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The purpose of this paper is to report the preparation, characterisation and machinability of resin hybrid GFRP composites, which are made of glass fibre and the mixture of epoxy & polyester resin.

Resin hybrid GFRP laminates containing 0, 20 and 40wt% of polyester resin with the epoxy resin are prepared by conventional hand layup technique using glass fibre as the reinforcement. The variation of break load and shear strength for three different combinations of epoxy and polyester resin are studied by ASTM. A plan of experiment based on Taguchi was established with prefixed cutting parameters and the machining was performed. A stylus type profilometer to examine the surface roughness and shop microscope to examine the delamination of resin hybrid GFRP laminates were used. An analysis of variance (ANOVA) was performed to investigate the cutting characteristics of resin hybrid GFRP composite materials using solid carbide end mill. The correlation was obtained by multiple‐variable linear regression using Minitab 14 software.

Taguchi analysis reveals that the resin hybrid GFRP laminate provides better machinability in terms of surface roughness and delamination when compared to homogenous GFRP laminates (pure epoxy resin). Polyester resin enhances the machinability of the GFRP laminates.

The machinability of the resin hybrid GFRP laminates can be improved further by modifying the polyester resin percentage.

The resin hybrid GFRP laminates so developed can be used in aircraft and aerospace applications to increase the shear and work of fracture properties.

The aim of this paper is to synthesise polyester/silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico‐chemical and thermal properties of polyurethane/silica (PU/Silica) hybrid coatings.

Silica particle‐containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester/silica resin was further crosslinked with TMP‐TDI adduct to synthesise PU/Silica hybrid coatings and studied for thermo‐mechanical, physico‐chemical properties.

It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.

In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.

The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.

Hybrid organic‐inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi‐functional properties.

Corrosion is an important problem to be taken care in terms of economic and ecological aspects. The aim of this paper is to identify the methods of protection and selection of materials for corrosion protection.

A novel attempt has been made to formulate a hybrid composite paint system using silicone (S2) and polyester (P3) resins. These resins have been blended in different weight ratios to develop binder for protection coatings. Cross‐hatch test, impact resistance test, thermal characterization, impedance measurement and potential‐time measurement were conducted on binder coated steel panels. Heat resistance test was carried out using ASTM D2485 standards.

The results showed that physical and mechanical properties of the coatings have been improved by the addition of silicone into the polyester matrix. The binder system developed using 50 wt per cent polyester and 50 wt per cent silicone showed good physical, mechanical properties and high thermal resistance. The maximum coating resistance of the coatings after 30 days exposure was found to be 9.7×10⁶ Ω and the coating can withstand high temperature up to 473 K.

The development of different types of coatings will be useful to achieve higher protection performance. The combinations of different resins and pigments have to be analysed and selected suitable compositions.

The objective of this study is to develop coating system with different resins to achieve better performance and reduce the cost of paint materials. It may be useful for the industries to move forward with new formulation using multicomponent coating materials. A critical combination of the above resins offers better protection for steel structures from high temperature corrosive environments.

The formulation of coating material using two different resins and a single curing agent is a novel approach in this research. This type of research will open new ideas of formulating different coatings using various types of resins. In high temperature corrosion environment, the coatings which is commonly used is silicone based and the price of the raw material is very high therefore to reduce the cost of the raw material, the silicone resin is being blended in different ratios with organic resin to obtain an optimum ratio which can be applied to overcome high temperature corrosion on steel panels.

The key purpose of this study was to investigate the effects of different ultrasonic irradiation times on the wettability and other properties of the resulting water-based coating. The subject water-based coating was prepared using water-soluble polyester and amino resins by ultrasonic oscillation.

The coating was prepared by polymerising polyester and amino resins in water using ultrasonic oscillation. The coating was baked for 40 seconds at 350°C to coalesce and solidify the film. The contact angle, thermal stability and mechanical properties of the film, as well as the molecular weight (MW) and structure of the polyester resin, were determined.

