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Personal thermal management in functional textiles is in increasing demand for health care, outdoor activity and energy saving. Thus, developing new strategies is highly desired for radiative cooling and/or heating by manipulation of the transmissivity, reflectivity and absorptivity of the textiles within solar energy and human body heat radiation ranges.

Inorganic additives including TiO2, Fe2O3, carbon black (CB), graphene and mica were incorporated into polymer films. The inorganic additives' full spectrum properties and thermal responses were comprehensively investigated.

The CB composite film showed the highest absorptivity over the full solar to human body radiation spectrum. The mica-white (mica-w) (mica coated with TiO2) and mica-red (mica-r) (mica coated with Fe2O3) composites showed the lowest solar energy absorptivity and a strong body heat radiation reflectivity. Furthermore, according to composites' thermal responses to the simulated solar and human body radiations, CB and mica are promising for both cooling and heating when applied in dual-functional thermal management textiles.

Research has limitation related the amount of additives which can be added to textile. When powder is added to polyester yarn, the amount is limited by 2–3%. When powder is added to the composite which is used for printing, the amount of powder is limited by 5%.

A lot of apparel, especially sport apparel, contains prints. Decoration is one part of print application. Now, a lot of companies work under development of different additives, which provide additional properties to apparel. The closest targets for powder added to prints are cooling and heat retention. Quite often, inorganic additives possess dual properties: the inorganic additives may be heat reflective which his needed for heat retention, but may have high-thermal conductivity, which works well for cooling. Human body has complicated mechanism of heat exchange: convection, radiation and moisture evaporations play main role. The same additive may be cooling if there is a contact with skin but may be heating (IR reflective) if placed in the second or third layer. Thus, effect is needed to be studied first before real application.

This work could provide a comprehensive guideline for the rational design and application of thermal management composite textile materials by revealing the full solar to human body radiation performance of a series of inorganic materials.

Rapid prototyping (RP) technology has been widely applied in biomedical research. The purpose of this paper is to describe how a scaffold composite drug delivery system (DDS) was fabricated using a nano composite deposition system (NCDS).

A biocompatible and biodegradable thermoplastic polymer (poly(DL‐lactide‐co‐glycolide acid)) was used as the matrix, and a mixture of anti‐cancer drug (5‐fluorouracil) and bio‐ceramic (hydroxyapatite – HA) was added to the polymer to form a bio‐composite material for the DDS. An in vitro drug release test showed that the release rate of the drug composite could be controlled by the amount of HA for 50 days.

Faster release was observed for the DDS with higher weight percent of HA. The relationship between release rate and the amount of HA showed a bi‐linear manner, and bi‐linear drug release models were developed based on the experimental results.

Cylindrical scaffolds were fabricated with polymer/drug/additive using an NCDS. A series of in vitro drug release tests was performed to evaluate the effectiveness of the additive, HA. Drug release models were developed based on the experimental results.

Composite cellular structures have wide application in advanced engineering fields due to their high specific stiffness and strength. As an emerging technology, continuous fiber-reinforced polymer additive manufacturing provides a cost-effective solution for fabricating composite cellular structures with complex designs. However, the corresponding path planning methods are case-specific and have not considered any manufacturing constraints. This study aims to develop a generally applicable path planning method to fill the above research gap.

This study proposes a path planning method based on the graph theory, yielding an infill toolpath with a minimum fiber cutting frequency, printing time and total turning angle. More specifically, the cellular structure design is converted to a graph first. Then, the graph is modified to search an Eulerian path by adding an optimal set of extra edges determined through the integer linear programming method. Finally, the toolpath with minimum total turning angle is obtained with a constrained Euler path search algorithm.

