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Article
Publication date: 22 October 2018

Kh.M. Mostafa, Heba Ameen, Mahmoud Morsy, Amal El-Ebissy, Mohamed Adel and Ali Salah

This study aims to explore the incorporation of starch nanoparticles (SNPs) in cross-linking formulation of cotton fabrics to see their impact on fabric performance like tensile…

Abstract

Purpose

This study aims to explore the incorporation of starch nanoparticles (SNPs) in cross-linking formulation of cotton fabrics to see their impact on fabric performance like tensile strength, dry wrinkle recovery angles, elongation at break, degree of whiteness and increase in weight as well as durability.

Design/methodology/approach

SNPs of size around 80-100 nm were successfully prepared from native maize starch by Nano precipitation technique and confirmed instrumentally by scanning electron microscope (SEM), transmittance electron microscope (TEM), Fourier transformer infrared (FTIR) spectroscopy and particle size analyzer. The latter were incorporated in cross-linking formulation of cotton fabrics encompassing different concentrations of citric acid and sodium hypophosphite at different curing time and temperature in 100 ml distilled water to a wet pickup of ca. 85 per cent. The fabric samples were dried for 3 min at 85°C and cured at specified temperatures for a specified time intervals in thermo fixing oven according to pad-dry-cure method.

Findings

FTIR spectra and SEM micrograph signified the chemical structure and surface morphology of cotton fabric before and after finishing in absence and presence of SNPs. Cotton fabric samples finished in presence of SNPs showed a higher tensile strength, elongation at break, comparable dry wrinkle recovery angles and degree of whiteness than that finished in their absence. On the other hand, the enhancement in the aforementioned performance reflects the positive impact of incorporation of SNPs in textile finishing especially with strength properties; which are one of the important requirements for industrial fabrics that can be used widely in heavy-duty applications.

Research limitations/implications

SNPs with its booming effect with respect to biodegradability, reactivity and higher surface area can be used as a novel reinforcement permanent finish for cotton fabrics instead of more hazardous materials likes poly acrylate and monomeric compounds.

Practical implications

As SNPs biopolymers is one of the important reinforcement agents, so it was expected that it would minimize the great loss in strength properties during easy-care cotton finishing and improve the fabric performance.

Originality/value

The novelty addressed here is undertaken with a view to remediate some of the serious defects of easy-care cotton fabrics using poly carboxylic acids; especially with the great loss in strength properties by virtue of using SNPs as a permanent finish. Besides, to the authors’ knowledge, there is no published work so far concerning the use of SNPs as an innovative base for production of easy-care finished cotton textiles with high performance.

Article
Publication date: 1 February 2013

Kh. M. Mostafa and A. A. El-Sanabary

Several research and developmental work attempts have been made in this manuscript to synthesize what is called tailored polymeric materials with new characteristics based on…

Abstract

Several research and developmental work attempts have been made in this manuscript to synthesize what is called tailored polymeric materials with new characteristics based on pregelled starch through a number of processes which, in turn, entail several chemical treatments. This is done by subjecting pregelled starch as a starting substrate to acid hydrolysis to obtain different molecular sizes. Pregelled starch with different molecular sizes are carbamoylethylated by using acrylamide and sodium hydroxide at different durations, then grafted with different monomers by using a potassium permanganate/citric acid redox system to initiate grafting. Furthermore, application of the newly tailored pregelled starch derived products as a sizing agent of cotton textiles is systematically studied. It is shown from the data that (a) the extent of carbamoylethylation expressed as N% increases by increasing the extent of hydrolysis and duration; (b) the graft yield expressed as mmol. monomer/100 g sample of different monomers onto carbamoylethylated and carbamoylethylated hydrolyzed pregelled starches increases by increasing the extent of carbamoylethylation and degree of hydrolysis, and follows the order: methacrylamide (MAam) > methacrylonitrile (MAN) > methacrylic acid (MAA), and (c) cotton fabrics sized with grafted carbamoylethylated hydrolyzed pregelled starch acquire higher mechanical properties, i.e. TS, elongation at break, and abrasion resistance values than hydrolyzed, carbamoylethylated and carbamoylethylated hydrolyzed pregelled starches. Finally, the use of the above tailored modified pregelled starch derived products in the sizing of cotton textiles contribute to reinforcement of the cotton textile after sizing to overcome the forced loss in fabrics/yarns during the spinning process as shown above.

