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Article
Publication date: 24 April 2018

B. Chen, Peisheng Liu and J.H. Chen

With the nickel foam made by the technique of electrodeposition on polymer foam, the purpose of this paper is to investigate the influence of several deferent processes on the…

Abstract

Purpose

With the nickel foam made by the technique of electrodeposition on polymer foam, the purpose of this paper is to investigate the influence of several deferent processes on the surface morphology and the specific surface area of this porous product.

Design/methodology/approach

The surface morphologies of the nickel foam were examined by SEM. The specific surface area of the porous product was measured by gas (N2) permeability method and also calculated by the reported formula.

Findings

The nickel foam from sintering in NH3 decomposition atmosphere at 850°C will achieve the same specific surface area as that at 980°C, whether this porous structure after electrodeposition comes through direct sintering in NH3 decomposition atmosphere, or through burning in air at 600°C for 4 min beforehand then the same reductive sintering.

Originality/value

There have been some studies on the preparation and application of nickel foam, but few works focus on the processing influence on the specific surface of this porous product. The present work provides the investigations on the difference of the product made under different producing conditions, and the influence of several deferent processes on the specific surface area of the product.

Details

Multidiscipline Modeling in Materials and Structures, vol. 14 no. 4
Type: Research Article
ISSN: 1573-6105

Keywords

Article
Publication date: 12 August 2019

Lei Guo, Lien Zhu, Lei Ma, Jian Zhang, QiuYu Meng, Zheng Jin, Meihua Liu and Kai Zhao

The purpose of this paper is to prepare a spherical modifier-modified activated carbon fiber of high specific capacitance intended for electrode materials of supercapacitor.

Abstract

Purpose

The purpose of this paper is to prepare a spherical modifier-modified activated carbon fiber of high specific capacitance intended for electrode materials of supercapacitor.

Design/methodology/approach

In this study, phenolic-based microspheres are taken as modifiers to prepare PAN-based fiber composites by electrospinning, pre-oxidation and carbonization. Pearl-chain structures appear in RFC/ACF composites, and pure polyacrylonitrile fibers show a dense network. The shape and cross-linking degree are large. After the addition of the phenolic-based microspheres, the composite material exhibits a layered pearlite chain structure with a large porosity, and the RFC/ACF composite material is derived because of the existence of a large number of bead chain structures in the composite material. The density increases, the volume declines and the mass after being assembled into a supercapacitor as a positive electrode material decreases. The specific surface area of RFC/ACF composites is increased as compared to pure fibers. The increase in specific surface area could facilitate the diffusion of electrolyte ions in the material. Owing to the large number of bead chains, plenty of pore channels are provided for the diffusion of electrolyte ions, which is conducive to enhancing the electrochemical performance of the composite and improving the RFC/ACF composite and the specific capacitance of the material. The methods of electrochemical testing on symmetric supercapacitors (as positive electrodes) are three-electrode cyclic voltammetry, alternating current impedance and cycle stability.

Findings

The specific capacitance value of the composite material was found to be 389.2 F/g, and the specific capacitance of the electrode operating at a higher current density of 20 mA/cm2 was 11.87 F/g (the amount of the microsphere modifier added was 0.3 g). Using this material as a positive electrode to assemble into asymmetrical supercapacitor, after 2,000 cycles, the specific capacitance retention rate was 87.46 per cent, indicating excellent cycle stability performance. This result can be attributed to the fact that the modifier embedded in the fiber changes the porosity between the fibers, while improving the utilization of the carbon fibers and making it easier for electrolyte ions to enter the interior of the composites, thereby increasing the capacitance of the composites.

Originality/value

The modified PAN-based activated carbon fibers in the study had high specific surface area and significantly high specific capacitance, which makes it applicable as an efficient and environment-friendly absorbent, as well as an advanced electrode material for supercapacitor.

Article
Publication date: 2 November 2015

Cheng Gao, Rui-Na Xu and Pei-Xue Jiang

Lattice Boltzmann method (LBM) is employed to explore friction factor of single-phase fluid flow through porous media and the effects of local porous structure including geometry…

Abstract

Purpose

Lattice Boltzmann method (LBM) is employed to explore friction factor of single-phase fluid flow through porous media and the effects of local porous structure including geometry of grains in porous media and specific surface of porous media on two-phase flow dynamic behavior, phase distribution and relative permeability. The paper aims to discuss this issue.

Design/methodology/approach

The 3D single-phase LBM model and the 2D multi-component multi-phase Shan-Chen LBM model (S-C model) are developed for fluid flow through porous media. For the solid site, the bounce back scheme is used with non-slip boundary condition.

Findings

The predicted friction factor for single-phase fluid flow agrees well with experimental data and the well-known correlation. Compared with porous media with square grains, the two-phase fluids in porous media with circle grains are more connected and continuous, and consequently the relative permeability is higher. As for the factor of specific porous media surface, the relative permeability of wetting fluids varies a little in two systems with different specific surface areas. In addition, the relative permeability of non-wetting fluid decreases with the increasing of specific surface of porous media due to the large flow resistance.

