Search results

Despite recessionary years in 1990 and 1991, West European demand for specialty silicas has increased at an average annual rate of 8% per year over the past five years as detailed in a new study from Kline and Company. In 1991, total European demand reached $425 million for the eight silica products listed in Table 1. These silicas, which include both synthetically manufactured products as well as natural minerals, are used in a wide variety of industrial and consumer applications. Specialty silicas impart such unique functions as reinforcement, thickening or electrical properties to these applications and are not used merely as cost reducing fillers.

Thixotropy can be regarded as the loss of viscosity in a paint or other material that is brought about by mechanical agitation, and where the viscosity continues to decrease provided that this disturbance is continued for a period of time. Conversely, when the mechanical force is removed, the material then increases in viscosity and this recovery toward the initial structure continues to take place over a period of time. Sometimes the time dependency of the viscosity is vanishingly small so that the material is then properly referred to as pseudoplastic. In most of the literature, however, it is not usually possible to differentiate between thixotropy and true pseudoplasticity and therefore both kinds of structure are included in this review as they each are destroyed by mechanical agitation and recover when this is discontinued.

The purpose of this paper is to highlight the sustainability benefits of using demolition and industrial wastes as a replacement for aggregates and cement in traditional concrete mixes.

Crushed concrete from demolition sites served as a replacement for fine and coarse aggregate in some of the mixes at various ratios. In addition, ground granulated blast furnace slag, metakaolin, silica fume, and fly ash each served as a cement replacement for cement content in the mixes tested in this research at various rates. Compression strength tests, permeability, and thermal expansion tests were performed on various mixes to compare their performance to that of traditional mixes with natural aggregate, and with no cement replacement.

The compressive strength results indicated the suitability of using such demolition wastes as replacements in producing green concrete (GC) without hindering its mechanical characteristics significantly. In addition, the results indicated an enhancement in the mechanical characteristics of GC when replacing cement with pozzolanic industrial wastes and byproducts.

The research assesses the utilization of sustainable GC using recycled waste aggregate and byproducts.

The purpose of this paper is to investigate the resistivity of geopolymer cement with nano-silica additive toward acid exposure for oil well cement application.

An experimental study was conducted to assess the acid resistance of fly ash-based geopolymer cement with nano-silica additive at a concentration of 0 and 1 wt.% to understand its effect on the strength and microstructural development. Geopolymer cement of Class C fly ash and API Class G cement were used. The alkaline activator was prepared by mixing the proportion of sodium hydroxide (NaOH) solutions of 8 M and sodium silicate (Na₂SiO₃) using ratio of 1:2.5 by weight. After casting, the specimens were subjected to elevated curing condition at 3,500 psi and 130°C for 24 h. Durability of cement samples was assessed by immersing them in 15 wt.% of hydrochloric acid and 15 wt.% sulfuric acid for a period of 14 days. Evaluation of its resistance in terms of compressive strength and microstructural behavior were carried out by using ELE ADR 3000 and SEM, respectively.

The paper shows that geopolymer cement with 1 wt.% addition of nano-silica were highly resistant to sulfuric and hydrochloric acid. The strength increase was contributed by the densification of the microstructure with the addition of nano-silica.

This paper investigates the mechanical property and microstructure behavior of emerging geopolymer cement due to hydrochloric and sulfuric acids exposure. The results provide potential application of fly ash-based geopolymer cement as oil well cementing.

The purpose of this paper is to make a contribution to understanding the influence of factors such as the water/cement (W/C) ratio and the granular class on the mechanical and physical properties of high-strength concretes (HSCs). In the formulations of HSC, aggregates by their high mass and volume proportion play an important role. When selecting aggregates, it is necessary to know their intrinsic properties. These properties influence the performance of concrete, in particular the quality of the granulate cimentary adhesion.

This experimental study focused on the effect of W/C ratio (0.25, 0.30, 0.35), the effect of replacing a part of cement by silica fume (SF) (8%), the effect of fraction of aggregate on properties of fresh and hardened concrete, the effect of different environment conversation like drinking water and sea water on compressive strength and the study of absorption of water and softening using the mix design method of the University of Sherbrooke combined with the Dreux-Gorisse method which gives good results.

At the end of our work, the examination of the results obtained made it possible to establish the correlations between the formulations studied and the physicomechanical characteristics of the concrete compositions (HSC25, HSC16, HSC8). The results of this study show that the use of three granular classifications (DMAX8, DMAX16 and DMAX25) and three report W/C (0.25, 0.30 and 0.35) in two different conservation environment (drinking water and sea water) give HSCs, HSC25 with an W/C = 0.25 ratio has reached the largest mechanical strength of 90 MPa for different environments of conservation. For selecting aggregates, it is necessary to know their intrinsic properties, these properties influence the strength of concrete. In general, there is a slight decrease in the compressive resistance of the specimens stored in seawater, it can be said that the conservation life has not had effect on the resistance (28 days). The effect of aggressive environment can appear in the long term.

Mixed design and concrete fabrication with a 28-day compressive strength of up to 68 MPa or more of 90 MPa can now be possible used in Jiel (Algeria), and it should no longer be considered to be used only in an experimental domain. Addition of SF in concrete showed good development of strength between 7 and 28 days, depending on the design of the mix.

Concrete containing 8% SF with W/B of 0.25 has higher compressive strength than the other concretes, and concretes with SF are more resistant than concretes without SF, so it is possible to have concrete with a compressive strength of 82 MPa for W/C 0.25 without SF. Like as a result, we can avoid the use of SF to affect the strength of concrete at compressive strength of 68 MPa, and a slump of 21 cm, because the SF is the most expensive ingredient used in the composition of concrete and is therefore very important economically. One of the main factors of production of HSC above 90 MPa is use of aggregate DMAX25, which is stronger with W/B of 0.25 and 0.30.

