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The purpose of this paper is to develop and parameterize a time‐invariant (equilibrium) material mechanical model for segmented polyureas, a class of thermoplastically linked co‐polymeric elastomers, using experimental data available in open literature.

The key components of the model are developed by first constructing a simple molecular‐level microstructure model and by relating the microstructural elements and intrinsic material processes to the material mechanical response. The new feature of the present material model relative to the ones currently used is that the physical origin and the evolution equation for the deformation‐induced softening and inelasticity observed in polyureas are directly linked to the associated evolution of the soft‐matrix/hard segment molecular‐level microstructure of this material. The model is first developed for the case of uniaxial loading, parameterized using one set of experimental results and finally validated using another set of experimental results.

The validation procedure suggested that the model can reasonably well account for the equilibrium mechanical response of polyureas under the simple uniaxial loading conditions.

The present approach enables a more accurate determination of the mechanical behavior of polyurea and related elastomeric materials.

Polyurea is an elastomeric two-phase co-polymer consisting of nanometer-sized discrete hard (i.e. high glass transition temperature) domains distributed randomly within a soft (i.e. low glass transition temperature) matrix. A number of experimental investigations reported in the open literature clearly demonstrated that the use of polyurea external coatings and/or internal linings can significantly increase blast survivability and ballistic penetration resistance of target structures, such as vehicles, buildings and field/laboratory test-plates. When designing blast/ballistic-threat survivable polyurea-coated structures, advanced computational methods and tools are being increasingly utilized. A critical aspect of this computational approach is the availability of physically based, high-fidelity polyurea material models. The paper aims to discuss these issues.

In the present work, an attempt is made to develop a material model for polyurea which will include the effects of soft-matrix chain-segment molecular weight and the extent and morphology of hard-domain nano-segregation. Since these aspects of polyurea microstructure can be controlled through the selection of polyurea chemistry and synthesis conditions, and the present material model enables the prediction of polyurea blast-mitigation capacity and ballistic resistance, the model offers the potential for the “material-by-design” approach.

The model is validated by comparing its predictions with the corresponding experimental data.

The work clearly demonstrated that, in order to maximize shock-mitigation effects offered by polyurea, chemistry and processing/synthesis route of this material should be optimized.

The purpose of this paper is to calculate the Hugoniot relations of polyurea; also to investigate the atomic-scale energy change, the related chain conformation evolution and the hydrogen bond dissociation of polyurea under high-speed shock.

The atomic-scale simulations are achieved by molecular dynamics (MD). Both non-equilibrium MD and multi-scale shock technique are used to simulate the high-speed shock. The energy dissipation is theoretically derived by the thermodynamic and the Hugoniot relations. The distributions of bond length, angle and dihedral angle are used to characterize the chain conformation evolution. The hydrogen bonds are determined by a geometrical criterion.

The Hugoniot relations calculated are in good agreement with the experimental data. It is found that under the same impact pressure, polyurea with lower hard segment content has higher energy dissipation during the shock-release process. The primary energy dissipation way is the heat dissipation caused by the increase of kinetic energy. Unlike tensile simulation, the molecular potential increment is mainly divided into the increments of the bond energy, angle energy and dihedral angle energy under shock loading and is mostly stored in the soft segments. The hydrogen bond potential increment only accounts for about 1% of the internal energy increment under high-speed shock.

The simulation results are meaningful for understanding and evaluating the energy dissipation mechanism of polyurea under shock loading, and could provide a reference for material design.

Polyurea falls into a category of elastomeric co‐polymers in which, due to the presence of strong hydrogen bonding, the microstructure is of a heterogeneous nature and consists of a compliant/soft matrix and stiff/hard nanometer size hard domains. Recent investigations have shown that the use of polyurea as an external or internal coating/lining had substantially improved ballistic‐penetration resistance of metallic structures. The present work aims to use computational methods and tools in order to assess the shock‐mitigation ability of polyurea when used in the construction of different components (suspension‐pads, internal lining and external coating) of a combat helmet.

Shock‐mitigation capability of combat helmets has become an important functional requirement as shock‐ingress into the intra‐cranial cavity is known to be one of the main causes of traumatic brain injury (TBI). To assess the shock mitigation capability of polyurea, a combined Eulerian/Lagrangian fluid/solid transient non‐linear dynamics computational analysis of an air/helmet/head core sample is carried out and the temporal evolution of the axial stress and particle velocities (for different polyurea augmented helmet designs) are monitored.