Originality/value

Fluid-fluid interaction and fluid-solid interaction in the SC LBM model are presented, and schemes to obtain immiscible two-phase flow and different contact angles are discussed. Two-off mechanisms acting on the wetting fluids is proposed to illustrate the relative permeability of wetting fluids varies a little in two systems with different specific surface.

Details

International Journal of Numerical Methods for Heat & Fluid Flow, vol. 25 no. 8
Type: Research Article
ISSN: 0961-5539

Keywords

Article
Publication date: 1 February 2016

Shunan Ren, Xiangdong Yang, Jing Xu, Guolei Wang, Ying Xie and Ken Chen

The purpose of this paper is to determine the base position and the largest working area for mobile manipulators. The base position determines the workspace of the mobile…

Abstract

Purpose

The purpose of this paper is to determine the base position and the largest working area for mobile manipulators. The base position determines the workspace of the mobile manipulator, particularly when the operation mode is intermittent (i.e. the mobile platform stops when the manipulator conducts the task). When the base of the manipulator is in the intersection area of the Base’s Workable Location Spaces (BWLSes), the end effector (EE) can reach all path points. In this study, the intersection line of BWLSes is calculated numerically, and the largest working area is determined using the BWLS concept. The performance of this method is validated with simulations on specific surface segments, such as plane, cylinder and conical surface segments.

Design/methodology/approach

The BWLS is used to determine the largest working area and the base position in which the mobile manipulator can reach all path points with the objective of reducing off-line planning time.

Findings

Without considering the orientation of the EE, the base position and the working area for the mobile manipulator are determined using the BWLS. Compared to other methods, the proposed algorithm is beneficial when the planning problem has six dimensions, ensuring the reachability and stability of the EE.

Originality/value

The algorithm needs no manual configuration, and its performance is investigated for typical surfaces in practical applications.

Details

Assembly Automation, vol. 36 no. 1
Type: Research Article
ISSN: 0144-5154

Keywords

Article
Publication date: 23 March 2012

Abdulaziz Jarkas

The purpose of this paper is to investigate the effects and relative influence of: surface floor area; number of trowelling machines used in the operation; machine floating ring…

Abstract

Purpose

The purpose of this paper is to investigate the effects and relative influence of: surface floor area; number of trowelling machines used in the operation; machine floating ring diameter size; and operative employment mode, on power‐trowelling productivity of concrete surface floors.

Design/methodology/approach

To achieve this objective, a sufficiently large volume of productivity data was collected and analyzed using the categorical‐regression method. As a result, the effects and relative influence of the factors investigated on trowelling productivity were determined and quantified.

Findings

The findings show significant influence of the factors explored on the trowelling productivity of concrete surface floors, which substantiate the importance of the “economy of scale” concept, and confirm the negative effect of “overcrowding”. On the other hand, contrary to many previous productivity research findings, and anecdotal perceptions of industry practitioners, the results obtained provide little evidence to the positive impact of the subcontracting employment mode on the trowelling operation.

Research limitations/implications

Further research into the influence of other factors which could not be determined by this study, i.e. quantifying the difference in trowelling productivity between the “walk‐behind” and “ride‐on” machine types, and the average change in the operation efficiency as a result of utilizing the 0.60 m “walk‐behind” floating ring diameter size, in comparison with the 0.80, 1.00, and 1.20 m explored ring‐size, is recommended. On the other hand, the results obtained suggest that for a specific surface floor area, there may be an optimum number of trowelling machines, which leads to optimum trowelling productivity. It is, therefore, recommended to determine this number in order to rationalize the use of such devices and optimize the efficiency of the operation.

Practical implications

The findings of this research can provide estimators, planners and construction managers guidance for reasonable estimates, effective planning and efficient operative utilization. The results obtained may be further used to “benchmark” the efficiency of the operation, and “formalize” the specific productivity knowledge acquired.

Originality/value

The outcomes of this study fill a gap in productivity knowledge of primary factors influencing an important surface floor finish technique, which is frequently encountered on concrete construction sites, especially parking structures, storages and industrial facilities.

Article
Publication date: 13 September 2011

Peter Greenwood and Borje Gevert

The purpose of this paper is to study methods of reacting the surface of the particles of silica sols with silanes, primarily gamma‐glycidoxypropyltrimethoxysilane (GPTMS) and…

1120

Abstract

Purpose

The purpose of this paper is to study methods of reacting the surface of the particles of silica sols with silanes, primarily gamma‐glycidoxypropyltrimethoxysilane (GPTMS) and study some basic properties of the modified sols and the nature and structure of the silane groups attached to the particle surface.

