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Line widths are rapidly shrinking and the complexities of boards place increased demands on the resolution capabilities of the photoresists. A new technology is emerging that offers the user unparalleled resolution, a completely aqueous system, and complete, uniform, three‐dimensional coverage of the panel. The unique properties of this system result from the extraordinary method of application of the photoresist. Electrophoresis, or electrocoating, allows the deposition of a very thin, uniform, highly chemically resistant photoresist layer. Any exposed conductive surface, including scratches or other panel imperfections, are coated. The combination of a very thin layer and no cover sheet allows the printing of sub‐mil geometries without the need for a collimated light source. This new application offers the user high yields, both from the chemistry and in circuit yields. Even more so, the resolution capabilities offer opportunities beyond the limitations of dry film and other liquid resists. The photoresist no longer needs to be the gating factor in process capability.

The demand for higher operating speeds and increasing densification in electronic packages is driving designers to reduce feature sizes in order to accommodate increases in I/O counts. Consequently, printed circuit board manufacturers are turning to new manufacturing techniques and new materials in order to meet these demands from their customers. Sequential build‐up is one such technique and a plethora of new materials is available to support these innovative routes to high‐density interconnect circuitry. The basic concept involves the addition of extra layers of dielectric and copper on to a multi‐layered board. The additional circuitry is then connected to the underlying board using suitably formed microvias. Focuses on the metallization of microvias using a straight‐through horizontal metallization process. Particular emphasis is placed on the importance of equipment design, the chemistry of the solutions used and optimization of fluid exchange to ensure good coverage of these small features.

Corrosion is considered as one of the issues that threaten the safe operation of steam generator (SG) tubing. Some sulfur-related specie can cause corrosion degradation of SG tubing. Sulfur-induced corrosion of SG alloys in high temperature and high-pressure water is one of the most complicated processes. The purpose of this study is to study the effect of reduced sulphur on passive film properties of steam generator (SG) tubing.

In this paper, the effects of reduced sulfur on passive film properties of SG tubing were reviewed from the aspects of thermodynamic calculations and experimental.

Thermodynamic calculations are mainly presented by E-pH diagrams, volt equivalent diagrams and species distribution curves. The stability of sulphur species highly depends on temperature, solution pH, and electrochemical potential. Experimental data indicated that reduced sulfur species can interact with the passive film, which led to changes in film thickness, film structure, semiconductivity and pitting growth rate.

The state-of-the-art discussed in this paper gives basis for resolving engineering problems regarding with sulfur-induced corrosion.

The purpose of this paper is to describe the collective exploration, process and knowledge production made in a learning study about solution chemistry.

Secondary school teachers conducted a learning study with variation theory as a guiding principle, supervised by a researcher. The relationship between teaching and learning was analyzed and evaluated in a learning study cycle of three lessons.

Critical aspects when teaching solution chemistry were identified, as well as enacted patterns of variation that significantly improved students’ learning. Examples of critical aspects were the particulate character of matter, especially the feature of “empty space” between particles, the connection between macroscopic phenomenon and sub‐microscopic explanations and the difference between answers with everyday language and scientific language.

The paper suggests that teachers in a learning study can produce new knowledge as well as use earlier research results when creating teaching activities that can improve their own practical work and students’ learning.

The study represents an example of research with the aim to improve teachers’ practice by generating knowledge in connection with teachers’ professional tasks.

The purpose of this paper is to evaluate the performance of polypropylene glycol (PPG), as a corrosion inhibitor for aluminium corrosion in 0.5 M H₂SO₄ solution at 303-333 K and the effect of addition of iodide ions on the corrosion inhibition efficacy of PPG.

The corrosion inhibition performance of PPG alone and on addition of iodide ions in the acid medium was evaluated using weight loss and electrochemical [electrochemical impedance spectroscopy (EIS), linear polarisation resistance (LPR) and potentiodynamic polarization (PDP)] methods as well as surface analysis approach at 303-333 K. The morphology of the corroding aluminium surface without and with the additives was visualised using scanning electron microscopy (SEM). The trend of inhibition efficiency with temperature was used to propose the mechanism of inhibition and type of adsorption.

Results obtained showed that PPG moderately retarded the corrosion of Al in 0.5 M H₂SO₄ solution. Addition of KI to PPG is found to synergistically improve the inhibitive ability of PPG. From the variation of inhibition efficiency, K_ads, and E_a, with rise in temperature, physisorption mechanism is proposed for the adsorption of PPG and PPG + KI onto the Al surface in 0.5 M H₂SO₄ solution. Polarisation results showed that PPG and PPG + KI acted as mixed type inhibitor. The adsorption of PPG and PPG + KI, respectively, onto the metal surface followed El-Awady et al. adsorption isotherm model. SEM and water contact angle analysis confirmed the adsorption of PPG and PPG + KI on Al surface.

