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Article
Publication date: 4 November 2013

Jeremy Cockrem, Tomasz Pawel Dudziak, Nigel Simms, Mikolaj Lukaszewicz and John Oakey

It is well known that alloys, based on iron, were exposed to steam oxidation environment producing thick and non-protective oxide scale. More expensive stainless steels contain…

Abstract

Purpose

It is well known that alloys, based on iron, were exposed to steam oxidation environment producing thick and non-protective oxide scale. More expensive stainless steels contain more Cr and are able to form more protective scales. The purpose of this research was to show ability to employ nitride coating on different alloys (T23, T91, E1250, 347HFG and HR3C) in order to enhance steam oxidation resistance.

Design/methodology/approach

The alloys were exposed to steam oxidation rig. Before the test, furnace was purged by nitrogen in order to remove moisture and oxygen. Di-ionised water was pumped from the reservoir using a peristaltic pump into the furnace. System was kept in the closed circle. To reduce solubility of oxygen, di-ionised water was constantly purged by nitrogen. The total exposure time was 2,000 h at 650°C under 1 bar pressure.

Findings

Due to the research, it was found that plasma nitriding process is detrimental for the protection of high-temperature structured materials; the high concentration and high activity of Cr produced a CrN phase. This phase is not stable in steam environment and underwent oxidation to Cr2O3 and further into volatile phase (CrO2(OH)2). Therefore, austenitic steels (E1250, 347HFG and HR3C) coated with nitride coating deposited by plasma nitriding process suffered similar degradation as the uncoated low Cr ferritic steel.

Research limitations/implications

The main limitation of the research conducted in this study was corrosion resistance of the exposed materials.

Originality/value

To the best of the authors' knowledge, this report is the first of its kind to present nitrided alloys (ferritic and austenitic) exposed in steam oxidation.

Details

Anti-Corrosion Methods and Materials, vol. 60 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 July 1966

C.W. Tuck, M. Odgers and K. Sachs

The work described in this paper is part of a current programme that has two objects: (1) to investigate further the reasons for the different scaling behaviour of steel in steam

Abstract

The work described in this paper is part of a current programme that has two objects: (1) to investigate further the reasons for the different scaling behaviour of steel in steam and carbon dioxide, although these gases have similar oxygen potentials; (2) to provide background information for an investigation into the effect of variations in re‐heating furnace atmospheres upon scaling and scale adhesion.

Details

Anti-Corrosion Methods and Materials, vol. 13 no. 7
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 1 June 1966

C.W. Tuck, M. Odgers and K. Sachs

The work described in this paper is part of a current programme that has two objects: (1) to investigate further the reasons for the different scaling behaviour of steel in steam

Abstract

The work described in this paper is part of a current programme that has two objects: (1) to investigate further the reasons for the different scaling behaviour of steel in steam and carbon dioxide, although these gases have similar oxygen potentials; (2) to provide background information for an investigation into the effect of variations in re‐heating furnace atmospheres upon scaling and scale adhesion.

Details

Anti-Corrosion Methods and Materials, vol. 13 no. 6
Type: Research Article
ISSN: 0003-5599

Content available
Article
Publication date: 1 October 2002

William M. Cox

492

Abstract

Details

Anti-Corrosion Methods and Materials, vol. 49 no. 5
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 8 June 2015

Shu-Hao Deng, Xi Yang, Mao Wang and Jiao Wang

– The purpose of this paper is to improve anti-corrosion, self-cleaning, hydrophily and sterilization properties of aluminum (Al) alloy.

Abstract

Purpose

The purpose of this paper is to improve anti-corrosion, self-cleaning, hydrophily and sterilization properties of aluminum (Al) alloy.

Design/methodology/approach

A multifunctional coating for medical external application on Al alloy had been prepared by anodic oxidation, electrolytic coloring silver (Ag) and sealed in boiling water with nano-sized titanium dioxide (TiO2) particles. The multifunctional coating was characterized by X-ray diffraction, scanning electron microscope and energy dispersive spectroscopy. Other properties such as corrosion-resistance, wipe-resistance, hydrophilicity, photochemical decomposition and bactericidal antiseptic effect were also investigated.

Findings

The results demonstrate that a golden film with multi-function had been obtained for medical external application. The main phase of coating is amorphous Al2O3, and nano-sized silver particle is electrodeposited in bottom of film hole, while nano-sized TiO2 is sealed on the external surface of coating. The properties of film, such as anti-corrosion, self-cleaning, hydrophily, sterilization are better than those of Al alloy substrate.

Originality/value

Considering about this usage for medical external application, a multifunctional coating which has the properties such as decoration, anti-corrosion, sterilize and self-cleaning has been first prepared on Al alloy surface in the study. This coating would meet the requirements of medical external using and provide theoretical and practical foundation about Al alloy for medical use.

