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This paper aims to prepare a composite film on LY12 aluminum (Al) alloy by immersing in dodecyl phosphate and cerium nitrate solution by self-assembling methods. The effect of dipping sequence in dodecyl phosphate and cerium nitrate solution on the corrosion resistance of the composite film is studied.

The corrosion resistance of the dodecyl phosphate/cerium composite film is investigated by electrochemical measurement and film composition analysis.

The dipping sequence in dodecyl phosphate and cerium nitrate solutions has a significant impact on the corrosion resistance of the composite film. It shows best corrosion resistance by first dipping in dodecyl phosphate and then dipping in cerium nitrate solution.

The research shown in this work lays a scientific basis of the film preparation for industrial applications in the future.

This paper aims to evaluate the inhibitive effect and adsorption behavior of the 2-amino-5-thiol-1,3,4-thiadiazole vanillin (A) on copper in 3 per cent NaCl solution.

A thiazole Schiff bases were synthesized, named, 2-amino-5-thiol-1,3,4-thiadiazole vanillin (A), which was fabricated respectively on copper surface by the molecular self-assembled. Evaluation was carried out by electrochemical measurement and surface analysis techniques. Measurement of static friction coefficient scanning electron microscopy and Contact angle analysis were applied, and it is finally confirmed the existence of the adsorbed film. The inhibitive mechanism of A was evaluated by means of quantitative calculation and molecular dynamics simulation.

The electrochemical measurement indicated that the self-assembled molecular film can effectively inhibit the corrosion of copper sheet, when the concentration was 15 mmol⋅L⁻¹ and the assembly time was 6 h, the corrosion inhibition effect was the best, reaching as high as 97.5 per cent. Scanning electron microscopy results showed that the Schiff base compound forms a protective film on the surface of the copper, which effectively blocks the transfer of corrosion particles to the metal substrate, thereby inhibiting the occurrence of corrosion. Adsorption behavior of A followed the Langmuir’s adsorption isotherm and attributed to mixed-type adsorption. The results of Quantitative calculation and molecular dynamics simulation showed that A was adsorbed on Cu (111) surface in parallel.

In this study, the corrosion inhibition properties of Schiff base film were investigated by combining theory with experiment. Theoretical calculation is helpful to guide the synthesis of efficient and environmentally friendly corrosion inhibitors.

The damage caused by metal corrosion is great. The self-assembled Schiff base membrane synthesized in this paper is simple and compact, and the corrosion inhibition efficiency of copper in 3 per cent NaCl solution is 97.5 per cent.

Inhibition of metal corrosion can better save energy and reduce economic losses.

The synthesized Schiff base was prepared on the copper surface by the molecular self-assembled. The Schiff base membrane has a good corrosion inhibition effect on copper in 3 per cent NaCl solution, and the corrosion inhibition efficiency is up to 97.5 per cent.

The purpose of this paper is to construct a self-assembled double layer of organosilane on the surface of stainless steel and to investigate its corrosion inhibitive capability.

A monolayer of 3-glycidoxypropyltrimethoxysilane (GPTMS) was grafted onto an oxidized AISI 430SS (AISI 430 stainless steel) surface substrate from dry toluene solution. The hydrolysis of 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDS) molecules was used to anchor a second organic layer from mixed water-ethanol solution. The adsorption behavior and corrosion inhibition properties of the monolayer and also the bilayer were investigated by potentiodynamic polarization, scanning electron microscope (SEM), Fourier transformed infrared spectroscopy (FTIR) and contact angle measurements.

The GPTMS/PFDS bilayer was successfully deposited onto the oxidized AISI 430SS surface. The optimal assembling time for the filming of the first GPTMS monolayer is 6 hours. Suitable values of pH and temperature of the PFDS self-assembly solution were pivotal to the successful deposition of the second layer. Compared to the GPTMS monolayer, the GPTMS/PFDS bilayer exhibited a significant enhancement of the corrosion inhibition performance of AISI 430SS in NaCl solution.

