Search results

The study aims to synthesise polyurethane dispersion from polyesteramide polyol. The polyesteramide polyol is a novel polyol for the synthesis of polyurethane dispersion.

Polyesteramide polyol has been synthesised from phthalic anhydride and fatty amide of mustard oil. Aminolysis of mustard oil had been carried out with diethanolamine. The novel polyurethane dispersion had been synthesised using a polyesteramide polyol as a precursor. Isophorone diisocyanate was used as an isocyanate component and polyurethane dispersion (PUDs) had been synthesised by an anionic method where DMPA was introduced to introduce –COOH groups as via grafting to the resin backbone. Triethylamine was used for neutralisation and, hence, for further dispersion in water. Hydroxyl ethyl methacrylate was used for the synthesis to introduce unsaturation in the backbone of PUDs. The coating was made by an UV curing process. The coating was characterised for mechanical properties, chemical properties, thermal properties as well as stain resistance.

The polyurethane dispersion formed through it has ester and amide linkage present in it. The acetone process is used for its synthesis. The nuclear magnetic resonance spectroscopy confirms the successful formation of polyesteramide polyol and PUDs. Even though long aliphatic chains present in polyol which may impart hydrophobicity the synthesis PUDs well dispersed in water. It is observed as the coating made from it have hardness and scratch resistance properties. The coating also exhibits good stain resistance properties.

The method is an easy one to synthesise polyurethane dispersion from polyesteramide polyol, which is based on ester and amide linkage.

To the best of the authors’ knowledge, this is the first report on synthesised polyurethane dispersion from polyesteramide polyol. The polyesteramide resin already proves its excellence and upcoming technology in the coating industry. Here, they are incorporated into the synthesis of polyurethane dispersion.

The present study aims to demonstrate the use of renewable source in the preparation of polyurethane (PU) coatings and mitigation of corrosion of mild steel using nano zinc phosphate. Results indicated improvement in the properties of the PU coatings, especially anticorrosive properties by the addition of nano zinc phosphate.

Renewable-source-based polyestermyristamide polyol was synthesized using myristic acid as a starting material. The synthesis of polyol was carried by amidation as well as by esterification by a one-pot route. The structure of the prepared polyestermyristamide was confirmed with the support of end-group analysis and spectral study. PU coatings were prepared from synthesized polyestermyristamide polyol and used to protect metal substrate against corrosion. Corrosion properties of the prepared PU were found to be lower; hence, to improve the performance of these coatings, nano zinc phosphate was added to the coatings. The nano zinc phosphate was synthesized in the laboratory by reported sonication method and analyzed for morphology by scanning electron microscopy. Performance of coatings was studied with respect to effect of percentage nano zinc phosphate on thermal stability, mechanical properties and chemical resistances of PU coatings.

The combination of zinc phosphate nano rods and particles in myristic acid-based PU coatings provided substantial corrosion barrier properties to the coatings. Different per cent of the synthesized zinc phosphate nano rods and particles were loaded into the matrix, and corresponding coatings were estimated for corrosion resistance, thermal and chemical properties. Immersion study of the coated panels in 3.5 per cent NaCl solution showed good corrosion resistance for both PU coatings containing 2 and 3 per cent nano zinc phosphate.

This paper has provided the solution to replace existing petroleum-based raw materials with myristic acid as a renewable source in preparing PU coatings. Conventional coatings act as physical barriers against aggressive species but do not have ability to perform as permanent impassable to corrosive species. Hence, nano-sized zinc phosphate is used as corrosion inhibitor in to the synthesized PU coatings for enhancing anticorrosive performance.

In the paper, polyesteramide polyol is synthesized using renewable-source-based material, i.e. myristic acid to replace existing petroleum-based acid as a greener approach. Normally, vegetable oils are preferred as they have such kinds of polyols. The polyesteramide reaction is one pot that avoids the extra steps required in the synthesis. Further, it has been found that the pristine renewable coatings are unable to fully protect subtract from corrosion, whereas an addition of the nano-size zinc phosphate has enhanced the corrosion properties of the coatings.

This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl methacrylate (HEMA) terminated urethane acrylate oligomer was synthesized and characterized to study its application in stereolithography 3D printing with different ratios of isobornyl acrylate and hexanediol diacrylate.

Polyester polyol was synthesized from suberic acid and butanediol. Additionally, isophorone diisocyanate, polyester polyol and HEMA were used to create urethane acrylate oligomer. Fourier transform infrared spectroscopy and ¹H NMR were used to characterize the polyester polyol and oligomer. Various formulations were created by combining oligomer with reactive diluents in concentrations ranging from 0% to 30% by weight and curing with ultraviolet (UV) radiation. The cured coatings and 3D printed specimens were then evaluated for their properties.

