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The purpose of this paper is to find an effective route to fabricate high transparent top electrode in quantum dots light-emitting diodes (QLEDs).
Abstract
Purpose
The purpose of this paper is to find an effective route to fabricate high transparent top electrode in quantum dots light-emitting diodes (QLEDs).
Design/methodology/approach
Al-doped ZnO (AZO) top cathode with high transparency have been deposited by an atomic layer deposition (ALD) method at 140°C for 1 h. The products are studied by UV-vis spectrometer and atomic force microscopy (AFM). The electroluminescence spectra of QLED are recorded using an Ocean Optics high-resolution spectrometer (HR4000). The devices were measured under ambient conditions without encapsulation.
Findings
The AZO-based QLED shows excellent performance with high luminance and current efficiency.
Originality/value
The AZO obtained by ALD method is a promising cathode candidate for application in QLEDs.
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Mohd Ann Amirul Zulffiqal Md Sahar, Zainuriah Hassan, Sha Shiong Ng, Way Foong Lim, Khai Shenn Lau, Ezzah Azimah Alias, Mohd Anas Ahmad, Nur Atiqah Hamzah and Rahil Izzati Mohd Asri
The aims of this paper is to study the effects of the V/III ratio of indium gallium nitride (InGaN) quantum wells (QWs) on the structural, optical and electrical properties of…
Abstract
Purpose
The aims of this paper is to study the effects of the V/III ratio of indium gallium nitride (InGaN) quantum wells (QWs) on the structural, optical and electrical properties of near-ultraviolet light-emitting diode (NUV-LED).
Design/methodology/approach
InGaN-based NUV-LED is successfully grown on the c-plane patterned sapphire substrate at atmospheric pressure using metal organic chemical vapor deposition.
Findings
The indium composition and thickness of InGaN QWs increased as the V/III ratio increased from 20871 to 11824, according to high-resolution X-ray diffraction. The V/III ratio was also found to have an important effect on the surface morphology of the InGaN QWs and thus the surface morphology of the subsequent layers. Apart from that, the electroluminescence measurement revealed that the V/III ratio had a major impact on the light output power (LOP) and the emission peak wavelength of the NUV-LED. The LOP increased by up to 53% at 100 mA, and the emission peak wavelength of the NUV-LED changed to a longer wavelength as the V/III ratio decreased from 20871 to 11824.
Originality/value
This study discovered a relation between the V/III ratio and the properties of QWs, which resulted in the LOP enhancement of the NUV-LED. High TMIn flow rates, which produced a low V/III ratio, contribute to the increased LOP of NUV-LED.
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Farah Khaleda Mohd Zaini, Vengadaesvaran Balakrishnan, A. Syafiq, Nasrudin Abd. Rahim, A.K. Pandey, Ramesh Kasi and Ramesh Subramaniam
The purpose of this paper is to implement coating system by varying the amount of nano-sized titanium dioxide, (nano-TiO2) combined with various organic binders and to study the…
Abstract
Purpose
The purpose of this paper is to implement coating system by varying the amount of nano-sized titanium dioxide, (nano-TiO2) combined with various organic binders and to study the coating effects on the performance of solar cell in terms of temperature and efficiency.
Design/methodology/approach
Nano-TiO2 coatings are developed in two types of binder networks; the combination of methyltrimethoxy silane (MTMS) and nitric acid and the combination of 3-aminopropyl triethoxysilane (APTES) and MTMS. Overall, the formulations method was cost-effective, produces good transparency, clear and managed to dry at room temperature. The coating mixtures were applied onto the glass substrate by using the dip-coating method and the coated substrate were sent for several characterizations.
Findings
This study demonstrated that TiO2 nanoparticle coating in APTES/MTMS matrix showed a thermal-decreasing result on solar cells, where the cell temperature is reduced to 46.81°C (T2 coating type) from 55.74°C (without coating) after 1-h exposure under 1,000 W/m2 irradiance in a solar simulator. Contrary to prior works where solar cell coatings were reported to reduce the cell temperature at the expense of the cell efficiency, the results from this study reported an improved fill factor (FF) of solar cells. From the photovoltaic (PV) characteristics study, the FF for solar cells is increased by approximately 0.2, i.e. 33.3 per cent, for all coatings compared to the non-coated cell.
