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This paper aims to report an experimental investigation of the galvanic corrosion that occurs between the base metal and the welds in X52 carbon steel petroleum pipelines…
This paper aims to report an experimental investigation of the galvanic corrosion that occurs between the base metal and the welds in X52 carbon steel petroleum pipelines when exposed in carbon dioxide (CO2)-containing saltwater at pH 4 at room temperature. The pipeline was fabricated by electric resistance welding (ERW).
The experimental setup was a closed glass cell equipped with a silver/silver chloride (Ag/AgCl) reference electrode, two working electrodes (the weld metal and the parent steel specimens) and a gas bubbler. The corrosion potential and polarization resistance of the base metal and the weld were determined using electrochemical testing methods: potentiodynamic polarization scans and linear polarization resistance measurement. The galvanic currents of the base metal when coupled to the weld metal were measured using zero resistance ammetry.
The weld metal was the anode of the couple for a very short time at the beginning of the experiment and then became the cathode until the end of the experiment. This indicates that electric resistance welded X52 steel pipe is a promising material to be operated in CO2-containing saltwater at pH 4 and 25°C because the weld area is cathodic to the parent metal, the value of the galvanic current is very low (in the order of nanoamps) and the area of the anode (i.e. the parent metal) is significantly larger than that of the cathode (weld metal).
Further experimental research could be performed to investigate the galvanic corrosion behavior between the parent metal and the weld area of X52 carbon steel petroleum pipelines in CO2-containing saltwater at different pH values, temperature and velocity.
Electric resistance welded X52 steel pipe is a promising material for use with CO2-containing saltwater environments at pH 4 and 25°C.
The new information presented in the paper is the galvanic corrosion behavior between the parent metal and the ERW weld metal of X52 carbon steel in CO2-containing solutions. The paper should be useful to researchers working in the field of oil industry corrosion.
The purpose of this study is to inspect the corrosion inhibition of API N80 steel pipelines in uninhibited solution and inhibited with a synthesized surfactant compound…
The purpose of this study is to inspect the corrosion inhibition of API N80 steel pipelines in uninhibited solution and inhibited with a synthesized surfactant compound [N-(3-(dimethyl octyl ammonio) propyl) palmitamide bromide] (DMDPP), which is prepared through a simple and applicable method.
Weight loss was inspected at five different temperatures of 25°C, 30°C, 40°C, 50°C and 60°C Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation were used at room temperature. Density functional theory was used to study the relation between the molecular structure and inhibition theoretically.
Adsorption of the prepared DMDPP fits the Langmuir isotherm model. The inhibition efficiency of the prepared DMDPP amphipathic inhibitor is directly proportional to temperature increase. Polarization results reveal that the investigated DMDPP amphipathic compound behaves as a mixed-type inhibitor. EIS spectra produced one individual capacitive loop.
The originality is the preparation of cationic surfactants through a simple method, which can be used as corrosion inhibitors in oil production. The synthesized inhibitors were prepared from low-price materials. The work studied the behavior of the synthesized surfactants in inhibiting the corrosion of the steel in an acidic medium. Electrochemical and theoretical studies were presented, besides gravimetric and surface examination.