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This study aims to optimise the effect of pre-oxidation on hot corrosion behaviour of Tribaloy T-900 at 900 °C in mixed Na₂SO₄ and K₂SO₄.

Prior to hot corrosion experiment, pre-oxidation treatments were carried in ambient air at 900 °C for 1, 5 and 10 h, respectively. The hot corrosion experiments were performed in a box type furnace at 900 °C. Both surfaces of specimens were brushed with saturated salt solution of 75 wt.% Na₂SO₄ + 25 wt.% K₂SO₄. After brushing, the salt-coated specimens were placed in electric stove to ensure drying of salt. After drying, presence of 3 mg/cm² salt on specimen’s surface was ensured through weighting.

The 1-h pre-oxidation treatment prior to hot corrosion showed superior hot corrosion resistance against molten salt attack. An optimum pre-oxidation time of 1 h helped timely formation of protective Cr₂O₃ layer and inhibited the formation of less stable and porous surface oxides of Ni and Mo during hot corrosion.

Pre-oxidation effect on hot corrosion behaviour of refractory metal (such as Mo in investigated alloy) containing alloy has never been reported previously. Refractory metals oxide (e.g. MoO3) could transform the corrosion phenomena to catastrophic failure through acidic fluxing.

The purpose of this study was to investigate the tribological properties of bulk Fe₂B with pre-oxidation treatment.

Bulk Fe₂B was oxidized in an electric box furnace with a soaking time of 9 min under 750°C in air. Then, the tribological experiments were carried out on an UMT-Tribolab tester.

The oxide layer was composed of Fe, Fe₂O₃, Fe₃O₄, B₂O₃ and H₃BO₃. The oxidative direction of bulk Fe₂B was perpendicular to the sample surface. But, the oxidative direction of Fe₂B crystals was irregular. At 0.1 m/s, the friction coefficient was the lowest. The effects of shortening the running-in period of friction and reducing the friction coefficient by pre-oxidation treatment at 0.1 m/s were remarkable. Nevertheless, the effect of pre-oxidation treatment was futile at 0.2 m/s. Wear mechanisms of oxidized Fe₂B mainly were adhesive and abrasive wear.

The effects of shortening the running-in period of friction and reducing the friction coefficient by pre-oxidation treatment were remarkable.

The purpose of this study is to improve the performance of AISI 430 stainless steel (430 SS) in increasing its oxidation resistance, suppressing coating spalling and cracking, sustaining appropriate conductivity and blocking Cr evaporation as an interconnect material for intermediate temperature solid oxide fuel cells; a protective co-contained coating is formed onto stainless steel via the surface alloying process and followed by thermal oxidation.

In this work, oxidation behavior of coated specimen is studied during isothermal and cyclic oxidation measurements. Moreover, the conductivity is also investigated by area specific resistance (ASR) measurement.

Co-contained spinel layer shows an outstanding performance in preventing oxidation and improving conductivity compared with uncoated specimens. The protective spinel coating also reduces the ASR for coated specimen (0.0576O cm²) as compared to the uncoated specimen (1.87296O cm²) after isothermal oxidation.

The probable mechanism of co-contained alloy converting into spinel and the spinel transfer electron is presented.

The term microbiologically induced corrosion (MIC) appears to be very closely related to the composition of the bio‐film which harbours the micro‐organism. Formation of an initial slimy layer on immersed metallic substrates is the rate‐controlling parameter of bio‐fouling, as uninterrupted undesirable growth of bio‐films occurs over this layer. To contain this bio‐film problem, formation of an adherent layer of toxic and inhibited corrosion product, that interacts with biofilm, could be exploited. Deals with the preliminary interactions of a few copper‐based alloys, with mildly toxic alkaloid class‐inhibitive compounds, in a simulated marine environment. It is assumed that the toxic and inhibited corrosion product and bio‐film interaction layer will interfere with the formation of the initial slimy cover on the immersed surface, responsible for bio‐fouling. It is seen that these alkaloid compounds exert a limited response on the inhibition of copper‐based alloys like monel. Brucine appears to be a more effective inhibitor for the monel surface. Pre‐oxidation of the uninhibited brass surface and also post‐oxidation of the inhibited surface appear to consolidate the corrosion product bio‐film‐inhibitor interaction layers, indicating the compatibility of these alkaloid compounds to the probable thermal strains to be encountered in engineering services. This indicates the possibility of using these compounds in heat transfer devices, like heat exchangers, where seawater is used as coolant.

The purpose of this paper is to prepare a spherical modifier-modified activated carbon fiber of high specific capacitance intended for electrode materials of supercapacitor.