Details

Research Journal of Textile and Apparel, vol. 17 no. 1
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 1 March 2024

Khaled Mostafa and Azza El-Sanabary

The novelty addressed here is undertaken by using tailor-made and fully characterized starch nanoparticles (SNPs) having a particle size ranging from 80 to 100 nm with a larger…

Abstract

Purpose

The novelty addressed here is undertaken by using tailor-made and fully characterized starch nanoparticles (SNPs) having a particle size ranging from 80 to 100 nm with a larger surface area, biodegradability and high reactivity as a starting substrate for cadmium ions and basic dye removal from wastewater effluent. This was done via carboxylation of SNPs with citric acid via esterification reaction using the dry preparation technique, in which a simple, energy-safe and sustainable process concerning a small amount of water, energy and toxic chemicals was used. The obtained adsorbent is designated as cross-linked esterified starch nanoparticles (CESNPs).

Design/methodology/approach

The batch technique was used to determine the CESNPs adsorption capacity, whereas atomic adsorption spectrometry was used to determine the residual cadmium ions concentration in the filtrate before and after adsorption. Different factors affecting adsorption were examined concerning pH, contact time, adsorbent dose and degree of carboxylation. Besides, to validate the esterification reaction and existence of carboxylic groups in the adsorbent, CESNPs were characterized metrologically via analytical tools for carboxyl content estimation and instrumental tools using Fourier-transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM) morphological analysis.

Findings

The overall adsorption potential of CESNPs was found to be 136 mg/g when a 0.1 g adsorbent dose having 190.8 meq/100 g sample carboxyl content at pH 5 for 60 min contact time was used. Besides, increasing the degree of carboxylation of the CESNPs expressed as carboxyl content would lead to the higher adsorption capacity of cadmium ions. FTIR spectroscopy analysis elucidates the esterification reaction with the appearance of a new intense peak C=O ester at 1,700 cm−1, whereas SEM observations reveal some atomic/molecules disorder after esterification.

Originality/value

The innovation addressed here is undertaken by studying the consequence of altering the extent of carboxylation reaction expressed as carboxyl contents on the prepared CESNPs via a simple dry technique with a small amount of water, energy and toxic chemicals that were used as a sustainable bio nano polymer for cadmium ions and basic dye removal from wastewater effluent in comparison with other counterparts published in the literature.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 March 2023

Khaled Mostafa, Heba Ameen, Amal El-Ebeisy and Azza El-Sanabary

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a…

42

Abstract

Purpose

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate for copper ions removal from wastewater effluent after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

Design/methodology/approach

The calorimetric sensor batch technique was used to determine the resin's adsorption capacity, while atomic adsorption spectrometry was used to determine the residual copper ions concentration in the filtrate before and after adsorption. This was done to convert the copolymer's abundant nitrile groups into amidoxime groups, and the resulting poly (amidoxime) resin was used as a copper ion adsorbent. To validate the existence of amidoxime groups, the resin was qualitatively characterized using a rapid vanadium ion test and instrumentally using Fourier transform infrared spectroscopy spectra and scanning electron microscopy morphological analysis.

