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Article
Publication date: 5 August 2022

Wenjun Wang, Luting Shen, Yinsong Si, Islam MD Zahidul, Azim Abdullaev and Yubing Dong

Sodium alginate (Na-Alg) is a natural polysaccharide with a rich and renewable production that is widely used in the food, pharmaceutical and daily necessities industries, among…

Abstract

Purpose

Sodium alginate (Na-Alg) is a natural polysaccharide with a rich and renewable production that is widely used in the food, pharmaceutical and daily necessities industries, among other fields. The purpose of this study is to obtain a green and degradable shape memory material, calcium alginate (Ca-Alg) film was prepared and the mechanical properties, the shape memory effect of the film were investigated and confirmed.

Design/methodology/approach

The Ca-Alg films were prepared by Na-Alg, calcium chloride (CaCl2) solution, and flow extension method. Dissolve sodium alginate powder, remove bubbles, pour into petri dish, dry at 60°C, add calcium chloride solution cross-linking and finally dry naturally. The effect of CaCl2 solution concentration on the mechanical properties of the films were investigated and discussed by universal tensile tester. The shape memory behavior and degradation performance of thin films were verified and studied by the fold-deploy shape memory test and soil embedding method, respectively.

Findings

The Ca-Alg films exhibited good mechanical and shape memory properties, with a 72.2% shape memory fixity ratio and a 92.3% shape memory recovery ratio, respectively. For a period of 120 days, the film treated with a 6 wt% CaCl2 solution degraded at a rate of approximately 53%.

Research limitations/implications

Shape memory polymers (SMPs) as intelligent materials are an important research direction for the development of modern high-tech materials. On the other hand, plastic pollution is a major problem today; as a result, preparing green degradable SMPs is essential.

Originality/value

This study synthesized transparent and degradable shape memory Ca-Alg films using Na-Alg and CaCl2 solution and the flow extension method.

Details

Pigment & Resin Technology, vol. 53 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 November 2022

Laiming Yu, Yaqin Fu and Yubing Dong

The purpose of this study is to investigate the thermomechanical condition on the shape memory property of Polybutylene adipate-co-terephthalate (PBAT). PBAT is a widely…

Abstract

Purpose

The purpose of this study is to investigate the thermomechanical condition on the shape memory property of Polybutylene adipate-co-terephthalate (PBAT). PBAT is a widely researched and rapidly developed biodegradable copolyester. In a tensile test, we found that the fractured PBAT samples had a heat-driven shape memory effect which piqued our interest, and it will lay a foundation for the application of PBAT in new fields (such as heat shrinkable film).

Design/methodology/approach

The shape memory effect of PBAT and the effect of the thermomechanical condition on its shape memory property were confirmed and systematically investigated by a thermal mechanical analyzer and tensile machine.

Findings

The results showed that the PBAT film had broad shape memory transform temperature and exhibited excellent thermomechanical stability and shape memory properties. The shape memory fixity ratio (Rf) of the PBAT films was increased with the prestrain temperature and prestrain, where the highest Rf exceeded 90%. The shape memory recovery ratio (Rr) of the PBAT films was increased with the shape memory recovery temperature and decreased with the prestrain value, and the highest Rr was almost 100%. Moreover, the PBAT films had high shape memory recovery stress which increased with the prestrain value and decreased with the prestrain temperature, and the highest shape memory recovery stress can reach 7.73 MPa.

Research limitations/implications

The results showed that PBAT had a broad shape memory transform temperature, exhibited excellent thermomechanical stability and shape memory performance, especially for the sample programmed at high temperature and had a larger prestrian, which will provide a reference for the design, processing and application of PBAT-based heat shrinkable film and smart materials.

Originality/value

This study confirmed and systematically investigated the shape memory effect of PBAT and the effect of the thermomechanical condition on the shape memory property of PBAT.

Details

Pigment & Resin Technology, vol. 53 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 14 December 2023

Yajun Chen, Zehuan Sui and Juan Du

This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain…

Abstract

Purpose

This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain literature review supports and development direction suggestions for future research on intelligent self-healing coatings in aviation.

Design/methodology/approach

This mini-review uses a systematic literature review process to provide a comprehensive and up-to-date review of intelligent self-healing anti-corrosion coatings that have been researched and applied in the field of aviation in recent years. In total, 64 articles published in journals in this field in the last few years were analysed in this paper.