This mixtures leads to a very dense microstructure and low porosity and produces increased permeability of HSC and is able to resist the penetration of aggressive agents. This combination has a positive effect on the economy of concrete.

The combination of the Dreux-Gorisse method with the Sherbrook method is very beneficial for determining the percentage of aggregates used, and the use of coarse aggregates of Jijel to obtain HSC with 90 MPa and 16 cm of workability.

To contribute to the identification of the parameters influencing the behavior of textile-reinforced concrete (TRC), the purpose of this paper is to investigate the flexural behavior of TRC-based plates under four-point bending notably designed in the context of sustainable development and the substitution of mortar components with natural and abundant materials.

An extensive experimental campaign was focused about two main parameters. The first one emphases the textile reinforcements, such as the number of layers, the nature and the textile mesh size. In the second step, the composition of the mortar matrix was explored through the use of dune sand as a substitute of the river one.

Test results in terms of load-displacement response and failure patterns were highlighted, discussed and confronted to literature ones. As key findings, an increase of the load-bearing capacity and ductility, comparable to the use of an industrially produced second textile layer was recorded with the use of dune sand in the mortar mix design. The designed ecofriendly samples with economic concerns denote the significance of obtained outcomes in this research study.

The novelty of the present work was to valorize the use of natural dune sand to design new TRC samples to respond to the environmental and economical requirements. The obtained values provide an improved textiles–matrix interface performance compared to classical TRC samples issued from the literature.

In 1982, the total volume of extender and filler pigments consumed in seven key industries in the USA reached 6.8m tons valued at over $750m according to a recently completed survey and analysis by C. H. Kline & Co., marketing consultants. While the effects of the recession continued to impact individual markets in 1982, causing moderate declines for such major pigments as calcium carbonate and kaolin, total demand is forecast to reach $1.2 bn by 1987.

The purpose of this paper is to prepare new modified polypropylene (PP) with phenolic microspheres (PFMs). Furthermore, the crystallinity and mechanical properties of PP modified by fillers (silicon dioxide [SiO₂] and light calcium carbonate [CaCO₃], respectively) have also been investigated and compared.

For effective toughening, three different fillers were added into the PP matrix. PP composites were prepared through melt blending with double-screw extruder and injection moulding machine.

It was found that with the addition of 3 Wt.% PFM, the impact strength was maximum in all PP composites and increased by 1.4 times compared to pure PP. Scanning electron microscopy (SEM) and polarised optical microscopy (POM) analysis confirmed that 3 Wt.% PFM, 3 Wt.% SiO₂ and 2 Wt.% CaCO₃ were optimal to add in PP and PFM to give the best compatibility with PP.

PFM particles not only are tougher and less brittle and can offer other advantages such as enhanced machinability, but also are important organic materials and have a good compatibility with polymer for reinforcing polymer properties.

The method developed provided a simple and practical solution to improving the toughness of PP.

There will be thermoplastic plastics with higher toughness in domestic, packaging and automotive applications, particularly at lower temperatures.

The PP modified by tiny amounts of fillers in this work had high toughness, which can be applied as an efficient material widely used in domestic, packaging and automotive applications.

This paper aims to predict the 28-day compressive strength of recycled thermal insulation concrete more accurately.

The initial weights and thresholds of BP neural network are improved by genetic algorithm on MATLAB 2014 a platform.

Genetic algorithm–back propagation (GA-BP) neural network is more stable. The generalization performance of the complex is better.

The GA-BP neural network based on the training sample data can better realize the strength prediction of recycled aggregate thermal insulation concrete and reduce the complex orthogonal experimental process. GA-BP neural network is more stable. The generalization performance of the complex is better.

The purpose of the study reported in this paper was to prepare modified C.I. Pigment Red (PR) 170 to reduce production cost and improve application performance. The structure of the modified pigment was characterised. The colour strength, thermal stability, mobility, aqueous dispersability and ultraviolet (UV) resistance of modified pigments were studied.

Silica fume was added into the diazonium salt solution under acidic condition, followed by the activation to generate new surface. Subsequently, coupling component was dropwise added to the system to form the modified pigments evenly on the surface of silica fume in situ. The structure and properties of the modified pigment were studied by fourier transform infrared spectoscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravity analysis (TG-DTA), UV-visible diffuse reflectance spectra (UV-Vis DRS), and commission internationale de L‘Eclairage (CIE L*a*b*) colour measurements.

The morphology and particle size of the modified pigment were controlled by the modification of the silica fume, and the organic pigment and silica fume formed a core–shell structure. The properties of the modified pigment including colour strength, thermal stability, mobility, aqueous dispensability and UV resistance were improved significantly.

The effect of the amount of silica fume on the thickness of the organic pigment layer and the effect of the thickness of the organic pigment layer on the properties of the modified pigment need to be studied further.

This paper shows a feasible method of the modification of the PR170 with the silica fume, and the modification can improve the properties of the PR170. The use of silica fume to modify organic pigment can realise the reuse of solid waste and reduce the production cost of the organic pigment.

This modification method of the organic pigment is adaptive and it can be adjusted to the modification of other species of the organic pigment.

The modification of the PR170 with the silica fume was carried out in its preparation process, which synchronised the preparation and modification of the organic pigment. The properties of the modified pigment were improved, which were beneficial for their application in inks and coatings.