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Coral aggregate seawater concrete (CASC) is a new type of lightweight aggregate concrete that is becoming widely used in reef engineering. To investigate the corrosion behavior of different kinds of rebar in CASC exposed to simulated seawater for 0-270 d, the electrochemical techniques, including linear polarization resistance (LPR) technique and the electrochemical impedance spectroscopy (EIS), were used in the present work.

The electrochemical techniques, including LPR technique and the EIS, were used in the present work.

Based on the time-varying law of linear polarization curves, self-corrosion potential (E_corr), polarization resistance (R_p), corrosion current density (I_corr), corrosion rate (i), and the characteristics of EIS diagrams for different types of rebar in CASC, it can be found that the anti-corrosion property of them can be ranked as epoxy resin coated steel > 2205 duplex stainless steel (2205S) > 316 L stainless steel (316 L) > organic coated steel > ordinary steel. Additionally, the linear regression equation between R_p and charge transfer resistance (R_ct) was established. Finally, the EIS corrosion standard of rebar was established from the LPR corrosion standard, which provides a direct standard for the EIS technique to determine the condition of rebar in CASC.

The linear regression equation between polarization resistance and charge transfer resistance was established. And the EIS corrosion standard of rebar was established from the LPR corrosion standard, which provides a direct standard for the EIS technique to determine the condition of rebar in CASC.

The purpose of this paper is to study the variations of composition and properties of the passive film on 316 L stainless steel surface in 80°C, 0.5 mol L-1 H2SO4 + 2 mg L-1 NaF solution, is helpful to understand the mechanisms of corrosion resistancethe of plated Pd on 316 L ss.

The variations of composition and properties of the passive film on 316 L stainless steel surface in 80°C, 0.5 mol L-1 H2SO4 + 2 mg L-1 NaF solution after connected to Pd electrode were studied with methods of potential monitor, X-ray photoelectron spectroscopy analysis and electrochemical impedance spectrum (EIS) measurement.

By connecting to a Pd electrode, the potential of the SS sample increased from the active region to the passive region. By connecting to the Pd electrode, the contents of Cr, Cr(OH)3 and Fe3O4 in passive film increased obviously. With increased Pd/SS area ratio, the Cr(OH)3 content in passive film increased but the Fe3O4 content changed little. The results show that after connecting to Pd the corrosion resistance of the passive film on 316 L stainless steel increases obviously, which may be attributed to the more compact passive film because of higher Cr, Cr(OH)3 and Fe3O4 contents and less point defects in the film.

The effects and mechanism of Pd on passivation of SS was studied.

The purpose of this paper is to address the concern of some stainless steel users. To understand the effect of surface white spots on corrosion performance of stainless steel.

White spots appeared on some component surfaces made of 316 L stainless steel in some industrial applications. To address the concern about the pitting performance in the spot areas, the pitting corrosion potential and corrosion resistance were measured in the spot and non-spot areas by means of potentiodynamic polarization and electrochemical impedance spectroscopy and the two different surface characteristics were analytically compared by using optical microscopy, laser confocal microscopy, scanning electron microscopy, x-ray diffraction, energy dispersive spectroscopy and auger energy spectroscopy. The results indicated that the pitting performance of the 316 L stainless steel was not negatively influenced by the spots and the white spots simply resulted from the slightly different surface morphology in the spot areas.

The white spots are actually the slightly rougher surface areas with some carbon-containing species. They do not reduce the pitting resistance. Interestingly, the white spot areas even have slightly improved general corrosion resistance.

Not all surface contamination or roughening can adversely affect the corrosion resistance of stainless steel.

Stainless steel components with such surface white spots are still qualified products in terms of corrosion performance.

The surface spot of stainless steel was systematically investigated for the first time for its effect on corrosion resistance and the conclusion was new to the common knowledge.

Fused filament fabrication (FFF) technique using metal filled filaments in combination with debinding and sintering steps can be a cost-effective alternative for laser-based powder bed fusion processes. The mechanical behaviour of FFF-metal materials is highly dependent on the processing parameters, filament quality and adjusted post-processing steps. In addition, the microstructural material properties and geometric characteristics are inherent to the manufacturing process. The purpose of this study is to characterize the mechanical and geometric performance of three-dimensional (3-D) printed FFF 316 L metal components manufactured by a low-cost desktop 3-D printer. The debinding and sintering processes are carried out using the BASF catalytic debinding process in combination with the BASF 316LX Ultrafuse filament. Special attention is paid on the effects of build orientation and printing strategy of the FFF-based technology on the tensile and geometric performance of the 3-D printed 316 L metal specimens.