Findings

The authors conclude that the incorporation of multiple external stimulus-response mechanisms makes the coatings smarter in addition to their original self-healing corrosion protection function. In the future, further research is still needed in the research and development of new coating materials, the synergistic release of multiple self-healing mechanisms, coating preparation technology and corrosion monitoring technology.

Originality/value

To the best of the authors’ knowledge, this is one of the few systematic literature reviews on intelligent self-healing anti-corrosion coatings in aviation. The authors provide a comprehensive overview of the topical issues of such coatings and present their views and opinions by discussing the opportunities and challenges that self-healing coatings will face in future development.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 17 November 2023

Jinyu Zhang, Danni Shen, Yuxiang Yu, Defu Bao, Chao Li and Jiapei Qin

This study aims to develop a four-dimensional (4D) textile composite that self-forms upon thermal stimulation while eliminating thermomechanical programming steps by using fused…

Abstract

Purpose

This study aims to develop a four-dimensional (4D) textile composite that self-forms upon thermal stimulation while eliminating thermomechanical programming steps by using fused deposition modeling (FDM) 3D printing technology, and tries to refine the product development path for this composite.

Design/methodology/approach

Polylactic acid (PLA) printing filaments were deposited on prestretched Lycra-knitted fabric using desktop-level FDM 3D printing technology to construct a three-layer structure of thermally responsive 4D textiles. Subsequently, the effects of different PLA thicknesses and Lycra knit fabric relative elongation on the permanent shape of thermally responsive 4D textiles were studied. Finally, a simulation program was written, and a case in this study demonstrates the usage of thermally responsive 4D textiles and the simulation program to design a wrist support product.

Findings

The constructed three-layer structure of PLA and Lycra knitted fabric can self-form under thermal stimulation. The material can also achieve reversible transformation between a permanent shape and multiple temporary shapes. Thinner PLA deposition and higher relative elongation of the Lycra-knitted fabric result in the greater curvature of the permanent shape of the thermally responsive 4D textile. The simulation program accurately predicted the permanent form of multiple basic shapes.

Originality/value

The proposed method enables 4D textiles to directly self-form upon thermal, which helps to improve the manufacturing efficiency of 4D textiles. The thermal responsiveness of the composite also contributes to building an intelligent human–material–environment interaction system.

Details

Rapid Prototyping Journal, vol. 30 no. 2
Type: Research Article
ISSN: 1355-2546

Keywords

Article
Publication date: 21 December 2023

Manikandaraja G., Pandiyarajan R., Vasanthanathan A. and Sabarish S.

This study aims to evaluate the development of composites made of epoxy (E) resin with different weight percentages of polypropylene (PP) and graphene oxide (Go) to form…

Abstract

Purpose

This study aims to evaluate the development of composites made of epoxy (E) resin with different weight percentages of polypropylene (PP) and graphene oxide (Go) to form nanocomposite plates.

Design/methodology/approach

A hand lay-up process was used to develop 21 different composites, with varying concentrations of PP (5%–35%) and Go (5%–35%). A ternary composite of E matrix was produced by combining binary fillers PP and Go (5%–35%) in a 1:1 ratio to a (95%–5%) solution. With the help of adopting the melt condensation deal to extract Go, the modified Hummers method was used to make Go platelets.

Findings

Through field emission scanning electron microscopy (FESEM) and X-ray diffraction investigations, the particulate’s size and structural characteristics were identified. Based on the FESEM analysis of the collapsed zones of the composites, a warp-and-weft-like structure is evident, which endorses the growth yield strength, flexural modulus and impact strength of the composites.

Originality/value

The developed nanocomposites have exceptional mechanical capabilities compared to plain E resin, with E resin exhibiting better tensile strength, modulus and flexural strength when combined with 10% PP and 10% Go. When compared to neat E resin, materials formed from composites have exceptional mechanical properties. When mixed with 10% PP and 10% Go, E resin in particular displays improved tensile strength (23 MPa), tensile modulus (4.15 GPa), flexural strength (75.6 MPa) and other attributes. Engineering implications include automobile side door panels, spacecraft applications, brake pads and flexible battery guards.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 September 2023

Thameem Hayath Basha, Sivaraj Ramachandran and Bongsoo Jang

The need for precise synthesis of customized designs has resulted in the development of advanced coating processes for modern nanomaterials. Achieving accuracy in these processes…

Abstract

Purpose

The need for precise synthesis of customized designs has resulted in the development of advanced coating processes for modern nanomaterials. Achieving accuracy in these processes requires a deep understanding of thermophysical behavior, rheology and complex chemical reactions. The manufacturing flow processes for these coatings are intricate and involve heat and mass transfer phenomena. Magnetic nanoparticles are being used to create intelligent coatings that can be externally manipulated, making them highly desirable. In this study, a Keller box calculation is used to investigate the flow of a coating nanofluid containing a viscoelastic polymer over a circular cylinder.

