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Article
Publication date: 23 April 2024

Xiaotong Zhang and Qiu Zhang

The purpose of this study is to develop a molecular imprinting electrochemical sensor for the specific detection of the anticancer drug amsacrine. The sensor used a composite of…

Abstract

Purpose

The purpose of this study is to develop a molecular imprinting electrochemical sensor for the specific detection of the anticancer drug amsacrine. The sensor used a composite of bacterial cellulose (BC) and silver nanoparticles (AgNPs) as a platform for the immobilization of a molecularly imprinted polymer (MIP) film. The main objective was to enhance the electrochemical properties of the sensor and achieve a high level of selectivity and sensitivity toward amsacrine molecules in complex biological samples.

Design/methodology/approach

The composite of BC-AgNPs was synthesized and characterized using FTIR, XRD and SEM techniques. The MIP film was molecularly imprinted to selectively bind amsacrine molecules. Electrochemical characterization, including cyclic voltammetry and electrochemical impedance spectroscopy, was performed to evaluate the modified electrode’s conductivity and electron transfer compared to the bare glassy carbon electrode (GCE). Differential pulse voltammetry was used for quantitative detection of amsacrine in the concentration range of 30–110 µM.

Findings

The developed molecular imprinting electrochemical sensor demonstrated significant improvements in conductivity and electron transfer compared to the bare GCE. The sensor exhibited a linear response to amsacrine concentrations between 30 and 110 µM, with a low limit of detection of 1.51 µM. The electrochemical response of the sensor showed remarkable changes before and after amsacrine binding, indicating the successful imprinting of amsacrine in the MIP film. The sensor displayed excellent selectivity for amsacrine in the presence of interfering substances, and it exhibited good stability and reproducibility.

Originality/value

This study presents a novel molecular imprinting electrochemical sensor design using a composite of BC and AgNPs as a platform for MIP film immobilization. The incorporation of BC-AgNPs improved the sensor’s electrochemical properties, leading to enhanced sensitivity and selectivity for amsacrine detection. The successful imprinting of amsacrine in the MIP film contributes to the sensor's specificity. The sensor's ability to detect amsacrine in a concentration range relevant to anticancer therapy and its excellent performance in complex sample matrices add significant value to the field of electrochemical sensing for pharmaceutical analysis.

Details

Sensor Review, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 6 November 2023

Huda Abdullah, Norshafadzila Mohammad Naim, Kok Seng Shum, Aidil Abdul Hamid, Mohd Hafiz Dzarfan Othman, Vidhya Selvanathan, Wing Fen Yap and Seri Mastura Mustaza

Regular monitoring of bacteria, especially Escherichia coli, in wastewater is crucial to ensure the maintenance of public health. Amperometric detection proves to be a fast…

Abstract

Purpose

Regular monitoring of bacteria, especially Escherichia coli, in wastewater is crucial to ensure the maintenance of public health. Amperometric detection proves to be a fast, sensitive and economically viable solution for E. coli enumeration. This paper reported a prototype amperometric sensor based on PANI-ZnO-NiO nanocomposite thin films prepared by sol–gel method and irradiated with gamma ray. The purpose of this study is to investigate the sensor performance of PANI-ZnO-NiO nanocomposite thin films to detect E. coli in water.

Design/methodology/approach

The films were varied with different compositions of ZnO and NiO by using the formula PANI-(ZnO)1-x-(NiO)x, with x = 0.2, 0.4, 0.6 and 0.8. PANI-ZnO-NiO nanocomposite thin films were characterized by using X-ray diffraction (XRD) and atomic force microscopy (AFM) to study the crystallinity and surface morphology of the films. The sensor performance was conducted using the current–voltage (I-V) measurement by testing the films in clean water and E. coli solution.

Findings

XRD diffractograms show the peaks of ZnO (1 0 0) and NiO (1 0 2). AFM analysis shows the surface roughness, and the grain size of PANI-ZnO-NiO thin films decreases when the concentration ratios of NiO increased. I-V curves show the difference in current flow, where the current in E. coli solution is higher than the clean water.

Originality/value

PANI-(ZnO)1-x-(NiO)x nanocomposite thin film with the highest concentration of ZnO performed the highest sensitivity among the other concentrations, which can be used to indicate the presence of E. coli bacteria in water.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 March 2023

Khaled Mostafa, Heba Ameen, Amal El-Ebeisy and Azza El-Sanabary

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a…

44

Abstract

Purpose

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate for copper ions removal from wastewater effluent after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

Design/methodology/approach

The calorimetric sensor batch technique was used to determine the resin's adsorption capacity, while atomic adsorption spectrometry was used to determine the residual copper ions concentration in the filtrate before and after adsorption. This was done to convert the copolymer's abundant nitrile groups into amidoxime groups, and the resulting poly (amidoxime) resin was used as a copper ion adsorbent. To validate the existence of amidoxime groups, the resin was qualitatively characterized using a rapid vanadium ion test and instrumentally using Fourier transform infrared spectroscopy spectra and scanning electron microscopy morphological analysis.

