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The purpose of this work is to investigate the influence of curcumin dye natural colorant on adhesion, mechanical, thermal and electrochemical properties of blend poly (methyl methacrylate) (PMMA) – acrylic polyol.

Extracted curcumin yellow dye colorant from Curcuma Demostica was mixed with PMMA‐acrylic polyol blended polymer in the volume ratios of 9:1, 8:2 and 7:3. The mixtures were applied on pre‐treated cold‐roll mild steel panels. All of the paint coating samples were subjected to potential time measurement (PTM), rapid impact deformation, differential scanning calorimetry (DSC), cross hatch and Fourier transform infrared spectroscopy (FTIR) tests.

The addition of curcumin dye colorant was able to improve the adhesion, flexibilities and resistance against electrolytes penetration of the blended poly (methyl methacrylate) (PMMA) – acrylic polyol polymer paint system. Cross hatch test studies showed that high amount of curcumin dye colorant (AP30 paint system) had the lowest peel‐off coating area from the substrate. The FTIR test had confirmed the high concentration of hydroxyl group in the AP30 sample. The hydroxyl group was able to promote hydrogen bonding between coating substrate interface. The AP30 sample had the highest coating flexibilities when tested with rapid impact test. This was due to the lowest glass transition value T_g which indicated lowest cross linking density in the coating molecules structure. In the PTM test, AP30 paint system had shown the highest rate electrolytes penetration within the AP sample.

The composition of curcumin dye colorant in the polymer blend is limited from 10 percent to 30 percent pigment volume concentration. Increasing the amount of lawsone pigment will result inhomogeneous mixtures.

The AP paint system is suitable for interior applications. This paint system has to be mixed with suitable additive materials to improve its performance for exterior purpose.

The purpose of this study is to investigate the synergism of convection, current density distribution and additives by numerical simulation and electrochemical experiments for good throwing power (TP) of copper electro-deposition in printed circuit board (PCB) manufacture.

The flow field of THs and current density distribution on various AR of THs are calculated and analyzed. Meanwhile, corresponding simulation is used to study the performance of plating electrolytes on TP. Two electrochemical parameters, overpotential (η) and potential difference (△η), are chosen to evaluate the electrochemical properties of different plating solutions by galvanostatic measurement and potentiodynamic cathode polarization at different rotating speeds.

By combining both the results of simulation and practical plating, these two electrochemical properties of electrolytes exhibit significant impact to the system at varied conditions. Especially, the electrolyte with higher polarizing η and △η values lead to the elevated TP for AR of more than 2:1.

The harring cell model is built as a bridge between the theoretical and experimental study for control of uniformity of plating THs in PCB manufacturing. This dual-parameter evaluation is validated to be a promising decisive method to guide the THs plating with particular AR in industry.

This research aims to unravel the role of salt contamination and corrosion inhibiting admixtures in the processes of cement hydration and rebar corrosion.

Mortar samples were prepared with NaCl and one of three corrosion inhibitors, sodium nitrite, disodium β‐glycerophosphate, or N,N′‐dimethylethanolamine, admixed. After 28 days curing, all steel‐mortar samples were ponded with 3 percent NaCl solution and electrochemical impedance spectroscopy (EIS) measurements were conducted periodically during the first 48 days. After 60 days of ponding by 3 percent NaCl solution, field‐emission scanning electron microscopy (FESEM) analyses were conducted on the fracture surface of the steel‐mortar sample.

The FESEM results revealed that admixing chlorides and inhibitors in fresh mortar changed the morphology and cement hydration product of hardener mortar at the steel‐mortar interface. The EIS data indicated that all inhibitors increased the polarization resistance of steel, implying reduced corrosion rate of the steel over 48‐day exposures to salt ponding. 0.05 M N,N′‐dimethylethanolamine was the most effective corrosion inhibitor, followed by 0.5 M sodium nitrite; whereas 0.05 M disodium β‐glycerophosphate was a slower and less capable corrosion inhibitor. The admixing of inhibitors in fresh mortar consistently increased the capacitance and decreased the electrical resistance of hardened mortar. The effect of sodium nitrite inhibitor on the resistance of steel mortar interfacial film compensated that of corrosive NaCl by participating to the formation of a protective ferric oxide film.

The results reported shed light on the complex role of admixed salt and corrosion inhibitors in cement hydration and their implications on the durability of steel‐reinforced concrete.

Modern Aspects of Electrochemistry, No. 2. Edited by J. O'M. Bockris, D.SC., Ph.D., D.I.C., F.R.I.C. Butterworths Scientific Publications, 1959. Pp. ix + 416. 75s. This book is similar in nature, though different in subject matter, to the volume having a similar title published in 1954 as part of the Modern Aspects Series of Chemistry. The contents comprise five lengthy chapters, the choice of subjects having been made on the assumption that ‘electrochemistry is that branch of physical chemistry concerned with the properties of electrolytes and electrified interfaces.’

This paper aims to provide a comprehensive literature review on modelling electro-osmotic flow in porous media.

Modelling electro-osmosis in fluid systems without solid particles has been first introduced. Then, after a brief description of the existing approaches for porous media modelling, electro-osmotic flow in porous media has been considered by analysing the main contributions to the development of this topic.

