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The effect of chlorides on corrosion of reinforcing steel is well documented in the literature. However, few studies have focused attention on the effect of sulphates on the corrosion of low carbon steel in alkaline media. This paper aims to address this issue.

This paper describes the results of the investigation into the corrosion behaviour of low carbon steel (typically used as reinforcing steel), exposed to alkaline media at a pH of 9 and 12 with varying concentrations of sulphate and chloride ions, as well as, in sulphate only solutions. An attempt was made to inhibit corrosion of steel exposed to the corrosive media using laser surface treatment of the steel specimens. Mass loss tests and electrochemical tests were conducted to evaluate the effect of sulphate only and the combined effect of sulphate and chloride ions in an alkaline media on steel.

It was found that sulphate ions could cause corrosion of steel in alkaline media. The severity of the attack increased with increasing sulphate ion concentrations, as well as with combinations of sulphate and chloride ions. The pH 12 conditions seem to show much more critical attack with evidence of pitting corrosion as compared to uniform corrosion for test conditions at a pH of 9. The attempt to inhibit the observed corrosion of steel exposed to the corrosive high alkaline media containing sulphate ions on their own and in combination of chloride ions by laser surface treatment proved to be successful.

The research undertaken here adds to the body of knowledge relating to the effect of sulphate ions on reinforcing steel corrosion in highly alkaline media. Most literature points out that sulphate ions on their own do not have a corrosive effect, but rather, a passivating effect!

Macro synthetic steel fibers were incorporated into the concrete material as a toughening agent to improve the corrosion and cracking resistances of concrete in a sulfate-containing service environment.

To study the basic mechanical properties of this system, an accelerated concrete degradation test was designed to evaluate the influence of the sulfate ions on the concrete. A three-point bending test was carried out in the laboratory to evaluate the fracture toughness. The thickness of the damaged concrete layer and changes of microstructure of the degraded concrete were monitored by using ultrasound, scanning electron microscopy and X-ray diffraction detection methods.

The results showed that compared to the performance of ordinary concrete, in an exposure environment containing sulfate ions, the structure compactness of macro synthetic steel fiber concrete was improved, degradation resistance to the sulfate solution was enhanced and the fracture resistance performance was improved significantly.

The thickness of the degradation layer on the macro synthetic steel fiber concrete was less than a half of that of ordinary concrete in the sulfate environment, and was generally unchanged with increase in the sulfate concentration. Through micro-structural analysis, it was confirmed that macro synthetic steel fiber improved the compactness of the concrete structure, inhibiting access of sulfate ions to the interior of the concrete and thereby reducing the degree of sulfate degradation to the concrete.

The influence of calcium nitrite corrosion inhibitor on the durability of Portland cement mortars against sulphate solutions was investigated experimentally in the present research. For this reason, mortar specimens were produced using CEM I 42.5N cement and were immersed in different sulphate and sulphate‐chloride contaminated solutions. Sulphate resistance was evaluated according to the procedure described in ASTM C1012. The properties measured were the specimens' expansion, development of compressive strength, changes in corrosion potential and corrosion current density measurements of steel‐containing specimens.

A number of local authority‐built properties in the Aberdeen area were found to display evidence of horizontal cracking. An investigation carried out on one of these properties suggested that this damage resulted from sulphate attack of the mortar joints and it was assumed that this was the cause of damage in similar properties at the same location. However, this paper argues that wall‐tie corrosion is a more probable cause of the damage evident in these properties. It is suggested that the only effective and reliable method to establish an incidence of cavity wall‐tie corrosion is to carry out a direct inspection through the removal of a sample of ties.

Introduction Concrete is a mixture of naturally occurring geological aggregates bonded together by a cementitious agent which ‘sets’ by reacting with water. This setting process is called ‘hydration’ and is not a dissolution process. The advantages of concrete are as follows:

The world abounds with numerous examples of fault‐free brickwork which have endured for centuries with little maintenance. In this country, bricks are an indigenous product and the use of brickwork is well understood, being a basically simple and economic method of building without sophisticated techniques.

Earthen construction does not meet today’s requirements due to certain limitations such as low water resistance and its high vulnerability to cracking damage. The purpose of this study is to improve the mechanical properties and low durability of adobe blocks by incorporating date palm wastes as a natural reinforcement and lime as a stabilizer.

Soil from the region of Biskra in Algeria was mixed with sand and lime in suitable ratios. Then, date palm wastes were added to the previous mixture at different ratios (0.3%, 0.6% and 0.9%) by dry mix weight to manufacture adobes. Cubical and cylindrical specimens were prepared and tested in a laboratory to investigate the curing time, mechanical and durability characteristics of the formulated blocks. In addition, X-ray diffraction and scanning electron microscopy (SEM) tests were used to identify the materials.