The research is limited to aqueous acid environment in aerated condition, and all tests were performed under static conditions.

The use of PPG as corrosion inhibitor for Al corrosion in acidic medium were reported for the first time. The results suggest that iodide ions could be used to enhance corrosion protection ability of PPG which could find practical application in corrosion control in aqueous acidic environment. The data obtained would form part of database on the synergistic effect of iodide ions addition to polymer to control acid-induced corrosion of metal.

The use of PPG as corrosion inhibitor for Al corrosion in acidic medium were reported for the first time. The results suggest that iodide ions could be used to enhance corrosion protection ability of PPG which could find practical application in corrosion control in aqueous acidic environment. The data obtained would form part of database on the synergistic effect of iodide ions addition to polymer to control acid-induced corrosion of metal.

The purpose of this paper was to investigate the effects of SO₄2− concentration on the corrosion behaviour of T23 and T12 steels in simulated water chemistry condition solution of 600 MW fossil-fired power boilers.

The influence and mechanism of SO₄2− ions on the pitting corrosion of T23 and T12 steels in simulated oxygenated treatment water chemistry solution was studied using electrochemical potentiodynamic polarization scans and electrochemical impedance spectroscopy.

The results showed that T23 and T12 were susceptible to pitting corrosion in the simulated solution with full SO₄2− concentration for the competitive adsorption of OH− and SO₄2− on the surface of steels. The pitting sensitivity of the steels improved with increasing SO₄2− concentration. The corrosion resistance for SO₄2− of T23 was stronger than that for T12.

This study is an attempt to provide direction for regulating the concentration of SO₄2− in boiler water and for selecting the material for boiler water wall tubes.

The effect of oxalic acid (OA) on corrosion resistance of carbon steel in sulphuric acid pH=2.5‐6.0 solutions containing 10⁻⁷‐10⁻³M OA was investigated by means of potentiodynamic polarisation measurements and immersion tests. The results suggest that OA is a good corrosion inhibitor for carbon steel, exhibiting inhibition efficiencies (IE) ranging from 50 to 85 per cent in dilute 10⁻⁷‐10⁻⁵M OA solutions of pH>3.0, whereas for pH≤3.0 solutions, an increase in corrosion rate was found. Non‐accelerated experiments (weight loss tests) carried out by immersing carbon steel specimens into OA‐containing solutions during at least 6 h revealed only positive IE values, regardless of both solution pH and OA content. The results were explained considering the solution composition as function of pH.

PART VI Practical chemistry textbooks and miscellaneous books. Thirty‐nine practical chemistry textbooks were received from publishers for this part of the review and they have been briefly analyzed under the headings Physical, Inorganic, Organic, Quantitative analysis, and Other features, in Tables 1–4. It has not been possible to examine these in the same detail as the theory books previously considered. A number of other books which are used at ‘A/S’ level were also received and these have been tabulated: problem and calculation books in Table 5, and others in Table 6.

This paper aims to evaluate the inhibitive action of the corrosion of mild steel in sulphuric acid solutions by ethanol extracts of Thymus vulgaris (TYV), Xylopia aethiopica (XYA) and Zingiber officinale (ZGO) as eco-friendly and non-toxic mild-steel corrosion inhibitors in H₂SO₄ solutions.

Ethanol extracts of TYV leaves, XYA fruits and ZGO roots were used as inhibitors in various corrosion tests. Gravimetric and gasometric techniques were used to characterize the mechanism of inhibition.

Results indicate that the extracts inhibit the corrosion process efficiently. Inhibition efficiency was found to increase with an increase in extract concentration and decrease with an increase in temperature. Inhibition efficiencies followed the trend TYV > ZGO > XYA. Thermodynamic considerations revealed that the energy of activation increased in the presence of the plant extracts. Adsorption of the plant extracts on mild steel surface occurred spontaneously, and E_a and ΔG_ads values confirm a physical adsorption processes. Phytochemical studies showed the presence of saponoids, flavonoids and polyphenols whose attachment to adsorption sites on the metal surface is responsible for the inhibition process. Experimental data fit the Langmuir adsorption isotherm.

The plant extracts can be used in chemical cleaning and picking processes.

The research provides information on the possible use of the ethanol extracts from TYV leaves, XYA fruits and ZGO roots as sources of cheap, eco-friendly and non-toxic corrosion inhibitors.