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Article
Publication date: 1 April 2022

Prashil Desai and R.N. Jagtap

There is a rising demand for high-performance 3D printed objects that have established potential applications in the sector of dental, automotive, electronics, aerospace, etc…

152

Abstract

Purpose

There is a rising demand for high-performance 3D printed objects that have established potential applications in the sector of dental, automotive, electronics, aerospace, etc. Thus, to meet the requirements of high-performance 3D printed objects, this study has synthesized, formulated and applied a resorcinol epoxy acrylate (REA) oligomer to a stereolithography (SLA) 3D printer.

Design/methodology/approach

Different formulations were developed by blending reactive diluents in the concentration of 10%, 15% and 20%, along with the fixed quantity of photo-initiators in the REA oligomer. The structure of synthesized REA oligomer was confirmed using 13 C nuclear magnetic resonance (NMR) and 1H NMR spectroscopy, and the rheological properties for prepared REA formulations were also evaluated. The ultraviolet (UV)-cured specimens of all REA formulations were thoroughly examined based on physical, chemical, optical, mechanical and thermal properties. The best suitable formulation was selected for SLA 3D printing.

Findings

As perceived, UV cured REA specimens exhibit superior mechanical, chemical and thermal properties, portraying the ability to use as a high-performance material. The increase in the concentration of reactive diluents indicated a significant improvement in the properties of REA resin. The 20% diluted formulation achieved excellent compatibility with a SLA 3D printer; thus, 3D objects are cast with good dimensional stability and printability.

Originality/value

Resorcinol-based resins have always been a key additive used to enhance properties in the coating and tire industry. In a new attempt UV, curable REA has been applied to a SLA 3D printer to cast high-performance 3D printed objects.

Details

Pigment & Resin Technology, vol. 52 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 February 2024

Umesh Mahajan and S.T. Mhaske

This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl…

Abstract

Purpose

This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl methacrylate (HEMA) terminated urethane acrylate oligomer was synthesized and characterized to study its application in stereolithography 3D printing with different ratios of isobornyl acrylate and hexanediol diacrylate.

Design/methodology/approach

Polyester polyol was synthesized from suberic acid and butanediol. Additionally, isophorone diisocyanate, polyester polyol and HEMA were used to create urethane acrylate oligomer. Fourier transform infrared spectroscopy and 1H NMR were used to characterize the polyester polyol and oligomer. Various formulations were created by combining oligomer with reactive diluents in concentrations ranging from 0% to 30% by weight and curing with ultraviolet (UV) radiation. The cured coatings and 3D printed specimens were then evaluated for their properties.

Findings

The findings revealed an improvement in thermal stability, contact angle value, tensile strength and surface properties of the product which indicated its suitability for use as a 3D printing material.

Originality/value

This study discusses how oligomers that have been cured by UV radiation with mono- and difunctional reactive diluents give excellent coating characteristics and demonstrate suitability and stability for 3D printing applications.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 February 1991

Edgar S. Lower

Oleochemicals are materials not derived from petroleum, but from the main chemical components of animal, marine and vegetable oils, glycerides, and include the fatty acids…

Abstract

Oleochemicals are materials not derived from petroleum, but from the main chemical components of animal, marine and vegetable oils, glycerides, and include the fatty acids themselves and glycerol, and many derivatives, e.g. fatty alcohols, fatty amides, fatty amines, fatty acid esters, sulphur derivatives, phosphorous derivatives, polyoxyethylated and polyoxypropylated materials, etc.

Details

Pigment & Resin Technology, vol. 20 no. 2
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 December 1984

Agreement has been reached between Lawtons Ltd of Liverpool, England and the American Slautterback Corporation of Monterey, California whereby Lawtons is the exclusive Western…

Abstract

Agreement has been reached between Lawtons Ltd of Liverpool, England and the American Slautterback Corporation of Monterey, California whereby Lawtons is the exclusive Western European distributor for the Lawco/Slautterback range of case sealing machines using hotmelt adhesives. With the right to appoint exclusive sub‐distributors covering all major European markets, Lawtons is actively seeking dealer enquiries through its Export Trade Division.

Details

Pigment & Resin Technology, vol. 13 no. 12
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 2 November 2012

Preeti Singh, Sven Saengerlaub, Ali Abas Wani and Horst‐Christian Langowski

The purpose of this paper is to review the new trends in plastic additives, with special focus on developments in food packaging materials.

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Abstract

Purpose

The purpose of this paper is to review the new trends in plastic additives, with special focus on developments in food packaging materials.

Design/methodology/approach

Phenomenological research has brought awareness and increased insight into the role of various plastic additives on the packaging of foods. The approach is based on the current trends and the industrial protocols for the additives used in plastic polymer processing for the development of food packaging materials.

Findings

Packaging of foodstuffs is a dynamic process which continually responds to the changes in supply and demand which are the result of adaptations to the varying demands of the consumer, changes in retail practices, technological innovations, new materials and developments in legislation, especially, with respect to environmental concerns. A wide range of additives is available for enhancing the performance and appearance of food packaging, as well as improving the processing of the compound. Polymer additives are important areas of innovation for packaging materials.

Originality/value

The paper reviews and summarizes the recent developments in the functionality of different additives, along with their advantages and disadvantages, currently being used to enhance the properties of food packaging materials that can positively influence the environment within the packaging for the increased demand for raw or processed foods.

Details

Pigment & Resin Technology, vol. 41 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 March 2018

Nivin M. Ahmed, Walaa M. Abd El-Gawad and Eglal M.R. Souaya

Core-shell is structured particles having several chemical compositions. The advantage of these particles arise from their specific design, to be used in decreasing costs by using…

Abstract

Purpose

Core-shell is structured particles having several chemical compositions. The advantage of these particles arise from their specific design, to be used in decreasing costs by using inexpensive material (natural ore or waste material) as carrier for thin shell of active material. This study aims to prepare ferrites/silica core-shell pigments and compare their inhibition efficiency to original ferrites. These pigments have shells of different ferrites that comprise 10-15 per cent of the prepared pigments on silica fume. Silica fume which is the core is a byproduct in the ferro–silicon industry; this core comprises 85-90 per cent of the prepared pigments.

Design/methodology/approach

The prepared core-shell pigments were characterized using transmission electron microscopy analysis, energy-dispersive X-ray analysis and sequential wavelength dispersive X-ray fluorescence. These pigments were integrated in epoxy-based paint formulations, and the physical, mechanical and corrosion properties of dry films were examined. The corrosion properties were studied by using immersion test in 3.5 per cent NaCl for 28 days.

Findings

This study showed that these new eco-friendly and inexpensive pigments are similar to ferrites in their inhibition performance, i.e. they exhibited high corrosion prevention.

Research limitations/implications

Domestic waste materials were reused in paints and only simple modification was used, and then, their effectiveness showed similar performance to that of the original pigments.

Originality/value

Ferrite and ferrite/silica pigments are environmentally friendly pigments that can replace other hazardous pigments (e.g. chromates) with almost the same quality in their performance; also, they can be used in industries other than paints (e.g. paper, rubber and plastics composites).

Details

Pigment & Resin Technology, vol. 47 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

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