Search results

The purpose of this paper is to analyze the performance of the gas turbine cycle integrated with solid oxide fuel cell technology. In the present work, intermediate temperature solid oxide fuel cell has been considered, as it is economical, can attain an activation temperature in a quick time, and also have a longer life compared to a high-temperature solid oxide fuel cell, which helps in the commercialization and can generate two ways of electricity as a hybrid configuration.

The conceptualized cycle has been analyzed with the help of computer code developed in MATLAB with the help of governing equations. In this work, the focus is on the performance investigation of a Gas turbine intermediate temperature solid oxide fuel cell hybrid cycle. The work also analyzes the performance behavior of the proposed cycle with various design and operating parameters.

It is found that the power generation efficiency of the IT-SOFC-GT hybrid system reaches up to 60% (LHV) for specific design and operating conditions. The cycle calculations of an IT-SOFC-GT hybrid system and its conceptual design have been presented in this work.

The unique feature of this work is that IT-SOFC has been adopted for integration instead of HT-SOFC, and this work also provides the performance behavior of the hybrid system with varying design and operating parameters, which is the novelty of this work. This work has significant scientific merit, as the cost involved for the commercialization of IT-SOFC is comparatively lower than HT-SOFC and provides a good option to energy manufacturers for generating clean energy at a low cost.

A reliability analysis of a solid oxide fuel cell (SOFC) system is presented for applications with strict constant power supply requirements, such as data centers. The purpose is to demonstrate the effect when moving from a module-level to a system-level in terms of reliability, also considering effects during start-up and degradation.

In-house experimental data on a system-level are used to capture the behavior during start-up and normal operation, including drifts of the operation point due to degradation. The system is assumed to allow replacement of stacks during operation, but a minimum number of stacks in operation is needed to avoid complete shutdown. Experimental data are used in conjunction with a physics-based performance model to construct the failure probability function. A dynamic program then solves the optimization problem in terms of time and replacement requirements to minimize the total negative deviation from a given target reliability.

Results show that multi-stack SOFC systems face challenges which are only revealed on a system- and not on a module-level. The main finding is that the reliability of multi-stack SOFC systems is not sufficient to serve as sole power source for critical applications such as data center.

The principal methodology may be applicable to other modular systems which include multiple critical components (of the same kind). These systems comprise other electrochemical systems such as further fuel cell types.

The novelty of this work is the combination of mathematical modeling to solve a real-world problem, rather than assuming idealized input which lead to more benign system conditions. Furthermore, the necessity to use a mathematical model, which captures sufficient physics of the SOFC system as well as stochasticity elements of its environment, is of critical importance. Some simplifications are, however, necessary because the use of a detailed model directly in the dynamic program would have led to a combinatorial explosion of the numerical solution space.

This study aims to offer a hybrid stand-alone system for electric vehicle (EV) charging stations (CS), an emerging power scheme due to the availability of renewable and environment-friendly energy sources. This paper presents the analysis of a photovoltaic (PV) with an adaptive neuro-fuzzy inference system (ANFIS) algorithm, solid oxide fuel cell (SOFC) and a battery storage scheme incorporated for EV CS in a stand-alone mode. In previous studies, either the hydrogen fuel of SOFC or the irradiance is controlled using artificial neural network. These parameters are not controlled simultaneously using an ANFIS-based approach. The ANFIS-based stand-alone hybrid system controlling both the fuel flow of SOFC and the irradiance of PV is discussed in this paper.

The ANFIS algorithm provides an efficient estimation of maximum power (MP) to the nonlinear voltage–current characteristics of a PV, integrated with a direct current–direct current (DC–DC) converter to boost output voltage up to 400 V. The issue of fuel starvation in SOFC due to load transients is also mitigated using an ANFIS-based fuel flow regulator, which robustly provides fuel, i.e. hydrogen per necessity. Furthermore, to ensure uninterrupted power to the CS, PV is integrated with a SOFC array, and a battery storage bank is used as a backup in the current scenario. A power management system efficiently shares power among the aforesaid sources.

A comprehensive simulation test bed for a stand-alone power system (PV cells and SOFC) is developed in MATLAB/Simulink. The adaptability and robustness of the proposed control paradigm are investigated through simulation results in a stand-alone hybrid power system test bed.

The simulation results confirm the effectiveness of the ANFIS algorithm in a stand-alone hybrid power system scheme.