The results obtained show that improvements in the shock‐mitigation performance of the helmet are obtained only in the case when polyurea is used as a helmet internal lining and that these improvements are relatively small. In addition, polyurea is found to slightly outperform conventional helmet foam, but only under relatively strong (greater than five atm) blastwave peak overpressures.

The present approach studies the effect of internal linings and external coatings on combat helmet blast mitigation performance.

The purpose of this paper is to address the problems of interaction of tensile stress-waves with polyurea/fused-silica and fused-silica/polyurea interfaces, and the potential for the accompanying interfacial decohesion.

The problems are investigated using all-atom non-equilibrium molecular-dynamics methods and tools. Before these methods/tools are employed, previously determined material constitutive relations for polyurea and fused-silica are used, within an acoustic-impedance-matching procedure, to predict the outcome of the interactions of stress-waves with the material-interfaces in question. These predictions pertain solely to the stress-wave/interface interaction aspects resulting in the formation of transmitted and reflected stress- or release-waves, but do not contain any information regarding potential interfacial decohesion. Direct molecular-level simulations confirmed some of these predictions, but also provided direct evidence of the nature and the extent of interfacial decohesion. To properly model the initial state of interfacial cohesion and its degradation during stress-wave-loading, reactive forcefield potentials are utilized.

Direct molecular-level simulations of the polyurea/fused-silica interfacial regions prior to loading revealed local changes in the bonding structure, suggesting the formation of an interphase. This interphase was subsequently found to greatly affect the polyurea/fused-silica decohesion strength.

To the authors’ knowledge, the present work is the first public-domain report of the use of the non-equilibrium molecular dynamics and reactive force-field potentials to study the problem of interfacial decohesion caused by the interaction of tensile waves with material interfaces.

The purpose of this paper is to study the mechanical response of polyurea, soda-lime glass (glass, for short), polyurea/glass/polyurea and glass/polyurea/glass sandwich structures under dynamic-loading conditions involving propagation of planar longitudinal shockwaves.

The problem of shockwave generation, propagation and interaction with material boundaries is investigated using non-equilibrium molecular dynamics. The results obtained are used to construct basic shock Hugoniot relationships associated with the propagation of shockwaves through a homogeneous material (polyurea or glass, in the present case). The fidelity of these relations is established by comparing them with their experimental counterparts, and the observed differences are rationalized in terms of the microstructural changes experienced by the shockwave-swept material. The relationships are subsequently used to predict the outcome of the interactions of shockwaves with polyurea/glass or glass/polyurea material boundaries. Molecular-level simulations are next used to directly analyze the same shockwave/material-boundary interactions.

The molecular-level simulations suggested, and the subsequent detailed microstructural analyses confirmed, the formation of topologically altered interfacial regions, i.e. polyurea/glass and glass/polyurea interphases.

To the authors’ knowledge, the present work is a first attempt to analyze, using molecular-level simulation methods, the interaction of shockwaves with material boundaries.

The purpose of this paper is to optimize the design of the advanced combat helmet (ACH) currently in use, by its designers in order to attain maximum protection against ballistic impacts (fragments, shrapnel, etc.) and hard-surface/head collisions. Since traumatic brain injury experienced by a significant fraction of the soldiers returning from the recent conflicts is associated with their exposure to blast, the ACH should be redesigned in order to provide the necessary level of protection against blast loads. In the present work, augmentations of the ACH for improved blast protections are considered. These augmentations include the use of a polyurea (a nano-segregated elastomeric copolymer)-based ACH external coating/internal lining.

To demonstrate the efficacy of this approach, instrumented (unprotected, standard-ACH-protected, and augmented-ACH-protected) head-mannequin blast experiments are carried out. These experimental efforts are complemented with the appropriate combined Eulerian/Lagrangian transient non-linear dynamics computational fluid/solid interaction analysis.

The results obtained indicated that: when the extent of peak over-pressure reduction is used as a measure of the blast-mitigation effectiveness, polyurea-based augmentations do not noticeably improve, and sometimes slightly worsen, the performance of the standard ACH; when the extent of specific impulse reduction is used as a measure of the blast-mitigation effectiveness, application of the polyurea external coating to the standard ACH improves the blast-mitigation effectiveness of the helmet, particularly at shorter values of the charge-detonation standoff distance (SOD). At longer SODs, the effects of the polyurea-based ACH augmentations on the blast-mitigation efficacy of the standard ACH are inconclusive; and the use of the standard ACH significantly lowers the accelerations experienced by the skull and the intracranial matter. As far as the polyurea-based augmentations are concerned, only the internal lining at shorter SODs appears to yield additional reductions in the head accelerations.

