cycles. And the texture, surface morphology and element composition of the coatings were characterized by scanning electron microscope, energy dispersive spectroscopy and X-ray diffractometry.

The additives La₂O₃ refined the coatings’ microstructure and improved the tribological properties of the coatings. The oxidation of Mo + 4 to Mo + 6 was effectively inhibited. And the amount of abrasive grains, peeling pits and local cracks on the coatings surface decreased and homogeneous lubricating films formed, which were attributed to the existence of La₂O₃. The wear mechanisms of unmodified coatings were severe abrasive wear, adhesive wear and delamination wear. However, it exhibited superior wear resistance of the La-modified coatings to unmodified coatings, presenting slight abrasive wear and adhesive wear. The service life of bearings was prolonged under the protection of the modified coatings.

The paper proposed a new modified MoS₂/Graphite composite coating for the self-lubricating spherical plain bearings. The investigation on the friction, wear and temperature increase behaviors and the wear mechanisms of the coatings are beneficial to prolonging the service life of the self-lubricating spherical plain bearings.