Search results

1 – 10 of 886
Article
Publication date: 19 June 2023

Ghania Mirouzi and Amina Houda

The objective of this research is to evaluate the influence of mineral additions on the mechanical performances of polymer concrete. This study aims to propose a novel approach…

Abstract

Purpose

The objective of this research is to evaluate the influence of mineral additions on the mechanical performances of polymer concrete. This study aims to propose a novel approach formulation of polymer concrete based on reduction in the quantity of the binder and disposal of large quantities of industrial by-products and household waste such as the marble, the brick and silica fume whose valuation in polymer concrete could be an interesting ecological and economical alternative. The incorporation of a rate of 10% brick powder affects the distribution of pores inside polymer concrete, that is, the pore diameters become thinner and decrease and the porosity becomes evenly distributed. The recycled mineral brick powder addition in polymer concrete mix improved the mechanical properties.

Design/methodology/approach

This polymer concrete was prepared by using polyester resin and two different types of sand, following a new formulation based on an empirical method. Furthermore, the optimal binder percentage was of 20% resin and a mixture of 52% dune sand and 48% quarry sand according to the Abrams method. To achieve our objective, five rates (from 2% to 10%) of brick powder, marble powder and silica fume were examined. Afterwards, its mechanical characteristics were evaluated via a three-point flexural with compressive resistance. The findings indicated that the addition of brick, marble and silica fume to polymer concrete increases the flexural strength with 21.84%, 12.76% and 9.07%, respectively.

Findings

Concerning the compressive strength, the best resistance is that of polymer concretes based on brick powder, and this economic formulation of polymer concrete serves the optimal cost/resistance ratio criteria. It allows an improvement in the mechanical resistance of concrete are obtained by adding brick powder that exceed that of the reference concrete.

Originality/value

In the past few decades, there has been several contribution concerning the subject of the reduction of the binder quantity in polymer concretes and adding the industrial and household wastes. However, previous studies revolving around the same area disregarded the effect of the brick powder, which appears scientifically of great importance for enriching the literature.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 12 May 2023

Maria Athar, Adeel Ahmad and Yasir Khan

To explore the fusion of dust particles and of polymers in a viscous liquid is the main purpose of this article. Newtonian fluid as a base fluid is considered and the mutual…

Abstract

Purpose

To explore the fusion of dust particles and of polymers in a viscous liquid is the main purpose of this article. Newtonian fluid as a base fluid is considered and the mutual presence of polymers and dusty bodies is investigated. It discusses the steady laminar flow and heat transportation of a polymeric dusty liquid induced by a uniformly heated, penetrable and stretchable surface inside the boundary layer.

Design/methodology/approach

The mathematical system incorporates separate equations of energy and momentum for dusty bodies and for fluid. The classical Oldroyd-B model is chosen for exploring polymer presence. For the fluid phase, this model adds another stress to the conservation law of momentum. Appropriate similarity variables are introduced to transform the system of partial differential equations (PDEs) into a system of nonlinear ordinary differential equations (ODEs). The problem is solved by introducing a numerical iterative procedure which turned out to be fastly converging.

Findings

Expeditious changes inside the boundary layer cause polymers to deform. No changes outside the boundary layer are noticed on account of polymer stretching. The dependence of heat transfer rate and skin friction on the parameter of polymer concentration and Weissenberg number is analyzed and displayed graphically against interaction parameters for temperature and velocity, dust particles’ mass concentration, Eckert and Prandtl numbers. Combining effects of polymers and dust particles cause skin friction to decrease and heat transfer rate to increase. Increasing values of interaction parameter for velocity, dust particles’ mass concentration and Eckert number reduces the drag coefficient and local Nusselt number. On the other hand, the Prandtl number and interaction parameter of temperature magnify the heat flux at the wall.

Research limitations/implications

This article studies the infinite extensibility of polymers. FENE and FENE-P models can be used to investigate the polymer presence in dusty fluids in the future.

Originality/value

In this article, the authors’ aim is to study the combined presence of polymers and dusty bodies. Keeping the existing literature in view, this type of fusion is not studied yet. Polymer inclusion in a viscous dusty fluid is studied and the behavior of fluid flow and heat transportation is investigated within the boundary layer over a permeable linearly stretching sheet.

