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1 – 10 of 487Fukang Yang, Wenjun Wang, Yongjie Yan and YuBing Dong
Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to…
Abstract
Purpose
Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to improve the thermal insulation performance of polyethylene terephthalate (PET), the SiO2 aerogel/PET composites slices and fibers were prepared, and the effects of the SiO2 aerogel on the morphology, structure, crystallization property and thermal conductivity of the SiO2 aerogel/PET composites slices and their fibers were systematically investigated.
Design/methodology/approach
The mass ratio of purified terephthalic acid and ethylene glycol was selected as 1:1.5, which was premixed with Sb2O3 and the corresponding mass of SiO2 aerogel, and SiO2 aerogel/PET composites were prepared by direct esterification and in-situ polymerization. The SiO2 aerogel/PET composite fibers were prepared by melt-spinning method.
Findings
The results showed that the SiO2 aerogel was uniformly dispersed in the PET matrix. The thermal insulation coefficient of PET was significantly reduced by the addition of SiO2 aerogel, and the thermal conductivity of the 1.0 Wt.% SiO2 aerogel/PET composites was reduced by 75.74 mW/(m · K) compared to the pure PET. The thermal conductivity of the 0.8 Wt.% SiO2 aerogel/PET composite fiber was reduced by 46.06% compared to the pure PET fiber. The crystallinity and flame-retardant coefficient of the SiO2 aerogel/PET composite fibers showed an increasing trend with the addition of SiO2 aerogel.
Research limitations/implications
The SiO2 aerogel/PET composite slices and their fibers have good thermal insulation properties and exhibit good potential for application in the field of thermal insulation, such as warm clothes. In today’s society where the energy crisis is becoming increasingly serious, improving the thermal insulation performance of PET to reduce energy loss will be of great significance to alleviate the energy crisis.
Originality/value
In this study, SiO2 aerogel/PET composite slices and their fibers were prepared by an in situ polymerization process, which solved the problem of difficult dispersion of nanoparticles in the matrix and the thermal conductivity of PET significantly reduced.
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The purpose of this paper is to study the non-isothermal degradation kinetics of recycled polybutylene terephthalate, polytrimethylene terephthalate and polyethylene terephthalate…
Abstract
Purpose
The purpose of this paper is to study the non-isothermal degradation kinetics of recycled polybutylene terephthalate, polytrimethylene terephthalate and polyethylene terephthalate using thermogravimetric analysis (TGA) in a nitrogen atmosphere.
Design/methodology/approach
To achieve this goal, the author utilized standard kinetic models, such as Coats-Redfern and Kissinger equations, for analysis of the TGA data.
Findings
When applied to the TGA data, the Kissinger model resulted in a coefficient of determination (R2) value greater than 0.99.
Originality/value
This study describes the maiden application of the Kissinger model to obtain the pre-exponential factor (A) and activation energy (E) for different polyester systems used in the textile industry.
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Samuel Furka, Daniel Furka, Nitin Chandra Teja Chandra Teja Dadi, Patrik Palacka, Dominika Hromníková, Julio Ariel Dueñas Santana, Javier Díaz Pineda, Saul Dueñas Casas and Juraj Bujdák
This study aims to describe the preparation of antimicrobial material usable in 3D printing of medical devices. Despite the wealth of technological progress at the time of the…
Abstract
Purpose
This study aims to describe the preparation of antimicrobial material usable in 3D printing of medical devices. Despite the wealth of technological progress at the time of the crisis caused by SARS-CoV-2 virus: Virus that causes current Pandemic situation (COVID-19), the global population had long been exposed beforehand to an acute absence of essential medical devices. As a response, a new type of composite materials intended for rapid prototyping, based on layered silicate saponite (Sap), antimicrobial dye phloxine B (PhB) and thermoplastics, has been recently developed.
Design/methodology/approach
Sap was modified with a cationic surfactant and subsequently functionalized with PhB. The hybrid material in powder form was then grounded with polyethylene terephthalate-glycol (PETG) or polylactic acid (PLA) in a precisely defined weight ratio and extruded into printing filaments. The stability and level of cytotoxicity of these materials in various physiological environments simulating the human body have been studied. The applicability of these materials in bacteria and a yeast-infected environment was evaluated.
Findings
Ideal content of the hybrid material, with respect to thermoplastic, was 15 weight %. Optimal printing temperature and speed, with respect to maintaining antimicrobial activity of the prepared materials, were T = 215°C at 50 mm/s for PETG/SapPhB and T = 230°C at 40 mm/s for PLA/SapPhB. 3 D-printed air filters made of these materials could keep inner air flow at 63.5% and 76.8% of the original value for the PLA/SapPhB and PETG/SapPhB, respectively, whereas the same components made without PhB had a 100% reduction of airflow.
