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Article
Publication date: 13 January 2021

Amruta Joglekar-Athavale and Ganapti S. Shankarling

A mixed metal oxide-based spinel ceramic pigment has been successfully synthesized incorporating inorganic, high-temperature stable furnace cement as an inbuilt binder. Step by…

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Abstract

Purpose

A mixed metal oxide-based spinel ceramic pigment has been successfully synthesized incorporating inorganic, high-temperature stable furnace cement as an inbuilt binder. Step by step synthesis was done for the spinel and cement mix formulations.

Design/methodology/approach

The pigment mix was synthesized by a solid-solid method where the inorganic binder was incorporated in the mix. The results suggested that CoCuMn-based spinel ceramic pigment with cement mix could be obtained at an annealing temperature of 1,100ºC for 1 h and the size, morphology and crystallinity of spinel mix were greatly influenced by the calcination temperature.

Findings

The pigment mix synthesized was applied as a coating to different substrates such as aluminum, glass and Mild steel. The results revealed that spectral selectivity of TSSS paint coatings based on the CoMnCu spinel ceramic mix was much better than that of solvent-based coatings for high-temperature applications. The presence of cement as an inorganic binder makes the functioning and application of paint easy as it becomes that of a waterborne type.

Originality/value

Ease of application, stability at high temperatures, best absorptivity at the solar selective spectrum and excellent adhesion properties for the selected surface are the key features of the designed pigment system. The applied pigment mix was studied as a coating to get the results for solar selective system.

Details

Pigment & Resin Technology, vol. 50 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 June 2013

Fawzia Fahim Abdel‐Mohsen and Hassan Salah Aly Emira

This work aimed to prepare black transition metal oxide pigments to be used as solar absorbers in the solar selective and other industrial paints.

Abstract

Purpose

This work aimed to prepare black transition metal oxide pigments to be used as solar absorbers in the solar selective and other industrial paints.

Design/methodology/approach

Mixed metal oxide CoCuMnOx spinel pigments were synthesised via the sol‐gel route. These oxides, namely (I‐Co0.50Cu0.25Mn0.25)Ox, (II‐Co0.25Cu0.50Mn0.25)Ox and (III‐Co0.25Cu0.25Mn0.50)Ox, were prepared with different molar ratios and annealed at 600, 800 and 900°C, respectively. The prepared oxides were characterised by infrared spectrometer (IS), differential scanning calorimetry analysis (DSC), X‐ray diffraction (XRD) and transmission electron microscope (TEM).

Findings

The prepared pigments have a spinel structure with the composition CoCuMnOx. All synthesised pigments consisted of nano particles ranged from 10 to 80 nm. The optical properties showed high absorption and moderately low reflectance in the solar wavelength range.

Research limitations/implications

The prepared samples, used in the present work, were synthesized from cobalt sulphate, copper chloride and manganese chloride. The salts were dispersed in polyacrylamide as a precursor.

Practical implications

The prepared samples were thermally stable and had good optical properties. They could be used as absorber materials in the painting of solar collectors.

Originality/value

These thermally stable mixed metal oxides could be used in the painting of solar collectors. The three mixed metal oxides could be used as absorber materials for heating solar collectors due to their high absorption and moderately low reflectance in the solar wavelength range.

Details

Pigment & Resin Technology, vol. 42 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 November 2015

Fawzia Fahim Abdel-Mohsen and Hassan Salah Aly Emira

– The purpose of this study was to prepare colour pigments for use as spectrally selective coatings for solar absorbers.

Abstract

Purpose

The purpose of this study was to prepare colour pigments for use as spectrally selective coatings for solar absorbers.

Design/methodology/approach

Nano-particles cobalt and nickel oxides were prepared by sol–gel techniques. These oxides were prepared with its molar ratios and annealed at 200, 400, 600 and 800°C. The structure of the pigments was characterized by infrared spectrometer, differential scanning calorimetry analysis, X-ray diffraction, transmission electron microscope and scanning electron microscope.

