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The interaction between the silver powder and organic vehicle largely determines the rheological behavior of silver conductive paste. This study aims to prepare silver conductive paste with an organic vehicle system consisting of ethyl cellulose (EC) and terpineol/butyl carbitol acetate solvent mixtures. The study also aims to measure the rheological behaviors of the silver conductive pastes with different solvent mixtures, EC molecular weights and silver content, to investigate the interaction among the polymer, solvent and silver powder and determine the main factors affecting the thixotropic index and maximum silver content.

The rheological behaviors of silver conductive pastes with different solvent mixtures, EC molecular weights and silver content were investigated using viscometer.

The shear thinning became significant with increasing EC molecular weight. The EC solvation with higher molecular weight in solvent is better than that of EC with lower molecular weight. This leads to a stronger interaction between the silver powder and EC with higher molecular weight and consequently good silver particle dispersion. The relative viscosity of silver conductive paste at 10 s⁻¹ increases significantly with increasing silver content, but the relative viscosity at 100 s⁻¹ is much less sensitive to the silver content. The viscosities at low and high shear rate can be increased by increasing the silver content and EC molecular weight, respectively.

The interaction among the polymer, solvent and silver powder was investigated for the silver paste with high solid content. The main factors affecting the viscosities at high and low shear rates, thixotropic index and maximum silver content were determined.

This study aims to develop a bimodal nano-silver paste with improved mechanical property and reliability. Silicon carbide (SiC) particles coated with Ag were introduced in nano-silver paste to improve bonding strength between SiC and Ag particles and enhance high-temperature stability of bimodal nano-silver paste. The effect of sintering parameters such as sintering temperature, sintering time and the proportion of SiC particles on mechanical property and reliability of sintered bimodal nano-silver structure were investigated.

Sandwich structures consist of dummy chips and copper substrates with nickel and silver coating bonded by nano-silver paste were designed for shear testing. Shear strength testing was conducted to study the influence of SiC particles proportions on the mechanical property of sintered nano-silver joints. The reliability of the bimodal nano-silver paste was evaluated experimentally by means of shear test for samples subjected to thermal aging test at 150°C and humidity and temperature testing at 85°C and 85 per cent RH, respectively.

Shear strength was enhanced obviously with the increase of sintering temperature and sintering time. The maximum shear strength was achieved for nano-silver paste sintered at 260°C for 10 min. There was a negative correlation between the proportion of SiC particles and shear strength. After thermal aging testing and humidity and temperature testing for 240 h, the shear strength decreased a little. High-temperature stability and high-hydrothermal stability were improved by the addition of SiC particles.

Submicron-scale SiC particles coated with Ag were used as alternative materials to replace part of nano-silver particles to prepare bimodal nano-silver paste due to its high thermal conductivity and excellent mechanical property.

The purpose of this paper is to investigate the influence of silver nanoparticle additions on the wetting properties of Sn‐Ag‐Cu (SAC) solder paste. In this investigation, the basic solder paste contained 85 wt.% of commercial Sn 96.5 Ag 3 Cu 0.5 powder (with the particle sizes in the range of 20‐38 μm) and 15 wt.% of self‐prepared middle activated rosin flux. To this paste was added 0.5, 1, 2 and 4 wt.% of self‐prepared silver nano‐powders of different grain sizes (from 9 to 138 nm). After the pastes had stabilized, their wetting properties were tested. The main goal of these investigations was to improve the wetting properties of SAC solder paste and to find correlations between the results of the wetting of solder paste with nanoparticles on the copper substrate with the microstructure of the solder joints.

The following methods were applied for the wetting solder paste investigation: spreading on the copper substrate, contact angle measurement on the copper and wetting on a FR‐4 laminate double sided with an 18‐μm thick copper foil. The investigations were performed at temperatures of 220, 230, 240 and 250°C. Cross‐sectioning was performed on the solder paste after reflow on the copper substrate. For the microstructural analysis of the “nano” modified solder joints obtained at 250°C, standard metallographic procedures were applied. Changes in the microstructure, the thickness of the inter‐metallic compounds (IMCs) and their chemical compositions were observed by means of scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS).

As expected, a higher silver nanoparticle addition to the SAC solder paste resulted in better wetting properties on copper. The results indicated the possibility of an improvement of the reflow soldering process by using SAC solder paste with silver nanoparticles and by lowering its soldering temperature. An improvement was also observed in the wettability with a decrease in the silver nanoparticle grain size. Also, the wettability proceeded at a lower temperature (20°C lower) than that for the SAC paste, without the nano‐additives. For the 4 per cent silver nanoparticle addition, Ag₃Sn star‐like IMCs were also found, which grew with the lowering of the silver nanoparticle grain size.

Further studies are necessary for confirmation of the practical application, especially of the mechanical properties, as well as the reliability properties of the solder joints, for the chosen solder paste with silver nanoparticles.