The contact angle of the coating was found to decrease with ultrasonic irradiation; the mechanical properties and thermal stability were not altered when the irradiation time was longer than 5 hours. The MW of the polyester initially decreased then increased and stabilized with ultrasonic irradiation. The structure of polyester molecule and aggregated state of the solidified coating were not changed by ultrasonic irradiation.

In the study reported here, the effects of different ultrasonic irradiation times were investigated. Results of this research could benefit in-depth understanding of the influence of ultrasonic treatment on polyester resins and polyester coatings and could further promote the development of water-based coatings.

The contact angle of the water-based coating decreased by mechanical means. The effects of ultrasound on microstructure and properties of the coating and resin were discussed in detail.

The purpose of this paper is to study the electrochemical, mechanical and thermal characteristics of polyester – epoxy coating systems using electrochemical impedance spectroscopy (EIS), pull-off test and differential scanning calorimetry (DSC). These are very important properties to evaluate the performance of a coating system. Proper measurement and analysis techniques are needed for a proper evaluation of these properties to ensure the coating performance.

Different ratios of polyester and epoxy resins have been blended to formulate good anticorrosive, mechanically strong and thermally stable binder coating system. EIS, pull-off test and DSC were used to evaluate these properties.

The sample containing 90 wt.% polyester exhibited the best corrosion resistance from the beginning until the end of exposure time. The value of corrosion resistance (R_c) obtained on the 30th day of exposure was found to be 2.89 × 108 ohm cm⁻². The glass transition temperature (T_g) was found to be increasing with the incorporation of epoxy to the binder system. The result from pull-off test showed the best adhesion with the sample containing 90 wt.% polyester which also has the lowest T_g promoted better adhesion properties.

The curing time must be reduced for practical applications.

Hybrid coatings systems have been formulated. This paper discusses on the highest coating resistance obtained polymer-substrate mechanical properties and thermal characteristic of the polyester/epoxy binder resin using DSC.

Formability is an important property of automotive pre-coated metals (PCMs). The purpose of this study is to investigate the effect of long alkyl chains of polycarbonatediol to control the formability of polyester coatings.

Polyester resins with long alkyl chains were synthesized using different contents of polycarbonatediol. These resins were characterised by gel permeation chromatography (GPC), ¹H nuclear magnetic resonance (¹H NMR) and fourier transform infrared spectroscopy (FT-IR). The polyester coatings were characterised according to their viscoelastic behaviour, formability, flexibility and anti-corrosion property.

The tensile strength of PCM should be larger than 5.6 MPa of the compressive stress at a strain of 23.4 per cent to overcome the harsh condition of deep drawing. To analyse the formability, F_ε (forming coefficient based on strain) and F_U (forming coefficient based on strain energy) were calculated. When F_ε and F_U were larger than 1, the polyester coatings exhibited good formability.

Long alkyl chains of polycarbonatediol gave flexibility and good formability to the polyester coatings.

There are two conditions that lead to the good formability of PCM. One is tensile strength and the other is forming coefficients based on strain and strain energy.

Long alkyl chains of polyester were a major factor to improve flexibility and formability. Thus, to have good formability, the tensile strength of PCM should be larger than 5.6 MPa, and the forming coefficients should be larger than 1.

To study the effect of addition of free diols and triols in the coating formulation on coating properties.

Polyester resins were synthesised from maleic anhydride, dimerised fatty acid, neopentyl glycol and tris (2‐hydroxyethyl) isocyanurate (THEIC). Then, ethylene glycol, propylene glycol, glycerol, trimethylol propane and THEIC were added as reactive components to the coating formulation. These coatings were then analysed for various coating properties and compared with those obtained with the base resins.

The coatings obtained with the addition of these reactive components were found to have improved properties compared with those of the base resins except in cases where the reactive component itself contributed to a reduction in performance, e.g. reduced alkali resistance with the addition of THEIC.

The addition of the free diols and triols required a corresponding increase in the amount of the curing agent to be added.

This process would allow for the tailoring of coatings to suit requirements to a certain extent without modifying the base resin. The addition of low molecular weight components in the coating formulation, which is then incorporated in coatings, could reduce the solvent requirement.