Findings

At pH 7, 400 ppm copper ions concentration and 0.25 g adsorbent at room temperature, the overall adsorption potential of poly (amidoxime) resin was found to be 115.2 mg/g. The process's adsorption, kinetics and isothermal analysis were examined using various variables such as pH, contact time, copper ion concentration and adsorbent dose. To pretend the adsorption kinetics, various kinetics models, including pseudo-first-order and pseudo-second-order, were applied to the experimental results. The kinetic analysis indicated that the pseudo-second-order rate equation promoted the development of the chemisorption phase better than the pseudo-first-order rate equation. In the case of isothermal investigations, a study of observed correlation coefficient (R2) values indicated that the Langmuir model outperformed the Freundlich model in terms of matching experimental data.

Originality/value

To the best of the author's information, there is no comprehensive study for copper ions removal from waste water effluent using the recently tailored and fully characterized poly (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 17 February 2023

Khaled Mostafa, Mohamed Ramadan and Azza El-Sanabary

The purpose of this study is to investigate the authors' previously prepared and fully characterized poly (methacrylamide)-chitosan nanoparticles (CNPs) graft copolymer having…

Abstract

Purpose

The purpose of this study is to investigate the authors' previously prepared and fully characterized poly (methacrylamide)-chitosan nanoparticles (CNPs) graft copolymer having 50.2% graft yield with respect to flocculation efficiency for ferric laurate aqueous dispersions. This was done to compare the ability of the latter cheap, biodegradable and ecofriendly hybrid natural-synthetic polymeric substrate as a flocculant in comparison with higher cost, nonbiodegradable and harmful polyacrylamide as a well-known synthetic flocculant counterpart.

Design/methodology/approach

The graft copolymerization process was carried out at 450°Cfor 120 min using (1.0 g) CNPs, methacrylamide (1.5 g), 100 mmol/l potassium chromate and 80 mmol/l mandelic acid. Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis and specific viscosity were used to characterize and analyze the resultant copolymer. The flocculation efficiency was conferred in terms of transmittance % and weight removal %. The main factors influencing the flocculation process, such as flocculent dose, flocculation medium pH, stirring speed, flocculation temperature and grafting extent, were comprehensively discussed.

Findings

The flocculation efficiency of the prepared copolymers revealed the following findings: increased by increasing the flocculant dose, pH, temperature and stirring speed to a maximum values denoted at 30 ppm, 6.0, 30°C and 50 r/min, respectively, then decreased thereafter; increased by increasing the extent of grafting within the range studied; showed a comparable flocculation efficiency in comparison with polyacrylamide as a synthetic polymeric flocculent; and, finally, a preliminary bridging mechanism representing the attraction between the anionic suspended particles ferric laurate and cationic poly (MAam)-CNPs graft copolymer has been projected.

Originality/value

The advancement addressed here is undertaken with using the authors’ poly (MAam)-CNPs graft copolymers having different extent of grafting (a point which is not cited in the literature especially for the authors’ prepared copolymer) as a hybrid natural-synthetic polymeric substrate as a flocculant for ferric laurate aqueous dispersions in comparison with the high cost and nondegradable polyacrylamide synthetic flocculant.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 January 2014

Padma S. Vankar and Rama Shanker Sahu

A graft copolymer (PBW-g-PAM) of Moringa seed was prepared. The phosphate buffer washed seed powder and polyacrylamide were reacted, using ceric ion initiator. The grafted…

Abstract

Purpose

A graft copolymer (PBW-g-PAM) of Moringa seed was prepared. The phosphate buffer washed seed powder and polyacrylamide were reacted, using ceric ion initiator. The grafted copolymer was tested for its efficiency for metal removal (Cr-VI) from tannery effluent and for color removal from textile effluent using standard spectroscopic methods. The paper aims to discuss these issues.

Design/methodology/approach

The PBW-g-PAM was prepared by standard method and characterized by FT-IR, SEM, UV-vis, XRD and DSC/TGA analyses.

Findings

The effects of PBW-g-PAM dose, contact time and pH on percent removal of Cr-VI and dye color, have been reported.

Originality/value

The efficiency of metal removal was shown to be 99 per cent in just 15 min. Similar results were obtained for efficient color removal from textile effluents. It is for the first time that graft polymer of Moringa seed has been used for metal and color removal.