Details

Multidiscipline Modeling in Materials and Structures, vol. 19 no. 4
Type: Research Article
ISSN: 1573-6105

Keywords

Article
Publication date: 15 August 2022

Wanting Zhao and Lijun Chen

Self-crosslinked long fluorocarbon acrylate polymer latex has good hydrophobic and oleophobicity, weather resistance, aging resistance, stability and other excellent properties…

Abstract

Purpose

Self-crosslinked long fluorocarbon acrylate polymer latex has good hydrophobic and oleophobicity, weather resistance, aging resistance, stability and other excellent properties, which make the polymer be widely used in coatings, dyes, adhesives and other products. The purpose of this study is to prepare self-crosslinked long fluorocarbon acrylate polymer latex via semi-continuous seeded emulsion technology and carry out comparative study on two different cross-linked monomers.

Design/methodology/approach

Methyl methacrylate (MMA) and butyl acrylate (BA) were used as the main monomers, dodecafluoroheptyl methacrylate (DFMA) as the fluoromonomer, hydroxypropyl methacrylate (HPMA) and N-methylol acrylamide (NMA) as cross-linked monomers, and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether (ANPEO10) and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether ammonium sulfate (DNS-86) as compound emulsifiers via the semicontinuous-seeded emulsion polymerization.

Findings

The properties of the polymer emulsions, which are prepared with two different cross-linked monomers, are compared and discussed, and it is concluded that HPMA is more suitable for the preparation of self-crosslinked polymer emulsions. The formula of the polymer latex is ANPEO10: DNS-86 = 1:1, and the mass ratio of the monomers used in the polymer is MMA: BA: DFMA: HPMA = 14.40:14.40:0.60:0.60.

Practical implications

Self-crosslinked long fluorocarbon acrylate polymer latex can be used in many fields such as coatings, dyes, adhesives and other products.

Originality/value

The self-crosslinked long fluorocarbon acrylate polymer latex is prepared by mixing the nonionic emulsifier ANPEO10 and the anionic emulsifier DNS-86 when potassium persulfate is used as the thermal decomposition initiator and the semicontinuous-seeded emulsion technology is adopted and the comparative study on two different cross-linked monomer is carried out, which is not reported in the open literatures.

Article
Publication date: 27 September 2022

Gomaa Abdel-Maksoud, Aya Abdallah, Rana Youssef, Doha Elsayed, Nesreen Labib, Wael S. Mohamed and Medhat Ibrahim

This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.

Abstract

Purpose

This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.

Design/methodology/approach

New vegetable-tanned leather samples were prepared. The consolidants used were polyacrylamide (PAM) and polymethyl methacrylate/hydroxyethyl methacrylate (MMA-HEMA). Accelerated heat aging was applied to the untreated and treated samples. Analytical techniques used were Fourier transform infrared spectroscopy (FTIR), digital microscope, scanning electron microscope (SEM), change of color and mechanical properties.

Findings

The characteristic FTIR bands showed the effect of accelerated heat aging on the molecular structure of the studied samples, but treated and aged treated samples used were better than aged untreated samples. Microscopic investigations (digital and SEM), and mechanical properties proved that 2% was the best concentration for polymers used. The change in the total color difference of the treated and aged treated samples was limited.

Originality/value

This study presents the important results obtained from PAM and poly(MMA-HEMA) used for the consolidation of vegetable-tanned leather artifacts. The best results of the studied polymers can be applied directly to protect historical vegetable-tanned leathers.

Article
Publication date: 19 August 2022

Hanieh Shaki

In this study, the removal of a series of acid dyes by hybrid polymer adsorbent was investigated. Textile industry wastewater is mainly consisted of suspended solid particles and…

Abstract

Purpose

In this study, the removal of a series of acid dyes by hybrid polymer adsorbent was investigated. Textile industry wastewater is mainly consisted of suspended solid particles and organic compounds with complex and nondecomposable structures. Treatment of such wastewaters has received much attention by researchers because of high water consumption and the presence of various chemical compounds, especially dyes. The use of polymers has recently attracted much attention for the treatment of textile wastewaters. According to the literature, hybrid polymers are highly capable of adsorbing dyes. In this research work, polyacrylamide/iron sulfate (PAM-FeSO4) hybrid polymer was successfully synthesized through solution polymerization of acrylamide with ammonium persulfate and sodium thiosulfate and gradual addition of iron sulfate. The hybrid polymeric adsorbent was then used for removing acidic dyes with different chemical structures.