Practical implications
The designed materials can be used for rapid prototyping of medical devices.
Originality/value
The new materials have been immediately used in the construction of an emergency lung ventilator, Q-vent, which has been used in different countries during the COVID-19 crisis.
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Mikael Lindeberg and Klas Hjort
The purpose of this paper is to present an update and the latest results from work on high aspect ratio “multiple wire” microvias in porous flexible Kapton foils for printed…
Abstract
Purpose
The purpose of this paper is to present an update and the latest results from work on high aspect ratio “multiple wire” microvias in porous flexible Kapton foils for printed circuit boards (PCBs).
Design/methodology/approach
Kapton foils are made porous by ion track technology and dry resist patterning. In combination with thin film deposition and electroplating the technology is used to define circuits and sensors with microvias made of many individual high aspect ratio wires. The processes are within the reach of many production environments and are suitable for flexible PCB fabrication.
Findings
The use of these novel processes enables new types of microvias and multiple wire structures in the foils for millimeter wave circuitry of substrate integrated waveguides and shielding, as well as for sensors with high thermal resistance.
Research limitations/implications
Today, through foil electroplating is fairly slow and more work should be made with copper electroplating. Ion track technology works well on polyethylene terephthalate (PET), polyethylene naphthalate (PEN), and polyimide (PI) but should also be studied for novel polymer foils such as liquid crystal polymers (LCPs).
Originality/value
The paper details how ion track and PCB technology can be combined to enable a new type of through the foil via interconnect that consists of a multitude of wires. With these porous substrates, double‐sided circuits with high aspect ratio microvias and other multiple wire structures can be created using only lithography, thin film deposition, and electroplating. A new type of electrothermal sensorfoil is presented with several advantages over its competing micro electro mechanical systems (MEMS) based Si sensors.
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Alena Pietrikova, Peter Lukacs, Dagmar Jakubeczyova, Beata Ballokova, Jerzy Potencki, Grzegorz Tomaszewski, Jan Pekarek, Katerina Prikrylova and Martin Fides
This paper aims to find an optimal surface treatment of commonly used polymeric substrates for achieve the high adhesion of printed structures. For this reason, the investigation…
Abstract
Purpose
This paper aims to find an optimal surface treatment of commonly used polymeric substrates for achieve the high adhesion of printed structures. For this reason, the investigation of substrates surfaces from different perspectives is presented in this paper.
Design/methodology/approach
The contact angle measurements as well as the roughness measurements were realised for the analysis of surface properties of investigated substrates. The impact of applied chemical agents for surface treatment onto the wettability is analysed for polyimide, polyethylene terephthalate and polyethylene naphthalene substrates.
Findings
The results prove the correlation among wettability, surface energy and work of adhesion with respect to the theoretical background. The surface treatment of polymeric substrates by chemical agents, such as acetone, toluene, ethanol, isopropyl and fluor silane polymer, has a significant impact onto the wettability of substrates which affects the final deposition process of nanoinks.
Originality/value
The main benefit of the surfaces’ investigation presented in this paper lays in surface modification by readily available chemical agents for optimising the deposition process nanoinks used in inkjet printing technology.
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Jorge Manuel Mercado-Colmenero, M. Dolores La Rubia, Elena Mata-García, Moisés Rodriguez-Santiago and Cristina Martin-Doñate
Because of the anisotropy of the process and the variability in the quality of printed parts, finite element analysis is not directly applicable to recycled materials manufactured…
Abstract
Purpose
Because of the anisotropy of the process and the variability in the quality of printed parts, finite element analysis is not directly applicable to recycled materials manufactured using fused filament fabrication. The purpose of this study is to investigate the numerical-experimental mechanical behavior modeling of the recycled polymer, that is, recyclable polyethylene terephthalate (rPET), manufactured by a deposition FFF process under compressive stresses for new sustainable designs.
Design/methodology/approach
In all, 42 test specimens were manufactured and analyzed according to the ASTM D695-15 standards. Eight numerical analyzes were performed on a real design manufactured with rPET using Young's compression modulus from the experimental tests. Finally, eight additional experimental tests under uniaxial compression loads were performed on the real sustainable design for validating its mechanical behavior versus computational numerical tests.
Findings
As a result of the experimental tests, rPET behaves linearly until it reaches the elastic limit, along each manufacturing axis. The results of this study confirmed the design's structural safety by the load scenario and operating boundary conditions. Experimental and numerical results show a difference of 0.001–0.024 mm, allowing for the rPET to be configured as isotropic in numerical simulation software without having to modify its material modeling equations.