The purpose of this work is to present the strategies and current state of development in the field of micro solid oxide fuel cells (μSOFC).

In the paper recent strategies of conventional and single chamber μSOFC are described. Some examples based on the author's research are presented.

It can be concluded that scale down of ceramic technologies is still more popular than MEMS. However, MEMS‐based technologies become recently to be used more frequently.

The work is limited to the description of materials and technologies used in μSOFC.

The review presents very recent research in μSOFC. The results demonstrate critical areas in development of suitable technologies.

The paper aims to present the innovative design of a planar multilayered high temperature solid oxide fuel cell (SOFC), which is easy to manufacture, and features high resistance to rapid temperature changes. Temperature resistance was accomplished thanks to easy to heat, thin flat ceramic structure of the cell and elimination of metallic interconnections.

The ceramic fuel cell consists of the anode core made of six to eight layers of nickel/yttria-stabilized zirconia tapes (Ni/YSZ) isostatically pressed into a laminate. Two networks of fuel distribution microchannels are engraved on both sides of the anode laminate. The microchannels are subsequently covered with a thin layer of the functional anode tape made of Ni/YSZ and a solid electrolyte tape made of YSZ.

The single planar double-sided ceramic SOFC of dimensions 19 × 60 × 1.2 mm3 provides 3.2 Watts of electric power. The prototype of the battery which consists of four SOFCs provides an output power of > 12 W. Tests show that the stack is resistant to the rapid temperature change. If inserted into a chamber preheated to 800°C, the stack provides the full power within 5 minutes. Multiple cycling does not destroy the stack.

This anode-supported fuel cell structure is provided with thin anode functional layers suspended on a large number of fine beams. The whole anode structure is made with the same ceramic material, so the mechanical stress is minimized during the cell operation.

The purpose of the conducted investigations is assessment of performance improvement of hybrid gas-turbine engine (HGTE) based on solid oxide fuel cell (SOFC) using cheaper and environmental alternative fuels (AF) such as liquid methane and propane – butane mixture (propane – butane). This paper also assessed the efficiency of mid-flight propulsion system (PS) based on HGTE for advanced short – medium hall aircrafts (SMHA) of 2025 (with level of parameters corresponding to technologies of 2025-2030 time period).

According to purposes of this paper, following are conducted: Analysis of properties of conventional and advanced aviation fuels, updating of architectures and parameters of energy system of HGTE based on SOFC using different fuels (kerosene, methane and propane – butane). Examination of rational architectures and updating of possible design parameters of HGTE using different types of fuel. Assessment of efficiency of PS with HGTE using different fuels under aircraft criteria. Assessment of emission of harmful substances and acoustical efficiency of SMHA with HGTE using different fuels.

Improvement of technical and environmental performances of SMHA with HGTE based on SOFC using AF in comparison with turbofan is shown.

Accuracy of research results is defined by a number of the adopted aircraft and engine restrictions, as well as accuracy of prediction concerning to the improvement of integral characteristics of elements SMHA and PS with HGTE for 2025.

Advantages of HGTE based on SOFC create good preconditions for initiation of works on development of new-generation aircrafts using AF after 2025.

Development of SOFC technologies result in evolution of new high-economic and environmental friendly hybrid gas-turbine PS for aircrafts using AF, Improvement of an environmental situation around the airport, decrease of CO₂ emission for full-flight cycle, creation of scientific and technological base for transition to electric PS of full electric aircraft.

Research results show that application of AF increases efficiency of electrochemical generator (ECG) based on SOFC and fuel efficiency of whole engine, which enable to use HGTE for PS of advanced aircrafts more effectively than turbofan. As distinct from storage battery (Bradley et al., 2010) and ECG based on Polymer Electrolyte Membrane Fuel Cell (Horyson Energy Systems, 2010), specific characteristics of ECG based on SOFC using methane allow to design PS for SMHA of 2025.

The purpose of this paper is to introduce a robust mathematical model and finite element‐based numerical approach to solve solid oxide fuel cell (SOFC) problems.

A robust mathematical model is constructed by studying pros and cons of different SOFC and other fuel cell models. The finite element‐based numerical approach presented is a unified approach to solve multi‐disciplinary aspects arising from SOFC problems. The characteristic‐based split approach employed here is an efficient way of solving various flow, heat and mass transfer regimes in SOFCs.

