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Polyurea falls into a category of elastomeric co‐polymers in which, due to the presence of strong hydrogen bonding, the microstructure is of a heterogeneous nature and consists of a compliant/soft matrix and stiff/hard nanometer size hard domains. Recent investigations have shown that the use of polyurea as an external or internal coating/lining had substantially improved ballistic‐penetration resistance of metallic structures. The present work aims to use computational methods and tools in order to assess the shock‐mitigation ability of polyurea when used in the construction of different components (suspension‐pads, internal lining and external coating) of a combat helmet.

Shock‐mitigation capability of combat helmets has become an important functional requirement as shock‐ingress into the intra‐cranial cavity is known to be one of the main causes of traumatic brain injury (TBI). To assess the shock mitigation capability of polyurea, a combined Eulerian/Lagrangian fluid/solid transient non‐linear dynamics computational analysis of an air/helmet/head core sample is carried out and the temporal evolution of the axial stress and particle velocities (for different polyurea augmented helmet designs) are monitored.

The results obtained show that improvements in the shock‐mitigation performance of the helmet are obtained only in the case when polyurea is used as a helmet internal lining and that these improvements are relatively small. In addition, polyurea is found to slightly outperform conventional helmet foam, but only under relatively strong (greater than five atm) blastwave peak overpressures.

The present approach studies the effect of internal linings and external coatings on combat helmet blast mitigation performance.

Polyurea is an elastomeric two-phase co-polymer consisting of nanometer-sized discrete hard (i.e. high glass transition temperature) domains distributed randomly within a soft (i.e. low glass transition temperature) matrix. A number of experimental investigations reported in the open literature clearly demonstrated that the use of polyurea external coatings and/or internal linings can significantly increase blast survivability and ballistic penetration resistance of target structures, such as vehicles, buildings and field/laboratory test-plates. When designing blast/ballistic-threat survivable polyurea-coated structures, advanced computational methods and tools are being increasingly utilized. A critical aspect of this computational approach is the availability of physically based, high-fidelity polyurea material models. The paper aims to discuss these issues.

In the present work, an attempt is made to develop a material model for polyurea which will include the effects of soft-matrix chain-segment molecular weight and the extent and morphology of hard-domain nano-segregation. Since these aspects of polyurea microstructure can be controlled through the selection of polyurea chemistry and synthesis conditions, and the present material model enables the prediction of polyurea blast-mitigation capacity and ballistic resistance, the model offers the potential for the “material-by-design” approach.

The model is validated by comparing its predictions with the corresponding experimental data.

The work clearly demonstrated that, in order to maximize shock-mitigation effects offered by polyurea, chemistry and processing/synthesis route of this material should be optimized.

Limitations in space and city planning constraints have led to the search for alternative shock mitigation devices that are architecturally appealing. The purpose of this paper is to consider a compromise solution which consists of partially open, thick, bending-resistant shapes made of acrylic material that may be Kevlar- or steel-reinforced. Seven different configurations were analyzed numerically.

For the flow solver, the FEM-FCT scheme as implemented in FEFLO is used. The flowfields are initialized from the output of highly detailed 1-D (spherically symmetric) runs. Peak pressure and impulse are stored and compared. In total, seven different configurations were analyzed numerically.

It is found that for some of these, the maximum pressure is comparable to usual, closed walls, and the maximum impulse approximately 50 percent higher. This would indicate that such designs offer a blast mitigation device eminently suitable for built-up city environments.

Future work will consider fully coupled fluid-structure runs for the more appealing designs, in order to assess whether such devices can be manufactured from commonly available materials such as acrylics or other poly-carbonates.

This would indicate that such designs offer a blast mitigation device eminently suitable for built-up city environments.

This is the first time such a semi-open blastwall approach has been tried and analyzed.