Research limitations/implications
Findings will be able to contribute in the development of temperature-reducing and efficiency-enhancing coating for PV panels.
Practical implications
A simple dip-coating method provides an even distribution of TiO2 nanoparticle coating on the glass panel, which is cost-effective and time-efficient to reduce the temperature of solar cell while maintaining its efficiency.
Originality/value
The ability of nano-TiO2 coatings with a simple fabrication method and the right solution to reduce the surface temperature of solar cells while improving the FF of the cells.
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Hong Ju, Jiejing Chen, Can Sun and Yan Li
The purpose of this study is to perform quantum chemical calculations based on the DFT method on four bipyrazoles used as corrosion inhibitors for the plain carbon (“mild”) steel…
Abstract
Purpose
The purpose of this study is to perform quantum chemical calculations based on the DFT method on four bipyrazoles used as corrosion inhibitors for the plain carbon (“mild”) steel in acid media to determine the relationship between inhibition efficiency and the molecular structure of inhibitors.
Design/methodology/approach
Several quantum chemical parameters, such as the charge distribution, energy and distribution of highest occupied molecular orbital and lowest unoccupied molecular orbital, the absolute electronegativity (χ) values and the fraction of electrons (△N) transferring from inhibitors to the steel surface, were calculated and correlated with inhibition efficiencies.
Findings
The results showed that the inhibition efficiency of bipyrazole increased with the increasing in EHOMO, and the areas containing N atoms were the most probable sites to donate electrons for adsorbing the inhibitor molecules onto the metal surface.
Originality/value
It is a useful method to investigate the mechanisms of reaction by calculating the structure and electronic parameters, which can be obtained by means of theoretical quantum theory. Thus, the behavior and mechanism of the organic inhibitors can be obtained. Quantum chemical method can also be used to guide the selection and molecular design of inhibitors.
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Ayodeji E. Oke and Seyi S. Stephen
Quantum computer design is a registration that utilises quantum-mechanical wonder, like superposition and entrapment, used to arrange the assets of a quantum computer. A…
Abstract
Quantum computer design is a registration that utilises quantum-mechanical wonder, like superposition and entrapment, used to arrange the assets of a quantum computer. A deliberate layered system can be planned to handle the difficulties, which emerge during the advancement of a quantum figuring. The plan usefulness is isolated into layers where the subsystems are planned in such a manner with the goal that it can investigate the issues freely and measures better between the layers bringing about a superior arrangement. Right now, all adaptable quantum figuring innovations are recommendations and critical advances in assembling necessities needed to carry them to the real world. By and by, a few recommendations have less cumbersome innovative obstacles before them than others. Even though its applications are somewhat limited in the construction industry, steps have been taken towards its implementation across the industry as well as other industries.
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Hayat Ayar Şentürk and Kaan Tuğrul Özkan
The logic of value innovation has received increased attention in the strategic marketing and innovation literature. Studies investigating how value innovation, as a firm’s…
Abstract
Purpose
The logic of value innovation has received increased attention in the strategic marketing and innovation literature. Studies investigating how value innovation, as a firm’s strategic mindset, contributes to creating new market space through more proximal market-driven factors such as strategic decisions and customer value are still lacking, nevertheless. This study aim to investigate how the logic of value innovation influences creating new market space through quantum strategy and customer value creation.
Design/methodology/approach
Survey data from a sample of 204 manufacturing and service firms was used to test the conceptual model and research hypotheses. The data were analyzed using structural equation modeling.
Findings
The findings reveal the direct and indirect effect of value innovation logic on the new market space through the mediation of quantum strategy and customer value creation. Besides, this study shows that quantum strategy does not directly contribute to customer value creation. A reason is that the quantum strategy as a both/and strategy is the more dominating factor in creating new market space.