To the authors’ knowledge, the present work contains the first report of a combined experimental/computational study addressing the problem of blast-mitigation by polyurea-based augmentation of ACH.

As a high-performance engineering plastic, polyimide (PI) is widely used in the aerospace, electronics and automotive industries. This paper aims to review the latest progress in the tribological properties of PI-based composites, especially the effects of nanofiller selection, composite structure design and material modification on the tribological and mechanical properties of PI-matrix composites.

The preparation technology of PI and its composites is introduced and the effects of carbon nanotubes (CNTs), carbon fibers (CFs), graphene and its derivatives on the mechanical and tribological properties of PI-based composites are discussed. The effects of different nanofillers on tensile strength, tensile modulus, coefficient of friction and wear rate of PI-based composites are compared.

CNTs can serve as the strengthening and lubricating phase of PI, whereas CFs can significantly enhance the mechanical properties of the matrix. Two-dimensional graphene and its derivatives have a high modulus of elasticity and self-lubricating properties, making them ideal nanofillers to improve the lubrication performance of PI. In addition, copolymerization can improve the fracture toughness and impact resistance of PI, thereby enhancing its mechanical properties.

The mechanical and tribological properties of PI matrix composites vary depending on the nanofiller. Compared with nanofibers and nanoparticles, layered reinforcements can better improve the friction properties of PI composites. The synergistic effect of different composite fillers will become an important research system in the field of tribology in the future.

Propagation of planar (i.e. one directional), longitudinal (i.e. uniaxial strain), steady (i.e. time‐invariant) structured shock waves within metal matrix composites (MMCs) is studied computationally. Waves of this type are typically generated during blast‐wave loading or ballistic impact and play a major role in the way blast/ballistic impact loads are introduced in, and applied to, a target structure. Hence, the knowledge of the basic physics of propagation of these waves is critical for designing structures with superior blast and impact protection capabilities. The purpose of this paper is to help advance the use of computational engineering analyses and simulations in the areas of design and application of the MMC protective structures.

To derive the overall response of the composite material to shock type loading, a dynamic‐mixture model is employed. Within this model, the known constitutive responses of the constituent materials are combined using the appropriate mixture rules. These mixture rules are of a dynamic character since they depend on the current state of the composite material and cannot be applied prior to the beginning of the analysis.

The approach is applied to a prototypical MMC consisting of an aluminum matrix and SiC particulates. Both the intermediate‐to‐strong shock regime (in which the contribution of stress deviators to the stress field can be ignored) and the weak shock regime (in which stress deviators provide a significant contribution to the stress field) are investigated. Finally, the computational results are compared with their experimental counterparts available in the open literature in order to validate the computational procedure employed.

Prediction of the spallation‐type failure in a metal‐matrix composite material (modeled using the dynamic‐mixture model) has not been done previously.

The behavior of joints has a significant effect on the stability of water conveyance tunnel. The purpose of this paper is to study the contact and friction at the joint of the tunneling segment lining and establish its contact friction model. At the same time, the stress and deformation characteristics at the joint of the segment under hydrostatic load are analyzed.

In this study, the contact and friction in a bolted joint are examined using shear testing. The feasibility of the proposed model is verified by a numerical simulation of tests and a theoretical analysis. Accordingly, the effect of joints on the lining is explored under internal hydrostatic loading.

The results show that the openings of tunnel segments in joints gradually expand from the positions of the inner and outer edges to the location of the bolt. Moreover, the stress concentration zone is formed at the bolt. Under hydraulic loading, the opening displacement at the joint increases as the water pressure increases; nevertheless, it does not exceed engineering requirements. When the water pressure of the tunnel lining joint reaches 0.5 MPa, the opening of the joint slowly increases. When the water pressure exceeds 0.7 MPa, the opening of the joint rapidly and significantly increases.

Contact and friction in a bolted joint were examined using shear testing. A cohesive zone model of bolted joints was proposed based on test results. The influence of joint behavior on the stability of water conveyance tunnel was studied.