Design/methodology/approach

The rheology of the coating polymer nanofluid is described using the viscoelastic model, while the effects of nanoscale are accounted for by using Buongiorno’s two-component model. The nonlinear PDEs are transformed into dimensionless PDEs via a nonsimilar transformation. The dimensionless PDEs are then solved using the Keller box method.

Findings

The transport phenomena are analyzed through a comprehensive parametric study that investigates the effects of various emerging parameters, including thermal radiation, Biot number, Eckert number, Brownian motion, magnetic field and thermophoresis. The results of the numerical analysis, such as the physical variables and flow field, are presented graphically. The momentum boundary layer thickness of the viscoelastic polymer nanofluid decreases as fluid parameter increases. An increase in mixed convection parameter leads to a rise in the Nusselt number. The enhancement of the Brinkman number and Biot number results in an increase in the total entropy generation of the viscoelastic polymer nanofluid.

Practical implications

Intelligent materials rely heavily on the critical characteristic of viscoelasticity, which displays both viscous and elastic effects. Viscoelastic models provide a comprehensive framework for capturing a range of polymeric characteristics, such as stress relaxation, retardation, stretching and molecular reorientation. Consequently, they are a valuable tool in smart coating technologies, as well as in various applications like supercapacitor electrodes, solar collector receivers and power generation. This study has practical applications in the field of coating engineering components that use smart magnetic nanofluids. The results of this research can be used to analyze the dimensions of velocity profiles, heat and mass transfer, which are important factors in coating engineering. The study is a valuable contribution to the literature because it takes into account Joule heating, nonlinear convection and viscous dissipation effects, which have a significant impact on the thermofluid transport characteristics of the coating.

Originality/value

The momentum boundary layer thickness of the viscoelastic polymer nanofluid decreases as the fluid parameter increases. An increase in the mixed convection parameter leads to a rise in the Nusselt number. The enhancement of the Brinkman number and Biot number results in an increase in the total entropy generation of the viscoelastic polymer nanofluid. Increasing the strength of the magnetic field promotes an increase in the density of the streamlines. An increase in the mixed convection parameter results in a decrease in the isotherms and isoconcentration.

Details

International Journal of Numerical Methods for Heat & Fluid Flow, vol. 34 no. 2
Type: Research Article
ISSN: 0961-5539

Keywords

Article
Publication date: 8 April 2024

Fukang Yang, Wenjun Wang, Yongjie Yan and YuBing Dong

Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to…

Abstract

Purpose

Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to improve the thermal insulation performance of polyethylene terephthalate (PET), the SiO2 aerogel/PET composites slices and fibers were prepared, and the effects of the SiO2 aerogel on the morphology, structure, crystallization property and thermal conductivity of the SiO2 aerogel/PET composites slices and their fibers were systematically investigated.

Design/methodology/approach

The mass ratio of purified terephthalic acid and ethylene glycol was selected as 1:1.5, which was premixed with Sb2O3 and the corresponding mass of SiO2 aerogel, and SiO2 aerogel/PET composites were prepared by direct esterification and in-situ polymerization. The SiO2 aerogel/PET composite fibers were prepared by melt-spinning method.

Findings

The results showed that the SiO2 aerogel was uniformly dispersed in the PET matrix. The thermal insulation coefficient of PET was significantly reduced by the addition of SiO2 aerogel, and the thermal conductivity of the 1.0 Wt.% SiO2 aerogel/PET composites was reduced by 75.74 mW/(m · K) compared to the pure PET. The thermal conductivity of the 0.8 Wt.% SiO2 aerogel/PET composite fiber was reduced by 46.06% compared to the pure PET fiber. The crystallinity and flame-retardant coefficient of the SiO2 aerogel/PET composite fibers showed an increasing trend with the addition of SiO2 aerogel.

Research limitations/implications

The SiO2 aerogel/PET composite slices and their fibers have good thermal insulation properties and exhibit good potential for application in the field of thermal insulation, such as warm clothes. In today’s society where the energy crisis is becoming increasingly serious, improving the thermal insulation performance of PET to reduce energy loss will be of great significance to alleviate the energy crisis.