It has been observed that the addition of lime to the soil is very beneficial for its stabilization, in particular for an optimum of 12%. The presence of date palm waste in the mixture (soil + lime) generated a significant improvement in tensile strength reaching a rate of about 67%. The same observation was made for the tests of resistance to dry abrasion, resistance to erosion, attack by external sulphate and wetting/drying. However, for cases of compressive strength, water absorption and swelling an unfavorable effect was recorded.

Based on the above-mentioned findings, this paper presents a novel solution to increase the durability of adobe materials using date palm wastes with oven curing at 65°C for about nine days. Adopting such an approach would certainly encourage building durable mud housing on a large scale. This can contribute to solving the acute housing shortage, particularly in poor countries.

One of the sources for the increase in the carbon footprint on the earth is the manufacturing of cement, which causes a severer environmental impact. Abundant research is going on to diminish CO₂ content in the atmosphere by appropriate utilization of waste by-products of industries. Alkali-activated slag concrete (AASC) is an innovative green new concrete made by complete replacement of cement various supplementary cementitious raw materials. Concrete is a versatile material used in different fields of structures, so it is very important to study the durability in different exposures along with the strength. The purpose of this paper is to study the performance of AASC by incorporating quartz sand as fine aggregate under different exposure conditions.

The materials for this innovative AASC are selected based on preliminary studies and literature surveys. Based on numerous trials a better performance mix proportion of AASC with quartz sand is developed with 1:2:4 mix proportion, 0.8 alkali Binder ratio, 19 M of NaOH and 50% concentration of Na₂SiO₃. Subsequently, AASC cubes are prepared and exposed for 3, 7, 14, 28, 56, 90, 112, 180, 252 and 365 days in ambient, acid, alkaline, sulfate, chloride and seawater and tested for compressive strength. In addition, to study the microstructural characteristics, scanning electron microscope (SEM), energy dispersive X-ray analysis and X-ray diffraction analysis was also performed.

Long-term performance of AASC developed with quartz sand is very good in the ambient, alkaline environment of 5% NaOH and seawater with the highest compressive strength values of 51.8, 50.83 and 64.46, respectively. A decrease in compressive strengths was observed after the age of 14, 56 and 112 days for acid, chloride and sulfate exposure conditions, respectively. SEM image shows a denser microstructure of AASC matrix for ambient, alkaline of 5% NaOH and seawater.

The proposed AASC is prepared with a mix proportion of 1:2:4, so the other proportions of AASC need to verify. In general plain, AASC is not used in practice except in few applications, in this work the effect of reinforced AASC is not checked. The real environmental exposure in fields may not create for AASC, as it was tested in different exposure conditions in the laboratory.

The developed AASC is recommended in practical applications where early strength is required, where the climate is hot, where water is scarce for curing, offshore and onshore constructions exposed to the marine environment and alkaline environment industries like breweries, distilleries and sewage treatment plants. As AASC is recommended for ambient air and in other exposures, its implementation as a construction material will reduce the carbon footprint.

The developed AASC mix proportion 1:2:4 is an economical mix, because of low binder content, but it exhibits a higher early age compressive strength value of 45.6 MPa at the age of 3 days. The compressive strength increases linearly with age from 3 to 365 days when exposed to seawater and ambient air. The performance of AASC is very good in the ambient, alkaline environment and seawater compared to other exposure conditions.

The purpose of this study was to reuse cement kiln dust (CKD) in cement products and report the results of determining the long-term compression and flexural tensile strengths of mortars containing CKD as a partial replacement of sulfate-resistant cement (SRC). During the manufacturing of Portland cement, voluminous quantities of the byproduct dust are produced, which is commonly known as CKD. In the past decade, according to environmental requirements, many researchers have attempted to reuse CKD in cement products.

The long-term compression and flexural tensile strengths of mortars containing CKD as a partial replacement of SRC were tested. The replacement ratios in this study were 0, 5, 10, 15 and 20 per cent. The specimens were exposed to a highly saline environment after normal curing in water for a 28-day period.

The results indicated a slight increase in the strength of CKD–SRC mortar containing 10 per cent CKD and moderate sulfate resistance when the CKD ratio reached 20 per cent, as compared to the reference mortar. In addition, CKD did not adversely affect the properties of SRC mortar subjected to sulfate exposure, even after one year.

The tests were inducted for the first time on SRC, and the new results can be used to produce an environmental-friendly concrete.