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Article
Publication date: 1 December 2023

Wan Xu, Xinsheng Liu, Huijuan Zhang, Ting Huo, Zhenbin Chen and Yuan Sun

This study aims to prepare an imprinted composite membrane with grafted temperature-sensitive blocks for the efficient adsorption and separation of rhenium(Re) from aqueous…

Abstract

Purpose

This study aims to prepare an imprinted composite membrane with grafted temperature-sensitive blocks for the efficient adsorption and separation of rhenium(Re) from aqueous solutions.

Design/methodology/approach

PVDF resin membrane was used as the substrate, dopamine and chitosan (CS) were used to modify the membrane surface and temperature-sensitive block PDEA was grafted on the membrane surface. Then acrylic acid (AA) and N-methylol acrylamide (N-MAM) were used as the functional monomers, ethyleneglycol dimethacrylate (EGDMA) as the cross-linker and ascorbic acid-hydrogen peroxide (Vc-H2O2) as the initiator to obtain the temperature-sensitive ReO4 imprinted composite membranes.

Findings

The effect of the preparation process on the performance of CS–Re–TIICM was investigated in detail, and the optimal preparation conditions were as follows: the molar ratios of AA–NH4ReO4, N-MAM and EGDMA were 0.13, 0.60 and 1.00, respectively. The optimal temperature and time of the reaction were 40 °C and 24 h. The maximum adsorption capacity of CS–Re–TIICM prepared under optimal conditions was 0.1071 mmol/g, and the separation was 3.90 when MnO4 was used as the interfering ion. The quasi first-order kinetics model and Langmuir model were more suitable to describe the adsorption process.

Practical implications

With the increasing demand for Re, the recovery of Re from Re-containing secondary resources becomes important. This study demonstrated a new material that could be separated and recovered Re in a complex environment, which could effectively alleviate the conflict between the supply and demand of Re.

Originality/value

This contribution provided a new material for the selective separation and purification of ReO4, and the adsorption capacity and separation of CS–Re–TIICM were increased with 1.673 times and 1.219 time compared with other Re adsorbents, respectively. In addition, when it was used for the purification of NH4ReO4 crude, the purity was increased from 91.950% to 99.999%.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 April 2023

Binh Bui, Zichao (Alex) Wang and Matthäus Tekathen

This study examines how carbon tools, including carbon accounting and management tools, can be created, used, modified and linked with other traditional management controls to…

Abstract

Purpose

This study examines how carbon tools, including carbon accounting and management tools, can be created, used, modified and linked with other traditional management controls to materialise and effectuate organisations’ response strategies to multiple interacting logics in carbon management and the role of sustainability managers in these processes.

Design/methodology/approach

This study utilises the construct of accounting toolmaking, which refers to practices of adopting, adjusting and reconfiguring accounting tools to unfold how carbon tools are used as means to materialise responses to multiple interacting carbon management logics. It embraces a field study approach, whereby 38 sustainability managers and staff from 30 organisations in New Zealand were interviewed.

Findings

This study finds that carbon toolmaking is an important means to materialise and effectuate organisations’ response strategies to multiple interacting carbon management logics. Four response strategies are identified: separation, selective coupling, combination and hybridisation. Adopting activity involves considering the additionality, detailing, localising and cascading of carbon measures and targets and their linkage to the broader carbon management programme. In adjusting carbon tools, organisations adapt the frequency and orientation of carbon reporting, intensity of carbon monitoring and breadth of carbon information sharing. Through focusing on either procedural sequencing, assimilating, equating or integrating, toolmaking reconfigures the relationship between carbon tools and traditional management control systems. Together, these three toolmaking activities can be configured differently to construct carbon tools that are fit for purpose for each response strategy. These activities also enact certain roles on sustainability managers in the process of representing, communicating and/or transferring carbon information knowledge, which also facilitate different response strategies.

Practical implications

The study demonstrates the various carbon toolmaking practices that allow organisations to handle the multiple interacting logics in carbon management. The findings provide suggestions for organisations on how to adopt, adjust and reconfigure carbon tools to better embed the ecological logic in organisations’ strategies and operations.

Originality/value

The authors identify how carbon toolmaking materialises and effectuates organisations’ responses to multiple interacting logics in carbon management.