Design/methodology/approach

The effects of various experimental conditions and parameters, such as initial concentrations of dye and adsorbent, on the adsorption capacity of the adsorbent were investigated. The dye concentration was measured by an UV–vis spectrophotometer. The adsorption equilibrium was studied by plotting adsorption isotherms. The experimental data was fitted to Langmuir and Freundlich isotherms.

Findings

The adsorption experiments indicated that the PAM-FeSO4 hybrid polymer has a high adsorption capacity (117.64 mg g−1 for the Orange ІІ and 80.64 mg g−1 for the Sunset Yellow [SY]) when 80 mg of adsorbent was immersed in the dye solution (1 g L−1) with a pH of 11 at 25°C. The analysis of the equilibrium isotherms using the Langmuir and Freundlich isotherms indicated that the Langmuir model fit well to the experimental data.

Originality/value

To the best of the authors’ knowledge, this study is original. The removal of acid dyes such as Sunset Yellow and Methyl Orange using PAM-FeSO4 hybrid polymer as flocculant was done for the first time.

Details

Pigment & Resin Technology, vol. 52 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 October 2023

Megavannan Mani, Thiyagu Murgaiyan and Pradeep Kumar Krishnan

This study focuses on the structural performance assessment of hybrid polymer composites for pick-and-place robot grippers used in critical infrastructure. This research involved…

Abstract

Purpose

This study focuses on the structural performance assessment of hybrid polymer composites for pick-and-place robot grippers used in critical infrastructure. This research involved the creation of composite materials with different nanoparticle concentrations, followed by extensive testing to assess the mechanical properties of the materials, such as strength, stiffness and durability.

Design/methodology/approach

The composites comprised bidirectional interply inclined carbon fibers (C), S-glass fibers (SG), E-glass (EG), an epoxy matrix and silica nanoparticles (SNiPs). During construction, the composite materials must be carefully layered using quasi-static sequence techniques (45°C1/45°SG2/45°EG2/45°C1/45°EG2/45°SG2/45°C1) to obtain the epoxy matrix reinforcement and bonding using 0, 2, 4 and 6 wt. % of silica nanoparticles.

Findings

According to various test findings, the 4 wt. % of SNiPs added to polymer plates exhibits the maximum strength outcomes. The average results of the tensile and flexural tests for the polymer composite plates with 4 wt. % addition SNiPs were 127.103 MPa and 223.145 MPa, respectively. The average results of the tensile and flexural tests for the plates with 0 wt.% SNiPs were 115.457 MPa and 207.316 MPa, respectively.

Originality/value

The authors hereby attest that the research paper they have submitted is the result of their own independent and unique labor. All of the sources from which the thoughts and passages were derived have been properly credited. The work has not been submitted for publication anywhere and is devoid of any instances of plagiarism.

Highlights

 

  1. The study enhances the engineering materials for innovative applications.

  2. The study explores the mechanical behavior of carbon/S-glass/E-glass fiber composites.

  3. Silica nanoparticles were enhancing mechanical characteristics of the composite structure.

The study enhances the engineering materials for innovative applications.

The study explores the mechanical behavior of carbon/S-glass/E-glass fiber composites.

Silica nanoparticles were enhancing mechanical characteristics of the composite structure.

Details

International Journal of Structural Integrity, vol. 14 no. 6
Type: Research Article
ISSN: 1757-9864

Keywords

Article
Publication date: 5 August 2022

Jianqing Hu, Hongjun He, Feiliang Dai, Xingyu Gong and Haowei Huang

The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical…

Abstract

Purpose

The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical properties.

Design/methodology/approach

For effective bacteria resistance and excellent mechanical properties, various concentrations of methacryloxyethylhexadecyl dimethylammonium bromide (MHDB) were synthesised and incorporated into SA emulsions. The properties of SA emulsions modified with MHDB were characterised and compared with those of unmodified ones according to the formulations of polymer cement waterproof coatings.