Details

Pigment & Resin Technology, vol. 43 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 July 2023

Khaled Mostafa, Nader Abdelaziz and Azza El-Sanabary

The purpose of this study is to undertake surface graft copolymerization of viscose fabric via altering its fibrous properties by using acrylic acid (AA) as a carboxyl-containing…

Abstract

Purpose

The purpose of this study is to undertake surface graft copolymerization of viscose fabric via altering its fibrous properties by using acrylic acid (AA) as a carboxyl-containing monomer and peroxydisulfate (PDS) in presence of ferrous sulfate as a novel redox pair for initiating grafting. The latter process acted as an energy-saving process with respect to the reduction in polymerization temperature and maximizing the graft yield %, in addition to rendering the grafted viscose fabrics dye-able with cationic dye (crystal violet), which has frequently no direct affinity to fix on fabric.

Design/methodology/approach

To make graft copolymerization more efficient and economic, the optimum conditions for graft copolymerization were established. The graft yield % was determined as a function of initiator, catalyst and monomer concentrations and the material to liquor ratio, in addition to polymerization time and temperatures. Metrological characterizations via Fourier transform infrared spectroscopy and scanning electron microscopy of topographic morphological surface change have also been established in comparison with the ungrafted samples.

Findings

The maximum graft yield of 70.6% is obtained at the following optimum conditions: monomer (150 % based on the weight of fabric), PDS (50 m mole), ferrous sulfate (80 m mole) and sulfuric acid (30 m mole) at 40° C for 1.5 h using a liquor ratio of 30. Remarkably, grafting with AA enabled a multifold upsurge in color strength, with improvements in the fastness properties of cationically dyed grafted viscose fabric measured on the blue scale in comparison with untreated viscose fabric.

Originality/value

The novelty addressed here is undertaken with studying the effect of altering the extent of grafting of poly (AA)-viscose graft copolymers expressed as graft yield % in addition to carboxyl contents on cationic dyeing of viscose fabric for the first time in the literature. Moreover, rendering the viscose fabrics after grafting is dye-able with cationic dye with high brilliance of shades, which has regularly no direct affinity to fix on this type of fabrics.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 23 February 2022

Khaled Mostafa

This paper aims to study previously prepared and fully characterized chitosan nanoparticles (CNPs) as a starting substrate and microwave initiation technique for grafting acrylic…

Abstract

Purpose

This paper aims to study previously prepared and fully characterized chitosan nanoparticles (CNPs) as a starting substrate and microwave initiation technique for grafting acrylic acid (AA). This was done to see the influence of both CNPs with respect to well-dispersed nanosized particles, large surface areas, biodegradability, biocompatibility and reactivity and microwave initiation technique with respect to reduction in organic solvents, toxic chemical initiator and exposer time on exploiting the graft yield % and enhancing water solubility and antibacterial properties.

Design/methodology/approach

For evaluating the best accurate standard metrological method for calculating the graft yield %, the grafting parameters were stated in terms of graft yield percent and measured gravimetrically (based on dry weight method) and titrimetrically (based on carboxyl content). Microwave power, AA and CNPs concentrations and reaction duration were shown to be the most important parameters influencing the grafting process.

Findings

The optimum reaction conditions were obtained when CNPs 1.5 g, AA 150 bows, microwave irradiation power 500 W and reaction duration 120 s were used. Various analytical methods were used to characterize CNPs and poly(AA)–CNPs graft copolymers. According to the findings, Fourier transform infrared spectroscopy examination determines the attachment of carboxyl groups to CNPs chains. The thermogravimetric analysis revealed that the copolymers were more thermally stable than CNPs counterparts. Furthermore, the resulting copolymers were shown to have greater water solubility biodegradability resistance and antibacterial properties than CNPs counterpart. Finally, a preliminary mechanism demonstrating all occasions that occur during the polymerization reaction has been proposed.