Findings

Encapsulated cobalt and nickel oxides were completely formed at 800 and 600°C, and its colour was black and dark green, respectively. The results confirmed that black and green pigments combined selectivity with colour. Optical properties such as absorption and reflection were affected by the firing temperatures on cobalt and nickel oxides–gel polymers. All synthesized pigments consisted of nano-particles.

Research limitations/implications

The prepared samples used in the present work were synthesized from cobalt chloride and nickel acetate. The salts were dispersed in polyacrylamide as a precursor.

Practical implications

The prepared metal oxides had good solar properties.

Originality/value

Colour becomes more important for thermal solar collectors, and it has attracted interest. This might be related to a generally growing attention towards architectural integration of solar energy systems into building. Architects would prefer different colours besides black, even if lower efficiency would have to be accepted.

Article
Publication date: 30 December 2020

Amruta Joglekar-Athavale, Ganapati Shankarling, Satishchandra Dubey, Vinita Deshpande, Bikashkumar Jaiswal and Arun Nayak

The spectrally selective solar absorption paint is prepared from spinel-based mixed metal oxides with inorganic binder as a key component. Inorganic binder (furnace cement) is…

Abstract

Purpose

The spectrally selective solar absorption paint is prepared from spinel-based mixed metal oxides with inorganic binder as a key component. Inorganic binder (furnace cement) is blended with mixed metal oxide pigment during synthesis. High temperature stability upto 1,100ºC is achieved by the use of this modified coating system. The purpose of this paper is to work on solar selective coating synthesis, and application of a coating as a water-borne paint is the additive key feature that helps in reduction of solvent use.

Design/methodology/approach

The paint was formulated using water-based system, and the main component of colorant was made by mixed metal oxide–based spinel pigment and highly temperature stable inorganic binder.

Findings

The paint formed shows excellent absorptive power with low emittance even at high temperature. Optical and thermal properties were determined along with adhesion, abrasion and other properties. The solar absorptance for these samples were as = 0.93–0.95 with corresponding thermal emittance of eT = 0.096 (at room temperature) and 0.2–0.22 (at elevated temperature 100°C).

Originality/value

The paint formed shows excellent absorptive power with low emittance even at high temperature. The paint can be applied in solar absorptive tower system. The obtained results indicated excellent thermal stability of prepared paint coatings. As inorganic binder was used, the paint has reduction in solvent use, and being water as a base, it is environment friendly, easy to apply and durable at high temperatures, as the binder itself is stable up to 1,500ºC.

Details

Pigment & Resin Technology, vol. 50 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 July 1982

Americus

Titanate coupling agents have been described for the past decade. What they will do and how they are used has been summarised in an article by Monte, Sugerman, and Seeman [Modern

Abstract

Titanate coupling agents have been described for the past decade. What they will do and how they are used has been summarised in an article by Monte, Sugerman, and Seeman [Modern Paint & Coatings, 67, July (1977) p. 27]. Thus the authors point out that the titanate coupling agents, which are basically organotitanium compounds whose structures are shown in the article, can make possible the formulation of metal oxides, pigments, and extenders into organic systems to produce coatings with improved physical properties, higher solids, and advantages from the points of view of manufacturing and application. In other words the organotitanium compound will couple a pigment or related material with the vehicle by forming chemical bonds. Thus, the authors propose that metal chromates may be replaced in corrosion‐resistant coatings with silica extenders if these silica extenders are coupled to the vehicle with an organopyrophosphatotitanate.

Details

Pigment & Resin Technology, vol. 11 no. 7
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 12 April 2022

Yingsi Wu, Kai Yang Thum, Hui Ting Yong, Aleksander Gora, Alfred Iing Yoong Tok and Vitali Lipik

Personal thermal management in functional textiles is in increasing demand for health care, outdoor activity and energy saving. Thus, developing new strategies is highly desired…

Abstract

Purpose

Personal thermal management in functional textiles is in increasing demand for health care, outdoor activity and energy saving. Thus, developing new strategies is highly desired for radiative cooling and/or heating by manipulation of the transmissivity, reflectivity and absorptivity of the textiles within solar energy and human body heat radiation ranges.

