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This paper aims to introduce a new type of analysis method to seek the actual working performance of the regulatable dry gas seal, including equilibrium film thickness, stiffness-leakage ratio and so on. Additionally, a parametric optimization of the hydrostatic structure is completed for this kind of seal.

From the point of axial force balance based on gas lubrication theory, a new analysis method, the Gas Film Divided Method, has been introduced. A four-factor and three-level hydrostatic structural parameters test scheme is designed by means of Central Composite Design test and then the hydrostatic structural parameters of regulatable dry gas seal were optimized. Three types of regulatable dry gas seal have been designed and manufactured to verify the theoretical analysis by measuring the equilibrium film thickness and inward leakage.

The results indicate that the numerical values of the Gas Film Divided (GFD) method agree well with the experimental ones. Test proves that the Central Composite Design test could achieve optimized hydrostatic structural parameters of regulatable dry gas seal effectively.

For validating the correctness of the GFD method, an experiment study of the regulatable dry gas seal is being carried out where atmosphere is selected as the lubricant for the sake of safety. Soon after, the author will discuss the application in the new paper.

The introduction of the GFD method proffers important insights to seek the performances of regulatable dry gas seal under the actual working conditions. The detailed optimal values of the hydrostatic structural parameters were given by the theoretical research which may be helpful for the design of regulatable dry gas seal.

This study aims to study the gas film stiffness of the spiral groove dry gas seal.

The present study represents the first attempt to calculate gas film stiffness in consideration of the slipping effect by using the new test technology for dry gas seals. First, a theoretical model of modified generalized Reynolds equation is derived with slipping effect of a micro gap for spiral groove gas seal. Second, the test technology examines micro-scale gas film vibration and stationary ring vibration to determine gas film stiffness by establishing a dynamic test system.

An optimum value of the spiral angle and groove depth for improved gas film stiffness is clearly seen: the spiral angle is 1.34 rad (76.8º) and the groove depth is 1 × 10^–5 m. Moreover, it can be observed that optimal structural parameters can obtain higher gas film stiffness in the experiment. The average error between experiment and theory is less than 20%.

The present study represents the first attempt to calculate gas film stiffness in consideration of the slipping effect by using the new test technology for dry gas seals.

This paper aims to a newly designed photoresponsive four-armed graft copolymer was synthesised and characterised. The synthesised polymer contains photochemical group and a greater part of the cross-linkable functional group which is not affected by short wavelength when subject to under ultraviolet (UV) irradiation in film status.

The four-armed macroinitiator was prepared by reacting diethanol amine with poly [methyl-2-chloro-4-{7-(chloroacetyl) oxy]-2-oxo-2H-chromen-4-yl}-2-methylbutanoate] and acylating the product with chloroacetyl chloride. A grafting reaction with n-butyl methacrylate was carried out in the presence of the four-armed macroinitiator and the catalyst CuBr/2, 2′-bipyridyne at 90°C. All of the synthesised polymers were structurally characterised by Fourier transform infrared spectroscopy (FT-IR) and Hydrogen-1 Nuclear Magnetic Resonance (1H-NMR) spectra. Gel permeation chromatography was used to obtain the molecular weights of polymer.

1H-NMR, FT-IR and ultraviolet-visible (UV-Vis) spectroscopy demonstrated that the four-armed macroinitiator and the graft copolymer was successfully synthesised. The end-functionalised poly(methyl methacrylate) with 7-hydroxyl-4-chloromethyl coumarin was irradiated at the wavelength larger than 300 nm to create the cyclobutane ring in between the 7-hydroxyl-4-chloro methyl coumarin unities. To characterise the polymer and show the transformation of coumarin unities into photodimers, 1H-NMR, FT-IR and UV-Vis spectroscopy were used.

Graft copolymer containing coumarin has involves photocrosslinkable functional group, in which reactive functional group has attracted great interest from both industrial and academic fields. Their synthesis provides the opportunity for a compatible modification of the graft copolymer structure to develop adapted macromolecules for a range of end practices.

A photoresponsive graft copolymer can have a role in an active area of polymer chemistry research due to its uses in the areas of photolithography, liquid crystal, non-linear optical materials, laser dyes, fluorescence materials and future microelectronics.

Graft copolymers containing a photocrosslinkable functional group, and a star polymer may be prepared using the method described in this paper and then used in technological applications. The method discussed here also allows photoinduced reversible self-healing in solid polymers.