Details

International Journal of Structural Integrity, vol. 6 no. 3
Type: Research Article
ISSN: 1757-9864

Keywords

Article
Publication date: 21 March 2008

Manpreet Kaur, Harpreet Singh and Satya Prakash

This paper seeks to summarise the results of available research on the use of high velocity oxy‐fuel (HVOF) thermal‐spray technique to provide protection against high temperature…

1454

Abstract

Purpose

This paper seeks to summarise the results of available research on the use of high velocity oxy‐fuel (HVOF) thermal‐spray technique to provide protection against high temperature corrosion and erosion‐corrosion of materials.

Design/methodology/approach

This paper describes one of the recent thermal‐spray processes, namely HVOF thermal‐spray technology and presents a survey of the studies on the use of this technique to provide protection against corrosion and erosion‐corrosion of high temperature alloys, with a special emphasis on boiler steels.

Findings

High temperature corrosion and erosion‐corrosion are serious problems observed in steam‐powered electricity generation plants, gas turbines, internal combustion engines, fluidized bed combustors, industrial waste incinerators and recovery boilers in paper and pulp industries. These problems can be prevented by changing the material or altering the environment, or by separating the component surface from the environment. Corrosion prevention by the use of coatings for separating materials from the environment is gaining importance in surface engineering. Amongst various surface modifying techniques, thermal spraying has developed relatively rapidly due to the use of advanced coating formulations and improvements in coating application technology. One of the variants of thermal spraying, namely HVOF has gained popularity in recent times due to its flexibility for in‐situ applications and superior coating properties.

Research limitations/implications

This review covers mainly information that has been reported previously in the open literature, international journals and some well‐known textbooks.

Practical implications

The paper presents a concise summary of information for scientists and academics, planning to start their research work in the area of surface engineering.

Originality/value

This paper fulfils an identified information/resources need and offers practical help to an individual starting out on a career in the area of surface engineering for erosion‐corrosion and wear.

Details

Anti-Corrosion Methods and Materials, vol. 55 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 June 1964

J.N. Wanklyn

THE Aqueous Corrosion Section forms a part of the Metallurgy Division, which also contains a complementary section covering the field of gaseous oxidation. The size of the section…

Abstract

THE Aqueous Corrosion Section forms a part of the Metallurgy Division, which also contains a complementary section covering the field of gaseous oxidation. The size of the section has fluctuated over the years, but has generally been of the order of six to eight professional staff. Initially the section's interests were in corrosion at temperatures below 100°C and, in connection with the DIDO reactor and other systems containing aluminium, work on the pitting corrosion of aluminium and aluminium alloys was carried out.

Details

Anti-Corrosion Methods and Materials, vol. 11 no. 6
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 1 August 1951

The Aluminium Company of America have recently investigated the catalytic effect of several metals on the oxidation of lubricating oils and have found that aluminium alloys and…

1075

Abstract

The Aluminium Company of America have recently investigated the catalytic effect of several metals on the oxidation of lubricating oils and have found that aluminium alloys and stainless steel have only a very slight or no effect in contrast with copper and low‐carbon steel which very definitely have an adverse effect. These facts were given by D. W. Sawyer, one of their Research Chemists, in a paper read before the Petroleum Division of the American Society of Mechanical Engineers at Toronto, in June.

Details

Industrial Lubrication and Tribology, vol. 3 no. 8
Type: Research Article
ISSN: 0036-8792

Article
Publication date: 1 May 1961

Last month we published abstracts and summaries of some of the papers presented at the Congress, which was held at the Imperial College of Science and Technology from April 10–15…

Abstract

Last month we published abstracts and summaries of some of the papers presented at the Congress, which was held at the Imperial College of Science and Technology from April 10–15 under the auspices of the International Union of Pure and Applied Chemistry. In this issue we publish further abstracts and summaries together with illustrations of many of the corrosionists attending and photographs of some of the many visits which were arranged to works and laboratories. The Congress attracted over 800 delegates.

Details

Anti-Corrosion Methods and Materials, vol. 8 no. 5
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 1 July 1965

E.G. ELLIS

A series of articles dealing, in as simple a way as possible, with the basic facts of lubrication, lubricants, their selection and prescription, specification, application, and…

Abstract

A series of articles dealing, in as simple a way as possible, with the basic facts of lubrication, lubricants, their selection and prescription, specification, application, and testing. This series is primarily intended for students, engineering personnel who may be unfamiliar with certain aspects and others who, one way or another, are interested in this important subject. Part One in our March Issue dealt with Friction, Lubrication and Wear.

Details

Industrial Lubrication and Tribology, vol. 17 no. 7
Type: Research Article
ISSN: 0036-8792

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