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1 – 10 of 330D.P. Chattopadhyay, R.B. Chavan and J.K. Sharma
Fibre reactive dyes are very popular for cellulosic garments as they are environmentally safe and having good overall fastness properties. But application of these dyes requires a…
Abstract
Purpose
Fibre reactive dyes are very popular for cellulosic garments as they are environmentally safe and having good overall fastness properties. But application of these dyes requires a very high concentration of salt. The salt released from garment dyeing increases salinity in drain water stream which has a negative impact on environmental ecology. The present work aims to eliminate the usage of salt during dyeing of cotton goods with reactive dyes.
Design/methodology/approach
The methodology adopted here, for the elimination of salt in cotton dyeing, was based on the principle of cationisation (to develop a positive charge) of cotton. The same was achieved by subjecting the caustic pretreated cotton fabric samples to a treatment of 1, 2 dichloroethane followed by methylamine to introduce amino groups in the cellulose structure. The treated cotton when dyed from slightly acidic bath generates positive sites due to protonation in the amino group. The reactive dyes being anionic (negatively charged) in solution get attracted to the positive charges on the fibre which eliminates the salt requirements for satisfactory dye exhaustion.
Findings
The investigation was conducted for cold brand, hot brand and highly exhaustive reactive dyes. The modified cotton showed excellent dye exhaustion for all the dyes in the absence of salt. The treatment was found to improve the dye fixation also. The modification was assessed through elemental analysis.
Research limitations/implications
This study may be further extended to viscose material after suitably modifying the treatment conditions.
Practical implications
A pretreatment to cotton which could eliminate the usage of salt in its dyeing with reactive dyes is revealed.
Originality/value
The study explored a newer technique of cotton dyeing without salt usage. Both garment dyeing units and fabric/yarn finishing industries would thus be helpful.
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Pitting inhibition efficiency of SO4− and NO3− on AISI 316L stainless steel in contact with Cl−-containing fiber dyeing solutions together with the influence of the anions on…
Abstract
Purpose
Pitting inhibition efficiency of SO4− and NO3− on AISI 316L stainless steel in contact with Cl−-containing fiber dyeing solutions together with the influence of the anions on absorption behavior of the solutions were investigated. The purpose of the study is to experimentally determine an optimized dyeing solution efficient on both – inhibition of the steel’s pitting and exhaustion of the dyes dissolved.
Design/methodology/approach
Methods such as electrochemical cyclic polarization, UV-visible range spectrophotometry and scanning electron microscopy have been used to assess the performance of two inhibitors on both pitting inhibition of the steel and dissolving ability over the reactive dyes. To find out a promising dyeing solution mixture in both aspects, Cl content of the original dyeing solution was replaced gradually with the inhibiting anions, where the total anionic content was kept constant to unchange the dye exhaustion potential of the solution. Then, those solutions came out with diverse pitting inhibition, and dye absorption levels were compared together for reducing/avoiding the pitting issues of the reactive dyeing vessels of the industry.
Findings
Rather high absorption levels detected by visible range spectrophotometry on the solutions showing sound inhibition levels indicated possibility of unaltered reactive dyeing qualities with an enhanced vessel lifetime as the inhibitive anions replace Cl−. Nitrate performed better than sulfate both on inhibition and absorption in the dyeing solutions. Also, 316L vessels became open to an extra anodic protection in inhibitor added solutions.
Research limitations/implications
The findings are valid for a certain group of reactive dyes and dyeing solutions held at 70°C. However, the testing methods are available to almost any dyeing solution and dyeing temperature.
Originality/value
The work presents a combined testing of pitting inhibition and absorption behavior of dyeing solutions involving Cl− that has not been reported so far. It shows that solution recipes least harmful to the steel vessels can be outlined for various reactive or other types of dye groups.
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Xuemei Guan, Wenfeng Li and Jingyi Huang
The purpose of this paper is to improve the dyeing effect of fast-growing fir wood dyed with reactive dyes.
Abstract
Purpose
The purpose of this paper is to improve the dyeing effect of fast-growing fir wood dyed with reactive dyes.
Design/methodology/approach
In this study, five factors including temperature, the dosage of dye accelerator, dyeing time, the dosage of fixing agent and fixing time were investigated. Then, the color difference and light resistance of the wood surface after dyeing were used as the evaluation indicators; the best dyeing process under the two indicators was obtained through the range analysis. Finally, the two indicators were considered comprehensively, and the fuzzy comprehensive evaluation method was used to obtain the best dyeing process under the comprehensive indicators.