This study uses a toolset of experimental analysis techniques [metallography and scanning electron microcope (SEM)] to characterize the effect of microstructure and defects on the material properties under tensile testing. Shrinkage and the resulting porosity of the 3-D printed 316 L stainless steel sintered samples are also analysed. The deformation behaviour is investigated for three different build orientations. The tensile test curves are further correlated with the damage surface using SEM images and metallographic sections to present grain deformation during the loading progress. Mechanical properties are directly compared to other works in the field and similar additive manufacturing (AM) and Metal Injection Moulding (MIM) manufacturing alternatives from the literature.

It has been shown that the effect of build orientation was of particular significance on the mechanical and geometric performance of FFF-metal 3-D printed samples. In particular, Flat and On-edge samples showed an average increase in tensile performance of 21.7% for the tensile strength, 65.1% for the tensile stiffness and 118.3% for maximum elongation at fracture compared to the Upright samples. Furthermore, it has been able to manufacture near-dense 316 L austenitic stainless steel components using FFF. These properties are comparable to those obtained by other metal conventional processes such as MIM process.

316L austenitic stainless steel components using FFF technology with a porosity lower than 2% were successfully manufactured. The presented study provides more information regarding the dependence of the mechanical, microstructural and geometric properties of FFF 316 L components on the build orientation and printing strategy.

This paper aims to investigate the galvanic corrosion of titanium/L 316 stainless steel, by electrochemical noise (EN), electrochemical impedance spectroscopy (EIS), and anode/cathode area ratio effect on the galvanic behavior of the couple.

The EN measurement was employed to examine effects of anode to cathode area ratio on the galvanic corrosion behavior between stainless steel L 316 and titanium in artificial seawater. Current noise and potential noise were monitored simultaneously using a three‐electrode configuration under open‐circuit condition. The noise resistance was evaluated as the ratio of the standard deviation of the potential to that of the current noise after removing the DC component. The time‐series noise patterns were transformed into frequency domain by fast Fourier transformation and then their power spectrum densities (PSDs) at specified frequency were determined and compared with the EIS and polarization results.

The EN, EIS and polarization results were in agreement. Galvanic corrosion density increase and galvanic potential moved slowly to negative direction with decrease in anode/cathode area ratio. The results showed that the slope of PSD of the current (i.e the “roll off”) was rising slowly where the anode/cathode area ratio was declined. The relationship between polarization resistance (Rp) and noise resistance (Rn) was investigated. Rt was determined by EIS for samples, and its value compared with Rp and Rn. The result indicates that galvanic corrosion has an inversely relation with anode/cathode area ratio that exposed to aggressive environment.

This paper presents the application of noise analysis to demonstrate galvanic corrosion and the effect of area ratio anode/cathode on current density and galvanic potential.

The purpose of this paper is to fill the knowledge gap in the microscopic origin of high corrosion resistance in the passivated 316 L stainless steel.

Here, the pitting corrosion potential of the passivated 316 L stainless steel is measured, as well as the non-passivated one. Using the aberration-corrected scanning transmission electron microscopy, the microstructure of the passive film is unambiguously revealed. Combining the electron energy loss spectroscopy with the X-ray photoelectron spectroscopy, the depth profiling analysis is conducted and the variations in composition from the very surface of the passive film to the internal steel are clarified.

By optimizing the passivation treatment process, the authors significantly increase the pitting corrosion potential of the passivated 316 L stainless steel by 300 mV, compared with the non-passivated one. The passive film features a unique amorphous multilayer structure. On the basis of the depth profiling analysis, the origin of the high corrosion resistance achieved is unraveled, in which the redistribution of elements in the multilayer passive film, especially the enrichment of Cr in the topmost layer and Ni at the film-metal interface, prevent the oxidization of the inner iron of the steel.

This study advances understanding of the nature of the passive film from a microscopic view, which can be helpful for the further improvement of the corrosion resistance performance.

This study introduces a model for the multilayer structure of passive films that reveals the reconstitution of the passive films after the opportune passivation treatments. Due to the redistribution of elements caused by passivation, the enrichment of Cr in the outer layer and Ni near the film-metal interface leads to enhance corrosion resistance performance.

An experimental and numerical study of thermal profiles of 316 L stainless steel during selective laser melting (SLM) was developed. This study aims to present a novel approach to determine the significance and contribution of thermal numerical modeling enhancement factors of SLM.

Surface and volumetric heat models were proposed to compare the laser interaction with the powder bed and substrate, considering the powder size, absorptance and propagation of the laser energy through the effective depth of the metal layer. The approach consists in evaluating the contribution of the thermal conductivity anisotropic enhancement factors to establish the factors that minimized the error of the predicted results vs the experimental data.

The level of confidence of the carried-out analysis is of 97.8% for the width of the melt pool and of 99.8% for the depth of the melt pool. The enhancement factors of the y and z spatial coordinates influence the most in the predicted melt pool geometry.

Nevertheless, the methodology presented in this study is not limited to 316 L stainless steel and can be applied to any metallic material used for SLM processes.