The contact angle value measured on the bilayer-modified surface was somewhat lower than the reported value of a complete fluorinated surface. However, further optimization of the assembling condition is needed to obtain more orderly and denser films.

This paper provides useful information regarding the preparation of an organosilane bilayer on the surface of stainless steel and its corrosion inhibition properties in NaCl solution. It illustrates potential application prospects of GPTMS/PFDS bilayers for surface treatment of stainless steel.

This paper aims to prepare highly hydrophobic films on aluminum AA3003 using myristic acid (MA) and evaluate its corrosion protection efficiency in a low-chloride solution.

The aluminum surface was initially treated with boiling water to develop a porous nanostructure, and then surface modification was carried out in ethanolic solutions with different concentrations of MA. The surface morphology, wetting behavior and film composition were first characterized, and then, the corrosion behavior was evaluated with electrochemical techniques.

The best hydrophobicity and corrosion resistance were obtained with 50 mM of MA. For such concentration, a water contact angle of 140° and protective efficiency of 96% were achieved. A multilayer structure was revealed by scanning electron microscope and X-ray photoelectron spectroscopy.

The results of this work shed light on the anticorrosion performance of fatty acid self-assembled multilayers on the surface of Al–Mn alloys.

This paper's aim is to study the tribological properties of hyrid monolayer composited by γ‐mercapto‐propyl trimethoxysilane (MPTS) and γ‐methacryloxy propyltrimethoxysilane (MPTES), and estimated the action mechanism.

MPTS‐MPTES were self‐assembled on a hydroxylated silicon substrate to form a two‐dimensional hybrid monolayer. Atomic force microscope (AFM), X‐ray photoelectron spectrometry and contact angle measurement were used to characterize the MPTS‐MPTES hybrid self‐assembled monolayer (SAM). The macrofriction and wear behaviors of the film sliding against an AISI‐52100 steel ball were examined on a unidirectional friction and wear tester, and the worn surface morphologies were observed on an AFM.

The tribological results show that the friction coefficient of silicon substrate reduces from 0.86 to 0.18 after the formation of the MPTS‐MPTES hybrid SAM on its surface, and the thin film has a long wear life (2,620 sliding pass). It is demonstrated that the MPTS‐MPTES SAM exhibited good wear resistant property with a low friction coefficient, and the superior friction reduction and wear life were attributed to the low surface energy and the characteristics of the hybrid SAM.

The film's tribological performance under dynamic load is not estimated.

A hybrid monolayer with superior tribological property was synthesized on a silicon substrate by self‐assembly process, and maybe it is the potential solution for micro‐electromechanical‐system lubrication.

This paper provides a study way of hybrid SAM on a silicon substrate as lubricating coating.

The self-assembled monolayers (SAMs) of inositol hexakisphosphoric (IP6) formed in NaCl solution at room temperature on the surface of Type 430 stainless steel (SS430) were studied. The paper aims to discuss these issues.

The corrosion inhibition behavior of the SAMs was examined by electrochemical polarization curves, and surface characterizations were studied by X-ray photoelectron spectroscopy.

The results showed that the IP6 molecules were adsorbed successfully on the SS430 surface and demonstrated the capability of corrosion inhibition. A maximum IE value of 71.81 percent was achieved due to co-adsorption of water. The SS430 electrodes exposed to media containing 5×10−3 mol/L of IP6 exhibited the best anti-corrosive performance.

The present paper will report for the first time the adsorption and corrosion inhibition performances of IP6 SAMs on the SS430.

The purpose of this paper is to investigate the self‐assembled monolayers (SAMs) of phytic acid on cupronickel B30 surface of anticorrosion and inhibiting mechanisms.

Electrochemical and photocurrent response methods were performed to determine the effect of phytic acid SAMs on cupronickel B30.