Findings
The results show that when the comprehensive index was used as the evaluation index, the optimal dyeing process for reactive red X-3B dyeing fast-growing fir veneer was that the dyeing temperature was 65°C; the amount of dye accelerator was 25 g L−1; the dyeing time was 2 h; the amount of fixing agent was 15 g L−1; and the fixing time was 35 min.
Originality/value
The technique of wood dyeing is an important method to increase the value of wood products. When using different kinds of dyes or dyeing substrates for wood dyeing, the dyeing process is different. This study determined the best process for reactive dye dyeing of fast-growing fir veneer and provided a solution for improving the value of fast-growing fir wood.
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Fatma Ali Mohamed and Rafaat Melad Mohareb
The purpose of this paper is to synthesise, characterise and find out properties of some new bifunctional dyes bis (monochlorotriazine) using tetrahydrobenzo[b]thiophene systems…
Abstract
Purpose
The purpose of this paper is to synthesise, characterise and find out properties of some new bifunctional dyes bis (monochlorotriazine) using tetrahydrobenzo[b]thiophene systems as the chromophoric moiety, bearing good colour strength, lightfastness, and other favourable properties.
Design/methodology/approach
The novel reactive dyes were prepared, containing bis monochlorotriazine as reactive groups. The dye is synthesised by diazotization and coupling reactions. Firstly the authors synthesised the ethyl 2‐amino 4,5,6,7‐tetrahydrobenzo[b]thiophen‐3‐carboxylate chromophoric moiety compound which in turn underwent diazotization and coupling then diazotized and coupled reaction with either 1‐amino‐8‐naphthol‐3,6‐disulphonic acid (H‐acid) and or 2‐amino‐8‐naphthol‐6‐sulphonic (γ acid) to give the monoazo dye intermediates compounds. The latter products reacted with 2,4,6‐trichloro‐1,3,5‐triazine in 1:1 molar ratio afforded, via nucleophilic displacement when subjected to condensation 2,4,6‐trichloro‐1,3,5‐triazine in 1:1 molar ratio afforded via nucleophilic displacement, which reacted with 1,4‐phenylenediamine in 2:1 molar ratio to give reaction with the 1,4‐phenylenediamine in 2:1 molar ratio, the bisazobifunctional bismonochlorotriazine reactive dyes.bisazo bifunctional bismonochlorotriazine reactive dyes thus yielding the new target reactive. The synthesised dyes were applied onto cotton fabric under the typical exhaust dyeing conditions and their dyeing properties were investigated.
Findings
The results assessed for dyeing indicate high quality dyeing properties However, the homobifunctional (bis MCT) dyes showed higher exhaustion and fixation values, colour yield and fastness properties.
Practical implications
The described method showed the synthesis of bis monochlorotriazines derived from the tetrahydrobenzo[b]thiophene derivative 3 followed by their application towards cotton fabric.
Social implications
Social implications are to prepare new reactive dyes having higher fastness and uses for dyeing cotton which is the commonest fabric use.
Originality/value
In this work, the novel reactive dyes derived from the tetrahydrobenzo[b]thiophene derivative 3 were synthesized and their structures were based on the analytical and spectral data. Such a group of compounds are considered to be excellent reactive dyes with different colour shades.
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Dawu Shu, Shaolei Cao, Yan Zhang, Wanxin Li, Bo Han, Fangfang An and Ruining Liu
This paper aims to find a suitable solution to degrade the C.I. Reactive Red 24 (RR24) dyeing wastewater by using sodium persulphate to recycle water and inorganic salts.
Abstract
Purpose
This paper aims to find a suitable solution to degrade the C.I. Reactive Red 24 (RR24) dyeing wastewater by using sodium persulphate to recycle water and inorganic salts.
Design/methodology/approach
The effects of temperature, the concentration of inorganic salts and Na2CO3 and the initial pH value on the degradation of RR24 were studied. Furthermore, the relationship between free radicals and RR24 degradation effect was investigated. Microscopic routes and mechanisms of dye degradation were further confirmed by testing the degradation karyoplasmic ratio of the product. The feasibility of the one-bath cyclic dyeing in the recycled dyeing wastewater was confirmed through the properties of dye utilization and color parameters.