Findings

At pH 7, 400 ppm copper ions concentration and 0.25 g adsorbent at room temperature, the overall adsorption potential of poly (amidoxime) resin was found to be 115.2 mg/g. The process's adsorption, kinetics and isothermal analysis were examined using various variables such as pH, contact time, copper ion concentration and adsorbent dose. To pretend the adsorption kinetics, various kinetics models, including pseudo-first-order and pseudo-second-order, were applied to the experimental results. The kinetic analysis indicated that the pseudo-second-order rate equation promoted the development of the chemisorption phase better than the pseudo-first-order rate equation. In the case of isothermal investigations, a study of observed correlation coefficient (R2) values indicated that the Langmuir model outperformed the Freundlich model in terms of matching experimental data.

Originality/value

To the best of the author's information, there is no comprehensive study for copper ions removal from waste water effluent using the recently tailored and fully characterized poly (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 April 2024

Jinwei Zhao, Shuolei Feng, Xiaodong Cao and Haopei Zheng

This paper aims to concentrate on recent innovations in flexible wearable sensor technology tailored for monitoring vital signals within the contexts of wearable sensors and…

Abstract

Purpose

This paper aims to concentrate on recent innovations in flexible wearable sensor technology tailored for monitoring vital signals within the contexts of wearable sensors and systems developed specifically for monitoring health and fitness metrics.

Design/methodology/approach

In recent decades, wearable sensors for monitoring vital signals in sports and health have advanced greatly. Vital signals include electrocardiogram, electroencephalogram, electromyography, inertial data, body motions, cardiac rate and bodily fluids like blood and sweating, making them a good choice for sensing devices.

Findings

This report reviewed reputable journal articles on wearable sensors for vital signal monitoring, focusing on multimode and integrated multi-dimensional capabilities like structure, accuracy and nature of the devices, which may offer a more versatile and comprehensive solution.

Originality/value

The paper provides essential information on the present obstacles and challenges in this domain and provide a glimpse into the future directions of wearable sensors for the detection of these crucial signals. Importantly, it is evident that the integration of modern fabricating techniques, stretchable electronic devices, the Internet of Things and the application of artificial intelligence algorithms has significantly improved the capacity to efficiently monitor and leverage these signals for human health monitoring, including disease prediction.

Details

Sensor Review, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 6 September 2023

Hafsat T. Rumah, Mansur B. Ibrahim and Sani M. Gumel

The purpose of this research is to identify and investigate some natural dyes with halochromic properties for potential use as food spoilage indicators to reduce waste and curve…

Abstract

Purpose

The purpose of this research is to identify and investigate some natural dyes with halochromic properties for potential use as food spoilage indicators to reduce waste and curve the negative effects of food borne diseases.

Design/methodology/approach

Exactly 10 potential dye-yielding plants were selected based on their colour (mostly purple, red, maroon and pink). Solvent extraction was used to extract the dyes and pH differential method was used to determine the concentrations of anthocyanin in the extracted dyes. Different concentrations of hydrochloric acid and sodium hydroxide (0.1 M, 1 M and 2 M) in drops and in excess as acidic and basic solution, respectively, were used to test the halochromicity of the extracted dyes. Methyl red (a synthetic dye) was used as a reference standard/control. The pH of the dyes was recorded before and after addition of both NaOH and HCl solutions.

Findings

Five out of the 10 dyes extracted (labelled as dye A–E for Ti plant (green Cordyline fruticosa), coleus (Coleus blumei), paper flower (Bougainvillea glabra), painted nettle (Palisandra coleus) and purple heart (Setcresea purpurea), respectively, were found to be halochromic (even at low doses) by changing its colour when exposed to both acidic and basic solutions. While other dyes labelled F–J for red acalypha (Acalypha wilkesiana), golden shower (Cassia fistula), golden dew drop (Duranta repens), wild sage (Lantana camara var Aculeata) and pink oleander (Apocynaceae Nerium oleander), respectively, were either completely insensitive to the solutions in drops, slightly sensitive at high doses or the colour change is insignificant. Although some dyes were found to be more sensitive than others but in most cases, the colour changes in halochromic dyes were more stable in acidic conditions than in basic making it more sensitive to the basic than the acidic solution with the exception of dye A and E (to some extent) which was sensitive to both acidic and basic solution. The anthocyanin contents of dye A–J were found to be between the range of 2.28–10.35 mg/l with dye E having the lowest and dye J with the highest anthocyanin concentration, respectively. The initial pH of all the dyes falls within the range of 4.8–7.3 with most found within the acidic range.