The effectiveness of the proposed method is validated through the fabrication of both periodic and nonperiodic composite cellular structures, i.e. triangular unit cell-based, Voronoi diagram-based and topology optimized structures. The proposed method provides the basis for manufacturing planar thin-walled cellular structures of continuous fiber-reinforced polymer (CFRP). Moreover, the proposed method shows a notable improvement compared with the existing method. The fiber cutting frequency, printing time and total turning angle have been reduced up to 88.7%, 52.6% and 65.5%, respectively.

A generally applicable path planning method is developed to generate continuous toolpaths for fabricating cellular structures in CFRP-additive manufacturing, which is an emerging technology. More importantly, manufacturing constraints such as fiber cutting frequency, printing time and total turning angle of fibers are considered within the process planning for the first time.

X-Ray-computed micro-tomography (micro-CT) is relatively well established in additive manufacturing as a method to determine the porosity and geometry of printed parts and, in some cases, the presence of inclusions or contamination. This paper aims to demonstrate that micro-CT can also be used to quantitatively analyse the homogeneity of micro-composite parts, in this case created using laser sintering (LS).

LS specimens were manufactured in polyamide 12 with and without incorporation of a silver phosphate glass additive in different sizes. The specimens were scanned using micro-CT to characterise both their porosity and the homogeneity of dispersion of the additive throughout the volume.

This work showed that it was possible to use micro-CT to determine information related to both porosity and additive dispersion from the same scan. Analysis of the pores revealed the overall porosity of the printed parts, with linear elastic fracture mechanics used to identify any pores likely to lead to premature failure of the parts. Analysis of the additive was found to be possible above a certain size of particle, with the size distribution used to identify any agglomeration of the silver phosphate glass. The particle positions were also used to determine the complete spatial randomness of the additive as a quantitative measure of the dispersion.

This shows that micro-CT is an effective method of identifying both porosity and additive agglomeration within printed parts, meaning it can be used for quality control of micro-composites and to validate the homogeneity of the polymer/additive mixture prior to printing.

This is believed to be the first instance of micro-CT being used to identify and analyse the distribution of an additive within a laser sintered part.

This study aims to investigate the behavior of vegetable oil with two additives. Base oil’s tribological qualities can be improved with the help of several additions. In the present investigation, soybean oil is served as the foundational oil due to its eco-friendliness and status as a vegetable oil with two additives, named polytetrafluoroethylene (PTFE) and molybdenum disulfide (MoS₂).

As additives, PTFE and MoS₂ are used; PTFE is renowned for its anti-friction (AF) properties, while MoS₂ is a solid lubricant with anti-wear (AW) properties. This investigation examines the synergistic impact of AF and AW additions in vegetable oil. The lubricity of the base oil is measured by using a four-ball tester, and the wear properties of the oil at different additive amounts are determined by using a universal tribometer.

PTFE (at 5 Wt.%) and MoS₂ (at 1 Wt.%) were found to improve the tribological performance of the base oil. The weld load is significantly increased when 5 Wt.% of PTFE + MoS₂ is added to the base oil.

A better tribological characteristic can be achieved by combining additives that amount to less than 1% of the base oil. In experiments with highly concentrated MoS₂, the adequate pressure improved dramatically, but the lubricant’s tribological characteristics did not.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-11-2022-0321/

This study aims to investigate the influence of additive manufactured polymer injection moulds on the mechanical properties of moulded parts. Therefore, polymer moulds are used to inject standard specimens to compare material properties to specimens produced using a conventional aluminium tool.

PolyJet technology is used to three-dimensional (3D)-print a mould insert in Digital ABS and selective laser sintering (SLS) technology is used to 3D-print a mould insert in polyamide (PA) 3200 GF. A conventionally aluminium milled tool serves as reference. Standard specimens are produced to compare resulting mechanical properties, shrinkage behaviour and morphology.

The determined material characteristics of the manufactured prototypes from the additive manufactured tools show differences in terms of mechanical behaviour to those from the aluminium reference tool. The most significant differences are an up to 25 per cent lower tensile elongation and an up to 63 per cent lower elongation at break resulting in an embrittlement of the specimens produced. These differences seem to be mainly due to the different morphological structure caused by the lower thermal conductivity and greater surface roughness of the polymer tools.