Findings
The appropriate conditions were 0.3 g/L of sodium persulphate and treatment at 95°C for 30 min, which resulted in a decolorization rate of 98.4% for the dyeing wastewater. Acidic conditions are conducive to rapid degradation of dyes, while ·OH or SO4−· have a destructive effect on dyes under alkaline conditions. In the early stage of degradation, ·OH played a major role in the degradation of dyes. For sustainable cyclic dyeing of RR24, inorganic salts were reused in this dyeing process and dye uptake increased with the times of cycles. After the fixation, some Na2CO3 may be converted to other salts, thereby increasing the dye uptake in subsequent cyclic staining. However, it has little impact on the dye exhaustion rate and color parameters of dyed fabrics.
Originality/value
The recommended technology not only reduces the quantity of dyeing wastewater but also enables the recycling of inorganic salts and water, which meets the requirements of sustainable development and clean production.
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H.Z. Shams, Y.A. Youssef, F.A. Mohamed, M.M. El‐Zawahry, M.H. Helal and E.A. El‐Kharadly
The purpose of this paper is to evaluate the efficiency of modifying reactive azo dyes using pyrazolo[1,2‐a]pyrazole fused systems as the chromophoric moiety which could satisfy…
Abstract
Purpose
The purpose of this paper is to evaluate the efficiency of modifying reactive azo dyes using pyrazolo[1,2‐a]pyrazole fused systems as the chromophoric moiety which could satisfy many and varied criteria drawn from economic, synthetic, physicochemical and fastness properties.
Design/methodology/approach
Six novel heterocyclic disazo reactive dyes were prepared, containing monofunctional sulphatoethylsulphone (SES) and hetero‐bifunctional monochlorotriazine (MCT)/SES reactive groups. Dyes intermediates based on 4‐arylazo‐1,5‐dioxopyrazolo[1,2‐a]pyrazole chromophoric moieties are initially synthesised and coupled with two different diazonium salts having the aforementioned reactive groups, thus yielding the new target reactive dyes. The synthesised dyes are applied to cotton, wool and silk fabrics under the typical exhaust dyeing conditions and their dyeing properties were investigated.
Findings
The results assessed for dyeing indicate high‐quality dyeing properties. However, the heterobifunctional MCT/SES dyes showed higher exhaustion and fixation values, colour yields and fastness properties than those of the monofunctional SES dyes.
Research limitations/implications
The method developed provided a simple and practical procedure for producing fused pyrazolo[1,2‐a]pyrazole disazo chromophoric systems that afford valuable reactive dyes. In addition, the dyes intermediates based on 4‐arylazo‐1,5‐dioxopyrazolo[1,2‐a]pyrazole as well as their disazo counterparts could be applied as acid dyes to wool and silk.
Originality/value
The method for producing novel disazo reactive dyes could find numerous applications for affording a variety of reactive dyes with different binding linkages and structural reactivity. These could be valuable as reactive dyes with different colour shades.
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Ping Zhang, Wenju Zhu, Md. Yousuf Hossain, Shamima Sarker, Md. Nahid Pervez, Md. Ibrahim H. Mondal, Chao Yan, Yingjie Cai and Vincenzo Naddeo
The conventional textile dyeing process requires various operational characteristics, and determining the most reliable factor in dyeing performance has always been a challenge…
Abstract
Purpose
The conventional textile dyeing process requires various operational characteristics, and determining the most reliable factor in dyeing performance has always been a challenge for the textile industry. Thus, the present paper aimed to evaluate the process sensitivity of C. I. Reactive Blue 194 dyeing of cotton fabric using a statistical technique.
Design/methodology/approach
An L27 orthogonal array-based Taguchi's methodology was used with six parameters and three levels of each parameter. The signal-to-noise (S/N) ratio and analysis of variance were studied using total fixation efficiency (T%) as the response of the process sensitivity.
Findings
Results showed that dyebath pH was the most influential factor on the process and total fixation efficiency (p-value = 0.00 and contribution percentage 45.03%), followed by dye-fixing temperature, dye mass, electrolyte concentration, dye-fixing time and material to liquor ratio.
Originality/value
Overall this study provides a foundation for the determination of dyeing process sensitivity that will be useful in textile industries toward further development.