Originality/value

In this study, SiO2 aerogel/PET composite slices and their fibers were prepared by an in situ polymerization process, which solved the problem of difficult dispersion of nanoparticles in the matrix and the thermal conductivity of PET significantly reduced.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 August 2023

Ashish Kaushik and Ramesh Kumar Garg

This study aims to cover the overall gamut of rapid prototyping processes and biomaterials used for the fabrication of occlusal splints in a comprehensive manner and elucidate the…

Abstract

Purpose

This study aims to cover the overall gamut of rapid prototyping processes and biomaterials used for the fabrication of occlusal splints in a comprehensive manner and elucidate the characteristics of the materials, which are essential in determining their clinical efficacy when exposed to oral surroundings.

Design/methodology/approach

A collective analysis of published articles covering the use of rapid prototyping technologies in the fabrication of occlusal splints, including manufacturing workflow description and essential properties (mechanical- and thermal-based) evaluation of biocompatible splinting materials, was performed.

Findings

Without advances in rapid prototyping processes and materials engineering, occlusal splints would tend to underperform clinically due to biomechanical limitations.

Social implications

Three-dimensional printing can improve the process capabilities for commercial customization of biomechanically efficient occlusal splints.

Originality/value

Rapid technological advancement in dentistry with the extensive utilization of rapid prototyping processes, intra-oral scanners and novel biomaterial seems to be the potential breakthrough in the fabrication of customized occlusal splints which have endorsed occlusal splint therapy (OST) as a cornerstone of orthodontic treatment.

Details

Rapid Prototyping Journal, vol. 29 no. 10
Type: Research Article
ISSN: 1355-2546

Keywords

Article
Publication date: 19 January 2024

Zhengwei Song, Zhi-Hui Xie, Lifeng Ding and Shengjian Zhang

This paper aims to comprehensively review the preparation methods of superhydrophobic surfaces (SHPS) for corrosion protection of Mg alloy in recent years.

Abstract

Purpose

This paper aims to comprehensively review the preparation methods of superhydrophobic surfaces (SHPS) for corrosion protection of Mg alloy in recent years.

Design/methodology/approach

The preparation methods, wettability and corrosion resistance of SHPS on Mg alloy in the past three years are systematically described in this paper.

Findings

Two types of SHPS, including single-layer and multilayer coatings for corrosion protection of Mg alloy are summarized. Preparing multilayered coatings with multifunction is the current trend in developing SHPS on Mg alloy.

Originality/value

This paper reviewed the preparation methods and corrosion resistance of SHPS on Mg alloys. It provides a valuable reference for researchers to develop highly durable SHPS with excellent corrosion resistance for Mg alloys.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 15 September 2022

Natiq Yaseen Taha Al-Menahlawi, Mohammad Reza Khoshravan Azar, Tajbakhsh Navid Chakherlou and Hussein Al-Bugharbee

The purpose of this study is a numerical simulation and an analytical analysis about the low-velocity impact on a functionally graded porous plate with porosity distribution in…

Abstract

Purpose

The purpose of this study is a numerical simulation and an analytical analysis about the low-velocity impact on a functionally graded porous plate with porosity distribution in the thickness direction. In this article, polymethyl methacrylate is used for matrix, and single-walled carbon nanotube (CNTs) (10,10) with consideration agglomeration sizes and lumping of CNT inside the agglomerations is applied for reinforcement.

Design/methodology/approach

In analytical formulation, the non-linear Hertz contact law is applied for interaction between projectile and plate surface. High-order shear deformation plate theory is developed, and energy of the system for impactor and plate is written. The governing equations are derived using Ritz method and Lagrange equations and are solved using the fourth-order Runge–Kutta method. Also, ABAQUS finite element model of functionally graded porous plate with all edges simply supported and reinforced by CNT under low-velocity impact is simulated and is compared with those is achieved in the present analytical approach.

Findings

In parametric studies, the influence of porosity distribution patterns include uniform, non-uniform symmetric and non-uniform asymmetric on the histories of contact force and impactor displacement of simply supported plate reinforced by CNT are presented. Eventually, the effects of porosity coefficient, impactor initial velocity, impactor radius and CNTs lumping inside agglomerations for non-uniform symmetric distribution patterns are discussed in impact event in detail.

Originality/value

In this paper, the effect of combination of polymethyl methacrylate and CNTs with consideration agglomeration sizes and lumping of CNTs inside the agglomerations in the form of a functionally graded porous plate is studied in the problem of low-velocity impact analysis.

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