Findings

The SA emulsions modified with MHDB exhibited significant enhancement of bacteria resistance and mechanical properties over the unmodified ones. The positive quaternary nitrogen and long-chain alkyl groups of MHDB in SA emulsions could attract phospholipid head groups of bacterial and insert them into the cell wall, which results in biomass leak and bactericidal effect. Moreover, MHDB as a softened monomer was beneficial to the synthesis of SA copolymer with low glass-transition temperature (Tg), then the copolymer and cement would form a more compact film which was the main reason for the enhancement of mechanical properties.

Research limitations/implications

The modifier MHDB was synthesised from diethylaminoethyl methacrylate (DEAM) and 1-bromohexadecane. Besides, the congeners of MHDB could be synthesised from DEAM and 1-bromododecane, 1-tetradecyl dromide, 1-octadecyl bromide, etc. In addition, the efficiency of other modifications into SA emulsions for antibacterial polymer cement waterproof coatings could be studied as well.

Practical implications

The method provided a practical solution for the improvement of water-based antibacterial acrylate polymer cement waterproof coatings.

Originality/value

The method for enhancing bacteria resistance and mechanical properties of the waterproof coating was novel and valuable.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 9 January 2024

Linghuan Li, Shibin Sun, Ronghua Zhuang, Bing Zhang, Zeyu Li and Jianying Yu

This study aims to develop a polymer cement-based waterproof coating with self-healing capability to efficiently and intelligently solve the building leakage caused by cracking of…

Abstract

Purpose

This study aims to develop a polymer cement-based waterproof coating with self-healing capability to efficiently and intelligently solve the building leakage caused by cracking of waterproof materials, along with excellent durability to prolong its service life.

Design/methodology/approach

Ion chelators are introduced into the composite system based on ethylene vinyl acetate copolymer emulsion and ordinary Portland cement to prepare self-healing polymer cement-based waterproof coating. Hydration, microstructure, wettability, mechanical properties, durability, self-healing performance and self-healing products of polymer cement-based waterproof coating with ion chelator are investigated systematically. Meanwhile, the chemical composition of self-healing products in the crack was examined.

Findings

The results showed that ion chelators could motivate the hydration of C2S and C3S, as well as the formation of hydration products (C-S-H gel) of the waterproof coating to improve its compactness. Compared with the control group, the waterproof coating with ion chelator had more excellent water resistance, alkali resistance, thermal and UV aging resistance. When the dosage of ion chelator was 2%, after 28 days of curing, cracks with a width of 0.29 mm in waterproof coating could fully heal and cracks with a width of 0.50 mm could achieve a self-healing efficiency of 72%. Furthermore, the results reveal that the self-healing product in the crack was calcite crystalline CaCO3.

Originality/value

A novel ion chelator was introduced into the composite coating system to endow it with excellent self-healing ability to prolong its service life. It has huge application potential in the field of building waterproofing.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 September 2023

Thameem Hayath Basha, Sivaraj Ramachandran and Bongsoo Jang

The need for precise synthesis of customized designs has resulted in the development of advanced coating processes for modern nanomaterials. Achieving accuracy in these processes…

Abstract

Purpose

The need for precise synthesis of customized designs has resulted in the development of advanced coating processes for modern nanomaterials. Achieving accuracy in these processes requires a deep understanding of thermophysical behavior, rheology and complex chemical reactions. The manufacturing flow processes for these coatings are intricate and involve heat and mass transfer phenomena. Magnetic nanoparticles are being used to create intelligent coatings that can be externally manipulated, making them highly desirable. In this study, a Keller box calculation is used to investigate the flow of a coating nanofluid containing a viscoelastic polymer over a circular cylinder.

Design/methodology/approach

The rheology of the coating polymer nanofluid is described using the viscoelastic model, while the effects of nanoscale are accounted for by using Buongiorno’s two-component model. The nonlinear PDEs are transformed into dimensionless PDEs via a nonsimilar transformation. The dimensionless PDEs are then solved using the Keller box method.

Findings

The transport phenomena are analyzed through a comprehensive parametric study that investigates the effects of various emerging parameters, including thermal radiation, Biot number, Eckert number, Brownian motion, magnetic field and thermophoresis. The results of the numerical analysis, such as the physical variables and flow field, are presented graphically. The momentum boundary layer thickness of the viscoelastic polymer nanofluid decreases as fluid parameter increases. An increase in mixed convection parameter leads to a rise in the Nusselt number. The enhancement of the Brinkman number and Biot number results in an increase in the total entropy generation of the viscoelastic polymer nanofluid.

