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Compared with traditional industrial processing technologies of sulfurized isobutylene, the one-step synthesis method involving high pressure is more environment-friendly and leads to better product performance. However, products from various sources perform differently because of the difference in the contents of their components. Therefore, the purpose of this study was to investigate the relationships between sulfide components of high-pressure sulfurized isobutylene and load carrying capacities.

A typical high-pressure sulfurized isobutylene was chosen, and the structure and contents of its sulfide components were characterized using gas chromatography-mass spectrometry and gas chromatography (GC). Extreme-pressure properties of the sample at different concentrations were evaluated using a four-ball tribometer.

A multiple regression equation model was established, and tert-butyl trisulfide made the greatest contribution to the extreme-pressure properties according to the equation coefficient, while tert-butyl tetrasulfide had no effect. The results can be attributed to the fact that the structure of a sulfurized additive having an impact is application-specific.

A precise and fast way to predict weld load values of high-pressure sulfurized isobutylene by using GC and the established equation model were successfully developed. Moreover, the empirical equation shows the relationships between sulfide component concentrations and load carrying capacities.

The purpose of this paper is to understand the effect of base media on the tribological performance and tribochemistry of bismuth thiophosphate additive.

The oil‐water double soluble additive bismuth dithiophosphate was prepared and identified. The contributions of the two base media on the additive tribological behavior and the tribofilm components were comparatively studied.

The extreme pressure (EP) and friction‐reducing properties are remarkably improved with water substituted for paraffin as the base medium. The EP performance of the lubricating media containing this additive mainly results from the tribochemical reaction film on the rubbing surface, not from the viscosity of the base media. In water or paraffin medium, the adsorption process of this additive from the lubricant bulk onto the rubbing surface and the components and the properties of the tribochemical reaction films formed are different, which have important effect on the tribological performance.

The paper mainly focuses on how the water medium with polarity and the liquid paraffin base medium with non‐polarity affect on the tribological performance of the bismuth thiophosphate additive.

The research has found a water‐oil double soluble lubrication additive with outstanding EP and friction‐reducing performance.

The designed experiment provides a new approach to further learn the action mechanism of thiophosphate additive.

The purpose of this paper is to study the tribological behavior and mechanism of water‐soluble bismuth dithiophosphate as the additive of water‐based cutting fluid in aluminum alloy tapping.

Comparable investigation has been made on the lubrication performance of bismuth dithiophosphate and sodium dithiophosphate in aluminum alloy tapping. The aluminum alloy‐machined surface finish was observed on scanning electron microscope. The films on the work‐piece‐machined surface and the tap tool working surface were analyzed by X‐ray photoelectron spectroscopy.

The results indicated that the water medium containing 1 wt% the prepared water‐soluble bismuth dithiophosphate exhibited better tapping efficiency than the liquid paraffin containing 2.5 wt% chlorinated paraffin and 2.5 wt% sulfurized olefin. The bismuth sulfide component in the reaction film on the tap working surface plays a leading role in elevating the tapping efficiency and improving the machined surface finish.

The paper is restricted to the lubrication performance of bismuth dithiophosphate as the water‐based cutting fluid additive in 2024 aluminum alloy tapping.

The test method adopted is very close to the machined method applied in industry. The test results show that the bismuth dithiophosphate can obviously improve the tapping efficiency and the machined surface finish. Thus, it can be applied to the aluminum alloy cutting in automotive and aviation.

An attempt has been made to identify the chemical reaction film sourced from bismuth element and dithiophosphate group on the work‐piece‐machined surface and the tool working surface and their contribution to enhancing the tapping efficiency and improving the machining surface finish. This is helpful to the designers and the practitioners of the additives of metalworking fluid.

The main purpose of this study in the field of automotive brake friction material is to find an effective material to replace the environmentally hazardous copper in the brake pad formulation.

Cu is used as functional filler in various forms in the friction material formulation. Because of its hazardous impact to the aquatic life, a suitable replacement of Cu is the main focus of this research. Three novel friction composite materials using ground granulated blast furnace slag (GGBFS) as a suitable alternative for Cu were developed by increasing its Wt.% from 5% to 15% in the step of 5%.

The physical, mechanical and chemical properties of the developed friction composites were tested as per the industrial standards. The tribological properties were analyzed as per SAE J661 standard using the chase test rig. Initial studies revealed that the friction composite having 5% GGBFS exhibited better physical, mechanical and chemical properties with excellent frictional performance having minimal fluctuations even at higher temperatures. Nonetheless, the results showed that the friction composite containing 15 Wt.% GGBFS revealed a better wear resistance property compared with the other two composites due to the tribo lubricating layer formation at the frictional interface. Scanning electron microscope analysis was performed to understand the wear mechanism and tribo layer formations through topography studies.

This paper explains the influence of GGBFS as a replacement of barytes in brake pads formulation to enhance the tribological performance.

GERMANY Metals in contact with aqueous solutions. When metals are brought into contact with aqueous solutions at room temperature there is said to be an initial or ‘incubation’ period which may be of extremely short duration, almost a transient. After this period corrosion may increase rapidly to a thousand times its initial value or more, or may decrease even more rapidly. The latter process can be followed only with a cathode ray oscilloscope. The formation of local elements is assumed to be the cause of the processes observed. The effect on corrosion is shown at the instance of aluminium of different degrees of purity. Dissolution speeds are 6 g./sq.m./day for Al 99.998% rising to 190,000 g./sq.m./day for Al 99.2%.— (F. Tödt, Werkstoffe & Korrosion, 1954, 5, (11), 430–433).