Details

Accounting, Auditing & Accountability Journal, vol. 37 no. 1
Type: Research Article
ISSN: 0951-3574

Keywords

Article
Publication date: 10 December 2021

Jun Zhang, Xiaojian Ou, Lin Li, Qianqian Chen, Zifan Zhang, Ting Huo, Xiaoyu Lin, Fangfang Niu, Shengyuan Zhao, Fang We, Hui Li, Chunli Liu, Zhenbin Chen, Sujun Lu, Peng Zhang and Jinian Zhu

A novel grafted temperature-responsive ReO4 Imprinted composite membranes (Re-ICMs) was successfully prepared by using polyvinylidene fluoride (PVDF) resin membranes as…

Abstract

Purpose

A novel grafted temperature-responsive ReO4 Imprinted composite membranes (Re-ICMs) was successfully prepared by using polyvinylidene fluoride (PVDF) resin membranes as substrates, this study aimed to separate and purify ReO effectively.

Design/methodology/approach

Re-ICMs were synthesized by PVDF resin membranes as the substrate, acrylic acid (AA), acrylamide (AM), ethylene glycol dimethacrylate (EGDMA) were functional monomers. The morphology and structure of Re-ICMs were characterized by scanning electron microscope and Fourier transform infrared spectroscopy.

Findings

The maximum adsorption capacity toward ReO4 was 0.1,163 mmol/g and the separation decree had relation to MnO4 was 19.3. The optimal operation conditions were studied detailedly and the results as follows: the molar ratios of AA, AM, EGDMA, ascorbic acid, NH4ReO4, were 0.8, 0.96, 0.02, 0.003 and 0.006. The optimal time and temperature were 20 h and 40°C, respectively. The Langmuir and pseudo-second-order models were fit these adsorption characteristics well.

Practical implications

Rhenium (Re) is mainly used to chemical petroleum and make superalloys for jet engine parts. This study was representing a technology in separate and purify of Re, which provided a method for the development of the petroleum and aviation industry.

Originality/value

This contribution provided a novel method to separate ReO4 from MnO4. The maximum adsorption capacity was 0.1163 mmol/g at 35°C and the adsorption equilibrium time was within 2 h. Meanwhile, the adsorption selectivity rate ReO4/MnO4 was 19.3 and the desorption rate was 78.3%. Controlling the adsorption experiment at 35°C and desorption experiment at 25°C in aqueous solution, it could remain 61.3% of the initial adsorption capacity with the adsorption selectivity rate of 13.3 by 10 adsorption/desorption cycles, a slight decrease, varied from 78.3% to 65.3%, in desorption rate was observed.

Details

Pigment & Resin Technology, vol. 52 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 September 2021

Nur Shahira Abdul Nasir, Revathy Deivasigamani, Muhammad Khairulanwar Abdul Rahim, Siti Nur Ashakirin Mohd Nashruddin, Azrul Azlan Hamzah, M. Farhanulhakim M. Razip Wee and Muhamad Ramdzan Buyong

The purpose of this paper is to visualize protein manipulation using dielectrophoresis (DEP) as a substantial perspective on being an effective protein analysis and biosensor…

81

Abstract

Purpose

The purpose of this paper is to visualize protein manipulation using dielectrophoresis (DEP) as a substantial perspective on being an effective protein analysis and biosensor method as DEP is able to be used as a means for manipulation, fractionation, pre-concentration and separation. This research aims to quantify DEP using an electrochemical technique known as cyclic voltammetry (CV), as albumin is non-visible without any fluorescent probe or dye.

Design/methodology/approach

The principles of DEP were generated by an electric field on tapered DEP microelectrodes. The principle of CV was analysed using different concentrations of albumin on a screen-printed carbon electrode. Using preliminary data from both DEP and CV methods as a future prospect for the integration of both techniques to do electrical quantification of DEP forces.

Findings

The size of the albumin is known to be 0.027 µm. Engineered polystyrene particle of size 0.05 µm was selected to mimic the DEP actuation of albumin. Positive DEP of the sample engineered polystyrene particle was able to be visualized clearly at 10 MHz supplied with 20 Vpp. However, negative DEP was not able to be visualized because of the limitation of the apparatus. However, albumin was not able to be visualized under the fluorescent microscope because of its translucent properties. Thus, a method of electrical quantification known as the CV technique is used. The detection of bovine serum albumin (BSA) using the CV method is successful. As the concentration of BSA increases, the peak current obtained from the voltammogram decreases. The peak current can be an indicator of DEP response as it correlates to the adsorption of the protein onto the electrodes. The importance of the results from both CV and DEP shows that the integration of both techniques is possible.

Originality/value

The integration of both methods could give rise to a new technique with precision to be implemented into the dialyzers used in renal haemodialysis treatment for manipulation and sensing of protein albumin.

Article
Publication date: 1 February 2021

Jun Zhang, Meng Wang, Pu Liu, Xiaoyan Zhang, Ting Huo, Zhengcan Chen, Chunli Liu, Boyuan Zhang, Shengyuan Zhao and Zhenbin Chen

In this study, a novel glutathione (GSH) surface molecular imprinting polymer (SMIP) was successfully prepared by using macroporous adsorption resins (MAR) as substrate, which…

Abstract

Purpose

In this study, a novel glutathione (GSH) surface molecular imprinting polymer (SMIP) was successfully prepared by using macroporous adsorption resins (MAR) as substrate, which could separate and purify GSH efficiently.