Design/methodology/approach

The surface of the silica particles was modified by reacting the silica sols with aqueous solutions of silanes, chiefly GPTMS. The presence and structure of silane groups on the particle surface were established by Si‐NMR and C‐NMR, respectively.

Findings

Several silanes were studied but silica sols could be readily modified only with GPTMS and glycidoxypropylmethoxydiethoxysilane (GPMDES), most readily if the silanes were pre‐hydrolysed in water. Higher degrees of silylation were preferably done by continuous addition of silane. Lower degrees of modification can be achieved at room temperature by the stepwise addition of the silane solution. The silylation of the silica surface with GPTMS significantly reduces the number of charged surface groups and silanol groups. GPTMS binds covalently to the silica surface and the epoxy ring opens and transforms into a diol. Silica sols modified with GPTMS and GPMDES are stable toward aggregation.

Research limitations/implications

Only organo‐reactive silanes were studied.

Originality/value

This is the first work to study the modification by silanes of silica aquasols with high concentrations of silica. The silane modification can extend the use of silica to areas of applications previously inaccessible to silica sols.

Details

Pigment & Resin Technology, vol. 40 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 13 January 2012

Jialin Yang, Hongwu Ouyang, Chao Xu and Yang Wang

The purpose of this paper is to describe the stability and properties of the direct metal laser fabrication (DMLF) process, by putting forward top surface quality (TSQ), which…

1129

Abstract

Purpose

The purpose of this paper is to describe the stability and properties of the direct metal laser fabrication (DMLF) process, by putting forward top surface quality (TSQ), which could be a unique and crucially important feature compared with traditional manufacturing methods.

Design/methodology/approach

Through the systematic and detailed analysis of DMLF process using related theories of additive manufacturing technologies, it was revealed that TSQ was the key factor for controlling the stability of DMLF process and thus tailoring final properties of metallic parts. Only good TSQ can ensure the stability of DMLF process and excellent performance of metal parts in theory.

Findings

TSQ was defined as the surface morphology in macro and micro scopes in laser scanning area of unit layers during DMLF, and could be characterized by three key elements: flatness, compactness and cleanliness. The flatness was the significant factor to assure the shaping during DMLF, while the compactness and cleanliness were the decisive factors to assure the final properties of metal part for DMLF. As an example, the typical top surface defects and their contributing factors in DMLF for Cu‐based metal powder mixtures were investigated thoroughly according to the proposed definition and requirements. Moreover, the specific controlling methods of TSQ were provided and discussed. Eventually, DMLF of three‐dimensional Cu‐based metal sample with complicate structure was successfully performed by taking some effective measures for adjusting TSQ parameters.

Originality/value

Few comprehensive investigations have been carried out on this topic. The definition and evaluation methods of TSQ for DMLF have been introduced for the first time in the present paper.

Article
Publication date: 1 June 2003

A. Krysztafkiewicz, S. Binkowski, A. Kaczmarek and T. Jesionowski

Two types of amorphous silica namely, the precipitated silica and the pyrogenic silica, were studied. The surfaces of such silica were modified with silane coupling agents such as…

Abstract

Two types of amorphous silica namely, the precipitated silica and the pyrogenic silica, were studied. The surfaces of such silica were modified with silane coupling agents such as 3‐aminopropyltriethoxysilane, N‐2‐(aminoethyl)‐3‐aminopropyltrimethoxysilane and 3‐ureidopropyltrimethoxysilane. Pigments were obtained by the adsorption of organic dyes, C.I. Reactive Blue 19 and C.I. Acid Green 16, onto the modified silica surface. Structural properties of the modified silica and the pigments obtained were evaluated using scanning electron microscopy, zeta potential analysis and particle size measurement techniques. Moreover, colour of the pigments obtained was evaluated using the CIE L *a*b* colour space system. The specific surface area of the pigment obtained was estimated using the BET method.

Details

Pigment & Resin Technology, vol. 32 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 October 2001

Teofil Jesionowski

The surface character of titanium dioxide (rutile) was altered by surface modification. Silane coupling agents were used as modifiers. Physicochemical properties of the obtained…

Abstract

The surface character of titanium dioxide (rutile) was altered by surface modification. Silane coupling agents were used as modifiers. Physicochemical properties of the obtained products were evaluated. Effects of the modifier concentration on changes in hydrophilic/hydrophobic properties of the surface were estimated. The tendency to form primary and secondary agglomerate structures was defined using dynamic light scattering and examining morphology and surface structure with the use of scanning electron microscopy. Specific surface area and pore volume were also measured in unmodified and modified titanium white.

Details

Pigment & Resin Technology, vol. 30 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 November 2010

George K. Stylios

Examines the fifteenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects…

Abstract

Examines the fifteenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.

Details

International Journal of Clothing Science and Technology, vol. 22 no. 6
Type: Research Article
ISSN: 0955-6222

Keywords

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