Although polyesters are an established polymeric system in coatings, the use of reactive diluents has not been investigated with the exception of unsaturated polyesters, whose curing chemistry is fundamentally different from that of polyesters focused on in this paper.

The need for seeking alternate materials with increased performance in the field of composites revived this research, to prepare and evaluate the mechanical properties of e-glass and aloe vera fiber-reinforced with polyester and epoxy resin matrices.

The composites are prepared by hand layup method using E-glass and aloe vera fibers with length 5-6 mm. The resin used in the preparation of composites was epoxy and polyester. Fiber-reinforced composites were synthesized at 18:82 fiber–resin weight percentages. Samples prepared were tested to evaluate its mechanical and physical properties, such as tensile strength, flexural strength, impact strength, hardness and scanning electron microscope (SEM).

SEM analysis revealed the morphological features. E-glass fiber-reinforced epoxy composite exhibited better mechanical properties than other composite samples. The cross-linking density of monomers of the epoxy resin and addition of the short chopped E-glass fibers enhanced the properties of E-glass epoxy fiber-reinforced composite.

This research work enlists the properties of e-glass and aloe vera fiber-reinforced with polyester and epoxy resin matrices which has not been attempted so far.

The purpose of this paper is to prepare cheap and environmentally friendly water soluble polyester coatings through the glycolysis of poly(ethylene terephthalate) (PET) waste.

A secondary value-added polyester coatings were prepared from PET waste. The first step was the de-polymerisation of PET waste by 2,2-dimethyl-1,3-propanediol with different molar ratios in the presence of different concentrations of zinc acetate as trans-esterification catalyst. The de-polymerised product was characterised by Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance spectroscopy (¹HNMR), differential scanning calorimetry and hydroxyl values. The polyesters were successfully synthesised by esterification of the glycolysed product with adipic acid, isophthalic acid, 2,2-dimethyl-1,3-propanediol and trimellitic anhydride in different ratios. FTIR and ¹HNMR were used qualitatively and quantitatively to elucidate the structure of the prepared polyesters. Hydroxyl value and the physical properties of the prepared polyesters were also investigated. Two different curing agents were used to prepare the coatings based on the prepared polyesters.

Useful coating products were obtained by chemical (glycolysis) of post consumed PET wastes. The 2,2-dimethyl-1,3-propanediol was found to be good glycol in the glycolysis of PET. It was noticed that the rate of glycolysis increases with increasing the amount of catalyst, time of glycolysis and amount of 2,2-dimethyl-1,3-propanediol. N,N-Dimethylethanol amine was a good neutralising agent used for the preparation of water soluble coatings based on glycolysed product of PET.

The use of waste products like PET waste in water soluble coating systems will bring down the costs of the coatings and will also open a new market of recycled plastic materials and, hence, may provide a potential solution to the problems of solid waste management. It is an attractive option for environmentally friendly and efficient disposal of plastic waste.

The paper provides a potential way to use undesirable PET waste as industrial raw material. The coatings prepared are eco-friendly, soluble in water that can replace other expensive polyester coatings that are soluble in organic solvents and not environmentally coatings.

The purpose of this study is to prepare thermal transfer ribbons with good alcohol resistance.

A variety of alcohol-resistant thermal transfer inks were prepared using different polyester resins. The printing temperature, printing effect, adhesion and alcohol resistance of the inks on the label were studied to determine the feasibility of using the ink for manufacturing thermal transfer ribbons. The ink formulations were prepared by a simple and stable grinding technology, and then use mature coating technology to make the ink into a thermal transfer ribbon.

The results show that the thermal transfer ink has good scratch resistance, good alcohol resistance and low printing temperature when the three resins coexist. Notably, the performance of the ribbon produced by 500 mesh anilox roller was better than that of other meshes. Specifically, the ink on the matte silver polyethylene terephthalate (PET) label surface was wiped with a cotton cloth soaked in isopropyl alcohol under 500 g of pressure. After 50 wiping cycles, the ink remained intact.

The proposed method not only ensures good alcohol resistance but also has lower printing temperature and wider label applicability. Therefore, it can effectively reduce the loss of printhead and reduce production costs, because of the low printing temperature.