Originality/value

Halochromic dye research studies are still at the infancy stage in developing world despite the vast available and abundant potential natural halochromic dye-yielding plants. The study explored this area of research and gives an opportunity for the development of smart packaging for pH-sensitive foods using natural dyes as an alternative to conventional synthetic dyes to reduce cost and also curve the negative effect of synthetic dyes as well as food borne diseases.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 3 April 2024

Adhithya Sreeram and Jayaraman Kathirvelan

Artificial fruit ripening is hazardous to mankind. In the recent past, artificial fruit ripening is increasing gradually due to its commercial benefits. To discriminate the type…

Abstract

Purpose

Artificial fruit ripening is hazardous to mankind. In the recent past, artificial fruit ripening is increasing gradually due to its commercial benefits. To discriminate the type of fruit ripening involved at the vendors’ side, there is a great demand for on-sight ethylene detection in a nondestructive manner. Therefore, this study aims to deal with a comparison of various laboratory and portable methods developed so far with high-performance metrics to identify the ethylene detection at fruit ripening site.

Design/methodology/approach

This paper focuses on various types of technologies proposed up to date in ethylene detection, fabrication methods and signal conditioning circuits for ethylene detection in parts per million and parts per billion levels. The authors have already developed an infrared (IR) sensor to detect ethylene and also developed a lab-based setup belonging to the electrochemical sensing methods to detect ethylene for the fruit ripening application.

Findings

The authors have developed an electrochemical sensor based on multi-walled carbon nanotubes whose performance is relatively higher than the sensors that were previously reported in terms of material, sensitivity and selectivity. For identifying the best sensing technology for optimization of ethylene detection for fruit ripening discrimination process, authors have developed an IR-based ethylene sensor and also semiconducting metal-oxide ethylene sensor which are all compared with literature-based comparable parameters. This review paper mainly focuses on the potential possibilities for developing portable ethylene sensing devices for investigation applications.

Originality/value

The authors have elaborately discussed the new chemical and physical methods of ethylene detection and quantification from their own developed methods and also the key findings of the methods proposed by fellow researchers working on this field. The authors would like to declare that the extensive analysis carried out in this technical survey could be used for developing a cost-effective and high-performance portable ethylene sensing device for fruit ripening and discrimination applications.

Details

Sensor Review, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 15 August 2023

Zul-Atfi Ismail

At the beginning of the Corona Virus Disease 2019 (COVID-19) pandemic, a digitalized construction environments surfaced in the heating, ventilation and air conditioning (HVAC…

Abstract

Purpose

At the beginning of the Corona Virus Disease 2019 (COVID-19) pandemic, a digitalized construction environments surfaced in the heating, ventilation and air conditioning (HVAC) systems in the form of a modern delivery system called demand controlled ventilation (DCV). Demand controlled ventilation has the potential to solve the building ventilation's biggest problem of managing indoor air quality (IAQ) for controlling COVID-19 transmission in indoor environments. However, the improper evaluation and information management of infection prevention on dense crowd activities such as measurement errors and volatile organic compound (VOC) generation failure rates, is fragmented so the aim of this research is to integrate this and explore potentials with machine learning algorithms (MLAs).

Design/methodology/approach

The method used is a thorough systematic literature review (SLR) approach. The results of this research consist of a detailed description of the DCV system and digitalized construction process of its IAQ elements.

Findings

The discussion revealed that DCV has a potential for being further integrated by perceiving it as a MLAs and hereby enabling the management of IAQ level from the perspective of health risk function mechanism (i.e. VOC and CO2) for maintaining a comfortable thermal environment and save energy of public and private buildings (PPBs). The appropriate MLA can also be selected in different occupancy patterns for seasonal variations, ventilation behavior, building type and locations, as well as current indoor air pollution control strategies. Furthermore, the conceptual framework showed that MLA application such as algorithm design/Model Predictive Control (MPC) integration can alleviate the high spread limitation of COVID-19 in the indoor environment.

Originality/value

Finally, the research concludes that a large unexploited potential within integration and innovation is recognized in the DCV system and MLAs which can be improved to optimize level of IAQ from the perspective of health throughout the building sector DCV process systems. The requirements of CO2 based DCV along with VOC concentrations monitoring practice should be taken into consideration through further research and experience with adaption and implementation from the ventilation control initial stage of the DCV process.