Taking into account the wetting data, the best results of the “nano” SAC solder pastes were obtained for the highest addition of the silver nanoparticles. It was found that the spreading on copper was higher and the contact angles were lower for the SAC solder paste with 4 per cent (by wt.) of 138‐nm grain size silver nanoparticles. A comparison of SAC solder pastes with a 4 per cent silver nanoparticle addition but of a different grain size (138‐9 nm), suggested a further improvement in wetting properties with lowering of the silver nanoparticle grain size. The results suggested the possibility of an improvement in the reflow soldering process by using SAC solder paste with silver nanoparticles and by lowering its soldering temperature.

Spreading, wetting and contact angle measurement methods were used for the wetting determination of the SAC solder paste with the silver nanoparticles on copper under the same temperature conditions. Also, the microstructure of the solder joints obtained at 250°C was determined with the use of SEM and EDS methods. The results obtained made it possible to draw conclusions regarding the correlation between the output of the wetting results and the amount and the grain size of the added silver nanoparticles, and also the microstructure and thickness of the IMCs of the “nano” solder joints.

The purpose of this paper is to investigate and report the impact of glass frit variation in silver thick film pastes used as surface conductors in low temperature co‐fired ceramics technology (LTCC), especially on the properties such as warpage of LTCC associated with conductors, microstructure of the fired thick films, sheet resistance and adhesion on LTCC.

Silver thick film paste compositions were formulated by changing the silver glass frit ratio. The compatibility of these formulated paste compositions with LTCC (DP 951AX) substrate were evaluated. The properties such as microstructure developments, the change in sheet resistance, warpage of LTCC substrate with respect to glass frit ratio of the developed silver films on LTCC were evaluated.

The results reveal that the glass frit percentage used in paste formulation is equally responsible for the disturbance in the properties such as microstructure, warping and electrical properties of the fired thick films on LTCC. It was observed that the paste composition, in particular sample SP10B containing the highest glass frit percentage, is compatible with the LTCC tape under processing conditions. The sheet resistance value in the range of 5 mΩ/□ and the fired films showed very good adhesion (3.95 N), irrespective of the glass frit composition.

The paper provides useful evaluations of properties such as microstructure developments, changes in sheet resistance and warpage of LTCC substrate with respect to glass frit ratio of the developed silver pastes on LTCC.

Traditional chip‐level interconnection materials show many weaknesses given the development trend of microelectronic packaging technology. In order to meet the needs of high‐temperature packaging for wide‐bandgap semiconductors, low‐temperature sintered nano‐silver as a novel semiconductor device‐metallized substrate interconnection material is being developed. One phenomenon that larger interconnection area would cause poor interconnection quality had been found in the industry butut the mechanisms were never previously studied. This paper aims to address these issues.

The changes in the shear strengths and microstructures of nano‐silver joints induced by the changes of interconnection areas were investigated by shear tests and scanning electron microscopy.

The increased interconnection area blocks the organic components to be burnout and causes a higher pore ratio. Thus, it reduces the bonding quality. To ensure a good and steady sintering quality, the interconnection area should be limited to 3 × 3 mm².

A sintering technology or paste with oxygen agent will be studied in the future.

A relationship of shear strength and interconnection area of sintering joints with nano‐silver paste was observed.

The paper gives design guidelines for polymer thick‐film technology (PTF). After an introduction reviewing the main PTF properties, materials and processes, detailed PTF design rules are presented. They are conservative, to achieve high production yield. The design rules are based on the considerable experience in the companies of the authors and of the persons mentioned in the acknowledgements, as well as on information from the open literature and from materials suppliers. The design guidelines are intended primarily for designers, but they are also important for production personnel, to facilitate a close coupling between design and production, and thus provide optimum use of PTF and obtain high production yield.

The aim of this paper is to present thermal and mechanical durability of conductive tracks screen-printed with silver polymer pastes on flexible magnetic sheets.

A test pattern that consisted of three straight lines was printed with two different silver pastes on a flexible magnetic sheet and a polyethylene naphthalate (PEN) foil for comparison. Electrical properties of these lines were examined by resistance measurements and their thickness was measured with a digital microscope on cross sections. Cyclic bending was performed to investigate mechanical properties of prepared samples as well as thermal shocks to analyse their thermal durability. Further, samples after thermal shocks underwent cyclic bending to test influence of thermal exposure on mechanical properties of the prepared samples. Changes in the test lines after the thermal and mechanical tests were assessed by resistance measurements and microscopic analysis of surface and internal structure of the test lines.

It was found that the most important factor having an impact on electrical, mechanical and thermal properties of the conductive tracks screen-printed on magnetic sheets is a type of paste used. The samples made with the paste PM-406 exhibited lower resistance because of a higher layer thickness compared to the lines printed with the paste PF-050. The PM-406 layers were revealed to be less durable to mechanical and thermal exposures. An analogical relationship was noticed for the samples made with PM-406 and PF-050 on a PEN foil after thermal shocks and cyclic bending. When magnetic sheets were used as a substrate, a bigger degree of damage was observed for the PF-050 samples, which even lost their electrical continuity after 1,000 bending cycles and thermal cycles, irrespective of their number. Some damage was also noticed in the magnetic sheet after the bending and thermal cycles.