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Marjo Määttänen, Sari Asikainen, Taina Kamppuri, Elina Ilen, Kirsi Niinimäki, Marjaana Tanttu and Ali Harlin
While aiming to create methods for fibre recycling, the question of colours in waste textiles is also in focus; whether the colour should be kept or should be removed while…
Abstract
Purpose
While aiming to create methods for fibre recycling, the question of colours in waste textiles is also in focus; whether the colour should be kept or should be removed while recycling textile fibre. More knowledge is needed for colour management in a circular economy approach.
Design/methodology/approach
The research included the use of different dye types in a cotton dyeing process, the process for decolourizing and the results. Two reactive dyes, two direct dyes and one vat dye were used in the study. Four chemical treatment sequences were used to evaluate colour removal from the dyed cotton fabrics, namely, HCE-A, HCE-P-A, HCE-Z-P-A and HCE-Y-A.
Findings
The objective was to evaluate how different chemical refining sequences remove colour from direct, reactive and vat dyed cotton fabrics, and how they influence the specific cellulose properties. Dyeing methods and the used refining sequences influence the degree of colour removal. The highest achieved final brightness of refined cotton materials were between 71 and 91 per cent ISO brightness, depending on the dyeing method used.
Research limitations/implications
Only cotton fibre and three different colour types were tested.
Practical implications
With cotton waste, it appears to be easier to remove the colour than to retain it, especially if the textile contains polyester residues, which are desired to be removed in the textile refining stage.
Originality/value
Colour management in the CE context is an important new track to study in the context of the increasing amount of textile waste used as a raw material.
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A. Waly, M.M. Marie, N.Y. Abou-Zeid, M.A. El-Sheikh and A.L. Mohamed
Cotton fabrics can be dyed with reactive and/or direct dyes in aqueous baths under certain specific conditions of pH, salt, temperature, time, etc., and rendered fire retardant…
Abstract
Cotton fabrics can be dyed with reactive and/or direct dyes in aqueous baths under certain specific conditions of pH, salt, temperature, time, etc., and rendered fire retardant through reaction with reactive phosphonopropionamide compounds. In the presence of reactive tertiary amines and reactive phosphorous derivatives, cotton fabrics can be dyed with reactive, direct or acid dyes in the absence of the usual added alkalis and salts, and in the mean time, the fabric becomes fire retardant with wash and wear properties. To verify such claims, reactive aminating agents are synthesized by reacting different amine compounds that have various numbers of amino groups with acryl amide and formaldehyde. The pad-dry-cure technique is applied to treated fabrics with aqueous finishing formulations that contain dyestuff and reactive amine-compounds; the cotton fabric will simultaneously impart reactive dyeing, easy-care inishing and fire-retardant properties. Systematic studies show that in the presence of 6% weight/weight, reactive amine in an aqueous formulation yields cotton fabric with the least loss in tensile strength and elongation at break, and an enhancement to the crease recovery angle. By adding the dyestuff to the aqueous formulation at fixed nitrogen content for treated cotton (0.2%) under identical dyeing conditions, the colour strength (K/S) increases for dyed cotton. The fastness properties of the dyed fabric are improved or remain unaltered for the three types of dyestuffs used
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The purpose of this paper was to study the dyeing properties of polysulphonamide (PSA)/aramid 1313 (MPIA) blended yarn by selecting suitable dyes and carriers required in the…
Abstract
Purpose
The purpose of this paper was to study the dyeing properties of polysulphonamide (PSA)/aramid 1313 (MPIA) blended yarn by selecting suitable dyes and carriers required in the dyeing process.
Design/methodology/approach
Dyeing the blended yarn with cationic dyes, acid dyes, disperse dyes, reactive dyes and pigment, and comparing the shades, K/S values and fastness of the blended yarns.
Findings
The PSA/MPIA blended fibre is suitable for dyeing with the cationic dye at high temperature and pressure in the presence of carrier acetophenone, and good homochromatism is seen on the two fibres when using same type of dye.
Originality/value
PSA fibre is a thermo-resistant and flame-retardant product made in China in recent years. Blended with aramid 1313 fibre, it may acquire good spinnability. But there is little technical report about properties of the blended yarn in the literature at present. This paper reports the dyeing property of such fibres for the first time.
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