Practical implications
The results obtained are of great help to industry, designers and researchers because they validate the use of recycled rPET for the ecological production of real-sustainable products using MEX technology under compressive stress and its configuration for numerical simulations. Major design companies are now using recycled plastic materials in their high-end designs.
Originality/value
Validation results have been presented on test specimens and real items, comparing experimental material configuration values with numerical results. Specifically, to the best of the authors’ knowledge, no industrial or scientific work has been conducted with rPET subjected to uniaxial compression loads for characterizing experimentally and numerically the material using these results for validating a real case of a sustainable industrial product.
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Aneta Araźna, Konrad Futera, Małgorzata Jakubowska and Łucja Dybowska-Sarapuk
– The purpose of this paper is to report surface properties of treated Teonex Du Pont polyethylene naphthalate (PEN) foil substrates.
Abstract
Purpose
The purpose of this paper is to report surface properties of treated Teonex Du Pont polyethylene naphthalate (PEN) foil substrates.
Design/methodology/approach
There were three different cleaning treatments among other: argon glow discharge, dipping into alkaline solution at 60°C as well as washing in an ultrasonic bath of acetone and ethyl alcohol in room temperature. The relation between PEN foil morphology and surface properties has been studied by contact angle measurements as well as evaluation of surface roughness of PEN foil samples by atomic force microscopy (AFM).
Findings
It was found that argon glow discharge (T3) of PEN treatment caused the maximum reduction in both values of contact angles. In addition, the argon glow discharge yielded the highest PEN surface energy (51.9 mJ/m2) and polarity (0.89). On the other hand, the AFM micrographs showed that the samples T3 had the highest value of average and root mean square surface roughness. Based on the experiments results, the authors stated that the alkaline cleaning (T2 treatment) could be considered as an effective method of PEN substrate treatment.
Originality/value
The influence of different cleaning treatment on the surface properties of PEN foil to inkjet application was analyzed. In the literature, there are not a lot of papers describing examinations of surface properties of PEN foil to inkjet application by contact angle measurements and AFM analysis.
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Plastic waste is one of the long-standing global issues in the recent era. Unfortunately, India is one of the countries which has been affected by the mismanagement of the use of…
Abstract
Plastic waste is one of the long-standing global issues in the recent era. Unfortunately, India is one of the countries which has been affected by the mismanagement of the use of plastics. India has recorded a substantial growth in the production of plastic and is considered a country of increased consumption of plastic. Due to the absence of an appropriate waste collection and segregation process, it has created the major issue of waste management and discarded used plastic items used for packaging application. There are various plastic waste management laws and programmes that have a cascading effect on almost every sector of business. In 2016, two years after the new union government took power in New Delhi, The Ministry of Environment, Forest and Climate Change (MoEFCC) has made some improvements in rules for the collection, segregation, processing, treatment and disposal of the waste. In the pandemic era, effective plastic waste management became more important than ever. The COVID-19 pandemic has created an increased demand for single-use plastic because of pressure on the already out-of-control global plastic waste problem. It is recorded to be large, and the magnitude of this pandemic related to mismanaged plastic waste is unknown. However, understanding the changing landscape and alarming need for effective plastic waste management, the government of India has proposed certain changes to prohibit imports, handling, manufacturing and use of single-use plastics in the country. This is in line with the government's intent to phase out single-use plastic by 2022. Considering this, this chapter highlights the changes in the rules and regulations in India related to plastic waste management and its effects on various sectors of business.
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Peter Lukacs, Alena Pietrikova and Pavol Cabuk
The purpose of this paper is to find optimal sintering conditions of silver-based nano-inks for achieving the high electrical conductivity of the deposited layers applied on…
Abstract
Purpose
The purpose of this paper is to find optimal sintering conditions of silver-based nano-inks for achieving the high electrical conductivity of the deposited layers applied on polyimide foils as well as the influence of ageing on the electrical conductivity. Therefore, the investigation in the field of silver layers deposited by inkjet printing technology is presented in this paper.
Design/methodology/approach
The four-point resistance measurements were realized for a detailed and precise analysis of the resistance of two different silver layers under different sintering conditions depending on the type of nano-ink varied about the recommended values. Highly accelerated stress tests (HASTs) were also applied as an ageing method for confirmation of the high electrical stability of the silver layers.
Findings
The results prove the strong influence of the temperature and the time of the sintering process on the sheet resistance of the investigated silver-based layers deposited by inkjet printing technology on polyimide foils. The HASTs caused significant changes in the electrical conductivity for both nano-inks presented in this paper. The existence of noticeable dependence among the resistivity, thermal treatment and ageing was proved.
Originality/value
The main benefit lays in the optimization of sintering conditions to improve the electrical conductivity of the silver layers. The paper also presents a new approach for a stability analysis of the silver layers by HASTs.
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