The findings revealed an improvement in thermal stability, contact angle value, tensile strength and surface properties of the product which indicated its suitability for use as a 3D printing material.

This study discusses how oligomers that have been cured by UV radiation with mono- and difunctional reactive diluents give excellent coating characteristics and demonstrate suitability and stability for 3D printing applications.

Polymeric systems based on polyesteramides (PEA) are high performance materials, which combine the useful properties of polyester and polyamide resins, and find many applications, most importantly as protective surface coatings. The purpose of this paper is to characterise and evaluate new modified anti‐corrosive PEA resins for use in protective coating formulations.

In the study report here, new modified PEA compositions were prepared and evaluated as vehicles for surface coating. The PEA resins were obtained by means of a condensation polymerisation reaction between phthalic anhydride (PA) and N,N‐bis‐(2‐hydroxyethyl) linseed oil fatty acid amide (HELA) as the ingredient source of the polyol used. The phthalic anhydride was partially replaced with N‐phthaloylglutamic acid NPGA as the ingredient source of the dibasic acid. The structure of the resin was confirmed by FT‐IR spectral studies. Coatings of 50±5 μm thickness were applied to the surface of glass panels and mild steel strips by means of a brush. The coating performance of the resins was evaluated using international standard test methods and involved the measurement of phyisco‐mechanical properties and chemical resistance.

The tests carried out revealed that the modified PEA based on N‐phthaloylglutamic acid (NPGA) enhanced both phyisco‐mechanical and chemical properties. Also, the resins were incorporated within primer formulations and evaluated as anti‐corrosive single coatings. The results illustrate that the introduction of N‐phthaloylglutamic acid, within the resin structure, improved the film performance and enhances the corrosion resistance performance of PEA resins.

The modified PEA compounds can be used as binder in paint formulations to improve chemical, physical and corrosion resistance properties.

Modified PEA resins are cheaper and can be used to replace other more expensive binders. These modified PEA resins can compensate successfully for the presence of many the anticorrosive paint formulations and thus lower the costs. The main advantage of these binders is that they combine the properties of both polyester and polyamide resins based on nitrogenous compound, are of lower cost, and they also overcome the disadvantages of both its counterparts. Also, they can be applied in other industrial applications.

Linseed oil was employed to modify polyesteramide resin via the condensation of hydroxyethylamide derivatives of fatty acids of linseed oil, i.e. {N, N′‐bis(2 hydroxylethyl) linseed amide} and phthalic anhydride and dicarboxylic acids such as adipic acid, succinic acid and sebacic acid. The polyesteramide resins obtained were tested for their application as a vehicle/binder in the preparation of surface coatings. The resins obtained were also characterised for their physico‐chemical properties, film forming properties and chemical resistance.

Polyesteramide resin based on the condensation of hydroxyethylamide derivatives of fatty acids of soybean {N, N′‐bis(2 hydroxyethyl)soybean amide} and various dibasic acid and anhydride were synthesized. Physico‐chemical characteristics and film forming properties of these resins were determined to prove its suitability as a vehicle for surface coatings. The study reveals that resins can be used for the baked type of finishes.

Rosin‐diethanolamin derivative is used partially or completely as the source of polyol for the formation of recently modified polyesteramid resins. Parameters affecting the reaction between abietic acid (the main constituent of rosin) and diethanolamine, in azeotropic solvent using Dean and Stark apparatus, are studied.

Rosin‐modified polyesteramide resins are prepared covering a wide range of oil lengths by partial replacement of hydroxy ethyl fatty acid amides employed in resin formulations by rosin‐diethanolamine derivative without affecting the resin constants. This is followed by a study of the optimum amount of modifier which improve the resins performance and durability without affecting the other properties. Optimum modifier concentration and durability characteristics are then determined.

Triethanolamine derivatives of fatty acids were incorporated in an alkyd formulation as the ingredient source of polyol. The various parameters affecting the resin formation were also studied.

Attempt has been made in this study, to utilize castor oil in the preparation of polyesteramide resins. Castor oil was first converted into dehydrated castor oils (DCO) to improve drying characteristics. DCO was then converted into diethanolamide {(N, N‐ bis hydroxethyl) castor oil amide} of mixed fatty acids using 0.5 per cent sodium methoxide as a catalyst and converted to polyesteramide resins after reacting with various dibasic acids such as phthalic anhydride, sebacic, succinic and adipic acids in presence of xylene as azeotropic solvent. The resins obtained were then analysed for its physico‐chemical, film performance properties and resistance to various chemicals.