In the recent work, a new blast-wave impact-mitigation concept involving the use of a protective structure consisting of bimolecular reactants (polyvinyl pyridine+cyclohexyl chloride), capable of undergoing a chemical reaction (to form polyvinyl pyridinium ionic salt) under shockwave loading conditions, was investigated using all-atom reactive equilibrium and non-equilibrium molecular-dynamics analyses. The purpose of this paper is to reveal the beneficial shockwave dispersion/attenuation effects offered by the chemical reaction, direct simulations of a fully supported single planar shockwave propagating through the reactive mixture were carried out, and the structure of the shock front examined as a function of the extent of the chemical reaction (i.e. as a function of the strength of the incident shockwave). The results obtained clearly revealed that chemical reactions give rise to considerable broadening of the shockwave front. In the present work, the effect of chemical reactions and the structure of the shockwaves are investigated at the continuum level.

Specifically, the problem of the (conserved) linear-momentum accompanying the interaction of an incident shockwave with the protective-structure/protected-structure material interface has been investigated, within the steady-wave/structured-shock computational framework, in order to demonstrate and quantify an increase in the time period over which the momentum is transferred and a reduction in the peak loading experienced by the protected structure, both brought about by the occurrence of the chemical reaction (within the protective structure).

The results obtained clearly revealed the beneficial shock-mitigation effects offered by a protective structure capable of undergoing a chemical reaction under shock-loading conditions.

To the authors’ knowledge, the present manuscript is the first report dealing with a continuum-level analysis of the blast-mitigation potential of chemical reactions.

Taking a gender-sensitive approach, this study examines the socio-economic and institutional drivers of household vulnerability to the shocks occasioned by the COVID-19 pandemic. The study employs country-level panel data for Nigeria. Data collected were analysed using descriptive statistics, Pearson's chi-square, and ordered logistic regression. The study found significant heterogeneity in vulnerability to the COVID-19 shocks between the male-headed households (MHHs) and female-headed households (FHHs) (p < 0.1). The econometric results reveal that in the MHHs, the geographical location, livelihood diversification, and ownership of television were the significant drivers of vulnerability to COVID-19–related shocks. In the FHHs, credit constraints, household size, value of the household assets, geographical location, ownership of television and radio, and experiences of previous shocks were found to be significant drivers of vulnerability to COVID-19–related shocks. This study provides insights for designing inclusive social protection interventions and gender-sensitive COVID-19 recovery policies.

The purpose of this paper is to study the mechanical response of polyurea, soda-lime glass (glass, for short), polyurea/glass/polyurea and glass/polyurea/glass sandwich structures under dynamic-loading conditions involving propagation of planar longitudinal shockwaves.

The problem of shockwave generation, propagation and interaction with material boundaries is investigated using non-equilibrium molecular dynamics. The results obtained are used to construct basic shock Hugoniot relationships associated with the propagation of shockwaves through a homogeneous material (polyurea or glass, in the present case). The fidelity of these relations is established by comparing them with their experimental counterparts, and the observed differences are rationalized in terms of the microstructural changes experienced by the shockwave-swept material. The relationships are subsequently used to predict the outcome of the interactions of shockwaves with polyurea/glass or glass/polyurea material boundaries. Molecular-level simulations are next used to directly analyze the same shockwave/material-boundary interactions.

The molecular-level simulations suggested, and the subsequent detailed microstructural analyses confirmed, the formation of topologically altered interfacial regions, i.e. polyurea/glass and glass/polyurea interphases.

To the authors’ knowledge, the present work is a first attempt to analyze, using molecular-level simulation methods, the interaction of shockwaves with material boundaries.

The purpose of this paper is to assess the blast‐mitigation potential and the protection ability of an air‐vacated buffer placed in front of a target structure under realistic combat‐theatre conditions.

The blast‐mitigation efficacy of the air‐vacated buffer concept is investigated computationally using a combined Eulerian‐Lagrangian (CEL) fluid‐structure interaction (FSI) finite‐element analysis.

The two main findings resulting from the present work are: the air‐vacated buffer concept yields significant blast‐mitigation effects; and the buffer geometry and vacated‐air material‐state parameters (e.g. pressure, mass density, etc.) may significantly affect the extent of the blast‐mitigation effect.

The main contribution of the present work is a demonstration of the critical importance of timely deployment of the buffer relative to the arrival of the incident wave in order to fully exploit the air‐vacated buffer concept.

