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The weld region obtained during friction stir welding (FSW) of metallic materials (including aluminum alloys) contains typically well-defined zones, each characterized by fairly unique microstructure and properties. The purpose of this paper is to carry out combined experimental and numerical investigations of the mechanical properties of materials residing in different weld zones of FSW joints of thick AA2139-T8 plates.

Within the experimental investigation, the following has been conducted: first, optical-microscopy characterization of the transverse sections of the FSW joints, in order to help identify and delineate weld zones; second, micro hardness field generation over the same transverse section in order to reconfirm the location and the extent of various weld zones; third, extraction of miniature tensile specimens from different weld zones and their experimental testing; and finally, extraction of a larger size tensile specimen spanning transversely the FSW weld and its testing. Within the computational investigation, an effort was made to: first, validate the mechanical properties obtained using the miniature tensile specimens; and second, demonstrate the need for the use of the miniature tensile specimens.

It is argued that the availability of weld-zone material mechanical properties is critical since: first, these properties are often inferior relative to their base-metal counterparts; second, the width of the weld in thick metallic-armor is often comparable to the armor thickness, and therefore may represent a significant portion of the armor exposed-surface area; and finally, modeling of the weld-material structural response under loading requires the availability of high-fidelity/validated material constitutive models, and the development of such models requires knowledge of the weld-material mechanical properties.

The importance of determining the mechanical properties of the material in different parts of the weld zone with sufficient accuracy is demonstrated.

The purpose of this paper is to understand the effect of four different factors: building orientation, heat treatment (solution annealing and aging), thermal history and process parameters on the mechanical properties and microstructural features of 17-4 precipitation hardening (PH) stainless steel (SS) parts produced using selective laser melting (SLM).

Various sets of test samples were built on a ProX 100™ SLM system under argon environment. Characterization studies were conducted using mechanical tensile and compression test, microhardness test, optical microscopy, X-ray diffraction and scanning electron microscopy.

Results indicate that building orientation has a direct effect on the mechanical properties of SLM parts, as vertically built samples exhibit lower yield and tensile strengths and elongation to failure. Post-SLM heat treatment proved to have positive effects on part strength and hardness, but it resulted in reduced ductility. Longer inter-layer time intervals between the melting of successive layers allow for higher austenite content because of lower cooling rates, thus decreasing material hardness. On the other hand, tensile properties such as elongation to failure, yield strength and tensile strength were not significantly affected by the change in inter-layer time intervals. Similar to other AM processes, SLM process parameters were shown to be instrumental in achieving desirable part properties. It is shown that without careful setting of process parameters, parts with defects (porosity and unmelted powder particles) can be produced.

Although the manufacturing of 17-4 PH SS using SLM has been investigated in the literature, the paper provides the first comprehensive study on the effect of different factors on mechanical properties and microstructure of SLM 17-4 PH. Optimizing process parameters and using heat treatment are shown to improve the properties of the part.

The purpose of this study is to understand the behavior of hybrid bio-composites under varied applications.

Fabrication methods and material characterization of various hybrid bio-composites are analyzed by studying the tensile, impact, flexural and hardness of the same. The natural fiber is a manufactured group of assembly of big or short bundles of fiber to produce one or more layers of flat sheets. The natural fiber-reinforced composite materials offer a wide range of properties that are suitable for many engineering-related fields like aerospace, automotive areas. The main characteristics of natural fiber composites are durability, low cost, low weight, high specific strength and equally good mechanical properties.

The tensile properties like tensile strength and tensile modulus of flax/hemp/sisal/Coir/Palmyra fiber-reinforced composites are majorly dependent on the chemical treatment and catalyst usage with fiber. The flexural properties of flax/hemp/sisal/coir/Palmyra are greatly dependent on fiber orientation and fiber length. Impact properties of flax/hemp/sisal/coir/Palmyra are depended on the fiber content, composition and orientation of various fibers.

This study is a review of various research work done on the natural fiber bio-composites exhibiting the factors to be considered for specific load conditions.

The purpose of this paper is to study the effect of nano hydroxyapatite (HA) and graphene oxide (GO) particles on thermal and mechanical performances of 3D printed poly(ε-caprolactone) (PCL) filaments used in bone tissue engineering (BTE).

Raw materials were prepared by melt blending, followed by 3D printing via 3D Discovery (regenHU Ltd., CH) with all fabricating parameters kept constant. Filaments, including pure PCL, PCL/HA and PCL/GO, were tested under the same conditions. Several techniques were used to mechanically, thermally and microstructurally evaluate properties of these filaments, including differential scanning calorimetry, tensile test, nano indentation and scanning electron microscope.