Practical implications

Intelligent materials rely heavily on the critical characteristic of viscoelasticity, which displays both viscous and elastic effects. Viscoelastic models provide a comprehensive framework for capturing a range of polymeric characteristics, such as stress relaxation, retardation, stretching and molecular reorientation. Consequently, they are a valuable tool in smart coating technologies, as well as in various applications like supercapacitor electrodes, solar collector receivers and power generation. This study has practical applications in the field of coating engineering components that use smart magnetic nanofluids. The results of this research can be used to analyze the dimensions of velocity profiles, heat and mass transfer, which are important factors in coating engineering. The study is a valuable contribution to the literature because it takes into account Joule heating, nonlinear convection and viscous dissipation effects, which have a significant impact on the thermofluid transport characteristics of the coating.

Originality/value

The momentum boundary layer thickness of the viscoelastic polymer nanofluid decreases as the fluid parameter increases. An increase in the mixed convection parameter leads to a rise in the Nusselt number. The enhancement of the Brinkman number and Biot number results in an increase in the total entropy generation of the viscoelastic polymer nanofluid. Increasing the strength of the magnetic field promotes an increase in the density of the streamlines. An increase in the mixed convection parameter results in a decrease in the isotherms and isoconcentration.

Details

International Journal of Numerical Methods for Heat & Fluid Flow, vol. 34 no. 2
Type: Research Article
ISSN: 0961-5539

Keywords

Article
Publication date: 11 May 2023

Ganesh Prabhu Ganapathy, Theodore C. Haupt and Pandimani

Cracking, deformation and rutting are the most prevalent types of pavement distress, and these deformations and flow characteristics greatly distress the pavement features while…

49

Abstract

Purpose

Cracking, deformation and rutting are the most prevalent types of pavement distress, and these deformations and flow characteristics greatly distress the pavement features while also limiting its use. In India, on the other hand, more than 300 million scrap tyres are generated each year, and their disposal has become a severe environmental issue. Furthermore, the scrap generated by the used tyre must be disposed of properly. Hence, this study presents the experimental investigations of bitumen incorporating with Crumb rubber as main additive along with SBS polymer, to enhance the engineering property.

Design/methodology/approach

Crumb rubber (CR) was used as an additive along with styrene–butadiene–styrene (SBS) polymer to enrich the engineering qualities of the bitumen to reduce the disposal problem of scrap tyres and reduce the risk of environmental pollution. Because SBS polymer is expensive, response surface methodology modelling's central composite design (CCD) was used to optimise the number of tests. CCD modelling's input factors (process variables) were the inclusion rates of SBS and CR, which ranged from 2% to 5% and 4% to 10%, respectively, by total weight. Furthermore, the influence of SBS polymer and CR on the characteristics of modified bitumen was prioritised.

Findings

The addition of SBS and CR enhanced the bitumen's penetration resistance at service temperatures. Furthermore, increasing the SBS and CR concentration affected the flow characteristics of the modified bitumen and enhanced its viscosity. The addition of SBS and CR as bitumen modifiers increased penetration resistance by 24.06%. The Dynamic Shear Rheometer test demonstrated that the complex modulus of virgin bitumen increases with increasing SBS and CR content, which is consistent with the shifting softening point trend. The dosing rate of up to 3.5% SBS and 11% CR considerably contributed to the creation of polymer link networks, which increased the complex modulus of the bitumen by 16.5%. The CCD model's analysis of variance and Pareto bar chart demonstrated that the dose of CR is significant in improving the engineering features of the virgin bitumen rather than the SBS.

Originality/value

The utilisation of CR as a bitumen modifier may solve the problem of waste tyre disposal while also lowering the risk of environmental damage. Furthermore, because the presence of CR increased the engineering properties, particularly the complex modulus of virgin bitumen, the use of CR in combination with SBS polymer can be an efficient and cost-effective strategy to improving bitumen qualities.

Details

Journal of Engineering, Design and Technology , vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1726-0531

Keywords

1 – 10 of 886