This study is focused on 316 L stainless steel, which is commonly used in SLM and is considered a durable material for high-temperature, high-corrosion and high-stress situations.

The additive manufacturing (AM) technology is a relatively new technology becoming global. The AM technology may have health benefits when compared to the conventional industrial processes, as the workers avoid extended periods of exposure present in conventional manufacturing.

This study presents a novel approach to determine the significance and contribution of thermal numerical modeling enhancement factors of SLM. It was found that the volumetric heat model and anisotropic enhancement thermal approaches used in the present research, had a good agreement with experimental results.

The purpose of this paper is to investigate the influence of the potential of hydrogen (pH) and dissolved oxygen in artificial seawater on the passivation behavior of 316L stainless steel.

The corrosion behavior was studied by using electrochemical measurements such as electrochemical impedance spectroscopy and polarization curve. The passive films were characterized with X-ray photoelectron spectroscopy.

The polarization resistance of the passive film decreases as the pH value drops ascribed to the formation of much more point defects. The donor carrier concentration (ND) in the passive film formed in the deaerated condition is lower than that in aerated conditions. Nevertheless, this phenomenon is the opposite when the pH value is 1 due to the significant decrease of Fe oxides/hydroxides coupled with the stable content of Cr oxides/hydroxides species. In addition, the compositional variation of the passive film also leads to the changes of its semiconductor properties from N-type to bipolar type.

This paper shows the variation of polarization resistance, corrosion potential, passive film composition and semiconductor properties with the pH value and dissolved oxygen. The results can serve as references to the further study on crevice corrosion of 316L in seawater.

Stainless-clad bimetallic steels (SCBS) are widely investigated in some extremely environmental applications areas, such as polar sailing area and tropical oil and gas platforms areas, because of their excellent anticorrosion performance and relatively lower production costs. However, the properties of SCBS, including the mechanical strength, weldability and the anticorrosion behavior, have a direct relation with the manufacturing process and can affect their practical applications. This paper aims to review the application and the properties requirements of SCBS in marine environments to promote the application of this new material in more fields.

In this paper, the manufacturing process, welding and corrosion-resistant properties of SCBS were introduced systematically by reviewing the related literatures, and some results of the authors’ research group were also introduced briefly.

Different preparation methods, such as rolling composite, casting rolling composite, explosive composite, laser cladding and plasma arc cladding, as well as the process parameters, including the vacuum degree, rolling temperature, rolling reduction ratio, volume ratios of liquid to solid, explosive ratio and the heat treatment, influenced a lot on the properties of the SCBS through changing the interface microstructures. Otherwise, the variations in rolling temperature, pass, reduction and the grain size of clad steel also brought the dissimilarities of the mechanical properties, microhardness, bonding strength and toughness. Another two new processes, clad teeming method and interlayer explosive welding, deserve more attention because of their excellent microstructure control ability. The superior corrosion resistance of SCBS can alleviate the corrosion problem in the marine environment and prolong the service life of the equipment, but the phenomenon of galvanic corrosion should be noted as much as possible. The high dilution rate, welding process specifications and heat treatment can weaken the intergranular corrosion resistance in the weld area.

This paper summarizes the application of SCBS in marine environments and provides an overview and reference for the research of stainless-clad bimetallic steel.

The purpose of this paper is to investigate effects of layer thickness on densification, surface morphology, microstructure and mechanical and corrosion properties of 420 stainless steel fabricated by laser-powder bed fusion (L-PBF).

Standard specimens were printed at layer thickness of 10, 20 and 30 µm to characterize Archimedes density, surface roughness, tensile strength, elongation, hardness, microstructural phases and corrosion performance in the as-printed and heat-treated condition.

Archimedes density slightly increased from 7.67 ± 0.02 to 7.70 ± 0.02g/cm³ and notably decreased to 7.35 ± 0.05 g/cm³ as the layer thickness was changed from 20 µm to 10 and 30 µm, respectively. The sensitivity to layer thickness variation was also evident in properties, the ultimate tensile strength of as-printed parts increased from 1050 ± 25 MPa to 1130 ± 35 MPa and decreased to 760 ± 35 MPa, elongation increased from 2.5 ± 0.2% to 2.8 ± 0.3% and decreased to 1.5 ± 0.2, and hardness increased from 55 ± 1 HRC to 57 ± 1 HRC and decreased to 51 ± 1 HRC, respectively. Following heat treatment, the ultimate tensile strength and elongation improved but the general trends of effects of layer thickness remained the same.

Properties obtained by L-PBF are superior to reported properties of 420 stainless steel fabricated by metal injection molding and comparable to wrought properties.

This study successfully the sensitivity of mechanical and corrosion properties of the as-printed and heat-treated parts to not only physical density but also microstructure (martensite content and tempering), as a result of changing the layer thickness. This manuscript also demonstrates porosity evolution as a combination of reduced energy flux and lower packing density for parts processed at an increasing layer thickness.