The purpose of this paper is to introduce and analyze a new blast-wave impact-mitigation concept using advanced computational methods and tools. The concept involves the use of a protective structure consisting of bimolecular reactants displaying a number of critical characteristics, including: a high level of thermodynamic stability under ambient conditions (to ensure a long shelf-life of the protective structure); the capability to undergo fast/large-yield chemical reactions under blast-impact induced shock-loading conditions; large negative activation and reaction volumes to provide effective attenuation of the pressure-dominated shockwave stress field through the volumetric-energy storing effects; and a large activation energy for efficient energy dissipation. The case of a particular bimolecular chemical reaction involving polyvinyl pyridine and cyclohexyl chloride as reactants and polyvinyl pyridinium ionic salt as the reaction product is analyzed.

Direct simulations of single planar shockwave propagations through the reactive mixture are carried out, and the structure of the shock front examined, as a function of the occurrence of the chemical reaction. To properly capture the shockwave-induced initiation of the chemical reactions during an impact event, all the calculations carried out in the present work involved the use of all-atom molecular-level equilibrium and non-equilibrium reactive molecular-dynamics simulations. In other words, atomic bonding is not pre-assigned, but is rather determined dynamically and adaptively using the concepts of the bond order and atomic valence.

The results obtained clearly reveal that when the chemical reactions are allowed to take place at the shock front and in the shockwave, the resulting shock front undergoes a considerable level of dispersion. Consequently, the (conserved) linear momentum is transferred (during the interaction of the protective-structure borne shockwaves with the protected structure) to the protected structure over a longer time period, while the peak loading experienced by the protected structure is substantially reduced.

To the authors’ knowledge, the present work is the first attempt to simulate shock-induced chemical reactions at the molecular level, for purposes of blast-mitigation.

This paper aims to utilize purpose advanced fluid‐structure interaction, non‐linear dynamics, finite‐element analyses in order to investigate various phenomena and processes accompanying blast wave generation, propagation and interaction and to assess the blast‐wave‐mitigation potential of a piston‐cylinder assembly placed in front of the target structure.

The employed computational methods and tools are verified and validated by first demonstrating that they can quite accurately reproduce analytical solutions for a couple of well‐defined blast wave propagation and interaction problems.

The methods/tools are used to investigate the piston‐cylinder blast‐mitigation concept and the results obtained clearly reveal that significant blast‐mitigation effects can be achieved through the use of this concept. Furthermore, the results showed that the extent of the blast‐mitigation effect is a sensitive function of the piston‐cylinder geometrical parameters. Specifically, the mass of the piston and the length of the cylinder are found to be the dominant factors controlling the extent of the blast‐wave‐mitigation.

The work demonstrates that, when assessing the blast‐wave‐mitigation potential of the piston‐cylinder concept, it is critical that loading experienced by the piston be defined by explicitly modeling (fluid/structure) interactions between the blast wave(s) and the piston.

The main purpose of this paper is to present and compare two different models for bubble growth and foam formation and to conduct a thorough assessment in terms of their numerical implementation and prediction accuracy.

The two models are assessed and validated against experimental measurements. The first model is known as a single bubble growth model and treats the foaming process as a single bubble growing in a large pool with enough gas available for growth, while the second model (cell model) takes into account the finiteness of gas supply availability as well as the effects of surrounding bubbles. The models are based on the application of the conservation of continuity and momentum principles and on constitutive equations to represent the viscosity of the melt. The models are numerically implemented using a finite difference scheme and their predictions are compared against experimental measurements.

The results demonstrate that the single bubble model predicts an infinite bubble growth with time due to the assumption of unlimited supply of the blowing agent. Meanwhile the cell model gives an equilibrium bubble size because it accounts for gas depletion. From this work, it was concluded that the cell model is the best model that adequately describes experimental data.

The problem of bubble growth and foam formation is of great importance in the process industry as it plays a key role in diverse technological fields such as the production of foamed plastics.

The findings here are important for the appropriate modeling of bubble growth and foam formation and for scheduling and optimizing the process. A simple model will suffice for the early stage of the process while a cell model is more appropriate for the entire duration of the process.