Originality/value

The advancement addressed here is undertaken using previously prepared and fully characterized CNPs as a green bio-nanocompatible polymer and microwave initiation technique as green and efficient tool with respect to reduction in organic solvents toxic chemical initiator and exposer time for grafting AA.

Details

Pigment & Resin Technology, vol. 52 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 December 2021

Khaled Mostafa

This paper aims at studying the oxygen plasma treatment and the previously prepared and fully characterized chitosan nanoparticles (CNPs) as a green and eco-friendly strategy for…

Abstract

Purpose

This paper aims at studying the oxygen plasma treatment and the previously prepared and fully characterized chitosan nanoparticles (CNPs) as a green and eco-friendly strategy for surface modification of viscose fabric. This was done to render viscose fabric dye able with two types of acid dyes that do not have direct affinity to fix on it via improving the fabric wettability.

Design/methodology/approach

To achieve the goal, viscose fabric was activated with oxygen plasma at optimum conditions and coated with different concentrations of CNPs solution via conventional pad dry cure technique. The untreated and plasma-treated fabrics with CNPs were dyed with two types of acid dyes, namely, Acid Orange 7 and Methyl Red under determined conditions. The color strength (K/S), fastness properties to light, rubbing and perspiration, add on %, tensile strength, wettability and durability of the dyed samples were determined and compared.

Findings

The results divulged that oxygen plasma-treated fabric with CNPs and the aforementioned dyes in question could improve the flowing properties in comparison with untreated fabric: (a) the fabric wettability expressed as wetting area mm2; (b) the dye ability and fastness properties of viscose fabrics expressed as K/S and fastness properties; and (c) the strength properties and add on % of the treated fabric. On the other hand, the durability of the plasma-treated fabric decreased with increasing washing cycles.

Originality/value

The novelty addressed here was using plasma treatment as an eco-friendly pre-treatment approach for attachment of CNPs as a multifunctional green bio-nano polymer onto viscose fabric, which improved the dyeing properties of the fabric with acid dyes that do not have direct affinity to fix onto it.

Details

Pigment & Resin Technology, vol. 52 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 December 2022

Khaled Mostafa, Heba Ameen and Ahmed Medhat

The purpose of this paper is to generate nitrogen-containing groups in the cotton fabric surface via low-temperature nitrogen plasma as an eco-friendly physical/zero-effluent…

Abstract

Purpose

The purpose of this paper is to generate nitrogen-containing groups in the cotton fabric surface via low-temperature nitrogen plasma as an eco-friendly physical/zero-effluent process. This was done for rendering cotton dye-able with Acid Blue 284, which in fact does not have any direct affinity to fix on it.

Design/methodology/approach

Dyeing characteristics of the samples such as color strength (K/S), fastness properties to light, rubbing and perspiration and durability, as well as tensile strength, elongation at break, whiteness, weight loss and wettability in addition to zeta potential of the dyed samples, were determined and compared with untreated fabric. Confirmation and characterization of the plasma-treated samples via chemical modifications and zeta potential was also studied using Fourier transform infrared spectroscopy (FTIR) and Malvern Zetasizer instrumental analysis.

Findings

The obtained results of the plasma-treated fabric reflect the following findings: FTIR results indicate the formation of nitrogen-containing groups on cotton fabrics; notable enhancement in the fabric wettability, zeta potential to more positive values and improvement in the dyeability and overall fastness properties of treated cotton fabrics in comparison with untreated fabric; the tensile strength, elongation at break, whiteness and weight % of the plasma treated fabrics are lower than that untreated one; and the durability of the plasma treated fabric decreased with increasing the number of washing cycles.

Originality/value

The novelty addressed here is rendering cotton fabrics dye-able with acid dye via the creation of new cationic nitrogen-containing groups on their surface via nitrogen plasma treatment as an eco-friendly and efficient tool with a physical/zero-effluent process.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

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