The results presented show that both the model and numerical algorithm proposed are robust. Furthermore, the approaches proposed are general and can be easily extended to other similar problems of practical interest.

The model proposed is the first of this kind and the unified approach for solving flow, heat and mass transfer within a fuel cell is also novel.

The purpose of this study is to develop a simulation method to calculate non-stationary distributions of the chemical potential of oxygen in a solid oxide fuel cell (SOFC) under operation.

The initial-boundary value problem was appropriately formulated and the appropriate boundary conditions were implemented so that the problem of non-stationary behavior of SOFC can be solved in accordance with actual operational and typical experimental conditions. The dependencies of the material properties on the temperature and partial pressure of oxygen were also elaborately introduced to realize actual material responses. The capability of the proposed simulation method was demonstrated under arbitrary operating conditions.

The steady state calculated with the open circuit voltage condition was conformable with the analytical solution. In addition, the transient states of the spatial distributions of potentials and currents under the voltage- and current-controlled conditions were successfully differentiated, even though they eventually became the same steady state. Furthermore, the effects of dense materials assumed for interconnects and current collectors were found to not be influential. It is thus safe to conclude that the proposed method enables us to simulate any type of transient simulations regardless of controlling conditions.

Although only uniaxial models were tested in the numerical examples in this paper, the proposed method is applicable for arbitrary shapes of SOFC cells.

The value of this paper is that adequate numerical simulations by the proposed method properly captured the electrochemical transient transport phenomena in SOFC under various operational conditions, and that the applicability was confirmed by some numerical examples.

The purpose of this paper is to present the embossing as a replication technique for structuring fuel channels in the anode-supported solid oxide fuel cells (SOFCs).

The anode laminate, which was exposed to embossing, consisted of eight layers of isostatic pressed Ni-yttria-stabilized zirconia tapes (Ni-YSZ). Preheating the mould and soaking the laminate in the plasticizer was applied before structuring of the channels to soften the laminate. Compressing tests were carried out to investigate the embossing ability of the Ni-YSZ laminate and to find the optimal processing parameters. Embossing was carried out with a testing machine, and the samples were exposed to embossing forces in the range up 20 kN with a certain speed of compression and a dwell time.

The embossing parameters (force of compression, speed of compression and dwell time) suitable for proper fuel channels formation were established. Shapes, profiles and dimensions of the embossed channels were analysed and compared to the micromachined channels. The model of the SOFC with embossed fuel channels was completed, and its current-voltage characteristic was measured.

Experiments proved that embossing can be the alternative method for patterning fuel microchannels in SOFCs. Embossing simplifies the process of fuel channel formation and reduces the time of SOFC fabrication. It is necessary to improve the geometry and quality of the mould formation to make the fuel channels deeper and of better surface finish.

The aim of this paper is to find the electrical representation of a solid oxide fuel cell (SOFC) that enables the application of typical exploitation characteristics of fuel cells for estimation of fuel cell parameters (for example, exchange current) and easy analysis of phenomena occurred during the fuel cell operation.

Three-layer structure of an SOFC, where a thin semi-conducting layer of electrolyte separates the anode from the cathode, shows a strong similarity to typical semiconductor devices built on the basis of P-N junctions, like diodes or transistors. Current–voltage (I-V) characteristics of a fuel cell can be described by the same mathematical functions as I-V plots of semiconductor devices. On the basis of this similarity and analysis of impedance spectra of a real fuel cell, two electrical representations of the SOFC have been created.

The simplified electrical representation of SOFC consists of a voltage source connected in series with a diode, which symbolizes a voltage drop on a cell cathode, and two resistors. This model is based on the similarity of Butler-Volmer to Shockley equation. The advanced representation comprises a voltage source connected in series with a bipolar transistor in close to saturation mode and two resistors. The base-emitter junction of the transistor represents voltage drop on the cell cathode, and the base-collector junction represents voltage drop on the cell anode. This model is based on the similarity of Butler-Volmer equation to Ebers-Moll equation.

The proposed approach based on the Shockley and Ebers-Moll formulas enables the more accurate estimation of the ion exchange current and other fuel cell parameters than the approach based on the Butler-Volmer and Tafel formulas. The usability of semiconductor models for analysis of SOFC operation was proved. The models were successively applied in a new design of a planar ceramic fuel cell, which features by reduced thermal capacity, short start-up time and limited number of metal components and which has become the basis for the SOFC stack design.