Results show that both HA and GO nano particles are capable of improving mechanical performance of PCL. Enhanced mechanical properties of PCL/HA result from reinforcing effect of HA, while a different mechanism is observed in PCL/GO, where degree of crystallinity plays an important role. In addition, GO is more efficient at enhancing mechanical performance of PCL compared with HA.

For the first time, a systematic study about effects of nano HA and GO particles on bioactive scaffolds produced by additive manufacturing for BTE applications is conducted in this work. Mechanical and thermal behaviors of each sample, pure PCL, PCL/HA and PCL/GO, are reported, correlated and compared with literature.

This paper aims to study the influence of the binder saturation level on the accuracy and on the mechanical properties of three-dimensional (3D)-printed scaffolds for bone tissue engineering.

To study the influence of the liquid binder volume on the models accuracy, two quality test plates with different macropore sizes were designed and produced. For the mechanical and physical characterisation, cylindrical specimens were used. The models were printed using a calcium phosphate powder, which was characterised in terms of composition, particle size and morphology, by X-ray diffraction (XRD), laser diffraction and Scanning electron microscopy (SEM) analysis. The sample’s physical characterisation was made using the Archimedes method (porosity), SEM, micro-computer tomography (CT) and digital scan techniques, while the mechanical characterisation was performed by means of uniaxial compressive tests. Strength distribution was analysed using a statistical Weibull approach, and the dependence of the compressive strength on the porosity was discussed.

The saturation level is determinant for the structural characteristics, accuracy and strength the models produced by three-dimensional printing (3DP). Samples printed with the highest saturation showed higher compressive strengths (24 MPa), which are over the human trabecular bone. The models printed with lower saturations presented the highest accuracy and pore interconnectivity.

This study allowed to acquire important knowledge concerning the effects of shell/core saturation on the overall performance of the 3DP. With this information it is possible to devise scaffolds with the required properties for bone scaffold engineering.

The literature reveals there is a limited knowledge regarding the extraction of long natural fibers, in particular those extracted from leaves. This investigation aims to present the extraction process and the characterization of long natural cellulose fibers from doum palm leaves (Hyphaene thebaica L.), with properties suitable for polymeric composite materials and textile applications.

The resulting H. thebaica L. fibers were identified using Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The physical properties of the extracted fibers were measured to estimate the reliability of extraction conditions. Mechanical properties were evaluated to determine ultimate strength, Young’s modulus and strain-at-failure of the fibers of the doum leaves.

The following properties of the doum palm are listed in this paper: physical properties of doum palm fibers (H. thebaica L.), TGA, XRD of doum palm fibers, tensile properties of doum palm fibers and surface morphology of doum palm fibers.

Like synthetic fibers, the inclusion of short or long natural fibers into the polymer matrix can increase tensile, flexural and compressive strengths of these matrixes. Compared to the short-length natural fibers, longer-length fibers provide better reinforcements and therefore accord higher performances to the composites. Long fibers can also provide exceptional opportunities to develop a new class of advanced lightweight composites and have the potential to rival glass fiber in the manufacture of composite materials, using matrix materials, such as polypropylene, epoxy and phenolic resins.

The following values are presented in this paper: density of doum palm fibers = 1.14-1.40 g/cm², linear density (Tex) = 33.10 ±11.5, equivalent diameter (µm) = 178.72 ± 41.7, diameter (µm) = 137.02-220.42, tensile strength (MPa) = 124.84-448.10, Young’s modulus (GPa) = 8.06-19.59, strain-at-failure (%) = 0.81-2.86.

The purpose of this paper is to present the review of natural fibre composites as well as a specific type of fibre, i.e., sugar palm fibre and its composites.

The approach of this review paper is to present previous work on natural fibres and their composites. Then a review of several important aspects such as history, origin, botanic description, distribution, application and characterisation of sugar palm tree, and its fibre is presented. Finally a review of properties and characterisation of sugar palm composites is presented.

Findings of this review include the potential application of natural fibres and their composites for engineering application, the use of sugar palm and its fibres, as well as the suitability of sugar palm composites in engineering application after conducting review of their performance and characterisation.

The value of this review is to highlight the potential of natural fibres, natural fibre composites, sugar palm, sugar palm fibres and sugar palm composites as materials for engineering applications.