The analysis of literature has highlighted the absence of a universal model to analyse electro-osmosis in porous media, whereas many different methods and assumptions are used.

For the first time, the existing approaches for modelling electro-osmotic flow in porous have been collected and analysed to provide detailed indications for future works concerning this topic.

GERMANY Inhibition of hydrogen corrosion of iron by phenyl thiourea. In de‐aerated acid solutions the corrosion of iron is much reduced by very small additions of phenyl thiourea. For a quantitative study of this, stationary current/voltage curves were studied at potentials close to the open‐circuit potential of carbonyl iron in NaClO‐HClO4 solution of pH 2. By control measurements of various kinds it was thus shown that it is possible to obtain the partial current/voltage curves of both iron dissolution and hydrogen deposition with high accuracy. Therefore a quantitative estimation of the anodic and cathodic components of the total inhibition efficiency is possible. With phenyl thiourea it was found that, under the experimental conditions, inhibition was nearly exclusively cathodic up to 10−6 mol/1. inhibitor, with gradually increasing anodic inhibition at higher concentration.—(H. Kaesche, Werks. u. Korr., 1959, 10 (10), 622–624.)

The rate of copper dissolution in the presence of phosphoric acid‐alcohol mixtures was studied by measuring the limiting current density which represents that the rate of electropolishing is decreased by increasing phosphoric acid concentration, electrode height, and mole fraction of alcohol. Thermodynamic parameters are calculated. The rotating disk electrode is being used as a tool to study the influence of organic solvent addition on the rate of electropolishing of copper. Different reaction conditions such as temperature, speed of rotation of copper disk, the physical properties of solution are studied to obtain a dimensionless correlation between all these parameters. The data can be correlated by the following equations: Sh = 1.835 (Sc)^0.33 (Re)^0.36 (for ethylene glycol) Sh = 1.25 (Sc)^0.33 (Re)^0.5 (for glycerol) It is obvious that the exponent in the two cases denotes a laminar flow mechanism.

This study aims at developing a comprehensive model for the analysis of electro-osmotic flow (EOF) through a fluid-saturated porous medium. To fully understand and exploit a number of applications, such a model for EOF through porous media is essential.

The proposed model is based on a generalised set of governing equations used for modelling flow through fluid saturated porous media. These equations are modified to incorporate appropriate modifications to represent electro-osmosis (EO). The model is solved through the finite element method (FEM). The validity of the proposed numerical model is demonstrated by comparing the numerical results of internal potential and velocity distribution with corresponding analytical expressions. The model introduced is also used to carry out a sensitivity analysis of the main parameters that control EOF.

The analysis carried out confirms that EO in free channels without porous obstruction is effective only at small scales, as largely discussed in the available literature. Using porous media makes EO independent of the channel scale. Indeed, as the channel size increases, the presence of the charged porous medium is essential to induce fluid flow. Moreover, results demonstrate that flow is significantly affected by the characteristics of the porous medium, such as particle size, and by the zeta potential acting on the charged surfaces.

To the best of the authors’ knowledge, a comprehensive FEM model, based on the generalised equations to simulate EOF in porous media, is proposed here for the first time.

The purpose of this paper is to investigate the performance of Passive Direct Methanol Fuel Cell (PDMFC) experimentally using various Membrane Electrode Assembly (MEA) shapes such as square, rectangle, rhombus, and circle with equal areas and equal perimeters. The variation in MEA shape/size is achieved by altering gasket openings in the dynamic regions.

In the equal areas of MEA shapes, gasket opening areas of 1963.5 (+/−0.2) mm2 are used. Whereas in the equal perimeters of shapes, gasket opening perimeters of 157.1 (+/−0.2) mm are used. In this experimentation, Nickel-201 current collectors with 45.3% of circular openings are used on both the anode and cathode sides. The experiment is carried out at a 5 molar methanol concentration to find out the highest power density of the cell.

In the equal areas, among the shapes that are chosen for investigation, the square shape opening consisting of a perimeter of 177.2 mm has developed a maximum power density of 6.344 mWcm⁻² and a maximum current density of 65.2 mAcm⁻². Similarly, in equal perimeters, the rhombus shape opening with an area of 1400 mm2 has developed a maximum power density of 7.714 mWcm⁻² and a maximum current density of 85.3 mAcm⁻².

The novelty of this research work is instead of fabricating various shapes and sizes of highly expensive MEAs, the desired shapes and sizes of the MEA are achieved by altering gasket openings over dynamic regions to find out the highest power density of the cell.

Introduction Much work has been done on the phenomenon of electropolishing since it was discovered by Jaquat. Most of this work was directed towards the elucidation of the polishing mechanism as well as establishing conditions for polishing of different metals and alloys. Studies on the polishing mechanism have revealed that electropolishing is a diffusion‐controlled process, which takes place at the limiting current, and electropolishing can therefore be treated quantitatively using the theory of mass transfer to the cathodic deposition of metal and metal powder. Some work has been done on the study of electropolishing under forced convection mass transfer conditions. A notable recent investigation involving copper and copper‐based alloys in a stirred cell is due to the study of Gabe and strongly suggests a diffusion‐limited mechanism at low temperature. Fouad et al. studied mass transfer under free convection in the electropolishing of vertical copper electrodes in phosphoric acid.