The determined differences in mechanical behaviour can partly be assigned to differences in surface roughness and morphological structure of the resulting parts. The exact extend of either cause, however, cannot be clearly determined.

This study provides a comparison between the part material properties from conventionally milled aluminium tools and polymer inserts manufactured via additive tooling.

Additive manufacturing (AM) of thermoplastic polymers for powder bed fusion processes typically requires each layer to be fused before the next can be deposited. The purpose of this paper is to present a volumetric AM method in the form of deeply penetrating radio frequency (RF) radiation to improve the speed of the process and the mechanical properties of the polymer parts.

The focus of this study was to demonstrate the volumetric fusion of composite mixtures containing polyamide (nylon) 12 and graphite powders using RF radiation as the sole energy source to establish the feasibility of a volumetric AM process for thermoplastic polymers. Impedance spectroscopy was used to measure the dielectric properties of the mixtures as a function of increasing graphite content and identify the percolation limit. The mixtures were then tested in a parallel plate electrode chamber connected to an RF generator to measure the heating effectiveness of different graphite concentrations. During the experiments, the surface temperature of the doped mixtures was monitored.

Nylon 12 mixtures containing between 10% and 60% graphite by weight were created, and the loss tangent reached a maximum of 35%. Selective RF heating was shown through the formation of fused composite parts within the powder beds.

The feasibility of a novel volumetric AM process for thermoplastic polymers was demonstrated in this study, in which RF radiation was used to achieve fusion in graphite-doped nylon powders.

Additive manufacturing (AM) methods such as material extrusion (ME) are becoming widely used by engineers, designers and hobbyists alike for a wide variety of applications. Successfully manufacturing objects using ME three-dimensional printers can often require numerous iterations to attain predictable performance because the exact mechanical behavior of parts fabricated via additive processes are difficult to predict. One of that factors that contributes to this difficulty is the wide variety of ME feed stock materials currently available in the marketplace. These build materials are often sold based on their base polymer material such as acrylonitrile butadiene styrene or polylactic acid (PLA), but are produced by numerous different commercial suppliers in a wide variety of colors using typically undisclosed additive feed stocks and base polymer formulations. This paper aims to present the results from an experimental study concerned with quantifying how these sources of polymer variability can affect the mechanical behavior of three-dimensional printed objects. Specifically, the set of experiments conducted in this study focused on following: several different colors of PLA filament from a single commercial supplier to explore the effect of color additives and three filaments of the same color but produced by three different suppliers to account for potential variations in polymer formulation.

A set of five common mechanical and material characterization tests were performed on 11 commercially available PLA filaments in an effort to gain insight into the variations in mechanical response that stem from variances in filament manufacturer, feed stock polymer, additives and processing. Three black PLA filaments were purchased from three different commercial suppliers to consider the variations introduced by use of different feed stock polymers and filament processing by different manufacturers. An additional eight PLA filaments in varying colors were purchased from one of the three suppliers to focus on how color additives lead to property variations. Some tests were performed on unprocessed filament samples, while others were performed on objects three-dimensional printed from the various filaments. This study looked specifically at four mechanical properties (Young’s modulus, storage modulus, yield strength and toughness) as a function of numerous material properties (e.g. additive loading, molecular weight, molecular weight dispersity, enthalpy of melting and crystallinity).