The purpose of this study is to undertake surface graft copolymerization of viscose fabric via altering its fibrous properties by using acrylic acid (AA) as a carboxyl-containing monomer and peroxydisulfate (PDS) in presence of ferrous sulfate as a novel redox pair for initiating grafting. The latter process acted as an energy-saving process with respect to the reduction in polymerization temperature and maximizing the graft yield %, in addition to rendering the grafted viscose fabrics dye-able with cationic dye (crystal violet), which has frequently no direct affinity to fix on fabric.

To make graft copolymerization more efficient and economic, the optimum conditions for graft copolymerization were established. The graft yield % was determined as a function of initiator, catalyst and monomer concentrations and the material to liquor ratio, in addition to polymerization time and temperatures. Metrological characterizations via Fourier transform infrared spectroscopy and scanning electron microscopy of topographic morphological surface change have also been established in comparison with the ungrafted samples.

The maximum graft yield of 70.6% is obtained at the following optimum conditions: monomer (150 % based on the weight of fabric), PDS (50 m mole), ferrous sulfate (80 m mole) and sulfuric acid (30 m mole) at 40° C for 1.5 h using a liquor ratio of 30. Remarkably, grafting with AA enabled a multifold upsurge in color strength, with improvements in the fastness properties of cationically dyed grafted viscose fabric measured on the blue scale in comparison with untreated viscose fabric.

The novelty addressed here is undertaken with studying the effect of altering the extent of grafting of poly (AA)-viscose graft copolymers expressed as graft yield % in addition to carboxyl contents on cationic dyeing of viscose fabric for the first time in the literature. Moreover, rendering the viscose fabrics after grafting is dye-able with cationic dye with high brilliance of shades, which has regularly no direct affinity to fix on this type of fabrics.

In this study, two novel fluorescent dyes, based on naphthalimide derivatives have been synthesised from acenaphthene as a starting material. The ability of the dyes to graft to polymer chain was then demonstrated. The novel synthesised dyes and self-coloured polymers were characterised by a variety of techniques.

The novel dyes were prepared through by halogenation, oxidation, imidation and amination reactions. All steps of these processes were monitored by thin layer chromatography. The fluorescent dyes and their intermediates were characterised by differential scanning calorimeter, fourier transform infrared spectroscopy (FTIR), Proton Nuclear Magnetic Resonance (1H-NMR) and carbon-13 nuclear magnetic resonance (13-CNMR) spectroscopic techniques. The molar extinction coefficients and absorption maximum wavelength were obtained by examining the dyes and polymer solutions in Dimethylformamide (DMF) and toluene solvents. The fluorescency of novel dyes and self-coloured polymers was evaluated. Their quantum yields and Stokes shift values were determined as DMF and toluene solutions. The percentage of the covalently bounded dyes into the polymer chain was calculated.

The characterisation of the synthesised dyes and self-coloured polymers verified their structural correctness. The results of reaction dyes with resin demonstrated that the dyes were covalently bonded to the chain of an acrylic polymer (resin) containing carboxylic acid groups giving self-coloured polymers. The extent of fluorescence of the synthesised dyes and their polymers showed that compounds containing functional amino group in C-4 position of naphthalimide ring have high fluorescence properties.

This study is original. Self-coloured polymers based on acrylic were synthesised by novel naphthalimide dyes with acrylic resin for the first time, successfully. The novel dyes and their self-coloured polymers exhibit good and acceptable fluorescent activity.

The purpose of this paper is to report the preparation and characterisation of nanocomposites, which are made of biodegradable poly(vinyl‐alcohol‐co‐ethylene) and wood dust. These nanocomposites can aptly be termed as green by nature as they are totally non‐toxic and ecofriendly.

Sample films containing 5, 10 and 15 wt% fillers are prepared by conventional solvent casting technique using glass plates as casting surfaces. The dispersion of filler in the polymer matrix is investigated by transmission electron microscope (TEM) analysis. Physical and chemical properties of the films are studied by various characterisation techniques (FTIR, X‐ray diffraction (XRD), TEM and TGA).

TEM analysis reveals that the average particle size of the nanodispersed filler in the nanocomposite materials is in the range of 12‐25 nm, which shows that a greater extent of matrix penetrated into fibre capillaries of wood dust. These results are supported by the XRD findings also. Wood enhances the thermal stability of the as synthesised nanocomposites.

The mechanical properties of the as synthesised nanocomposites can be improved further by modifying wood dust.

The method developed provides a simple and practical solution to improve the biodegradability, as well as the thermal stability of the composite films.

The nanocomposites so developed can be used in automotive parts like front door liners, boot liners, parcel shelves, headliners, etc. also as mulching films in agriculture.