Design/methodology/approach

Inorganic additives including TiO2, Fe2O3, carbon black (CB), graphene and mica were incorporated into polymer films. The inorganic additives' full spectrum properties and thermal responses were comprehensively investigated.

Findings

The CB composite film showed the highest absorptivity over the full solar to human body radiation spectrum. The mica-white (mica-w) (mica coated with TiO2) and mica-red (mica-r) (mica coated with Fe2O3) composites showed the lowest solar energy absorptivity and a strong body heat radiation reflectivity. Furthermore, according to composites' thermal responses to the simulated solar and human body radiations, CB and mica are promising for both cooling and heating when applied in dual-functional thermal management textiles.

Research limitations/implications

Research has limitation related the amount of additives which can be added to textile. When powder is added to polyester yarn, the amount is limited by 2–3%. When powder is added to the composite which is used for printing, the amount of powder is limited by 5%.

Practical implications

A lot of apparel, especially sport apparel, contains prints. Decoration is one part of print application. Now, a lot of companies work under development of different additives, which provide additional properties to apparel. The closest targets for powder added to prints are cooling and heat retention. Quite often, inorganic additives possess dual properties: the inorganic additives may be heat reflective which his needed for heat retention, but may have high-thermal conductivity, which works well for cooling. Human body has complicated mechanism of heat exchange: convection, radiation and moisture evaporations play main role. The same additive may be cooling if there is a contact with skin but may be heating (IR reflective) if placed in the second or third layer. Thus, effect is needed to be studied first before real application.

Originality/value

This work could provide a comprehensive guideline for the rational design and application of thermal management composite textile materials by revealing the full solar to human body radiation performance of a series of inorganic materials.

Details

International Journal of Clothing Science and Technology, vol. 34 no. 4
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 1 December 1988

L. Cutrone, D.V. Moulton and L.A. Simpson

A review of the common photodegradation processes in polymeric coatings is presented, and the photoactivity of titanium dioxide and its consequences are discussed. Experimental…

Abstract

A review of the common photodegradation processes in polymeric coatings is presented, and the photoactivity of titanium dioxide and its consequences are discussed. Experimental work which explores the durability implications of the use of titanium dioxide in coatings is presented. This includes the effects of pigment flocculation, film thickness and photostability of the pigment. The importance of the correct selection of light source for accelerated weathering is stressed. Finally, results are presented from a recent study of the influence of geographical location on the weathering of titanium dioxide pigmented paint films.

Details

Pigment & Resin Technology, vol. 17 no. 12
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 19 August 2021

B. Norerama D. Pagukuman and M. Kamel Wan Ibrahim

The purpose of this paper is to present and discuss the external factors of the solar dryer design that influenced the thermal efficiency of the solar dryer that contribute to the…

Abstract

Purpose

The purpose of this paper is to present and discuss the external factors of the solar dryer design that influenced the thermal efficiency of the solar dryer that contribute to the better quality of dried food products.

Design/methodology/approach

From the reviewed works of literature, the external factors including the drying temperature, airflow rate and relative humidity have significant effects to increase the rate of moisture diffusivity of the freshly harvested products during the drying process. The proper controls of airflow rate (Q), velocity (V), relative humidity (RH%) and drying temperature (°C) can influence the dried product quality. The dehydration ratio is the procedure to measure the quality of the dried food product.

Findings

The indirect solar dryer including the mixed-mode, hybrid and integrated was found shorter in drying time and energy-intensive compared to sun drying and direct drying. The recommended drying temperature is from 35.5°C to 70°C with 1–2 m/s velocity and 20%–60% relative humidity. The optimum thermal efficiency can be reached by additional devices, including solar collectors and solar accumulators. It gives a simultaneous effect and elongated the drying temperature 8%–10% higher than ambient temperature with 34%–40% energy saving. The recommended airflow rate for drying is 0.1204 to 0.0894 kg/s. Meanwhile, an airflow rate at 0.035–0.04 kg/m2 is recommended for an optimum drying kinetic performance.

Research limitations/implications

This paper discusses the influence of the external factors of the solar dryer design on the thermal performance of the solar dryer and final dried food products quality. Therefore, the findings cannot serve as a statistical generalization but should instead be viewed as the quantitative validation subjected to fundamentals of the solar dryer design process and qualitative observation of the dried food product quality.