In order to meet the requests of exploring environmental-friendly and multifunctional lubricant additives, some novel dimercaptothiadiazole derivatives containing hydroxyl are prepared and used as antiwear (AW) and extreme-pressure (EP) additives in biodegradable lithium grease. The paper aims to discuss these issues.

The tribological performances of the grease samples containing these derivatives are evaluated by using a four-ball tester. X-ray absorption near edge structure (XANES) spectroscopy is used to analyze the chemistry of tribofilms under AW/EP regime, and thermal films are also considered for comparison.

The tribological tests show that these derivatives are all effective in reducing wear, especially at lower additive concentrations, but they are basically failed in reducing friction. They are also helpful in improving the EP characteristic of the base grease. The thermal films generated by these derivatives are composed of adsorbed organic sulfide and ferrous sulfate, though for short-chain derivatives, organic sulfide is the only component at 5.0 wt.%. Ferrous sulfide is the main component of the tribofilms formed by these derivatives at various additive concentrations. But for short-chain derivatives, these tribofilms consist of ferrous sulfide and ferrous disulfide at 5.0 wt.%, and the appearance of disulfide suggests that the interfacial temperature between the upper ball and three lower balls under these conditions is considerably low. The EP films generated by short-chain derivatives are all composed of organic sulfide and ferrous sulfide, while for long-chain derivatives, ferrous sulfide is the main component.

These low-toxic and oil-soluble dimercaptothiadiazole derivatives are effective in improving the tribological characteristic of the biodegradable lithium grease, and these heterocyclic derivatives may be good substitutes for some harmful traditional additives.

Purpose – This paper aims to detect or identify the presence of hydrocarbon infiltration on sampling point in the Rambe River area according to the obtained VOCs and the adsorbed SVOCs.

Design/Methodology/Approach – The Gore-sorber method has been used to capture volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) as indicators of subsurface hydrocarbon generation and entrapment. This method is usually used in environmental surveys for the oil investigations in certain areas for surface survey screening, designed to collect a broad range of VOCs and (SVOCs) at lower concentrations, quickly and inexpensively. The results also indicated a general correlation between the GORE-SORBER and reference method data. The research was conducted in Rambe River Village, Tebing Tinggi sub-district of Tanjung Jabung Barat district, Jambi Province Indonesia. The collection of the Gore-Sorber modules were analyzed using a gas chromatography-mass spectrometer thermal desorption (GC/MS).

Findings – The results showed that from all sampling points in Tebing Tinggi areas, the dominant components detected are carbonyl sulphide, dimethyl sulfide, ethane, propane, butane, 2-methyl butane, pentane, and carbon sulfide with carbon chain in the range C2-C5. These hydrocarbon gases (C1-C4) which may be from thermogenic or microbial processes. The highest concentrations of carbonyl sulfide were 392.67 ng and dimethyl disulfide 261.90 ng.

Originality/Value – In addition to estimate and predict the petroleum formation, this article provides information about the presence of oil fields in the area of the Sungai Rambe Village

This paper aims to evaluate the inhibition efficiency of thiadiazole derivatives, such as 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 5-methly-2-mercapto-1,3,4-thiadiazole (MMTD) and 2,5-dithiododecyl-1,3,4-thiadiazole (DDTD), in 50 mg/L hydrogen sulfide for silver strip.

Evaluation was carried out by corrosion-inhibiting test, electrochemical measurement and surface analysis techniques. 3D surface profiler, atom force microscopy, scanning electron microscopy and energy-dispersive X-ray analysis were applied and finally confirmed the existence of the adsorbed film.

The electrochemical measurement showed that the inhibition efficiency increases with increasing inhibitor concentration in 50 mg/L hydrogen sulfide solution, while the corrosion rate and the corrosion current decrease. Weight-gained measurements also indicated that inhibitor decreases the corrosion rate in the studied solution. The adsorption of DMTD and MMTD on the silver surface obeys Temkin’s adsorption isotherm, but the adsorption of DDTD follows Langmuir’s adsorption isotherm. That means that the inhibition mechanism is different between DMTD, MMTD and DDTD. The ΔG0_ad values of DMTD, MMTD and DDTD were −37.47, −37.29 and −38.69 kJ/mol, respectively. It showed that there was an adsorption bond between silver surface and inhibitor, and the adsorption belongs to chemical adsorption.

The inhibitors have an excellent inhibition efficiency, and the best inhibition efficiency is 91.76 per cent. Inhibitors can effectively inhibit metal corrosion in the oil and gas.

This study aims to compare the influence of different solid lubricants on the friction stability of a non-asbestos disc brake pad.

Three brake pads were developed using three lubricants, namely, non-asbestos brake pad with sulfide mix (NASM), non-asbestos brake pad with bismuth sulfide (NABS) and non-asbestos brake pad with molybdenum disulfide (NAMO). Sulfide mix was indigenously developed by physically mixing friction modifiers, alkaline earth chemicals and various metallic sulfides homogeneously dispersed in graphite medium. The physical, chemical, mechanical and thermal properties of brake pads were characterized as per industrial standards. The tribological performances were studied using the Chase testing machine as SAE-J661-2012. The worn surface of the pads was studied using scanning electron microscope to analyze the dominating wear mechanism.

NASM was excellent in fade as well as wear resistance. NABS was better from a wear point of view, but fade resistance was moderate despite its higher cost. NAMO fared average in fade and wear despite its excellent dry lubricating properties. NASM was excellent in terms of fade as well as wear resistance.

Among the selected metal sulfides, the indigenously developed sulfide mix was better than the other two sulfides, which indicates that the synergetic effect of metal sulfides was always preferable to the individual sulfides.