Details

Open House International, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0168-2601

Keywords

Open Access
Article
Publication date: 13 August 2021

Habeeb Balogun, Hafiz Alaka and Christian Nnaemeka Egwim

This paper seeks to assess the performance levels of BA-GS-LSSVM compared to popular standalone algorithms used to build NO2 prediction models. The purpose of this paper is to…

1131

Abstract

Purpose

This paper seeks to assess the performance levels of BA-GS-LSSVM compared to popular standalone algorithms used to build NO2 prediction models. The purpose of this paper is to pre-process a relatively large data of NO2 from Internet of Thing (IoT) sensors with time-corresponding weather and traffic data and to use the data to develop NO2 prediction models using BA-GS-LSSVM and popular standalone algorithms to allow for a fair comparison.

Design/methodology/approach

This research installed and used data from 14 IoT emission sensors to develop machine learning predictive models for NO2 pollution concentration. The authors used big data analytics infrastructure to retrieve the large volume of data collected in tens of seconds for over 5 months. Weather data from the UK meteorology department and traffic data from the department for transport were collected and merged for the corresponding time and location where the pollution sensors exist.

Findings

The results show that the hybrid BA-GS-LSSVM outperforms all other standalone machine learning predictive Model for NO2 pollution.

Practical implications

This paper's hybrid model provides a basis for giving an informed decision on the NO2 pollutant avoidance system.

Originality/value

This research installed and used data from 14 IoT emission sensors to develop machine learning predictive models for NO2 pollution concentration.

Details

Applied Computing and Informatics, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2634-1964

Keywords

Open Access
Article
Publication date: 4 April 2024

Yanmin Zhou, Zheng Yan, Ye Yang, Zhipeng Wang, Ping Lu, Philip F. Yuan and Bin He

Vision, audition, olfactory, tactile and taste are five important senses that human uses to interact with the real world. As facing more and more complex environments, a sensing…

Abstract

Purpose

Vision, audition, olfactory, tactile and taste are five important senses that human uses to interact with the real world. As facing more and more complex environments, a sensing system is essential for intelligent robots with various types of sensors. To mimic human-like abilities, sensors similar to human perception capabilities are indispensable. However, most research only concentrated on analyzing literature on single-modal sensors and their robotics application.

Design/methodology/approach

This study presents a systematic review of five bioinspired senses, especially considering a brief introduction of multimodal sensing applications and predicting current trends and future directions of this field, which may have continuous enlightenments.

Findings

This review shows that bioinspired sensors can enable robots to better understand the environment, and multiple sensor combinations can support the robot’s ability to behave intelligently.

Originality/value

The review starts with a brief survey of the biological sensing mechanisms of the five senses, which are followed by their bioinspired electronic counterparts. Their applications in the robots are then reviewed as another emphasis, covering the main application scopes of localization and navigation, objection identification, dexterous manipulation, compliant interaction and so on. Finally, the trends, difficulties and challenges of this research were discussed to help guide future research on intelligent robot sensors.

Details

Robotic Intelligence and Automation, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2754-6969

Keywords

Article
Publication date: 29 August 2023

Erik Velasco and Elvagris Segovia

Waiting for a bus may represent a period of intense exposure to traffic particles in hot and noisy conditions in the street. To lessen the particle load and tackle heat in bus…

Abstract

Purpose

Waiting for a bus may represent a period of intense exposure to traffic particles in hot and noisy conditions in the street. To lessen the particle load and tackle heat in bus stops a shelter was equipped with an electrostatic precipitator and a three-step adiabatic cooling system capable of dynamically adjust its operation according to actual conditions. This study evaluates the effectiveness of the Airbitat Oasis Smart Bus Stop, as the shelter was called, to provide clean and cool air.

Design/methodology/approach

The particle exposure experienced in this innovative shelter was contrasted with that in a conventional shelter located right next to it. Mass concentrations of fine particles and black carbon, and particle number concentration (as a proxy of ultrafine particles) were simultaneously measured in both shelters. Air temperature, relative humidity and noise level were also measured.

Findings

The new shelter did not perform as expected. It only slightly reduced the abundance of fine particles (−6.5%), but not of ultrafine particles and black carbon. Similarly, it reduced air temperature (−1 °C), but increased relative humidity (3%). Its operation did not generate additional noise.

Practical implications

The shelter's poor performance was presumably due to design flaws induced by a lack of knowledge on traffic particles and fluid dynamics in urban environments. This is an example where harnessing technology without understanding the problem to solve does not work.

Originality/value

It is uncommon to come across case studies like this one in which the performance and effectiveness of urban infrastructure can be assessed under real-life service settings.

Details

Smart and Sustainable Built Environment, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2046-6099

Keywords

1 – 10 of 132