The results indicated that phytic acid was liable to interact with B30 as a result of formation of complexes on B30 surface for anti‐rust and anti‐corrosion. The SAMs changed the structure of the electrochemical double layer and made the value of double layer capacitance decrease significantly. The B30 electrode showed p‐type photoresponse, which came from Cu₂O layer on its surface. The photoresponse decreased greatly due to the SAMs of phytic acid as the corrosion resisting property was enhanced. This finding was in good agreement with the results obtained from EIS and polarization curves. Adsorption of phytic acid was found to follow the Langmuir adsorption isotherm and the adsorption mechanism was typical of chemisorption.

The SAMs of phytic acid on cupronickel B30 was gained for the first time. The photo‐electrochemical method was an in situ method, which was effective for characterizing optical and electronic properties of passive films.

This study aims to improve the tribological performance of Babbitt alloy under oil lubricant condition. Thus, the surface was treated into oleophobic state by modifying with low surface energy fluorosilane (1H,1H,2H,2H-perfluorodecyltriethoxysilane). It is believed that the oleophobic surface offered excellent wear resistance of Babbitt-based tribo-pairs.

By modifying the Babbitt alloy with low surface energy fluorosilane and measuring the oil contact angle, the wetting behavior was evaluated. Using Pin on Disk tribometer, the tribological properties of bare Babbitt and modified Babbitt were quantified. The samples after the friction test were characterized by scanning electron microscope (SEM) and the anti-wear performance was evaluated under dry and oil lubrication conditions.

Results showed that oil contact angle of modified Babbitt was109° which was tripled compared to that of prime surface, which indicates the oleophobic behavior was greatly improved. Under dry conditions, the friction coefficient of the modified surface with different load conditions is slightly lower than that of the bare surface, while the friction coefficient of the modified surface under lubrication conditions is significantly decreased compared to that of the bare surface. Interestingly, under low load and high load, the wear rate of the modified Babbitt alloy surface is only 1/4 and 1/3 of that of the bare surface, respectively.

The work proposed an effective method to improve the Babbitt tribological performances and will lighten future ideas for the Babbitt alloy bearing with high wear resistance, which is beneficial to improve the service life of sliding bearings and has huge promotion and application value in the manufacture of sliding bearings.

The authors have prepared the triazole film on copper surface by click reaction and explored its inhibition mechanism.

The protective film is assembled by immersing bronze in solution containing p-toluenesulfonyl azide (TA) and propiolic acid (PA).

Fourier transform infrared spectroscopy (FT-IR) indicates that triazole (TTP) film was formed on bronze surface via click chemistry reaction between TA and PA. It shows TTP film has a good protection for bronze in the atmospheric environment simulation solution. Quantum chemical calculation (QC) and molecule dynamics simulation suggests TTP molecule adsorbs on bronze surface via N and O.

This is beneficial to develop the corrosion inhibitors for the corroded copper alloys.

The purpose of this paper is to study the effect of vapor assembly sequence and assembly temperature on the corrosion protection of the complex silane films Al alloy. The performance and application range of silane films are enhanced.

The complex silane films were successfully prepared on the surface of aluminum alloy using via vapor phase assembly of 1,2,3-benzotriazole (BTA) and dodecyltrimethoxysilanes (DTMS). The protection of the assembly films against corrosion of Al alloy is investigated by the electrochemical measurements and the alkaline solution accelerated corrosion test. Thickness and hydrophobicity of the complex films are studied using ellipsometric spectroscopy and contact angle tests.

It shows that the anti-corrosion ability of the complex films is overall superior to that of the single-component assembled films. DTMS-BTA films have larger thickness and best anti-corrosion ability. The alkyl chains in DTMS have better compatibility with BTA molecules. The rigid BTA molecule can permeate into the long alkyl chain of DTMS as fillers and improve the barrier properties of the complex films.

In this paper, a green and efficient method of vapor phase assembly is proposed to rust prevention during manufacture of Al alloy workpiece.