In this study, phenolic-based microspheres are taken as modifiers to prepare PAN-based fiber composites by electrospinning, pre-oxidation and carbonization. Pearl-chain structures appear in RFC/ACF composites, and pure polyacrylonitrile fibers show a dense network. The shape and cross-linking degree are large. After the addition of the phenolic-based microspheres, the composite material exhibits a layered pearlite chain structure with a large porosity, and the RFC/ACF composite material is derived because of the existence of a large number of bead chain structures in the composite material. The density increases, the volume declines and the mass after being assembled into a supercapacitor as a positive electrode material decreases. The specific surface area of RFC/ACF composites is increased as compared to pure fibers. The increase in specific surface area could facilitate the diffusion of electrolyte ions in the material. Owing to the large number of bead chains, plenty of pore channels are provided for the diffusion of electrolyte ions, which is conducive to enhancing the electrochemical performance of the composite and improving the RFC/ACF composite and the specific capacitance of the material. The methods of electrochemical testing on symmetric supercapacitors (as positive electrodes) are three-electrode cyclic voltammetry, alternating current impedance and cycle stability.

The specific capacitance value of the composite material was found to be 389.2 F/g, and the specific capacitance of the electrode operating at a higher current density of 20 mA/cm2 was 11.87 F/g (the amount of the microsphere modifier added was 0.3 g). Using this material as a positive electrode to assemble into asymmetrical supercapacitor, after 2,000 cycles, the specific capacitance retention rate was 87.46 per cent, indicating excellent cycle stability performance. This result can be attributed to the fact that the modifier embedded in the fiber changes the porosity between the fibers, while improving the utilization of the carbon fibers and making it easier for electrolyte ions to enter the interior of the composites, thereby increasing the capacitance of the composites.

The modified PAN-based activated carbon fibers in the study had high specific surface area and significantly high specific capacitance, which makes it applicable as an efficient and environment-friendly absorbent, as well as an advanced electrode material for supercapacitor.

The contamination of groundwater by natural arsenic is currently a worldwide epidemic. Arsenic-contaminated groundwater has been reported in Argentina, Chile, Mexico, China, Hungary, West Bengal in India, Bangladesh, and Vietnam. Of these regions, Bangladesh and West Bengal are the most seriously affected in terms of the size of the population at risk and magnitude of health problems. Hence, chronic exposure to arsenic >50′′μg/L in drinking water can result in serious health problems. Common symptoms of arsenic-related ailments are skin, cardiovascular, renal, hematological, and respiratory disorders. Therefore, this chapter focuses on nature, origin, and extent of groundwater arsenic contamination, probable causes, and its impacts on food, drinking water, and social coverage. It further discloses mitigation approaches proposed and practiced by the different research groups to combat this problem and finally concludes.

The purpose of this paper is to prepare a new modified activated carbon fibers (ACFs) of high specific capacitance used for electrode material of supercapacitor.

In this study, the specific capacitance of ACF was significantly increased by using the phenolic resin microspheres and melamine as modifiers to prepare modified PAN-based activated carbon fibers (MACFs) via electrospinning, pre-oxidation and carbonization. The symmetrical supercapacitor (using MACF as electrode) and hybrid supercapacitor (using MACF and activated carbon as electrodes) were tested in term of electrochemical properties by cyclic voltammetry, AC impedance and cycle stability test.

It was found that the specific capacitance value of the modified fibers were increased to 167 Fg^-1 by adding modifiers (i.e. 20 wt.% microspheres and 15 wt.% melamine) compared to that of unmodified fibers (86.17 Fg^-1). Specific capacitance of modified electrode material had little degradation over 10,000 cycles. This result can be attributed to that the modifiers embedded into the fibers changed the original morphology and enhanced the specific surface area of the fibers.

The modified ACFs in our study had high specific surface area and significantly high specific capacitance, which can be applied as efficient and environmental absorbent, and advanced electrode material of supercapacitor.

This paper represents an analytical study conducted in the laboratory. The purpose of this paper is to monitor changes of some parameters related to water treatment in Hamman Bebagh (Bouhamdane Watershed).

This study was focused on three sites: river water, dam water and treated water during the first six months of 2014 (January-June). It included 16 physico-chemical parameters (PH, T, conductivity, etc.) and two bacteriological (E. coli, fecal streptococci). These parameters were analyzed to make a comparison between stagnant dam water (before and after treatment) and river water.

The obtained results over the whole period of analysis indicated that treated dam water was less loaded with organic materials, solids, dissolved salts (Cl⁻, Ca²⁺, and Mg²⁺) that were deposited at the bottom of the dam than dam water before treatment. On the other hand, river water was found to be more charged of suspended matter than the dam water and the treated water since flowing water carried all materials in its course. In terms of bacteriological quality, treated water was found to be free from all traces of bacteria analyzed that were present in the dam and the river before the treatment.

This study was proposed in order to see if it is necessary to establish a second treatment plant in the medium term. On the basis of this analysis, the end results have shown that the treatment plant was effective enough to reach the desired goal (treated water which respects the norms of OMS).

ALUMINIUM coated steel was first introduced as a commercial product in the mid‐nineteen thirties. Its growth and development was comparatively slow until 1950, but since then the use of aluminium coatings has rapidly expanded. There have been numerous attempts to develop quality aluminium coatings commercially, and considerable research and development is in progress. The more important processes are:

A historical review of the development of metal‐cored substrates is given, together with a detailed account of glass‐ceramic coated metal substrates as currently manufactured by Wade plc. The advantages over monolithic ceramics are discussed, and an indication is given as to future developments in this technology.