Practical implications

A well-designed of solar dryer with low operating and initial fabrication cost, which is simple to operate is useful for the farmers to preserve surplus harvested crops to an acceptable and marketable foods product. The optimization of the external and internal factors can contribute to solar dryer thermal performance that later provides an organoleptic drying condition that results in good quality of dried product and better drying process. The recommended drying temperature for a drying method is between 35°C up to 70°C. Drying at 65.56°C was effective to kill microorganisms. Meanwhile, drying at 50°C consider as average drying temperature. The recommended airflow rate for drying is 0.1204 to 0.0894 kg/s. Meanwhile, air flowrate at 0.035–0.04 kg/m2 is recommended for optimum drying kinetic performance. The recommended value of aspect ratio and mass flow rate is 200 to 300 for an optimum evaporation rate. The good quality of dried products and good performance of solar dryers can be developed by proper control of airflow rate (Q), velocity (V), relative humidity (RH%) and drying temperature (°C).

Social implications

The proper control of the drying temperature, relative humidity and airflow rate during the drying process will influence the final dried food products in terms of shape, color, aroma, texture, rupture and nutritious value. It is crucial to control the drying parameters because over-drying caused an increment of energy cost and reduces the dry matter. The quick-drying will disturb the chemical process during fermentation to be completed.

Originality/value

This study identifies the potential of the solar drying method for dehydrating agricultural produces for later use with the organoleptic drying process. The organoleptic drying process can reduce mold growth by promising an effective diffusion of moisture from freshly harvested products. The research paper gives useful understandings that well-designed solar drying technology gives a significant effect on dried product quality.

Details

Journal of Engineering, Design and Technology , vol. 20 no. 6
Type: Research Article
ISSN: 1726-0531

Keywords

Article
Publication date: 1 October 1990

Edgar S. Lower

Calcium stearate has been incorporated into carbon paper (7683), e.g. as a filler (7684), and in paper coatings (7685). It can act as a lubricant, leveller, and plasticizer in…

Abstract

Calcium stearate has been incorporated into carbon paper (7683), e.g. as a filler (7684), and in paper coatings (7685). It can act as a lubricant, leveller, and plasticizer in paper coatings (7686), and gives improved anti‐dust and gloss properties in calendering (7687), and enhanced flow and levelling (7688). Along with ammonium stearate the calcium soap has been used as a lubricant in paper coatings to improve tear strength and gloss (7689), and wet strength. Paper and paperboard have been coated with equal parts of calcium stearate and acrylic/styrene copolymers to increase water resistance (7690). Particles of aluminium hydroxide have been coated with calcium stearate and with stearic acid to give the material hydrophobic properties, resistant to exposure to boiling water and solvents, and useable as a filler in paper (and plastics) (7691). Ketene dimers along with calcium stearate have been used in paper sizing (7692), and the stearate alone has been used to make water resistant abrasive papers (7693), and also, at a concentration of 2/3%, has been employed to render cardboard resistant to water steeping and swelling (7694). Stable dispersions of the stearate soap have been utilized in the surface treatment of computer cards (7695). Titanium dioxide coated with calcium stearate has been included in polyethylene coating compositions for photographic paper supports (7696). Release paper for adhesive lables have contained calcium stearate, to give improved workability on automatic labelling machines (7697).

Details

Pigment & Resin Technology, vol. 19 no. 10
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 October 1981

Americus

The number of new alkyd resin‐based coatings introduced decreases yearly. To be sure, alkyd resins are the most important vehicles used for solvent‐based paints. On the other…

Abstract

The number of new alkyd resin‐based coatings introduced decreases yearly. To be sure, alkyd resins are the most important vehicles used for solvent‐based paints. On the other hand, the technology is mature and the major variations in the products are those which must be made to accommodate needs of the user. For the most part, these do not lead to completely new types of compositions.

Details

Pigment & Resin Technology, vol. 10 no. 10
Type: Research Article
ISSN: 0369-9420

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