For the 11 filaments tested the following mean values and standard deviations were observed for the material properties considered: p_a = 1.3 ± 0.9% (percent additives), M_w = 98.6 ± 16.4 kDa (molecular weight), Ð = 1.33 ± 0.1 (molecular weight dispersity), H_m = 37.4 ± 7.2 J/g (enthalpy of melting) and = 19.6 ± 2.1% (crystallinity). The corresponding mean values and standard deviations for the resulting mechanical behaviors were: E = 2,790 ± 145 MPa (Young’s modulus), E’ = 1,050 ± 125 MPa (storage modulus), S_y = 49.6 ± 4.93 MPa (yield strength) and U_t = 1.87 ± 0.354 MJ/m^³ (toughness). These variations were observed in filaments that were all manufactured from the same base polymer (e.g. PLA) and are only different in terms of the additives used by the manufacturers to produce different colors or different three-dimensional printing performance. Unfortunately, while the observed variations were significant, no definitive strong correlations were found between these observed variations in the mechanical behavior of the filaments studied and the considered material properties.

These variations in mechanical behavior and material properties could not be ascribed to any specific factor, but rather show that the mechanical of three-dimensional printed parts are potentially affected by variations in base polymer properties, additive usage and filament processing choices in complex ways that can be difficult to predict.

These results emphasize the need to take processing and thereby even filament color, into account when using ME printers, they emphasize the need for designers to use AM with caution when the mechanical behavior of a printed part is critical and they highlight the need for continued research in this important area. While all filaments used were marked as PLA, the feedstock materials, additives and processing conditions created significant differences in the mechanical behavior of the printed objects evaluated, but these differences could not be accurately and reliably predicted as function of the observed material properties that were the focus of this study.

The testing methods used in the study can be used by engineers and creators alike to better analyze the material properties of their filament printed objects, to increase success in print and mechanical design. Furthermore, the results clearly show that as AM continues to evolve and grow as a manufacturing method, standardization of feedstock processing conditions and additives would enable more reliable and repeatable printed objects and would better assist designers in effectively implementing AM methods.

Powder bed-based additive manufacturing (AM) is a promising family of technologies for industrial applications. The purpose of this study is to provide a new metrics based on the analysis of the compaction behavior for the evaluation of flowability of AM powders.

In this work, a novel qualification methodology based on a camera mounted onto a commercially available tap density meter allowed to assess the compaction behavior of a selection of AM materials, both polymers and metals. This methodology automatizes the reading of the powder height and obtains more information compared to ASTM B527. A novel property is introduced, the “tapping modulus,” which describes the packing speed of a powdered material and is related to a compression/vibration powder flow.

The compaction behavior was successfully correlated with the dynamic angle of repose for polymers, but interestingly not for metals, shedding more light to the different flow behavior of these materials.

Because of the chosen materials, the results may lack generalizability. For example, the application of this methodology outside of AM would be interesting.

This paper suggests a new methodology for assessing the flowing behavior of AM materials when subjected to compression. The device is inexpensive and easy to implement in a quality assurance environment, being thus interesting for industrial applications.

Material extrusion additive manufacturing processes inevitably produce bead-shaped surface patterns on the walls of parts, which create stress concentrations under load. This study aims to investigate the influence of such stress concentrations on the strength along the build direction (“Z-strength”).

This work consists of two main parts – an experimental demonstration to show the significance of stress concentrations on the Z-strength, followed by numerical modeling to evaluate the theoretical stress concentration factors (k_t) for such shapes. Meso-scale finite element analysis (FEA) was performed to evaluate k_t at the roots of the intersecting bead shapes. The critical bead shape parameters influencing k_t were identified, and parametric FEA studies were performed on different bead shapes by varying the normalized parameters.

The experimental results showed that up to a 40% reduction in the effective Z-strength could be attributed only to the presence of surface bead shapes. Bead overhang and root radius were identified as critical shape parameters influencing k_t. The results of the parametric FEA studies were used to generate a single empirical equation to determine k_t for any bead shape.

Predictive models for Z-strength often focus on crystallization kinetics and polymer chain interdiffusion to predict interlayer adhesion strength. The authors propose that the results of such studies must be combined with surface bead-shape induced stress concentration factors to obtain the combined, “effective” Z-strength.