Originality/value
There is still a lack of a systematic understanding of how value innovation, as a firm’s strategic mindset, contribute to creating new market space through a firm’s strategic choices and superior customer value creation, as more proximal market-driven factors. This study empirically attempted to address this research problem. This study contributes to the strategic marketing literature by providing a model for the interwoven relationships between value innovation, quantum strategy, customer value and new market space.
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Ehsan Jafarnejad, Jafar Abolhasani and Arezoo Derakhshan
This study aims to develop a new simple and sensitive method for the microextraction of trace levels of lead in environmental samples. It is based on the use of ionic liquids…
Abstract
Purpose
This study aims to develop a new simple and sensitive method for the microextraction of trace levels of lead in environmental samples. It is based on the use of ionic liquids based dispersive liquid–liquid microextraction (IL–DLLME) before spectrofluorometry.
Design/methodology/approach
Cadmium sulphide quantum dots have been synthesised using thioglycolic acid as capping agent through a one-step process with stability and excellent water-solubility, and have strong affinity for lead (Pb). This probe is based on the fluorescence quenching effect of functionalised cadmium sulphide quantum dots.
Findings
Factors affecting the extraction efficiency and fluorescence quenching of metals, such as the amount of ionic liquid, amount of metanol, microextraction and centrifugation time, volume of quantum dots and buffer pH, were investigated. Under optimum conditions, the calibration graph was linear in the range of 0.01-3 µg.L-1, with the detection limit of 0.004 µg.L-1 for Pb2+. The relative standard deviation (RSD%, n = 5) of 5.4 per cent at 1 µg.L-1 of Pb2+ was obtained.
Originality/value
This method for pre-concentration of the Pb ions by dispersive liquid–liquid microextraction is novel and could be used for various applications in the synthesis of a wide variety of determination of fluorescence quenching of cadmium sulphide quantum dots.
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Keywords
Barbara Swatowska, Piotr Panek, Dagmara Michoń and Aleksandra Drygała
The purpose of this study was the comparison and analysis of the electrical parameters of two kinds of silicon solar cells (mono- and multicrystalline) of different emitter…
Abstract
Purpose
The purpose of this study was the comparison and analysis of the electrical parameters of two kinds of silicon solar cells (mono- and multicrystalline) of different emitter resistance.
Design/methodology/approach
By controlling of diffusion parameters, silicon mono- (Cz-Si) and multicrystalline (mc-Si) solar cells with different emitter resistance values were produced – 22 and 48 Ω/□. On the basis of current-voltage measurements of cells and contact resistance mapping, the properties of final solar cells based on two different materials were compared. Additionally, the influence of temperature on PV cells efficiency and open circuit voltage (Uoc) were investigated. The PC1D simulation was useful to determine spectral dependence of external quantum efficiency of solar cells with different emitter resistance. The silicon solar cells of 25 cm2 area and 240 µm thickness were investigated.
Findings
Considering the all stages of cell technology, the best structure is silicon solar cell with sheet resistance (Rsheet) of 45-48 Ω/□. Producing of an emitter with this resistance allowed to obtain cells with a fill factor between 0.725 and 0.758, Uoc between 585 and 612 mV, short circuit current (Isc) between 724 and 820 mA.
Originality/value
Measurements and analysis confirmed that mono- and multicrystalline silicon solar cells with 48 Ω/□ emitter resistance have better parameters than cells with Rsheet of 22 Ω/□. The contact resistance is the highest for mc-Si with Rsheet of 48 Ω/□ and reaches the value 3.8 Ωcm.
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Mergers and acquisitions are notoriously risky, especially when they involve organizations in different countries. Mercer Human Resource Consulting believes that up to 70 percent…
Abstract
Mergers and acquisitions are notoriously risky, especially when they involve organizations in different countries. Mercer Human Resource Consulting believes that up to 70 percent of mergers and acquisitions fail to deliver their intended benefits. Other research has shown that perhaps less than a fifth of international mergers and acquisitions add to shareholder value.
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Abstract
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