Further investigations are required to examine the influence of other types of thermal exposure on electrical properties of lines printed on magnetic sheets. Other types of magnetic sheets are also recommended to be investigated as substrate materials.

The results reported in this study can be useful among others for designers of radio frequency identification (RFID) systems, which are intended to operate in a challenging environment with strong mechanical and thermal exposures.

This paper contains valuable information concerning mechanical and thermal properties of conductive tracks screen-printed on magnetic sheets which can be used, i.e. for designing of reliable near field communication/high frequency (NFC/HF)-RFID tags suitable for metallic surface.

This paper aims to investigate the usability of the nickel copper zinc ferrite with the composition Ni_0.4Cu_0.2Zn_0.4Fe_1.98O_3.99 for the realization of high-temperature multilayer coils as discrete components and integrated, buried function units in low temperature cofired ceramics (LTCC).

LTCC tapes were cast and test components were produced as multilayer coils and as embedded coils in a dielectric tape. Different metallization pastes are compared. The properties of the components were measured at room temperature and higher temperature up to 250°C. The results are compared with simulation data.

The silver palladium paste revealed the highest inductance values within the study. The measured characteristics over a frequency range from 1 MHz to 100 MHz agree qualitatively with the measurements obtained from toroidal test samples. The inductance increases with increasing temperature and this influence is lower than 10%. The characteristic of embedded coils is comparable with this of multilayer components. The effective permeability of the ferrite material reaches values around 130.

The research results based on a limited number of experiments; therefore, the results should be verified considering higher sample sizes.

The results encourage the further investigation of the material Ni_0.4Cu_0.2Zn_0.4Fe_1.98O_3.99 for the use as high-temperature ferrite for the design of multilayer coils with an operation frequency in the range of 5-10 MHz and operation temperatures up to 250°C.

It is demonstrated for the first time, that the material Ni_0.4Cu_0.2Zn_0.4Fe_1.98O_3.99 is suitable for the realization of high-temperature multilayer coils and embedded coils in LTCC circuit carriers with high performance.

The purpose of this paper is to investigate screen-printed high-frequency (HF) antennas for radio frequency identification (RFID) on-metal transponders in which a magnetic sheet was used as a substrate material.

A transponder antenna was designed in the form of square coil using a high-frequency electromagnetic software. Then, the antenna was fabricated with screen printing technique on two different magnetic sheets (RFN4 and RFN7) and on polyethylene naphthalate (PEN) foil for comparison. Its printing was carried out with polymer pastes based on silver flakes (PM-406 and SF). Thickness, track width and spacing were examined for the antennas using digital microscope and contact profilometer. Resistance and inductance were also measured, and resonant frequency, quality factor and target values of capacitance to achieve resonant frequency of the tested antenna at 13.56 MHz were calculated. Finally, RFID chips were mounted to the prepared antennas using an isotropic conductive adhesive, and a maximum read distance was measured with a reader installed in a smartphone.

It was found that an antenna thickness on the magnetic sheets used was higher than on PEN foil. At the same time, surface roughness of the fabricated antennas on these sheets was revealed to be higher as well. Inductance of the measured antennas exhibited good conformity with the antenna design, but higher divergence was noticed in the measured resistance. Its lowest value was achieved when the antenna was printed with the paste PM-406 on PEN foil and the highest one when it was fabricated with the paste SF on the same substrate. This suggests that high attention needs to be paid to a polymer paste selected for antenna printing. The performed tests showed that the magnetic sheet RFN4 seems to be better substrate for on-metal transponders compared to RFN7 due to lower resistance and higher quality factor of the prepared antennas.

Further investigations are required to examine mechanical and thermal durability of the HF antennas printed on the magnetic sheets.

The investigated HF antennas fabricated on magnetic sheets can find application in near field communication (NFC) transponders designed to be placed on metallic surfaces, e.g. on frames of advertising screens.

Influence of used magnetic sheets and polymer pastes on geometry and electrical properties of HF antennas for RFID on-metal transponders was investigated. The presented investigations can be interesting for NFC/RFID designers who are involved in designing systems suitable for metallic surfaces.

This paper aims to find proper technological parameters of low-temperature joining technique by silver sintering to eventually use this technique for reliable electronic packaging.

Based on the literature and author’s own experience, the factors influencing the nanosized Ag particle sintering results were identified, and their significance was assessed.

It has been shown that some important technological parameters clearly influence the quality of the joints, and their choice is unambiguous, but the meaning of some parameters is dependent on other factors (interactions), and they should be selected experimentally.

The value of this research is that the importance of all technological factors was analyzed, which makes it easy to choose the technological procedures in the electronic packaging.