Design/methodology/approach

SMIP was synthesized by chloromethylated modified MAR (LX1180-Cl) as the substrate, N, N’-methylenebisacrylamide (NMBA) as a crosslinker, GSH as a template, acrylamide (AM) and N-vinylpyrrolidone (NVP) as functional monomers. The morphology and structure of the polymer were characterized by scanning electron microscope and Fourier transforms infrared spectroscopy.

Findings

The maximum adsorption capacity toward GSH was 39.0 mg/g and the separation decree had relation to L-cysteine (L-cys) was 4.2. The optimal operation conditions were studied in detail and the got as follows: the molar ratios of NMBA, AM, GSH and NVP, were 7.0, 0.8 and 0.5. The optimal time and temperature were 14 h and 40°C, respectively. The Langmuir and pseudo-first-order model were fitting these adsorption characteristics well.

Practical implications

GSH has a diversity of medicinal and bioactive functions, so the purpose of this study representing a method in separate and purify technology of GSH, which provided a way for the development of medicine.

Originality/value

This contribution provided a novel way to separate GSH from L-cys. Under the optimal conditions, the maximum adsorption capacity toward GSH was 39.0 mg/g and the separation decree had relation to L-cys was 4.2.

Details

Pigment & Resin Technology, vol. 50 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 March 2020

Yongfeng Liu, Yi Liu and Duolong Di

The purpose of this study is to focus on the preparation of macroporous adsorption resins (MARs) functionalized with carbazole and N-methylimidazole, and adsorption behaviors of…

Abstract

Purpose

The purpose of this study is to focus on the preparation of macroporous adsorption resins (MARs) functionalized with carbazole and N-methylimidazole, and adsorption behaviors of (–)-epigallocatechin gallate (EGCG) and caffeine (CAF) on the functionalized MARs.

Design/methodology/approach

Based on the Friedel–Crafts and amination reactions, novel MARs functionalized with carbazole and N-methylimidazole were synthesized and characterized by the BET method. Accordingly, adsorption behaviors and structure-activity relationships for EGCG and CAF were studied in detail.

Findings

The results showed that pseudosecond-order kinetic model was provided with a better correlation for the adsorption of EGCG and CAF onto L-1 and L-2, and pseudofirst-order kinetic model was the most suitable model to illustrate the adsorption process for EGCG and CAF on L-3. The result indicated that Langmuir, Freundlich, Temkin–Pyzhev and Dubinin–Radushkevich isotherms all could better illustrate the adsorption processes of EGCG and CAF on L-1, L-2 and L-3.

Practical implications

This study provides theoretical guidance and technical support for the efficient separation and purification of EGCG and CAF from waste tea leaves by MARs on a large scale. In addition, the results showed that this novel MARs would provide useful help and be used in large-scale production of active ingredients from natural products in the industry and other fields.

Originality/value

Adsorption kinetic models such as pseudofirst-order, pseudosecond-order and intra-particle diffusion kinetic models, and adsorption isotherm models such as Langmuir, Freundlich, Temkin–Pyzhev and Dubinin–Radushkevich isotherms models were adopted to illustrate the adsorption mechanisms of EGCG and CAF. The main driving forces for MARs with no functional groups were pore sieving effects, pp conjugation effects and hydrophobic interactions, and the other significant driving forces for MARs functionalized with carbazole and N-methylimidazole were electrostatic interactions, ion-dipole and hydrogen bonding interactions. This study might provide scientific references and useful help for large-scale separating and enriching active ingredients in natural products using the technology of MARs with special functional groups.

Details

Pigment & Resin Technology, vol. 49 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Content available
Article
Publication date: 13 February 2007

65

Abstract

Details

Nutrition & Food Science, vol. 37 no. 1
Type: Research Article
ISSN: 0034-6659

Content available
Article
Publication date: 3 April 2007

45

Abstract

Details

Nutrition & Food Science, vol. 37 no. 2
Type: Research Article
ISSN: 0034-6659

Article
Publication date: 9 November 2012

George K. Stylios

Examines the seventeenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects…

1099

Abstract

Examines the seventeenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.

Details

International Journal of Clothing Science and Technology, vol. 24 no. 6
Type: Research Article
ISSN: 0955-6222

Keywords

Content available
Article
Publication date: 18 September 2007

120

Abstract

Details

Nutrition & Food Science, vol. 37 no. 5
Type: Research Article
ISSN: 0034-6659

1 – 10 of over 3000